摘要:
A catalyst for purifying an exhaust gas for simultaneously removing carbon monoxide, hydrocarbons and nitrogen oxides contained in the exhaust gas under an oxygen rich atmosphere, comprising a carrier composed of a porous material, and barium oxide, lanthanum oxide and platinum supported on the carrier, and a method for purifying an exhaust gas by bringing the exhaust gas under an oxygen rich atmosphere into contact with the above-mentioned catalyst.
摘要:
Hydrogen gas from a hydrogen generator which creates hydrogen gas by the electrolysis of water or water vapor is supplied at the entrance to a catalyzer provided in an exhaust line. The catalyzer performs a catalytic reaction between hydrogen gas and nitrogen oxides to achieve decomposition into nitrogen gas and water vapor in the exhaust from an internal combustion engine. The nitrogen oxides are directly reduced with said hydrogen gas in a low temperature atmosphere not higher than 350.degree. C. to achieve efficient reduction in the nitrogen oxides. The improved method and apparatus provide a catalytic system with which the nitrogen oxides in the exhaust from a lean burnt engine or a diesel engine can be effectively reduced irrespective of the concentration of oxygen gas in the exhaust without impairing the good fuel economy of those engines.
摘要:
An exhaust gas purifying catalyst for oxidizing HC and CO and for reducing NOx is provided, which comprises at least one oxide of rare earth element, rhodium, and at least one of platinum and palladium loaded on alumina grains. The major amount of rhodium is dispersed on the oxide of rare earth element. Thus, the rhodium solidification into the alumina grains is prevented. Further, when cerium oxide accompanying lanthanum oxide, neodymium oxide or a mixture thereof is used as the oxide of rare earth element, the sintering of cerium oxide or palladium at a high temperature is suppressed since it forms a complex oxide with lanthanum oxide, neodymium oxide or a mixture thereof. Additionally, when stabilized alumina grains in which a rare earth element and an alkali earth element are present in a solid solution state are used, the deterioration of NOx purifying activity of the catalyst at a high temperature is suppressed. The exhaust gas purifying catalyst of this invention has high durability as well as high activity at a high temperature.
摘要:
A catalyst for the steam reforming of hydrocarbons into gases such as methane, hydrogen and carbon monoxide and a method of preparing the same. The catalyst which comprises cerium oxide and rhodium supported on a carrier can maintain high catalytic activity and durability for steam reforming without any carbon deposition on its surface.
摘要:
An apparatus for decreasing nitrogen oxides in a combustion device of Stirling engine which performs continuous combustion includes a combustion chamber, means for supplying the combustion chamber with fuel and air, an exhaust passageway for discharging exhaust gas produced by combustion in the combustion chamber, a catalytic unit arranged in the exhaust passageway for purging toxic components contained in the exhaust gas discharged, and hydrogen supply means for supplying hydrogen gas to the exhaust gas which enters the catalytic unit. The hydrogen gas is supplied to the combustion exhaust gas which has entered the catalytic unit, and the combustion exhaust gas is then catalytically reduced in an environment of a comparatively low temperatures of less than 250.degree. C., whereby the nitrogen oxides in the exhaust gas are decreased.
摘要:
A lean NOx reduction catalyst capable of reducing NOx through reaction of H.sub.2 with NOx at low temperatures below 350.degree. C. is installed in a downstream portion of an exhaust pipe of an internal combustion engine in or near a muffler. Such an NOx reduction catalyst comprises, for example, Pt/zeolite catalyst. An H.sub.2 generator is installed so as to supply the H.sub.2 to an inlet side of the NOx reduction catalyst. The H.sub.2 generator may include a reforming catalyst for reforming methanol, LPG, or natural gas to generate H.sub.2. The generated H.sub.2 flows to the NOx reduction catalyst where it reacts with NOx to purify the exhaust gas.
摘要:
A NO.sub.x absorbent (18) which absorbs the NO.sub.x when the air-fuel ratio of the exhaust gas flowing into the NO.sub.x absorbent (18) is lean and releases the absorbed NO.sub.x when the oxygen concentration of the exhaust gas flowing into the NO.sub.x absorbent (18) is lowered, is arranged in the exhaust passage of the engine. The amount of alkali metals, alkali-earth metals or rare-earth metals contained in the NO.sub.x absorbent (18) positioned on the downstream side, is made lower than the amount of alkali metals, alkali-earth metals or rare-earth metals contained in the NO.sub.x absorbent (18) positioned on the upstream side, to increase a reducing ability of the NO.sub.x absorbent (18) positioned on the downstream side as compared to the reducing ability of the NO.sub.x absorbent (18) positioned on the upstream side.
摘要:
A method for purifying an oxygen excess exhaust gas by catalytically reducing nitrogen oxides contained in the exhaust gas, which comprises bringing a catalyst comprising at least one noble metal supported on a carrier composed mainly of an oxide or a complex oxide of at least one metal selected from rare earth metals and metals of the group IV A of the periodic table of elements into contact the exhaust gas.
摘要:
The exhaust gases, such as of an internal combustion engine are contacted with a catalyst containing copper in the presence of hydrocarbons in an oxidizing atmosphere, whereby nitrogen oxides are reduced from the exhaust gases. Then, the exhaust gases are preferably contacted with an oxidizing catalyst. The former catalyst contains copper loaded on a porous support formed from alumina, silica, silica-alumina or zeolite or mixture thereof. The support is preferably a monolithic body having a first portion loaded with copper and a second portion loaded with a metal or metals defining the oxidizing catalyst.
摘要:
Exhaust gas purifying method and apparatus for internal combustion engines in which the temperature of an exhaust gas purifying catalyst is detected and, as desired, oxygen content of exhaust gas is further detected, and in which the actual air-fuel ratio is varied toward the higher air-fuel ratio side and the lower air-fuel ratio side with respect to the theoretical air-fuel ratio, in accordance with the frequency and amplitude preset dependent on the kind of the catalyst and set based on these measured values.