摘要:
It comprises a mask (11) having a first, a second and a third action edge (11a, 11b, 11c), and a drive means for moving the mask (11) relative to a substrate (12) in a uniaxial direction (A) whereby moving the mask at a fixed rate of movement to cause the edges to successively act on an identical substrate region while successively applying different materials thereto forms thin films of three components successively with respective film thickness gradients oriented in three different directions mutually angularly spaced apart by an angle of 120° to allow these films to overlap, thereby forming a ternary phase diagrammatic thin film 13.
摘要:
A flux assisted solid phase epitaxy that can make a thin film having a crystalline perfection comparable with that of a bulk crystal and at a reduced cost is provided in which an amorphous film of a mixture of an objective substance to be grown epitaxially and a flux of a substance producing a eutectic with the objective substance but not producing any compound therewith is deposited on a substrate at a temperature less than a eutectic point of the substances, and the substrate is heat-treated at a temperature not less than the eutectic point of the objective and flux substances. A solid phase reaction, namely solid phase diffusion causes the objective and flux substances to be mixed together to form a liquid phase in their eutectic state from which the objective substance precipitates and epitaxially grows on the substrate.
摘要:
A flux assisted solid phase epitaxy that can make a thin film having a crystalline perfection comparable with that of a bulk crystal and at a reduced cost is provided in which an amorphous film of a mixture of an objective substance to be grown epitaxially and a flux of a substance producing a eutectic with the objective substance but not producing any compound therewith is deposited on a substrate at a temperature less than a eutectic point of the substances, and the substrate is heat-treated at a temperature not less than the eutectic point of the objective and flux substances. A solid phase reaction, namely solid phase diffusion causes the objective and flux substances to be mixed together to form a liquid phase in their eutectic state from which the objective substance precipitates and epitaxially grows on the substrate.
摘要:
A titanium dioxide.cobalt magnetic film is provided that is useful to make up a photocatalyst having high catalytic capability, a semiconductor material having an optical, an electrical and a magnetic function all in combination, and a transparent magnet. The titanium dioxide.cobalt magnetic film has a composition expressed by chemical formula: Ti1-xCoxO2 where 0
摘要:
The present invention is an tri-phase epitaxy method for preparing a single crystal oxide thin film, comprising the steps of depositing on a substrate an oxide thin film serving as a seed layer and having the same composition as that of an oxide thin film to be formed, depositing on the seed layer a thin film comprising a substance capable of being melted and liquidized by heat from the substrate and dissolving the oxide to be subsequent by deposited onto the seed layer, heating the substrate to form a liquid layer, and depositing an oxide on the seed layer through the liquid layer by use of a vapor-phase epitaxy method to form the single crystal oxide thin film. In this method, the oxygen partial pressure on the liquid layer is set in the range of 1.0 to 760 Torr during the film-forming step.
摘要:
A Bi4Ti3O12 nanoplate, an array of such Bi4Ti3O12 nanoplate and their making methods as well as their applications are provided. Using a vapor phase growth method, a flux layer of VOx is deposited on a SrTiO3 (001) faced substrate and then Bi4Ti3O12 is deposited on the flux layer. A Bi4Ti3O12 single crystal nanoplate is formed standing up on the flux layer in the form of a rectangular solid whose independent three sides are crystallographically oriented in directions coincident with particular crystallographic directions of the single crystal substrate, respectively. The nanoplates as a nanostructure grown by the bottom-up method are substantially fixed in shape and are densely arrayed not in contact with one another, and are applicable to a low-cost ferroelectric memory and the like.
摘要:
A Bi4Ti3O12 nanoplate, an array of such Bi4Ti3O12 nanoplate and their making methods as well as their applications are provided. Using a vapor phase growth method, a flux layer of VOx is deposited on a SrTiO3 (001) faced substrate and then Bi4Ti3O12 is deposited on the flux layer. A Bi4Ti3O12 single crystal nanoplate is formed standing up on the flux layer in the form of a rectangular solid whose independent three sides are crystallographically oriented in directions coincident with particular crystallographic directions of the single crystal substrate, respectively. The nanoplates as a nanostructure grown by the bottom-up method are substantially fixed in shape and are densely arrayed not in contact with one another, and are applicable to a low-cost ferroelectric memory and the like.
摘要:
The present invention provides methods for producing a multi-element oxide single crystal which contains Bi, which has high crystallinity independently of a preparation process, and which is represented by the formula (Bi2O2)Am−1BmO3m+1, wherein A is Sr, Ba, Ca, or Bi and B is Ti, Ta, or Nb.A flux layer, containing a composition satisfying the inequality 0
摘要翻译:本发明提供了制备含有Bi的多元素氧化物单晶的方法,该Bi具有独立于制备方法的高结晶度,并且由式(Π2 O 2) 其中A是Sr,Ba,Ca或Bi和B,其中A是Sr,Ba,Ca或Bi和B 是Ti,Ta或Nb。 包含满足不等式0的组成的通量层,和/或0 <= TIO / BI2 SUB 以摩尔为基础沉积在基片上,然后将单晶薄膜沉积在放置在晶片上的助熔剂层上。 制备含有原料和助熔剂并且满足上述不等式的组合物的熔体,并且将熔体冷却以使单晶生长。 将CuO助熔剂层沉积在晶片上,并且使用Bi 6 Ti 3 O 12 12将Bi-Ti-O供应到焊剂层。 ,Bi 7,Ti 3 O 12,或Bi 8 Ti 3 O 2, 其中Bi含量大于目标薄膜的Bi含量,使得Bi 4 N 3 O 12 O / 12 >晶片上方形成单晶薄膜。
摘要:
The present invention provides methods for producing a multi-element oxide single crystal which contains Bi, which has high crystallinity independently of a preparation process, and which is represented by the formula (Bi2O2)Am-1BmO3m+1, wherein A is Sr, Ba, Ca, or Bi and B is Ti, Ta, or Nb. A flux layer, containing a composition satisfying the inequality 0
摘要翻译:本发明提供了制备含有Bi的多元素氧化物单晶的方法,该Bi具有独立于制备方法的高结晶度,并且由式(Π2 O 2) 其中A是Sr,Ba,Ca或Bi和B,其中A是Sr,Ba,Ca或Bi和B 是Ti,Ta或Nb。 包含满足不等式0的组成的通量层,和/或0 <= TIO / BI2 SUB 以摩尔为基础沉积在基片上,然后将单晶薄膜沉积在放置在晶片上的助熔剂层上。 制备含有原料和助熔剂并且满足上述不等式的组合物的熔体,并且将熔体冷却以使单晶生长。 将CuO助熔剂层沉积在晶片上,并且使用Bi 6 Ti 3 O 12 12将Bi-Ti-O供应到焊剂层。 ,Bi 7,Ti 3 O 12,或Bi 8 Ti 3 O 2, 其中Bi含量大于目标薄膜的Bi含量,使得Bi 4 N 3 O 12 O / 12 >晶片上方形成单晶薄膜。
摘要:
There are provided a method of superflattening an oxide crystal that is soluble neither with acid nor with alkaline, a method of making a ReCa4O(BO3)3 family oxide single crystal thin film using the superflattening method, a ReCa4O(BO3)3 family oxide single crystal thin film having a SHG property, a superflattening method for light incident/emitting surfaces, and a defect assessing method for oxide crystals. The surface of an oxide crystal that is soluble neither with acid nor with alkaline is reduced with a reducing agent, the reduced oxide crystal surface is dissolved with an aqueous solution of acid or alkaline, the surface dissolved oxide crystal is heat-treated in the atmosphere, whereby the surface of an oxide crystal that is soluble neither with acid nor with alkaline is superflattened to an atomic level. According to this method, a chemically stable oxide which because of its complexity in both composition and structure is soluble neither with acid nor with alkaline and is insoluble even with a fluoric acid is allowed by reduction to be converted into a simpler oxide conventionally soluble with hydrochloric, nitric or sulfuric acid; hence a surface of its crystal is rendered capable of dissolving. Then, heat-treating the dissolved surface in the atmosphere at a suitable temperature for a suitable time period allows surface atoms to be rearranged and the surface to be superflattened to an atomic level. The present invention is applicable to the technical fields that require ultraviolet laser light, especially as core technologies of optical devices applied to optical information processing, optical communication or the like.