公开(公告)号：US20240301294A1

公开(公告)日：2024-09-12

申请号：US18662222

申请日：2024-05-13

申请人： Duke Technologies, LLC

发明人： Michael D. Ackerson ,  Michael Steven Byars

IPC分类号： C10B53/02 ,  B01D5/00 ,  B01D33/27 ,  B01J8/00 ,  C01B3/36 ,  C10B49/16 ,  C10G2/00 ,  C10J3/66 ,  C10K1/02 ,  C10K1/08 ,  C10K1/18

CPC分类号： C10B53/02 ,  B01D5/0027 ,  B01D5/0048 ,  B01D5/0069 ,  B01D5/0075 ,  B01D33/27 ,  B01J8/003 ,  C01B3/36 ,  C10B49/16 ,  C10G2/33 ,  C10J3/66 ,  C10K1/026 ,  C10K1/08 ,  C10K1/18 ,  B01D5/0087 ,  C01B2203/025 ,  C01B2203/0272 ,  C01B2203/062 ,  C01B2203/0872 ,  C10G2300/1011 ,  C10G2400/08 ,  C10J2300/0906 ,  C10J2300/0926 ,  C10J2300/1637 ,  C10J2300/1861

摘要： A system and method for the pyrolysis of a pyrolysis feedstock utilizes a pyrolysis reactor having a pyrolysis conduit and a solids return conduit segment. Each segment is configured with an outlet and an inlet to receive and discharge solid materials that are circulated through the reactor through the different segments. A solids conveyor is disposed within the pyrolysis conduit segment to facilitate conveying solid materials from the solids inlet upward through the pyrolysis conduit segment toward the solids discharge outlet. A pyrolysis feedstock is introduced into the pyrolysis reactor and at least a portion of the feedstock is converted to pyrolysis gases within the pyrolysis conduit segment, which are discharged through a gas outlet. An eductor condenser unit with an eductor assembly having a venturi-restricted flow path for receives a pressurized coolant fluid. A second flow path for receiving the discharged pyrolysis gases intersects the venturi-restricted flow path so that the received pyrolysis gases are combined with the coolant fluid and are discharged together to a mixing chamber that is used to condense pyrolysis gases.

公开(公告)号：US11718796B2

公开(公告)日：2023-08-08

申请号：US17004745

申请日：2020-08-27

申请人： L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude

发明人： Sophia Schmidt ,  Sharon Corbet

IPC分类号： C10G5/04 ,  C10G31/08 ,  C10G33/00 ,  B01D53/14 ,  C10K1/00 ,  C10K1/08

CPC分类号： C10G5/04 ,  B01D53/1406 ,  B01D53/1418 ,  B01D53/1425 ,  B01D53/1487 ,  C10G31/08 ,  C10G33/00 ,  C10K1/004 ,  C10K1/005 ,  C10K1/08 ,  B01D2252/2021 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/306 ,  B01D2257/308 ,  B01D2257/504 ,  B01D2257/702

摘要： The invention relates to a process and a plant for staged separation of concomitants from a raw synthesis gas stream to produce synthesis gas and a sulfur-free naphtha product as a by-product, To remove naphtha compounds and sulfur-containing concomitants, raw synthesis gas is treated with a scrubbing medium in a prescrubbing stage and withdrawn from the prescrubbing stage, and the laden scrubbing medium is mixed with water to bring about a phase separation into a scrubbing medium-water mixture and naphtha, wherein sulfur-containing concomitants are in solution in naphtha. To remove the sulfur-containing concomitants the naphtha is heated to obtain sulfur-free naphtha as a by-product of the gas scrubbing.

公开(公告)号：US20230117862A1

公开(公告)日：2023-04-20

申请号：US17917940

申请日：2021-04-01

申请人： Velocys Technologies Limited

发明人： Ivan Philip GREAGER ,  Roger Allen HARRIS ,  Neil Alexander KING ,  Soumitra R. DESHMUKH ,  Zheyan QIU

IPC分类号： C10G2/00 ,  C10J3/00 ,  C10K1/00 ,  C10K1/08 ,  C10K1/10 ,  C10K3/04 ,  C10K3/00 ,  C10G1/00

摘要： The present invention provides a process for the manufacture of a synthetic fuel comprising gasifying a carbonaceous feedstock comprising waste materials and/or biomass to generate a raw synthesis gas; supplying the raw synthesis gas to a primary clean-up zone to wash particulates and ammonia or HCl out of the raw synthesis gas; contacting the synthesis gas in a secondary clean-up zone with a physical solvent for sulphurous materials; contacting the desulphurised raw synthesis gas in a tertiary clean-up zone with a physical solvent for CO2 effective to absorb CO2; removing at least part of the absorbed CO2 in a solvent regeneration stage to recover CO2 in a form sufficiently pure for sequestration or other use; and supplying the clean synthesis gas to a further reaction train to generate a synthetic fuel.

公开(公告)号：US20210402347A1

公开(公告)日：2021-12-30

申请号：US17362194

申请日：2021-06-29

申请人： L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude

发明人： Robert Szabo ,  Sophia Schmidt

IPC分类号： B01D53/14 ,  C10K1/00 ,  C10K1/08 ,  B01D53/18

摘要： The invention relates to a process and plant for purifying a raw synthesis gas containing hydrogen and carbon monoxide as target components and carbon dioxide and sulfur components as disruptive components by gas scrubbing with a physically acting, liquid scrubbing medium selective for carbon dioxide and sulfur components. The process/the plant comprise an absorption apparatus, a hot regeneration apparatus, a preferably multistage flash regeneration apparatus and a reabsorber column supplied with the first portion of a stripping gas. According to the invention the flash regeneration apparatus is supplied with the second portion of the stripping gas

公开(公告)号：US10300428B2

公开(公告)日：2019-05-28

申请号：US14911329

申请日：2014-08-19

申请人： LINDE AKTIENGESELLSCHAFT

发明人： Ulvi Kerestecioglu ,  Alexander Brandl

IPC分类号： B01D53/14 ,  B01D53/18 ,  C01B3/52 ,  C10K1/08

摘要： A method and device for gas scrubbing, in which, in a first scrubbing step, substances of a first kind and, in a subsequent second scrubbing step, substances of a second kind are selectively washed out from the gas mixture that is made to flow in countercurrent to physically acting scrubbing agents, wherein part of the scrubbing agent that is free from substances of the first kind but laden with substances of the second kind in the second scrubbing step is used in the first scrubbing step, and so there occurs a scrubbing agent stream that is laden with substances of the first and second kinds, during the regeneration of which a partly regenerated scrubbing agent stream (semilean); that contains substances of the first and second kinds but has a lower content of substances of the first kind than the scrubbing agent stream laden in the first scrubbing step is generated.

公开(公告)号：US10266775B2

公开(公告)日：2019-04-23

申请号：US14893704

申请日：2015-10-26

申请人： TECHNIP FRANCE

发明人： Rémi Moniot ,  William Lewis Errol Davey

IPC分类号： C10G2/00 ,  C01B3/24 ,  C10K1/00 ,  C10K1/08 ,  C10K1/32 ,  C10G7/00 ,  C10G57/00

摘要： The process comprises: introducing a feed flow in a synthesis gas generation unit to form a synthesis gas flow and introducing the synthesis gas flow in a Fischer-Tropsch synthesis unit at least partially removing carbon dioxide from a first flow formed from a Fischer-Tropsch tail gas flow to form a carbon dioxide depleted flow; forming a tail gas recycle flow from the carbon dioxide depleted flow; introducing the tail gas recycle flow in the synthesis gas generation unit and/or in the synthesis gas flow. The process comprises adjusting the carbon dioxide content in the tail gas recycle flow to control the hydrogen to carbon monoxide molar ratio in the synthesis gas flow to a target hydrogen to carbon monoxide molar ratio.

公开(公告)号：US09771531B2

公开(公告)日：2017-09-26

申请号：US14952060

申请日：2015-11-25

申请人： Sundrop Fuels, Inc.

发明人： Renus C. Kelfkens ,  Wayne W. Simmons ,  Douglas S. Jack ,  Jerrod Wayne Hohman ,  Sidney P. White

IPC分类号： C10G3/00 ,  C10G2/00 ,  C10J3/46 ,  C10G45/44 ,  C10K1/08 ,  C10K1/32 ,  C10K3/02 ,  C10G45/00 ,  C10L1/04 ,  C10K3/00 ,  C10J3/84 ,  C10J3/50 ,  C01B3/38 ,  C10J3/48

CPC分类号： C10J3/466 ,  C01B3/38 ,  C01B2203/0233 ,  C01B2203/062 ,  C01B2203/1241 ,  C10G2/32 ,  C10G2/34 ,  C10G3/00 ,  C10G45/00 ,  C10G45/44 ,  C10G2300/1011 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10J3/485 ,  C10J3/506 ,  C10J3/84 ,  C10J2300/0916 ,  C10J2300/0976 ,  C10J2300/1659 ,  C10J2300/1807 ,  C10J2300/1853 ,  C10K1/08 ,  C10K1/32 ,  C10K3/008 ,  C10K3/023 ,  C10L1/04 ,  C10L2200/0492 ,  C10L2270/023 ,  C10L2270/026 ,  C10L2270/04 ,  C10L2290/04 ,  C10L2290/06 ,  C10L2290/10 ,  C10L2290/42 ,  C10L2290/541 ,  C10L2290/542 ,  C10L2290/543 ,  C10L2290/548 ,  Y02E50/32 ,  Y02P20/145 ,  Y02P20/582 ,  Y02P30/20

摘要： An integrated plant to generate chemical grade syngas from a steam biomass reforming in a multiple stage bio reforming reactor for use with either a high temperature or low temperature Fischer-Tropsch synthesis process to produce fuel from biomass is discussed. The first stage has a reactor to cause a chemical devolatilization of a biomass feedstock from the biomass feedstock supply lines into its constituent gases of CO, H2, CO2, CH4, tars, chars, and other components into a raw syngas mixture. A second stage performs further reforming of the raw syngas from the first stage into the chemical grade syngas by further applying heat and pressure to chemically crack at least the tars, reform the CH4, or a combination of both, into their corresponding syngas molecules. The second stage feeds the chemical grade syngas derived from the biomass feedstock to the downstream Fischer-Tropsch train to produce the fuel from the biomass. One or more recycle loops supply tail gas or FT product back into the plant.

公开(公告)号：US09682343B2

公开(公告)日：2017-06-20

申请号：US14682636

申请日：2015-04-09

申请人： UOP LLC

发明人： Lubo Zhou ,  Bart Beuckels ,  Ernest James Boehm

IPC分类号： C10K1/08 ,  C10K1/34 ,  B01D53/14 ,  C01B17/04

CPC分类号： B01D53/1462 ,  B01D53/1406 ,  B01D2252/2021 ,  B01D2252/2025 ,  B01D2252/20468 ,  B01D2256/16 ,  B01D2256/20 ,  B01D2256/24 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/308 ,  B01D2257/504 ,  C01B17/043 ,  C10K1/08 ,  C10K1/34 ,  Y02C10/06 ,  Y02P20/152

摘要： Sour syngas treatment apparatuses and processes for treating a sour syngas stream are provided herein. In an embodiment, a process for treating a sour syngas stream that includes sulfur components and carbon dioxide includes absorbing the sulfur components and carbon dioxide from the sour syngas stream in a primary liquid/vapor phase absorption stage with a solvent to produce a liquid absorbent stream. The liquid absorbent stream includes the solvent, the sulfur components, and carbon dioxide. A portion of the sulfur components from the liquid absorbent stream is directly oxidized in the presence of a direct oxidation catalyst to produce elemental sulfur and a recycle stream. The recycle stream includes an unconverted portion of the sulfur components and carbon dioxide. The recycle stream is recycled for further absorption of the unconverted portion of the sulfur components and carbon dioxide through liquid/vapor phase absorption.

公开(公告)号：US09505999B1

公开(公告)日：2016-11-29

申请号：US14738859

申请日：2015-06-13

申请人： Wanwang Peng

发明人： Wanwang Peng

IPC分类号： C01B3/36 ,  C10K3/04 ,  C10K1/02 ,  C10K1/08 ,  C10K1/04 ,  C10J3/84

CPC分类号： C10K3/04 ,  C10J3/84 ,  C10J2300/093 ,  C10J2300/0976 ,  C10J2300/1807 ,  C10J2300/1853 ,  C10K1/02 ,  C10K1/04 ,  C10K1/101 ,  Y02E20/18

摘要： A method to reduce formation of waste water in coal gasification and syngas pretreatment process by increasing the salinity of the waste water thereby reducing the overall volume of waste water formed.

摘要翻译： 一种减少煤气化和合成气预处理过程中废水形成的方法，通过提高废水的盐度，从而降低形成的废水总体积。

公开(公告)号：US09410096B2

公开(公告)日：2016-08-09

申请号：US14316842

申请日：2014-06-27

申请人： WUHAN KAIDI GENERAL RESEARCH INSTITUTE OF ENGINEERING & TECHNOLOGY CO., LTD.

发明人： Yanfeng Zhang ,  Wenyan Liu ,  Minggui Xia ,  Liang Zhang

IPC分类号： C01B7/00 ,  C10J3/84 ,  C10K1/02 ,  C10K1/06 ,  C10K1/10 ,  C10K1/08 ,  C10J3/20 ,  C10J3/72 ,  C10J3/74 ,  C10J3/86 ,  C10K1/04

CPC分类号： C10J3/845 ,  C10G2300/1011 ,  C10J3/20 ,  C10J3/723 ,  C10J3/74 ,  C10J3/86 ,  C10J2300/1693 ,  C10J2300/1884 ,  C10J2300/1892 ,  C10K1/02 ,  C10K1/028 ,  C10K1/046 ,  C10K1/06 ,  C10K1/08 ,  C10K1/10 ,  C10K1/101 ,  Y02P20/124 ,  Y02P20/129 ,  Y02P30/20

摘要： A method for cooling and washing biomass syngas, the method including the following steps: 1) introducing biomass syngas having a temperature of between 1000 and 1100° C., a dust content of less than 20 g/Nm3, and a tar content of less than 3 g/Nm3 to a quench tower for condensing a slag; 2) introducing the biomass syngas after slag condensation to a waste heat boiler for recovering waste heat and condensing a heavy tar in the syngas; 3) introducing the biomass syngas from the waste heat boiler to a scrubbing-cooling tower for removing dust and decreasing a temperature of the syngas; and 4) introducing the biomass syngas after dust removal and temperature decrease from the scrubbing-cooling tower to an electro-precipitator for further removal of the dust and the tar.

摘要翻译： 一种用于冷却和洗涤生物质合成气的方法，所述方法包括以下步骤：1）引入温度在1000℃至1100℃之间的生物质合成气，粉尘含量小于20g / Nm 3，焦油含量较低 超过3g / Nm 3，用于冷凝炉渣的骤冷塔; 2）将炉渣冷凝后的生物质合成气引入废热锅炉，以回收废热并冷凝合成气中的重质焦油; 3）将来自废热锅炉的生物质合成气引入洗涤冷却塔，以除去灰尘并降低合成气的温度; 和4）将除尘和降温后的生物质合成气从洗涤 - 冷却塔引入电除尘器，以进一步除去灰尘和焦油。