公开(公告)号：US5206203A

公开(公告)日：1993-04-27

申请号：US795491

申请日：1991-11-21

申请人： Michael Schneider ,  Gerd Maletz ,  Karl Kochloefl

发明人： Michael Schneider ,  Gerd Maletz ,  Karl Kochloefl

IPC分类号： B01J23/86 ,  C07B61/00 ,  C07C29/149 ,  C07C31/02 ,  C07C31/125

CPC分类号： B01J23/868 ,  C07C29/149

摘要： Acid-resistant copper oxide-chromium oxide catalysts for hydrogenation of fatty acids or fatty acid mixtures and/or the esters thereof are obtained through heat treatment of copper oxide and chromium oxide or of precursor compounds that are convertible into copper oxide or chromium oxide and which contain aluminum zirconium, cerium and/or lanthanum oxide as an additional metal component. The acid resistance is defined by the fact that the amount of copper which is dissolved by stirring 10 g of the catalyst for 2 minutes in 100 ml of 10 weight percent acetic acid at 20.degree. C., is a maximum of 200 mg.

摘要翻译： 通过热处理氧化铜和氧化铬或可转化为氧化铜或氧化铬的前体化合物，可获得用于脂肪酸或脂肪酸混合物和/或其酯氢化的耐酸氧化铜 - 氧化铬催化剂，其中 含有锆锆，铈和/或氧化镧作为附加金属组分。 耐酸性由以下事实定义：通过在20℃下在100ml 10重量％乙酸中搅拌10g催化剂2分钟而溶解的铜的量最多为200mg。

公开(公告)号：US4734391A

公开(公告)日：1988-03-29

申请号：US895559

申请日：1986-08-11

申请人： Michael Schneider ,  Hans J. Wernicke ,  Karl Kochloefl ,  Gerd Maletz

发明人： Michael Schneider ,  Hans J. Wernicke ,  Karl Kochloefl ,  Gerd Maletz

IPC分类号： B01D53/86 ,  B01J21/16 ,  B01J20/16

CPC分类号： B01J21/16 ,  B01D53/8628

摘要： A catalyst for decreasing the content of nitrogen oxides in flue gases. The catalyst contains at least one of the metals titanium, zirconium, vanadium, tungsten, molybdenum, or cerium in the form of one or more of their oxides combined with a silicate with a three-layer structure (three-layer silicate) selected from the group consisting of illite and mica. The atomic ratio of the silicon in the three-layer silicate to the metal in the oxide is from 0.2 and 50 and preferably from 0.4 to 25.

摘要翻译： 用于降低烟道气中氮氧化物含量的催化剂。 催化剂含有至少一种金属钛，锆，钒，钨，钼或铈，其中一种或多种氧化物与具有三层结构（三层硅酸盐）的硅酸盐形式组合，所述三层结构（三层硅酸盐）选自 由伊利石和云母组成的组。 三层硅酸盐中的硅与氧化物中的金属的原子比为0.2〜50，优选为0.4〜25。

公开(公告)号：US4105467A

公开(公告)日：1978-08-08

申请号：US729231

申请日：1976-10-04

申请人： Hans Buckl ,  Bernd Brenner ,  Wolfgang Eisenschmid

发明人： Hans Buckl ,  Bernd Brenner ,  Wolfgang Eisenschmid

IPC分类号： C07C29/132 ,  C07C27/00 ,  C07C29/141 ,  C07C31/18 ,  C07C67/00 ,  C08B37/14 ,  C13K13/00 ,  C07C29/00 ,  C13K1/02

CPC分类号： C13K13/002

摘要： An improvement in a process for the production of xylose or xylitol wherein a vegetable material is contacted with a basic substance and the solid residue is thereafter treated with an acid, the improvement resides in the use of stone nut shells, in employing a two-stage digestion initially with a 1.5-6 molar alkali metal hydroxide solution at 10.degree.-50.degree. C. and thereafter diluting the digestion mass to 0.75 molar or less and digesting at a temperature of at least 60.degree. C.

公开(公告)号：US4906602A

公开(公告)日：1990-03-06

申请号：US261674

申请日：1988-10-24

申请人： Michael Schneider ,  Karl Kochloefl ,  Jurgen Ladebeck ,  Gerd Maletz

发明人： Michael Schneider ,  Karl Kochloefl ,  Jurgen Ladebeck ,  Gerd Maletz

IPC分类号： B01J23/50 ,  B01J23/48 ,  B01J23/52 ,  B01J23/66 ,  B01J23/89 ,  B01J35/10 ,  C10G45/52

CPC分类号： B01J23/66 ,  B01J23/8926

摘要： A catalyst for the selective hydrogenation of polyunsaturated hydrocarbons which contain entirely or predominantly more than five carbon atoms, containing palladium with a promotor on a metal oxide support. The promotor is a metal from the subgroup IB of the periodic system (preferably silver) and the metal oxide support (TiO.sub.2 optionally mixed with CeO.sub.2 and/or ZrO.sub.2) is macroporous, the pore volume being about 0.2 to 0.4, preferably about 0.25 to 0.30 ml per g of carrier and the proportion of the macropores having a diameter of more than 14 nm being at least 65%.

摘要翻译： 用于选择氢化多不饱和烃的催化剂，其含有完全或主要多于五个碳原子，在金属氧化物载体上含有启动子的钯。 促进剂是来自周期系统（优选为银）的亚组IB的金属，并且金属氧化物载体（任选与CeO 2和/或ZrO 2混合的TiO 2）是大孔的，孔体积为约0.2至0.4，优选约0.25至0.30 ml，并且直径大于14nm的大孔的比例为至少65％。

公开(公告)号：US4720476A

公开(公告)日：1988-01-19

申请号：US895405

申请日：1986-08-11

申请人： Michael Schneider ,  Hans J. Wernicke ,  Karl Kochloefl ,  Gerd Maletz

发明人： Michael Schneider ,  Hans J. Wernicke ,  Karl Kochloefl ,  Gerd Maletz

IPC分类号： B01J21/16 ,  B01D53/56 ,  B01D53/86 ,  B01D53/94 ,  B01J8/00 ,  B01J20/12 ,  B01J21/12 ,  B01J23/10 ,  B01J23/16 ,  B01J23/22 ,  B01J23/24 ,  B01J37/00 ,  C01B21/20

CPC分类号： B01J21/16 ,  B01D53/8628 ,  B01J23/22 ,  B01J23/28 ,  B01J23/30 ,  B01J35/1066

摘要： A catalyst for decreasing the content of nitrogen oxides in flue gases. The catalyst contains at least one of the metals titanium, zirconium, vanadium, tungsten, molybdenum, or cerium in the form of one or more of their oxides combined with a silicate with a three-layer structure (three-layer silicate) comprising acid-activated pyrophyllite. The crystalline layer structure of the acid-activated pyrophyllite is essentially retained, while being not yet X-ray amorphous. The acid activation increases the BET surface area at least 15% and preferably at least 50% in terms of the BET surface area of the pyrophyllite before acid activation. The atomic ratio of the silicon in the acid-activated pyrophyllite to the metal in the oxide is from 0.2 and 50 and preferably from 0.4 to 25.

摘要翻译： 用于降低烟道气中氮氧化物含量的催化剂。 催化剂含有至少一种金属钛，锆，钒，钨，钼或铈中的一种或多种氧化物与具有三层结构（三层硅酸盐）的硅酸盐形式， 活性叶蜡石。 酸活化的叶蜡石的结晶层结构基本上保持不变，而尚未成为X射线无定形。 在酸活化之前，酸活化使得BET表面积在叶蜡石的BET表面积方面增加至少15％，优选至少50％。 酸活化的叶蜡石中的硅与氧化物中的金属的原子比为0.2〜50，优选为0.4〜25。

公开(公告)号：US4613714A

公开(公告)日：1986-09-23

申请号：US785472

申请日：1985-10-08

申请人： Karl-Heinz Stadler ,  Karel Kochloefl

发明人： Karl-Heinz Stadler ,  Karel Kochloefl

IPC分类号： C07C5/05 ,  B01J23/12 ,  B01J23/16 ,  B01J23/18 ,  B01J23/40 ,  B01J23/44 ,  B01J23/56 ,  B01J23/58 ,  B01J23/63 ,  B01J23/648 ,  B01J23/652 ,  C07C1/00 ,  C07C5/02 ,  C07C5/03 ,  C07C11/02 ,  C07C67/00

CPC分类号： C07C5/02 ,  B01J23/40 ,  B01J23/56 ,  B01J23/58 ,  C07C5/03 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/02 ,  C07C2523/12 ,  C07C2523/20 ,  C07C2523/22 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/40 ,  C07C2523/44

摘要： Catalyst for the selective hydrogenation of multi-unsaturated organic compounds, in particular of diolefins and dienes in mixtures with other hydrocarbons; the catalyst is characterized by(A) a metal component from one or more elements of Group VIII of the Periodic Table on(B) a support material on the basis(b.sub.1) of one or more n-semiconducting oxides of one or more elements from the Subgroups IVb, Vb and VIb of the Periodic Table or of thorium or cerium, or respectively on the basis(b.sub.2) of one or more n-semiconducting mixed oxide systems of the formula Me.sub.2 Me.sub.1 (0).sub.x, where Me.sub.1 is an element of the group defined in (b.sub.1), Me.sub.2 an alkaline earth metal or an element different from Me.sub.1 or the group defined in (b.sub.1), and x signifies the number of oxygen atoms required for the saturation of Me.sub.1 and Me.sub.2 to the range of an n-semiconducting state;the hydrogen chemisorption capacity, expressed as the atomic ratio between chemisorbed hydrogen atoms and metal atoms of the metal component (A) present on the surface of the metal particles, (H/Me.sub.A), being at least 0.6:1.

摘要翻译： 用于多不饱和有机化合物，特别是与其它烃混合的二烯烃和二烯烃的选择性氢化的催化剂; 催化剂的特征在于（A）在（B）上周期表第Ⅷ族的一种或多种元素的金属组分，基于（b1）的一种或多种一种或多种元素的n-半导体氧化物的载体材料， 周期表的子组IVb，Vb和VIb，或钍或铈的分组IVb，或分别基于式（b2）的一种或多种式Me2Me1（0）x的n-半导体混合氧化物体系，其中Me1是 （b1）中定义的基团，Me2是碱土金属或不同于Me1的元素或（b1）中定义的基团，x表示Me1和Me2饱和所需的氧原子数在n的范围内 半导体状态; 以化学吸附氢原子和存在于金属颗粒表面上的金属组分（A）的金属原子之间的原子比（H / MeA）表示的氢化学吸附能力为至少0.6:1。

公开(公告)号：US4585632A

公开(公告)日：1986-04-29

申请号：US682094

申请日：1984-12-14

申请人： Michael Schneider ,  Karel Kochloefl

发明人： Michael Schneider ,  Karel Kochloefl

IPC分类号： B01D53/86 ,  B01D53/94 ,  B01J23/40 ,  B01J23/63 ,  B01J37/02 ,  B01J8/00 ,  C01B21/00

CPC分类号： B01J37/024 ,  B01D53/8625 ,  B01D53/9418 ,  B01J23/40 ,  B01J23/63 ,  B01D2251/21 ,  B01D2255/102 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/20761

摘要： Process for the removal of nitrogen oxides from exhaust gases, in particular from exhaust gases containing sulfur oxides, by catalytic reduction. As a reduction agent a gas mixture obtained by catalytic conversion of methanol either by catalytic dissociation or by steam reforming is mixed with the exhaust gases and passed over a catalyst, wherein the nitrogen oxides are reduced to nitrogen. According to the first variant, one operates with conventional catalysts above 300.degree. C., according to the second variant, with new catalysts below 300.degree. C.

摘要翻译： 通过催化还原从废气中除去氮氧化物的方法，特别是从含有硫氧化物的废气中除去氮氧化物。 作为还原剂，通过催化离解或通过蒸汽重整将甲醇催化转化获得的气体混合物与废气混合并通过催化剂，其中氮氧化物被还原成氮气。 根据第一个变体，根据第二个变体，一个使用高于300℃的常规催化剂，新催化剂低于300℃。

公开(公告)号：US4253991A

公开(公告)日：1981-03-03

申请号：US28428

申请日：1979-04-09

申请人： Karl-Heinz Kanzler, deceased ,  Karl Kochloefl

发明人： Karl-Heinz Kanzler, deceased ,  Karl Kochloefl

IPC分类号： C07C1/04 ,  B01J23/755 ,  B01J23/78 ,  B01J23/85 ,  B01J37/00 ,  C07C1/00 ,  C07C9/04 ,  C07C67/00 ,  C10K3/02 ,  C10L3/08 ,  B01J21/08 ,  B01J21/12

CPC分类号： B01J23/755 ,  B01J37/0009 ,  C10L3/08 ,  B01J37/0036 ,  Y10S502/504

摘要： A fluidized-bed catalyst for the production of synthetic natural gas by the methanization of carbon monoxide which catalyst in the unreduced state contains nickel oxide on a carrier material resistant to temperature changes, and a hydraulic cement, said catalyst obtainable by compressing a composition comprising a carrier material and nickel oxide in admixture with hydraulic cement as binder in the wetted condition at a pressure above 1600 kp/cm.sup.2 into a formed body, calcining the so-compressed formed body, curing the so-calcined formed body by treatment with water or steam, recalcining the so-cured formed body and comminuting the same and recovering a comminuted material having a particle size fraction ranging from 40 to 350.mu.. Also disclosed is a process for production of synthetic natural gas by fluidized-bed methanization of carbon monoxide with hydrogen employing such a catalyst.

摘要翻译： 一种用于通过一氧化碳甲烷化生产合成天然气的流化床催化剂，其中未还原状态的催化剂在耐温度变化的载体材料上含有氧化镍，以及水硬性水泥，所述催化剂可通过将包含 载体材料和氧化镍与水硬性水泥作为粘合剂在湿度条件下在1600kp / cm2以上的压力下进入成型体，煅烧如此压缩的成形体，通过用水或蒸汽处理固化如此煅烧的成形体 重新煅烧固化的成形体并粉碎，并回收粒度分数为40至350μm的粉碎材料。 还公开了通过使用这种催化剂的氢气通过一氧化碳与氢气的流化床甲烷化生产合成天然气的方法。

公开(公告)号：US5217937A

公开(公告)日：1993-06-08

申请号：US795493

申请日：1991-11-21

申请人： Michael Schneider ,  Gerd Maletz ,  Karl Kochloefl

发明人： Michael Schneider ,  Gerd Maletz ,  Karl Kochloefl

IPC分类号： B01J23/86 ,  C07B61/00 ,  C07C29/149 ,  C07C31/125

CPC分类号： B01J23/868 ,  C07C29/149 ,  Y10S502/524

摘要： An SiO.sub.2 -containing copper oxide-chromium oxide catalyst is obtained through heat treatment of copper oxide and chromium oxide, or of a precursor compound convertible into copper oxide or chromium oxide in the presence of an SiO.sub.2 component; it is characterized by the fact that, after the heat treatment,(a) the intensity ratio between the X-ray diffraction lines (XRD reflexes) of the copper oxide with d=0.232 nm and of the CuCr.sub.2 O.sub.4 spinel with d=0.240 nm formed through heat treatment, determined as the ratio of the reflex amplitudes, is 0.7 to 4.0:1, and(b) the copper mass, which is dissolved by stirring 10 g of the catalyst in 100 ml of 10 weight percent acetic acid at 20.degree. C. for 2 minutes, amounts to a maximum of 200 mg.

摘要翻译： 通过氧化铜和氧化铬的热处理，或在SiO2组分存在下可转化为氧化铜或氧化铬的前体化合物，得到含SiO 2的氧化铜 - 氧化铬催化剂; 其特征在于，在热处理后，（a）形成d = 0.232nm的氧化铜的X射线衍射线（XRD反射）与d = 0.240nm的CuCr 2 O 4尖晶石之间的强度比 通过作为反射幅度的比率确定的热处理为0.7〜4.0:1，（b）通过在10g 20重量％乙酸中在20℃下搅拌10g催化剂而溶解的铜质量 2分钟，最多达200毫克。

公开(公告)号：US4722918A

公开(公告)日：1988-02-02

申请号：US895406

申请日：1986-08-11

申请人： Michael Schneider ,  Hans J. Wernicke ,  Karl Kochloefl ,  Gerd Maletz

发明人： Michael Schneider ,  Hans J. Wernicke ,  Karl Kochloefl ,  Gerd Maletz

IPC分类号： B01J21/16 ,  B01D53/56 ,  B01D53/86 ,  B01D53/94 ,  B01J8/00 ,  B01J20/12 ,  B01J21/12 ,  B01J23/10 ,  B01J23/16 ,  B01J23/22 ,  B01J23/24 ,  B01J37/00 ,  C01B21/20

CPC分类号： B01J21/16 ,  B01D53/8628 ,  B01J23/22 ,  B01J23/28 ,  B01J23/30 ,  B01J35/1066

摘要： A catalyst for decreasing the content of nitrogen oxides in flue gases. The catalyst contains at least one of the metals titanium, zirconium, vanadium, tungsten, molybdenum, or cerium in the form of one or more of their oxides combined with a silicate with a three-layer structure (three-layer silicate). The three-layer silicate is acid-activated while essentially retaining its crystalline layer structure. The three-layer silicate has a cation-exchange capacity of 30 mvals/100 g or more before acid activation. The acid activation lowers the concentration of interlayer cations and increases the BET surface at least 15% and preferably at least 50% in terms of the BET surface of the three-layer silicate before acid activation. The atomic ratio of the silicon in the acid-activated three-layer silicate to the metal in the oxide is from 0.2 and 50 and preferably from 0.4 to 25.

摘要翻译： 用于降低烟道气中氮氧化物含量的催化剂。 该催化剂含有一种或多种氧化物与具有三层结构的硅酸盐（三层硅酸盐）结合的钛，锆，钒，钨，钼或铈中的至少一种。 三层硅酸盐是酸活化的，同时基本保持其结晶层结构。 三层硅酸盐在酸活化之前的阳离子交换容量为30mΩ/ 100g以上。 酸活化降低了层间阳离子的浓度，并且在酸活化之前，三层硅酸盐的BET表面以BET表示增加至少15％，优选至少为50％。 酸活化三层硅酸盐中的硅与氧化物中的金属的原子比为0.2〜50，优选为0.4〜25。