公开(公告)号：US11338271B2

公开(公告)日：2022-05-24

申请号：US16965121

申请日：2019-01-24

申请人： Dexerials Corporation

发明人： Katsuya Tanba ,  Yoshiharu Okuda ,  Teiko Kuroda

IPC分类号： B01J21/18 ,  B01J23/44 ,  B01J35/00 ,  B01J35/10 ,  B01J37/08 ,  C07C35/08 ,  C07C37/01

摘要： A porous carbon material including a porous carbon material having a specific resistance value of 30 Ωcm or less at a packing density of 0.3 g/cc, wherein a mesopore volume (cm3/g) of the porous carbon material as measured by the BJH method is 0.5 cm3/g or greater.

公开(公告)号：US20090192337A1

公开(公告)日：2009-07-30

申请号：US12261351

申请日：2008-10-30

申请人： Suman Lata JAIN ,  Jomy K. JOSEPH ,  Sweety SINGHAL ,  Bir SAIN ,  Ragunathan SIVAKUMARAN ,  Basant KUMAR

发明人： Suman Lata JAIN ,  Jomy K. JOSEPH ,  Sweety SINGHAL ,  Bir SAIN ,  Ragunathan SIVAKUMARAN ,  Basant KUMAR

IPC分类号： C07C37/01

CPC分类号： C07C29/48 ,  C07C41/26 ,  C07C43/23

摘要： The present invention provides a process for direct hydroxylation of aromatic hydrocarbons like benzene to phenol, toluene to cresols and anisole to methoxy phenols by using hydrogen peroxide as environmentally benign oxidant in polar solvent like acetonitrile using vanadium phthalocyanine or its derivative as a catalyst, at a temperature in the range of 25-100° C.

摘要翻译： 本发明提供了一种通过在极性溶剂如乙腈中使用过氧化氢作为环境友好的氧化剂，使用钒酞菁或其衍生物作为催化剂，将芳香烃如苯，苯酚，甲苯至甲酚和苯甲醚直接羟基化为甲氧基酚的方法， 温度范围在25-100℃

公开(公告)号：US5741821A

公开(公告)日：1998-04-21

申请号：US553714

申请日：1995-11-30

申请人： Basil Don Roufogalis ,  Colin Charles Duke ,  Qian Li

发明人： Basil Don Roufogalis ,  Colin Charles Duke ,  Qian Li

IPC分类号： C07D311/18 ,  A61K31/047 ,  A61K31/05 ,  A61K31/055 ,  A61K31/065 ,  A61K31/11 ,  A61K31/12 ,  A61K31/215 ,  A61K31/235 ,  A61K31/35 ,  A61K31/352 ,  A61K31/365 ,  A61K31/37 ,  A61P9/00 ,  A61P9/04 ,  A61P43/00 ,  B01J27/10 ,  C07B61/00 ,  C07C37/01 ,  C07C37/14 ,  C07C39/14 ,  C07C39/15 ,  C07C39/16 ,  C07C39/19 ,  C07C39/21 ,  C07C39/23 ,  C07C205/22 ,  C07C205/26 ,  C07D311/16 ,  C07D311/32 ,  C07C39/04

CPC分类号： C07C39/16 ,  A61K31/05 ,  A61K31/235 ,  A61K31/35 ,  A61K31/365 ,  A61K31/37 ,  C07C39/14 ,  C07D311/16

摘要： Use of a compound of formula (I), wherein Ar is an aromatic ring system comprising one or more optionally substituted phenyl rings optionally linked to or fused with one or more other optionally substituted phenyl rings or one or more 5 or 6-membered, optionally substituted heterocyclic rings wherein the heteroatom is oxygen; and wherein the ring system comprises 1-4 phenyl rings and wherein Ar can be linked to another Ar via a group X wherein the Ar is independently selected; where X is optionally substituted C.sub.1-20 alkylene, C.sub.2-20 alkenylene or C.sub.2-20 alkynylene; R is hydrogen; C.sub.1-20 alkenyl, C.sub.2-20 alkynyl, C.sub.2-20 alkanoyl, C.sub.2-20 alkynoyl, each of which can be optionally substituted; R.sub.1 is independently selected and is hydrogen; optionally substituted C.sub.1-12 alkyl, C.sub.2-12 alkenyl, C.sub.2-20 alkynyl; --COOR'--NR'R', halogen, --OR', --COR', --CONR'R', .dbd.O, --SR', --SO.sub.3 R', --SO.sub.2 NR'R', --SOR', --SO.sub.2 R', --NO.sub.2, --CN, glycoside, silyl; where R' is independently hydrogen; alkyl, alkenyl or alkynyl each optionally substituted; and where two groups R.sub.1 can be joined; wherein the optional substituents are one or more independently selected from C.sub.1-10 alkyl, C.sub.2-10 alkenyl, C.sub.2-10 alkynyl; --COOR"--NR"R", halogen, OR", --COR", --CONR"R", --SR", .dbd.O, --SO.sub.3 R", --SO.sub.2 NR"R", --SOR", --S.sub.2 ", --NO.sub.2, --CN: wherein R" is independently hydrogen, alkyl, alkenyl, or alkynyl; n=1, 2 or 3; m=1, 2, 3 or 4; or a pharmaceutically acceptable derivative thereof in the manufacture of a medicament for inhibiting the action of Ca.sup.2+ -ATPase enzymes. Certain compounds of formula (I) and 8-lavandulyl flavone pharmaceutical formulations are new. ##STR1##

公开(公告)号：US5739076A

公开(公告)日：1998-04-14

申请号：US374588

申请日：1995-04-19

申请人： Diane Renata Cornelia Huybrechts ,  Philip Luc Buskens ,  Georges Marie Karel Mathys ,  Luc Roger Marc Martens

发明人： Diane Renata Cornelia Huybrechts ,  Philip Luc Buskens ,  Georges Marie Karel Mathys ,  Luc Roger Marc Martens

IPC分类号： B01J29/70 ,  B01J29/74 ,  B01J29/89 ,  B01J31/02 ,  C01B37/00 ,  C01B39/04 ,  C01B39/06 ,  C01B39/48 ,  C07B41/00 ,  C07B61/00 ,  C07C37/01 ,  C07C51/285 ,  C07C51/31 ,  C07C55/14 ,  C07D301/19 ,  C07C55/00 ,  B01J23/00

CPC分类号： C07D301/19 ,  B01J29/7007 ,  B01J29/7415 ,  B01J29/89 ,  C01B37/005 ,  C01B39/04 ,  C01B39/065 ,  C01B39/48 ,  C07B41/00 ,  C07C37/50 ,  C07C37/60 ,  C07C51/285 ,  C07C51/313 ,  B01J2229/36 ,  Y02P20/52

摘要： New titanium zeolite Beta catalysts which have been found to be useful as catalysts for the oxidation of organic compounds using organic hydroperoxides as oxidation catalysts. They are particularly useful as ring opening oxidation catalysts and may be used to produce adipic acid from cyclohexane.

摘要翻译： PCT No.PCT / EP93 / 01972 Sec。 371日期1995年04月19日 102（e）1995年4月19日PCT PCT 1993年7月23日PCT公布。 出版物WO94 / 02245 日期1994年2月3日新的钛沸石β-催化剂已被发现可用作有机氢过氧化物作为氧化催化剂氧化有机化合物的催化剂。 它们特别用作开环氧化催化剂，并且可用于从环己烷产生己二酸。

公开(公告)号：US5543564A

公开(公告)日：1996-08-06

申请号：US371153

申请日：1995-01-11

申请人： J urgen Kulpe ,  Heinz Strutz ,  Hans-Martin R uffer ,  Siegbert Rittner

发明人： J urgen Kulpe ,  Heinz Strutz ,  Hans-Martin R uffer ,  Siegbert Rittner

IPC分类号： C07B63/00 ,  C07C37/00 ,  C07C37/01 ,  C07C39/14 ,  C07C51/00 ,  C07C51/02 ,  C07C63/36 ,  C07C63/38 ,  C07C65/11 ,  C07C303/22 ,  C07C303/44 ,  C07C309/35 ,  C07C311/19 ,  C08G63/06 ,  C08G63/78 ,  C07C27/34 ,  C07C29/74

CPC分类号： C07C303/40 ,  C07C303/22 ,  C07C303/44 ,  C07C37/72 ,  C07C37/86 ,  C07C51/02 ,  C08G63/06

摘要： This invention embodies a process for releasing acidic organic compounds in high yield and good purity from aqueous solutions of their salts which comprises converting the salts by carbon dioxide to their corresponding free acidic organic compounds and metal hydrogen carbonates, removing the acidic organic compounds from the mixture by extraction with an essentially water-insoluble organic solvent, and re-extracting the organic phase with carbon dioxide containing water. Using this process, the acidic organic compounds are completely released from their corresponding salts, i.e., the organic solution is free of salt. The acidic organic compounds released by the claimed process are organic compounds which contain acidic protons which can be replaced by metals. Some examples are carboxylic acids, sulfonic acids, phosphonic acids, phenols, naphthols, and aliphatic alcohols.

摘要翻译： 本发明体现了一种从其盐的水溶液中以高产率和高纯度释放酸性有机化合物的方法，其包括将二氧化碳转化成其相应的游离酸性有机化合物和金属碳酸氢盐，从混合物中除去酸性有机化合物 通过用基本上不溶于水的有机溶剂萃取，并用含二氧化碳的水重新萃取有机相。 使用该方法，酸性有机化合物从其相应的盐完全释放，即有机溶液不含盐。 通过要求保护的方法释放的酸性有机化合物是含有可被金属取代的酸性质子的有机化合物。 一些实例是羧酸，磺酸，膦酸，酚，萘酚和脂族醇。

公开(公告)号：US5003115A

公开(公告)日：1991-03-26

申请号：US500636

申请日：1990-03-28

申请人： Heinz Strutz

发明人： Heinz Strutz

IPC分类号： B01J23/40 ,  B01J23/86 ,  B01J25/02 ,  C07B61/00 ,  C07C37/00 ,  C07C37/01 ,  C07C37/055 ,  C07C39/11 ,  C07D303/16

CPC分类号： C07C67/29 ,  C07C37/0555 ,  C07D303/16

摘要： A method for producing 4-hydroxyphenethyl alcohol by epoxidizing 4-acetoxystyrene with a percaboxylic acid to produce 4-acetoxyphenyl oxirane; and catalytically hydrogenating the 4-acetoxyphenyl oxirane with hydrogen to produce 4-acetoxyphenethyl alcohol; and saponifying or transesterifying the 4-acetoxyphenethyl alcohol to produce 4-hydroxyphenethyl alcohol.

公开(公告)号：US4595489A

公开(公告)日：1986-06-17

申请号：US757908

申请日：1985-07-22

申请人： Charles G. Scouten

发明人： Charles G. Scouten

IPC分类号： C07C37/01 ,  C07C37/66 ,  C07C39/04 ,  C10G17/00

CPC分类号： C07C37/66 ,  C07C37/055

摘要： Disclosed is a process for recovering phenols from phenol-containing streams having at least a sufficient amount of water. The stream is contacted with a metal composition comprised of one or more oxides and/or hydroxides of metals capable of forming a metal phenate with the phenols of the stream. The resulting metal phenates are separated from the stream and are treated with steam at a temperature from about 250.degree. C. to about 450.degree. C., thereby producing phenols, and hydroxides of the metals of the phenate.

摘要翻译： 公开了一种从具有至少足够量的水的含苯酚流中回收酚的方法。 将该物流与金属组合物接触，所述金属组合物由一种或多种能够与所述物流的酚形成金属酚盐的金属的氧化物和/或氢氧化物组成。 将得到的金属酚盐与物流分离，并在约250℃至约450℃的温度下用蒸汽处理，从而产生酚类和酚盐金属的氢氧化物。

公开(公告)号：US4383127A

公开(公告)日：1983-05-10

申请号：US283148

申请日：1981-07-14

申请人： Paul C. van Geem ,  Antonius J. J. M. Teunissen

发明人： Paul C. van Geem ,  Antonius J. J. M. Teunissen

IPC分类号： B01J23/847 ,  B01J23/89 ,  C07C37/56 ,  C07C37/01

CPC分类号： B01J23/8472 ,  B01J23/8946 ,  C07C37/56 ,  Y02P20/52

摘要： The invention relates to a method for the preparation of a substituted or unsubstituted phenol by oxidation of the corresponding substituted or unsubstituted benzoic acid in the gas phase in the presence of a copper and vanadium and/or silver and lithium and/or sodium and/or magnesium containing catalyst and catalysts therefor. The invention particularly relates to the gas phase oxidation of unsubstituted benzoic acid to unsubstituted phenol.

摘要翻译： 本发明涉及通过在铜和钒和/或银和/或锂和/或钠和/或钠和/或钠和/或钠的存在下，在气相中氧化相应的取代或未取代的苯甲酸来制备取代或未取代的苯酚的方法和/或 含镁催化剂及其催化剂。 本发明特别涉及未取代苯甲酸与未取代苯酚的气相氧化。

公开(公告)号：US20180179564A1

公开(公告)日：2018-06-28

申请号：US15881197

申请日：2018-01-26

申请人： Teewinot Technologies Limited

发明人： Robert Winnicki ,  Marc Donsky ,  Mingyang Sun ,  Richard Peet

IPC分类号： C12P17/06 ,  C12M1/34 ,  C12M1/36 ,  C12P7/22 ,  C12P7/42 ,  C12N9/02 ,  C07C37/74 ,  C07C37/01 ,  C07C29/80 ,  C12M1/00 ,  C12M1/40

CPC分类号： C12P17/06 ,  C07C29/80 ,  C07C37/01 ,  C07C37/74 ,  C12M21/18 ,  C12M29/00 ,  C12M29/04 ,  C12M41/12 ,  C12M41/26 ,  C12M41/30 ,  C12M41/32 ,  C12M41/40 ,  C12M41/48 ,  C12M47/10 ,  C12N9/0004 ,  C12P7/22 ,  C12P7/42 ,  C12Y121/03 ,  C12Y121/03007 ,  C12Y121/03008

摘要： The present invention provides an apparatus and methods for producing tetrahydrocannabinolic acid (THCA), cannabichromenic acid (CBCA) and cannabichromenic acid (CBCA) in different ratios. The apparatus comprises: (i) a bioreactor comprising (a) an automated supply system configured to deliver a first automated supply of cannabigerolic acid (CBGA), a cannabinoid acid synthase, and a reaction mixture; and (b) a second automated system to cease the reaction; (ii) a controller configured to modify a property of the reaction mixture to produce the desired products; and (iii) an extractor configured to recover the tetrahydrocannabinolic acid (THCA), cannabichromenic acid (CBCA) or cannabidiolic acid (CBDA) and cannabichromenic acid.

公开(公告)号：US09988333B2

公开(公告)日：2018-06-05

申请号：US15311951

申请日：2015-05-18

申请人： BASF SE

发明人： Andreas Pletsch ,  Nicole Holub ,  Thomas Ulrich ,  Petr Kvita ,  Laurent Cavin

IPC分类号： C07C37/01 ,  C07C51/353 ,  C07C37/045 ,  C07C37/76 ,  C07C241/02 ,  C07C209/36 ,  C07C201/08 ,  C07C51/00 ,  C07C67/00

CPC分类号： C07C51/353 ,  C07C37/045 ,  C07C37/76 ,  C07C51/00 ,  C07C51/15 ,  C07C51/367 ,  C07C67/00 ,  C07C201/08 ,  C07C209/365 ,  C07C241/02 ,  C07C39/30 ,  C07C65/05 ,  C07C65/21

摘要： The present invention relates to a process for reacting chemical compounds comprising the step of reacting a compound of formula (IV) wherein Hal is independently selected from Cl or Br, and X− is a monovalent anion, in the presence of an inorganic acid, wherein the aqueous inorganic acid has a concentration of at least about 60%, at a temperature of about 140° C. to about 250° C., to obtain a compound of formula (V) wherein Hal is as defined above.