公开(公告)号：US08974743B2

公开(公告)日：2015-03-10

申请号：US13378258

申请日：2010-06-09

Applicant: Matthias Krull ,  Roman Morschhaeuser

Inventor： Matthias Krull ,  Roman Morschhaeuser

IPC: A62D3/00 ,  C07C1/32 ,  B01J19/12 ,  C07C67/08 ,  C07C231/02 ,  C07D307/60 ,  H05B6/80 ,  B01J19/00 ,  B01J19/24 ,  B01J7/00 ,  B01J8/00 ,  B01J10/00 ,  B01J12/00 ,  H05B6/64 ,  H05B6/68 ,  H05B6/70 ,  A62D3/10 ,  A62D3/17

CPC classification number: C07C1/321 ,  B01J19/126 ,  B01J2219/0871 ,  B01J2219/1227 ,  C07C67/08 ,  C07C231/02 ,  C07C2531/24 ,  C07D307/60 ,  H05B6/80 ,  H05B6/806 ,  C07C15/14 ,  C07C69/24 ,  C07C69/52 ,  C07C233/05 ,  C07C233/09 ,  C07C233/36

Abstract: The invention relates to a device for continuously carrying out chemical reactions. The device comprises a microwave generator, a microwave applicator accommodating a microwave-transparent tube, and an isothermal reaction section which is arranged such that the material to be reacted is guided inside the microwave-transparent tube through a microwave applicator which is used as the heating zone and in which it is heated to reaction temperature by means of microwaves that are emitted from the microwave generator into the microwave applicator. The material to be reacted, which is heated and optionally under pressure, is transferred from the microwave applicator to an isothermal reaction zone once it has left the heating zone, said reaction zone being arranged downstream of the heating zone, and is cooled once it has left the isothermal reaction zone.

Abstract translation: 本发明涉及连续进行化学反应的装置。 该装置包括微波发生器，容纳微波透明管的微波加热器和等温反应部分，该等温反应部分被布置为使得待反应的材料通过微波加热器被引导到微波透明管内部，该微波加热器用作加热 区域，并且通过从微波发生器发射到微波施加器中的微波将其加热至反应温度。 待加热和任选在压力下的材料一旦离开加热区，就从微波加热器转移到等温反应区，所述反应区设置在加热区的下游，并且一旦冷却 离开等温反应区。

公开(公告)号：US08974556B2

公开(公告)日：2015-03-10

申请号：US13637491

申请日：2011-05-20

Applicant: Kouji Tada ,  Masaki Nobuoka ,  Kazuya Shima

Inventor： Kouji Tada ,  Masaki Nobuoka ,  Kazuya Shima

IPC: C01B3/00 ,  C01B3/32 ,  B01J7/00 ,  B01J8/04 ,  C01B3/38 ,  C01B3/48 ,  H01M8/06 ,  H01M8/04

CPC classification number: B01J7/00 ,  B01J8/0469 ,  B01J8/0492 ,  B01J8/0496 ,  B01J2208/00504 ,  B01J2208/0053 ,  B01J2208/00929 ,  B01J2208/00938 ,  B01J2208/025 ,  C01B3/384 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/1294 ,  C01B2203/1614 ,  C01B2203/82 ,  H01M8/04022 ,  H01M8/04201 ,  H01M8/0631 ,  H01M8/0668 ,  Y02E60/324 ,  Y02E60/50

Abstract: Disclosed is a hydrogen generator that prevents the reformate water from bypassing the evaporator in a hydrogen generator, and the occurrence of sudden temperature changes within an evaporation flow path. The hydrogen generator comprises: an evaporator that produces a mixed gas by mixing a raw material gas containing methane with water vapor; a reformer that changes the mixed gas into a hydrogen-containing gas through a steam reforming reaction; and a combustor that supplies heat to the evaporator and the reformer. The evaporator comprises: an inner cylinder; an outer cylinder enclosing the inner cylinder; and a middle cylinder that is inserted between the inner cylinder and the outer cylinder, and that defines a helical flow path between the inner cylinder and the outer cylinder, through which water supplied from the outside flows.

Abstract translation: 公开了一种氢发生器，其防止重整油水在氢发生器中绕过蒸发器，并且在蒸发流路内发生突然的温度变化。 氢发生器包括：蒸发器，其通过将含有甲烷的原料气体与水蒸气混合而产生混合气体; 通过蒸汽重整反应将混合气体变成含氢气体的重整器; 以及向蒸发器和重整器供给热量的燃烧器。 蒸发器包括：内筒; 封闭内筒的外筒; 以及插入在所述内筒和所述外筒之间并且在所述内筒和所述外筒之间限定螺旋状流路的中筒，所述外筒供给的水流过所述中筒。

公开(公告)号：US08969647B2

公开(公告)日：2015-03-03

申请号：US13384436

申请日：2010-07-07

Applicant: Giacomo Fernando Rispoli ,  Felicia Massetti ,  Michelangelo D'Abbieri ,  Medardo Pinti ,  Maria Ilaria Pistelli

Inventor： Giacomo Fernando Rispoli ,  Felicia Massetti ,  Michelangelo D'Abbieri ,  Medardo Pinti ,  Maria Ilaria Pistelli

IPC: A62D3/20 ,  C01B3/36 ,  B01J7/00 ,  C10J3/10 ,  C10J3/00 ,  C10J3/14 ,  C10J3/20 ,  C10J3/80

CPC classification number: C10J3/10 ,  C10J3/005 ,  C10J3/14 ,  C10J3/20 ,  C10J3/80 ,  C10J2300/0909 ,  C10J2300/0926 ,  C10J2300/0989 ,  C10J2300/1606 ,  Y02P20/145

Abstract: A continuous process for the thermal treatment of a refinery sludge, comprising the following operations: a. drying of the refinery sludge, possibly mixed with pet-coke, at a temperature ranging from 110 to 120° C.; b. gasification of the dried sludge, at a temperature ranging from 750 to 950° C., for a time of 30 to 60 minutes, in the presence of a gas containing oxygen and water vapour, with the associated production of synthesis gas (CO+H2) and a solid residue; c. combustion of the synthesis gas at a temperature ranging from 850 to 1,200° C. and recycling of the combustion products for the drying and gasification phases; and d. inertization of the solid residue, at a temperature ranging from 1,300 to 1,500° C., by vitrification with plasma torches.

Abstract translation: 炼油厂污泥热处理的连续工艺，包括以下操作：a。 在110至120℃的温度范围内干燥可能与宠物焦炭混合的炼油厂污泥; b。 在含有氧气和水蒸汽的气体存在下，在750〜950℃的温度范围内，将干燥的污泥气化30〜60分钟，伴随生产合成气（CO + H2 ）和固体残渣; C。 在850〜1200℃的温度下对合成气进行燃烧，再循环用于干燥和气化阶段的燃烧产物; 和d。 通过用等离子炬玻璃化，在1300至1500℃的温度下使固体残余物惰性化。

公开(公告)号：US08968433B2

公开(公告)日：2015-03-03

申请号：US13309354

申请日：2011-12-01

Applicant: Ravi Chandran

Inventor： Ravi Chandran

IPC: B01J7/00 ,  F02C3/28 ,  H01M8/06 ,  C10J3/48 ,  C01B3/44 ,  H01M8/12 ,  C10J3/62

CPC classification number: H01M8/0631 ,  B01J21/04 ,  C01B3/02 ,  C01B3/12 ,  C01B3/36 ,  C01B3/44 ,  C01B3/50 ,  C01B2203/0205 ,  C01B2203/0233 ,  C01B2203/025 ,  C01B2203/0283 ,  C01B2203/0425 ,  C01B2203/0465 ,  C01B2203/0475 ,  C01B2203/062 ,  C01B2203/066 ,  C01B2203/067 ,  C01B2203/0811 ,  C01B2203/0844 ,  C01B2203/085 ,  C01B2203/1041 ,  C01B2203/1205 ,  C10J3/463 ,  C10J3/466 ,  C10J3/482 ,  C10J3/62 ,  C10J3/726 ,  C10J2300/0909 ,  C10J2300/0916 ,  C10J2300/094 ,  C10J2300/0959 ,  C10J2300/0969 ,  C10J2300/0976 ,  C10J2300/1215 ,  C10J2300/123 ,  C10J2300/1246 ,  C10J2300/1276 ,  C10J2300/1606 ,  C10J2300/1612 ,  C10J2300/1646 ,  C10J2300/1653 ,  C10K1/02 ,  F02C3/28 ,  F05D2220/32 ,  F05D2220/72 ,  H01M8/0618 ,  H01M8/0643 ,  H01M2008/1293 ,  Y02E20/16 ,  Y02E20/18 ,  Y02E20/185 ,  Y02E50/12 ,  Y02E60/50 ,  Y02E60/525 ,  Y02P20/52 ,  Y02T50/672

Abstract: A direct carbonaceous material to power generation system integrates one or more solid oxide fuel cells (SOFC) into a fluidized bed gasifier. The fuel cell anode is in direct contact with bed material so that the H2 and CO generated in the bed are oxidized to H2O and CO2 to create a push-pull or source-sink reaction environment. The SOFC is exothermic and supplies heat within a reaction chamber of the gasifier where the fluidized bed conducts an endothermic reaction. The products from the anode are the reactants for the reformer and vice versa. A lower bed in the reaction chamber may comprise engineered multi-function material which may incorporate one or more catalysts and reactant adsorbent sites to facilitate excellent heat and mass transfer and fluidization dynamics in fluidized beds. The catalyst is capable of cracking tars and reforming hydrocarbons.

Abstract translation: 直接碳质材料发电系统将一种或多种固体氧化物燃料电池（SOFC）集成到流化床气化器中。 燃料电池阳极与床材料直接接触，使得床中产生的H 2和CO被氧化成H 2 O和CO 2，以产生推挽式或源沉降反应环境。 SOFC是放热的并且在气化器的反应室内提供热量，其中流化床进行吸热反应。 来自阳极的产物是重整器的反应物，反之亦然。 反应室中的较低床可以包括工程化的多功能材料，其可以结合一种或多种催化剂和反应物吸附剂位点，以促进流化床中优异的热传质和流化动力学。 催化剂能够开裂焦油和重整碳氢化合物。

公开(公告)号：US20150045458A1

公开(公告)日：2015-02-12

申请号：US14522625

申请日：2014-10-24

Applicant: Wuhan Kaidi Engineering Technology Research Institute Co., Ltd.

Inventor： Yanfeng ZHANG ,  Yilong CHEN ,  Zhilong WANG ,  Zhangjian FANG ,  Xingcai ZHENG

IPC: C10L3/08 ,  B01J7/00

CPC classification number: C10L3/08 ,  B01J7/00 ,  C07C1/12 ,  C10L3/06 ,  C10L2290/06 ,  C10L2290/10 ,  C10L2290/38 ,  C10L2290/42 ,  C10L2290/54 ,  Y02E60/366 ,  Y02P20/133 ,  C07C9/04

Abstract: A method for converting carbon dioxide in flue gas into natural gas using dump energy. The method includes: 1) transforming and rectifying a voltage of dump energy generated from a renewable energy plant, introducing the voltage-transformed and rectified dump energy into an electrolyte solution to electrolyze water therein to yield H2 and O2; 2) purifying industrial flue gas to separate CO2 therein and purifying CO2; 3) transporting H2 generated and CO2 to a synthesis equipment, allowing a methanation reaction between H2 and CO2 to happen to yield a high-temperature mixed gas with main ingredients of CH4 and water vapor; 4) employing the high-temperature mixed gas to conduct indirect heat exchange with process water to yield superheated water vapor; 5) delivering the superheated water vapor to a turbine to generate electric energy, and returning the electric energy to step 1); and 6) condensing and drying the mixed gas.

Abstract translation: 使用倾倒能量将烟道气中的二氧化碳转化为天然气的方法。 该方法包括：1）对可再生能源厂产生的倾倒能量的电压进行变换和整流，将电压转换和整流的能量转化为电解液，对其中的水进行电解，得到H2和O2; 2）净化工业烟气，分离二氧化碳，净化二氧化碳; 3）将生成的H 2和CO 2输送到合成设备中，使H 2和CO 2之间的甲烷化反应发生，产生与主要成分为CH 4和水蒸气的高温混合气体; 4）采用高温混合气体与工艺水进行间接热交换，产生过热水蒸气; 5）将过热水蒸气输送到涡轮机以产生电能，并将电能返回到步骤1）; 6）冷凝干燥混合气体。

公开(公告)号：US20150044126A1

公开(公告)日：2015-02-12

申请号：US14371474

申请日：2013-01-07

Applicant: SUMITOMO METAL MINING CO., LTD.

Inventor： Osamu Nakai ,  Satoshi Matsubara ,  Tomoyuki Hirose ,  Masafumi Nakamura

IPC: B01J7/00 ,  C01B17/16

CPC classification number: B01J7/00 ,  B01J2219/00002 ,  C01B17/162 ,  C01B17/168

Abstract: An object is to provide a hydrogen sulfide gas production plant that can recover discharged waste hydrogen sulfide gas and efficiently supply the gas to a process plant where processing is conducted by using hydrogen sulfide gas, and also provide a method for recovering and using the waste hydrogen sulfide gas by the hydrogen sulfide gas production plant. In the present invention, the hydrogen sulfide gas production plant is provided with a pipe that recovers the waste hydrogen sulfide gas discharged from the hydrogen sulfide gas production plant and that has one end connected to the process plant where the hydrogen sulfide gas is used, and the discharged waste hydrogen sulfide gas is recovered and the recovered waste hydrogen sulfide gas is supplied to the process plant through the pipe.

Abstract translation: 本发明的目的是提供一种能够回收排出的废硫化氢气体并有效地将气体供给到通过使用硫化氢气体进行加工的工艺设备的硫化氢气体生产设备，并且还提供回收和使用废氢 硫化氢气体由硫化氢气体生产厂。 在本发明中，硫化氢气体生产装置设置有回收从硫化氢气体制造装置排出的废硫化氢气体的管道，其一端与使用硫化氢气体的处理装置连接， 回收排出的废硫化氢气体，回收的废硫化氢气体通过管道供给工艺装置。

公开(公告)号：US08951312B2

公开(公告)日：2015-02-10

申请号：US13373258

申请日：2011-11-09

Applicant: Alvin Gabriel Stern

Inventor： Alvin Gabriel Stern

IPC: B01J7/00 ,  C01B3/02 ,  C01B3/08 ,  C25C1/02 ,  B01J7/02

CPC classification number: C25C1/02 ,  B01J7/02 ,  C01B3/08 ,  Y02E60/36 ,  Y02P10/212

Abstract: A compact, chemical-mechanical apparatus, having no electrical components, for storing and generating hydrogen safely, on-demand, at the time and point of use in small or large quantities using the environmentally clean chemical reaction between sodium metal and water to generate hydrogen (H2) gas and sodium hydroxide (NaOH) byproduct is presented, for powering electricity generating fuel cells for large scale commercial and private electric motor vehicle transport. The apparatus of the present invention supports hydrogen gas generation by the controlled addition of liquid water to solid sodium metal to produce hydrogen gas and sodium hydroxide using only mechanical components without electrical components that require external power and can generate sparks or short circuits, producing catastrophic failure in hydrogen systems. The sodium hydroxide can be reclaimed and recycled by electrolysis using hydroelectric power to recover the sodium metal for reuse in generating hydrogen, thereby forming a complete clean energy hydrogen power cycle.

Abstract translation: 一种紧凑的化学机械设备，没有电气部件，用于在使用时间和点使用时以安全，按需的方式储存和生成氢气，使用金属和水之间的环境清洁化学反应，以少量或大量的方式产生氢气 （H2）气和氢氧化钠（NaOH）副产物，用于为大规模商业和私人电动汽车运输的发电燃料电池供电。 本发明的装置通过将液态水控制加入到固体钠金属中来支持产生氢气，以仅使用机械部件来产生氢气和氢氧化钠，而不需要外部电力的电气部件并且可能产生火花或短路，从而产生灾难性故障 在氢气系统中。 可以通过使用水力发电的电解回收和再循环氢氧化钠，以回收钠金属，用于产生氢气再利用，从而形成完整的清洁能源氢能循环。

公开(公告)号：US08926719B2

公开(公告)日：2015-01-06

申请号：US14209572

申请日：2014-03-13

Applicant: McAlister Technologies, LLC

Inventor： Roy Edward McAlister

IPC: B01J7/00

CPC classification number: C01B3/10 ,  B01J7/02 ,  B01J19/087 ,  Y02E60/36

Abstract: A hydrogen generator including a reactor chamber having a feedstock inlet and an inlet seal positioned at the feedstock inlet. At least one pair of feed rollers is positioned to draw a feedstock through the inlet seal and into the reactor chamber. At least one pair of distressing rollers is positioned in line with the feed rollers to produce stress in the feedstock. Steam is provided to the reactor chamber through a steam inlet and hydrogen is collected from a hydrogen outlet.

Abstract translation: 一种氢发生器，其包括具有原料入口和位于原料入口处的入口密封件的反应器室。 定位至少一对进料辊以通过入口密封件抽吸进料并进入反应器室。 至少一对令人不快的辊与进料辊定位成一致，以在原料中产生应力。 通过蒸汽入口将蒸汽提供给反应室，氢气从氢气出口收集。

公开(公告)号：US08920772B2

公开(公告)日：2014-12-30

申请号：US14061280

申请日：2013-10-23

Applicant: Air Products and Chemicals Inc.

Inventor： Xiang-Dong Peng ,  Xianming Jimmy Li ,  Kalman Tari

IPC: C01B3/24 ,  B01J7/00 ,  C02F1/16 ,  C02F1/06 ,  C01B3/38

CPC classification number: C02F1/16 ,  B01J7/00 ,  C01B3/384 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/043 ,  C01B2203/0495 ,  C01B2203/0816 ,  C01B2203/0827 ,  C01B2203/0883 ,  C02F1/048 ,  C02F1/06 ,  C02F1/20 ,  C02F1/42 ,  C02F1/4695 ,  C02F2103/007 ,  C02F2103/06 ,  C02F2103/08 ,  Y02A20/128 ,  Y02W10/37

Abstract: System and process for producing a H2-containing product gas and purified water from an integrated H2-producing reforming and thermal water purification process. Raw water, such as salt water, is heated by indirect heat transfer with reformate from the H2-producing reforming process for purifying raw water in a multiple effect distillation process.

Abstract translation: 从生成H2的重整和热水净化过程中生产含H2产物气体和净化水的系统和方法。 诸如盐水的原水通过在多效蒸馏过程中用于纯化原水的H 2生成重整过程的重整产物进行间接热转移而被加热。

公开(公告)号：US08920732B2

公开(公告)日：2014-12-30

申请号：US13028044

申请日：2011-02-15

Applicant: Zhen Chen ,  Xun Ouyang

Inventor： Zhen Chen ,  Xun Ouyang

IPC: F01N3/20 ,  B01J8/00 ,  B01J7/00 ,  H01M8/06 ,  H01M8/04 ,  C01B3/38

CPC classification number: H01M8/0618 ,  C01B3/384 ,  C01B2203/043 ,  C01B2203/0445 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/085 ,  C01B2203/146 ,  C01B2203/1657 ,  C01B2203/169 ,  H01M8/0432 ,  H01M8/04694 ,  H01M8/04776 ,  H01M8/04992 ,  Y02E60/50

Abstract: The present disclosure is directed to systems and methods for actively controlling the steam-to-carbon ratio in hydrogen-producing fuel processing systems that include a feedstock delivery system. The feedstock delivery system supplies a combined feedstock stream including steam and carbon-containing feedstock to a hydrogen-producing region, which produces a mixed gas stream including hydrogen gas as a majority component therefrom. The systems and methods may include measuring a thermodynamic property of a steam stream, a carbon-containing feedstock stream, and/or the combined feedstock stream and controlling the flow rate and/or pressure of a water stream, the steam stream, and/or the carbon-containing feedstock stream based on a desired steam-to-carbon ratio in the combined feedstock stream and/or a desired flow rate of the mixed gas stream and may include feedforward and/or feedback control strategies.

Abstract translation: 本公开涉及用于在包括原料输送系统的制氢燃料处理系统中主动控制蒸汽与碳之比的系统和方法。 原料输送系统将包括蒸汽和含碳原料的组合原料流供应到产氢区，其产生包含氢气作为其主要成分的混合气流。 系统和方法可以包括测量蒸汽流，含碳原料流和/或组合的原料流的热力学性质，并控制水流，蒸汽流和/或蒸汽流的流速和/或压力。 基于组合的原料流中所需的蒸汽 - 碳比和/或混合气流的期望流速的含碳原料流，并且可以包括前馈和/或反馈控制策略。