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    Annealed and promoted catalyst
    1.
    发明申请
    Annealed and promoted catalyst 失效
    退火和促进催化剂

    公开(公告)号：US20040029725A1

    公开(公告)日：2004-02-12

    申请号：US10636113

    申请日：2003-08-07

    Inventor： Anne Mae Gaffney ,  Michele Doreen Heffner ,  Ruozhi Song

    IPC: B01J027/14 ,  B01J027/186 ,  B01J027/187 ,  B01J027/199 ,  B01J027/198 ,  B01J027/188 ,  B01J027/19 ,  B01J027/192 ,  B01J023/00

    CPC classification number: C07C51/252 ,  B01J23/002 ,  B01J23/10 ,  B01J23/22 ,  B01J23/28 ,  B01J27/0576 ,  B01J2523/00 ,  C07C51/215 ,  C07C253/24 ,  C07C253/26 ,  Y02P20/52 ,  C07C57/04 ,  B01J2523/3737 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68 ,  C07C255/08

    Abstract: A mixed metal oxide, which may be an orthorhombic phase material, is improved as a catalyst for the production of unsaturated carboxylic acids, or unsaturated nitrites, from alkanes, or mixtures of alkanes and alkenes, by: contacting with a liquid contact member selected from the group consisting of organic acids, alcohols, inorganic acids and hydrogen peroxide to form a contact mixture; recovering insoluble material from the contact mixture; calcining the recovered insoluble material in a non-oxidizing atmosphere; admixing the calcined recovered insoluble material with (i) at least one promoter element or compound thereof and (ii) at least one solvent for the at least one promoter element or compound thereof; removing the at least one solvent to form a catalyst precursor; and calcining the catalyst precursor.

    Abstract translation: 可以是斜方相材料的混合金属氧化物作为用于从烷烃或烷烃和烯烃的混合物生产不饱和羧酸或不饱和亚硝酸盐的催化剂，通过以下方式改进：与选自 由有机酸，醇，无机酸和过氧化氢组成的组合形成接触混合物; 从接触混合物中回收不溶物质; 在非氧化性气氛中煅烧回收的不溶物; 将煅烧回收的不溶物与（i）至少一种助催化剂元件或其化合物和（ii）至少一种用于至少一种助催化剂元件或其化合物的溶剂混合; 除去所述至少一种溶剂以形成催化剂前体; 并煅烧催化剂前体。

    Catalyst Support
    3.
    发明申请
    Catalyst Support 有权
    催化剂支持

    公开(公告)号：US20040063575A1

    公开(公告)日：2004-04-01

    申请号：US10670222

    申请日：2003-09-26

    Applicant: Degussa AG

    Inventor： Hemanus Gerhardus Jozef Lansink Rotgerink ,  Heike Reidemann ,  Helmfried Krause

    IPC: B01J021/08 ,  B01J021/12 ,  B01J027/199 ,  B01J027/187 ,  B01J027/14 ,  B01J027/186 ,  B01J027/188 ,  B01J021/14

    CPC classification number: B01J21/066 ,  B01J21/063 ,  B01J21/08 ,  B01J27/16 ,  B01J37/0009 ,  B01J37/0018

    Abstract: A catalyst support consisting mainly of synthetic silica, with 0.5-10 parts by weight of one or more oxides or phosphates of the elements of group IIA, IIIB, IVB, VB, VIIB, VIIB, VIII, IB, IIB, IIIA, IVA and the lanthanides characterised in that the support preparation method comprises mixing particulate synthetic silica with particulate oxides or phospates of the elements of Groups IIA, IIIB, IVB, VB, VIIB, VIIB, VIII, IB, IIB, IIIA, IVA and the lanthanides, or with precursors thereof, a forming step and calcination. The catalyst support is used together with phosphoric acid in the production of alcohols from olefins by hydration.

    Abstract translation: 主要由合成二氧化硅组成的催化剂载体，其具有0.5-10重量份的IIA，IIIB，IVB，VB，VIIB，VIIB，VIII，IB，IIB，VIIA，IVA族元素的一种或多种氧化物或磷酸盐，以及 镧系元素的特征在于载体制备方法包括将颗粒状合成二氧化硅与IIA，IIIB，IVB，VB，VIIB，VIIB，VIII，IB，IIB，VIIA，IVA族和镧系元素的元素的颗粒氧化物或磷酸盐混合，或 其前体，成型步骤和煅烧。 催化剂载体与磷酸一起用于通过水合由烯烃生产醇。

    Method for producing hydro-refining catalyst
    7.
    发明申请
    Method for producing hydro-refining catalyst 有权
    生产加氢精制催化剂的方法

    公开(公告)号：US20040186013A1

    公开(公告)日：2004-09-23

    申请号：US10482041

    申请日：2003-12-29

    Inventor： Yoshiki Iwata ,  Chikanori Nakaoka ,  Yasuhito Goto

    IPC: B01J027/14 ,  B01J027/186 ,  B01J027/187 ,  B01J027/19

    CPC classification number: B01J35/002 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J27/19 ,  B01J35/1019 ,  B01J35/1061 ,  B01J37/0203 ,  C10G45/08

    Abstract: A method for producing a hydrorefining catalyst has the steps of preparing an impregnation solution containing molybdenum, phosphorus, cobalt and/or nickel, and citric acid, bringing a carrier into contact with the impregnation solution, and then calcinating the carrier in an oxidizing atmosphere at a temperature at which citric acid is removed. In the impregnation solution, a molar ratio of molybdenum/phosphorus is 6 to 13, a molar ratio of (cobalt and nickel)/phosphorus is 0.5 to 7, and a molar ratio of (cobalt and nickel)/citric acid is 0.5 to 2. As for the hydrorefining catalyst obtained by this method, the activity of the catalyst is high, and the catalyst life is long.

    Abstract translation: 一种加氢精制催化剂的制造方法，其特征在于，制备含有钼，磷，钴和/或镍的浸渍溶液和柠檬酸，使载体与浸渍溶液接触，然后在氧化气氛中煅烧载体 去除柠檬酸的温度。 在浸渍溶液中，钼/磷的摩尔比为6〜13，（钴和镍）/磷的摩尔比为0.5〜7，（钴和镍）/柠檬酸的摩尔比为0.5〜2 对于通过该方法获得的加氢精制催化剂，催化剂的活性高，催化剂寿命长。

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