Electrolytic deposition of metal-based composite coatings comprising nano-particles
    12.
    发明授权
    Electrolytic deposition of metal-based composite coatings comprising nano-particles 有权
    包含纳米颗粒的金属基复合涂层的电解沉积

    公开(公告)号:US09217205B2

    公开(公告)日:2015-12-22

    申请号:US12747681

    申请日:2008-12-10

    IPC分类号: C25D15/02 C25D3/02

    CPC分类号: C25D15/02 C25D3/02 C25D15/00

    摘要: A method is provided for imparting corrosion resistance onto a surface of a substrate. The method comprises contacting the surface of the substrate with an electrolytic plating solution comprising (a) a source of deposition metal ions of a deposition metal selected from the group consisting of zinc, palladium, silver, nickel, copper, gold, platinum, rhodium, ruthenium, chrome, and alloys thereof, (b) a pre-mixed dispersion of non-metallic nano-particles, wherein the non-metallic particles have a pre-mix coating of surfactant molecules thereon; and applying an external source of electrons to the electrolytic plating solution to thereby electrolytically deposit a metal-based composite coating comprising the deposition metal and non-metallic nano-particles onto the surface.

    摘要翻译: 提供了一种赋予衬底表面的耐腐蚀性的方法。 该方法包括使基板的表面与电解电镀溶液接触,所述电解电镀溶液包括(a)选自锌,钯,银,镍,铜,金,铂,铑等的沉积金属的沉积金属离子源, 钌,铬及其合金,(b)非金属纳米颗粒的预混合分散体,其中所述非金属颗粒在其上具有表面活性剂分子的预混合涂层; 以及将外部电子源施加到所述电解电镀溶液中,从而将包含所述沉积金属和非金属纳米颗粒的金属基复合涂层电沉积到所述表面上。

    Metallic surface enhancement
    14.
    发明授权
    Metallic surface enhancement 有权
    金属表面增强

    公开(公告)号:US07883738B2

    公开(公告)日:2011-02-08

    申请号:US11736647

    申请日:2007-04-18

    IPC分类号: B05D5/12 B32B15/04

    摘要: A method and composition for enhancing corrosion resistance, wear resistance, and contact resistance of a device comprising a copper or copper alloy substrate and at least one metal-based layer on a surface of the substrate. The composition comprises a phosphorus oxide compound selected from the group consisting of a phosphonic acid, a phosphonate salt, a phosphonate ester, a phosphoric acid, a phosphate salt, a phosphate ester, and mixtures thereof; an aromatic heterocycle comprising nitrogen; and a solvent having a surface tension less than about 50 dynes/cm as measured at 25° C.

    摘要翻译: 一种用于提高包含铜或铜合金基底和至少一种金属基层在该基底表面上的装置的耐腐蚀性,耐磨性和接触电阻的方法和组合物。 该组合物包含选自膦酸,膦酸盐,膦酸酯,磷酸,磷酸盐,磷酸酯及其混合物的磷氧化物化合物; 包含氮的芳族杂环; 和在25℃下测得的表面张力小于约50达因/厘米的溶剂

    ELECTROLYTIC DEPOSITION OF METAL-BASED COMPOSITE COATINGS COMPRISING NANO-PARTICLES
    15.
    发明申请
    ELECTROLYTIC DEPOSITION OF METAL-BASED COMPOSITE COATINGS COMPRISING NANO-PARTICLES 有权
    包含纳米颗粒的金属基复合涂层的电沉积

    公开(公告)号:US20100294669A1

    公开(公告)日:2010-11-25

    申请号:US12747681

    申请日:2008-12-10

    CPC分类号: C25D15/02 C25D3/02 C25D15/00

    摘要: A method is provided for imparting corrosion resistance onto a surface of a substrate. The method comprises contacting the surface of the substrate with an electrolytic plating solution comprising (a) a source of deposition metal ions of a deposition metal selected from the group consisting of zinc, palladium, silver, nickel, copper, gold, platinum, rhodium, ruthenium, chrome, and alloys thereof, (b) a pre-mixed dispersion of non-metallic nano-particles, wherein the non-metallic particles have a pre-mix coating of surfactant molecules thereon; and applying an external source of electrons to the electrolytic plating solution to thereby electrolytically deposit a metal-based composite coating comprising the deposition metal and non-metallic nano-particles onto the surface.

    摘要翻译: 提供了一种赋予衬底表面的耐腐蚀性的方法。 该方法包括使基板的表面与电解电镀溶液接触,所述电解电镀溶液包括(a)选自锌,钯,银,镍,铜,金,铂,铑等的沉积金属的沉积金属离子源, 钌,铬及其合金,(b)非金属纳米颗粒的预混合分散体,其中所述非金属颗粒在其上具有表面活性剂分子的预混合涂层; 以及将外部电子源施加到所述电解电镀溶液中,从而将包含所述沉积金属和非金属纳米颗粒的金属基复合涂层电沉积到所述表面上。

    METALLIC SURFACE ENHANCEMENT
    16.
    发明申请
    METALLIC SURFACE ENHANCEMENT 有权
    金属表面增强

    公开(公告)号:US20080261025A1

    公开(公告)日:2008-10-23

    申请号:US11736647

    申请日:2007-04-18

    IPC分类号: B32B15/04 B05D5/12 C04B9/02

    摘要: A method and composition for enhancing corrosion resistance, wear resistance, and contact resistance of a device comprising a copper or copper alloy substrate and at least one metal-based layer on a surface of the substrate. The composition comprises a phosphorus oxide compound selected from the group consisting of a phosphonic acid, a phosphonate salt, a phosphonate ester, a phosphoric acid, a phosphate salt, a phosphate ester, and mixtures thereof; an aromatic heterocycle comprising nitrogen; and a solvent having a surface tension less than about 50 dynes/cm as measured at 25° C.

    摘要翻译: 一种用于提高包含铜或铜合金基底和至少一种金属基层在该基底表面上的装置的耐腐蚀性,耐磨性和接触电阻的方法和组合物。 该组合物包含选自膦酸,膦酸盐,膦酸酯,磷酸,磷酸盐,磷酸酯及其混合物的磷氧化物化合物; 包含氮的芳族杂环; 和在25℃下测得的表面张力小于约50达因/厘米的溶剂

    METALLIC SURFACE ENHANCEMENT
    20.
    发明申请
    METALLIC SURFACE ENHANCEMENT 有权
    金属表面增强

    公开(公告)号:US20100151263A1

    公开(公告)日:2010-06-17

    申请号:US12596559

    申请日:2008-04-18

    IPC分类号: B32B15/04

    摘要: A method and composition for enhancing corrosion resistance, wear resistance, and contact resistance of a device comprising a copper or copper alloy substrate and at least one metal-based layer on a surface of the substrate. The composition comprises a phosphorus oxide compound selected from the group consisting of a phosphonic acid, a phosphonate salt, a phosphonate ester, a phosphoric acid, a phosphate salt, a phosphate ester, and mixtures thereof; an organic compound comprising a nitrogen-containing functional group; and a solvent having a surface tension less than about 50 dynes/cm as measured at 25° C.

    摘要翻译: 一种用于提高包含铜或铜合金基底和至少一种金属基层在该基底表面上的装置的耐腐蚀性,耐磨性和接触电阻的方法和组合物。 该组合物包含选自膦酸,膦酸盐,膦酸酯,磷酸,磷酸盐,磷酸酯及其混合物的磷氧化物化合物; 包含含氮官能团的有机化合物; 和在25℃下测得的表面张力小于约50达因/厘米的溶剂