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11.发明授权Stabilized boehmite-derived catalyst supports, catalysts, methods of making and using 有权稳定的勃姆石衍生的催化剂载体，催化剂，制备和使用方法公开(公告)号：US07449496B2
公开(公告)日：2008-11-11
申请号：US11875484
申请日：2007-10-19
Applicant: Yaming Jin , Kandaswamy Jothimurugesan , Kristi A. Fjare , J. Dale Ortego, Jr. , Beatrice C. Ortego , Rafael L. Espinoza
Inventor： Yaming Jin , Kandaswamy Jothimurugesan , Kristi A. Fjare , J. Dale Ortego, Jr. , Beatrice C. Ortego , Rafael L. Espinoza
CPC classification number: B01J37/0207 , B01J21/04 , B01J21/12 , B01J23/40 , B01J23/74 , B01J23/8913 , B01J32/00 , B01J35/006 , B01J35/023 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/0045 , B82Y30/00 , C01F7/442 , C01P2002/60 , C01P2002/72 , C01P2004/64 , C01P2006/13 , C01P2006/14 , C01P2006/16 , C10G2/33 , C10G2/332 , C10G2300/70
Abstract: A stabilized catalyst support having improved hydrothermal stability, catalyst made therefrom, and method for producing hydrocarbons from synthesis gas using said catalyst. The stabilized support is made by a method comprising treating a crystalline hydrous alumina precursor in contact with at least one structural stabilizer or compound thereof. The crystalline hydrous alumina precursor preferably includes an average crystallite size selected from an optimum range delimited by desired hydrothermal resistance and desired porosity. The crystalline hydrous alumina precursor preferably includes an alumina hydroxide, such as crystalline boehmite, crystalline bayerite, or a plurality thereof differing in average crystallite sizes by at least about 1 nm. The crystalline hydrous alumina precursor may be shaped before or after contact with the structural stabilizer or compound thereof. The treating includes calcining at 450° C. or more. Preferred structural stabilizers can include cobalt, magnesium, manganese, manganese, zirconium, boron, aluminum, barium, silicon, lanthanum, oxides thereof, or combinations thereof.
Abstract translation: 具有改进的水热稳定性的稳定的催化剂载体，由其制备的催化剂，以及使用所述催化剂从合成气生产烃的方法。 稳定的载体通过包括处理与至少一种结构稳定剂或其化合物接触的结晶含水氧化铝前体的方法制备。 结晶含水氧化铝前体优选包括平均微晶尺寸，其选自由期望的耐热热性和所需孔隙率限定的最佳范围。 结晶含水氧化铝前体优选包括平均微晶尺寸不同至少约1nm的氧化铝氢氧化物，例如结晶勃姆石，结晶三羟铝石或其多个。 结晶含水氧化铝前体可以在与结构稳定剂或其化合物接触之前或之后成型。 处理包括在450℃或更高温度下煅烧。 优选的结构稳定剂可包括钴，镁，锰，锰，锆，硼，铝，钡，硅，镧，氧化物或其组合。
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公开(公告)号：US07341976B2
公开(公告)日：2008-03-11
申请号：US11114804
申请日：2005-04-26
Applicant: Rafael L. Espinoza , Kandaswamy Jothimurugesan , Yaming Jin , J. Dale Ortego, Jr. , Kristi A. Fjare , Beatrice C. Ortego
Inventor： Rafael L. Espinoza , Kandaswamy Jothimurugesan , Yaming Jin , J. Dale Ortego, Jr. , Kristi A. Fjare , Beatrice C. Ortego
CPC classification number: B01J37/0207 , B01J21/04 , B01J21/12 , B01J23/40 , B01J23/74 , B01J23/8913 , B01J32/00 , B01J35/006 , B01J35/023 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/0045 , B82Y30/00 , C01F7/442 , C01P2002/60 , C01P2002/72 , C01P2004/64 , C01P2006/13 , C01P2006/14 , C01P2006/16 , C10G2/33 , C10G2/332 , C10G2300/70
Abstract: A stabilized catalyst support having improved hydrothermal stability, catalyst made therefrom, and method for producing hydrocarbons from synthesis gas using said catalyst. The stabilized support is made by a method comprising treating a crystalline hydrous alumina precursor in contact with at least one structural stabilizer or compound thereof. The crystalline hydrous alumina precursor preferably includes an average crystallite size selected from an optimum range delimited by desired hydrothermal resistance and desired porosity. The crystalline hydrous alumina precursor preferably includes an alumina hydroxide, such as crystalline boehmite, crystalline bayerite, or a plurality thereof differing in average crystallite sizes by at least about 1 nm. The crystalline hydrous alumina precursor may be shaped before or after contact with the structural stabilizer or compound thereof. The treating includes calcining at 450° C. or more. Preferred structural stabilizers can include cobalt, magnesium, manganese, manganese, zirconium, boron, aluminum, barium, silicon, lanthanum, oxides thereof, or combinations thereof.
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公开(公告)号：US20080039539A1
公开(公告)日：2008-02-14
申请号：US11875484
申请日：2007-10-19
Applicant: Rafael Espinoza , Kandaswamy Jothimurugesan , Yaming Jin , J. Ortego , Kristi Fjare , Beatrice Ortego
Inventor： Rafael Espinoza , Kandaswamy Jothimurugesan , Yaming Jin , J. Ortego , Kristi Fjare , Beatrice Ortego
CPC classification number: B01J37/0207 , B01J21/04 , B01J21/12 , B01J23/40 , B01J23/74 , B01J23/8913 , B01J32/00 , B01J35/006 , B01J35/023 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/0045 , B82Y30/00 , C01F7/442 , C01P2002/60 , C01P2002/72 , C01P2004/64 , C01P2006/13 , C01P2006/14 , C01P2006/16 , C10G2/33 , C10G2/332 , C10G2300/70
Abstract: A stabilized catalyst support having improved hydrothermal stability, catalyst made therefrom, and method for producing hydrocarbons from synthesis gas using said catalyst. The stabilized support is made by a method comprising treating a crystalline hydrous alumina precursor in contact with at least one structural stabilizer or compound thereof. The crystalline hydrous alumina precursor preferably includes an average crystallite size selected from an optimum range delimited by desired hydrothermal resistance and desired porosity. The crystalline hydrous alumina precursor preferably includes an alumina hydroxide, such as crystalline boehmite, crystalline bayerite, or a plurality thereof differing in average crystallite sizes by at least about 1 nm. The crystalline hydrous alumina precursor may be shaped before or after contact with the structural stabilizer or compound thereof. The treating includes calcining at 450° C. or more. Preferred structural stabilizers can include cobalt, magnesium, manganese, manganese, zirconium, boron, aluminum, barium, silicon, lanthanum, oxides thereof, or combinations thereof.
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公开(公告)号：US07323100B2
公开(公告)日：2008-01-29
申请号：US11180089
申请日：2005-07-13
Applicant: Rafael L. Espinoza , Keith H. Lawson , Kandaswamy Jothimurugesan
Inventor： Rafael L. Espinoza , Keith H. Lawson , Kandaswamy Jothimurugesan
CPC classification number: B01J37/036 , B01J21/12 , B01J23/24 , B01J23/40 , B01J23/42 , B01J23/652 , B01J23/85 , B01J23/89 , B01J35/0006 , B01J35/002 , B01J35/0066 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/04 , C10G2/32 , C10G47/02 , C10G47/04 , C10G47/12 , C10G47/14
Abstract: An amorphous support, methods for making the same and methods of using, particularly in hydrocracking. A method of making may comprise mixing a first amorphous material and a second amorphous material of different acidities to form a mixture, and treating by either separately treating the first and second amorphous materials before mixing or treating the mixture, so as to form an amorphous catalyst support. Treating preferably includes calcining. The acidity of the amorphous support may be modified by the different acidities of the precursor amorphous materials, their proportions in the mixture, and/or the order of the mixing and treating steps. A method of use may comprise reacting a hydrocarbon fraction with hydrogen over a hydrocracking catalyst comprising the amorphous catalyst support to form a hydrocracked product. Further embodiments include the first and second amorphous materials comprising silica-alumina, and/or differing in Brönsted acidity, Lewis acidity, or acidity index.
Abstract translation: 无定形支撑物，制备方法和使用方法，特别是在加氢裂化中。 制备方法可以包括混合不同酸度的第一无定形材料和第二无定形材料以形成混合物，并且在混合或处理混合物之前单独处理第一和第二非晶材料进行处理，以形成无定形催化剂 支持。 处理优选包括煅烧。 无定形载体的酸度可以通过前体无定形材料的不同酸度，它们在混合物中的比例和/或混合和处理步骤的顺序来改变。 使用的方法可以包括使烃馏分与氢气在包含无定形催化剂载体的加氢裂化催化剂上反应以形成加氢裂化产物。 另外的实施方案包括包含二氧化硅 - 氧化铝的第一和第二无定形材料和/或布朗斯台德酸度，路易斯酸度或酸度指数不同。
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15.发明授权Attrition resistant bulk iron catalysts and processes for preparing and using same 有权耐磨散体铁催化剂及其制备和使用方法公开(公告)号：US07259286B2
公开(公告)日：2007-08-21
申请号：US10344896
申请日：2001-08-28
Applicant: Kandaswamy Jothimurugesan , James G. Goodwin, Jr. , Santosh K. Gangwal
Inventor： Kandaswamy Jothimurugesan , James G. Goodwin, Jr. , Santosh K. Gangwal
CPC classification number: C10G2/332 , B01J21/08 , B01J23/745 , B01J23/78 , B01J27/22 , B01J35/002 , B01J35/0026 , B01J35/08 , B01J35/1014 , B01J35/1019 , B01J37/0009 , B01J37/0045 , B01J37/03 , B01J37/08 , C01B3/16 , C01B2203/0283 , C01B2203/1047 , Y02P20/52
Abstract: An attrition resistant precipitated bulk iron catalyst is prepared from iron oxide precursor and a binder by spray drying. The catalysts are preferably used in carbon monoxide hydrogenation processes such as Fischer-Tropsch synthesis. These catalysts are suitable for use in fluidized-bed reactors, transport reactors and, especially, slurry bubble column reactors.
Abstract translation: 通过喷雾干燥由氧化铁前体和粘合剂制备耐磨耗的沉淀体铁催化剂。 催化剂优选用于一氧化碳氢化方法如费 - 托合成。 这些催化剂适用于流化床反应器，运输反应器，特别是浆液鼓泡塔反应器。
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Patent Agency Ranking
16.发明授权公开(公告)号：US07176160B2
公开(公告)日：2007-02-13
申请号：US10688412
申请日：2003-10-16
Applicant: Rafael L. Espinoza , Kandaswamy Jothimurugesan , Yaming Jin
Inventor： Rafael L. Espinoza , Kandaswamy Jothimurugesan , Yaming Jin
CPC classification number: C10G2/332 , B01J21/04 , B01J23/74 , B01J23/75 , B01J23/8913 , B01J37/0045 , B01J37/0201 , B01J37/0205 , B01J37/0207
Abstract: A method is provided for forming a highly active Fischer-Tropsch catalyst using boehmite having a particular crystallite size. In this method, a support material comprising boehmite is contacted with a catalytic metal-containing compound to form a catalyst precursor. The boehmite is selected to have an average crystallite size in the range of from about 6 nanometers (nm) to about 30 nm. An alternate embodiment uses a mixture of boehmites with various average crystallite sizes in the range of from about 4 nm to about 30 nm, differing by at least by 1 nm. Subsequently, the catalyst precursor is calcined to convert the boehmite to a stabilized aluminum oxide structure, thereby forming a catalyst support having a good attrition resistance and a relatively high hydrothermal stability.
Abstract translation: 提供了使用具有特定微晶尺寸的勃姆石形成高活性费 - 托催化剂的方法。 在该方法中，将包含勃姆石的载体材料与含催化金属的化合物接触以形成催化剂前体。 勃姆石被选择为具有在约6纳米（nm）至约30nm范围内的平均微晶尺寸。 替代实施例使用具有在约4nm至约30nm范围内的各种平均微晶尺寸的勃氏混合物，至少不同于1nm。 随后，将催化剂前体煅烧以将勃姆石转化为稳定的氧化铝结构，从而形成具有良好耐磨性和较高水热稳定性的催化剂载体。
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17.发明申请Stabilized boehmite-derived catalyst supports, catalysts, methods of making and using 有权稳定的勃姆石衍生的催化剂载体，催化剂，制备和使用方法公开(公告)号：US20050234137A1
公开(公告)日：2005-10-20
申请号：US11114804
申请日：2005-04-26
Applicant: Rafael Espinoza , Kandaswamy Jothimurugesan , Yaming Jin , J. Ortego , Kristi Fjare , Beatrice Ortego
Inventor： Rafael Espinoza , Kandaswamy Jothimurugesan , Yaming Jin , J. Ortego , Kristi Fjare , Beatrice Ortego
CPC classification number: B01J37/0207 , B01J21/04 , B01J21/12 , B01J23/40 , B01J23/74 , B01J23/8913 , B01J32/00 , B01J35/006 , B01J35/023 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/0045 , B82Y30/00 , C01F7/442 , C01P2002/60 , C01P2002/72 , C01P2004/64 , C01P2006/13 , C01P2006/14 , C01P2006/16 , C10G2/33 , C10G2/332 , C10G2300/70
Abstract: A stabilized catalyst support having improved hydrothermal stability, catalyst made therefrom, and method for producing hydrocarbons from synthesis gas using said catalyst. The stabilized support is made by a method comprising treating a crystalline hydrous alumina precursor in contact with at least one structural stabilizer or compound thereof. The crystalline hydrous alumina precursor preferably includes an average crystallite size selected from an optimum range delimited by desired hydrothermal resistance and desired porosity. The crystalline hydrous alumina precursor preferably includes an alumina hydroxide, such as crystalline boehmite, crystalline bayerite, or a plurality thereof differing in average crystallite sizes by at least about 1 nm. The crystalline hydrous alumina precursor may be shaped before or after contact with the structural stabilizer or compound thereof. The treating includes calcining at 450° C. or more. Preferred structural stabilizers can include cobalt, magnesium, manganese, manganese, zirconium, boron, aluminum, barium, silicon, lanthanum, oxides thereof, or combinations thereof.
Abstract translation: 具有改进的水热稳定性的稳定的催化剂载体，由其制备的催化剂，以及使用所述催化剂从合成气生产烃的方法。 稳定的载体通过包括处理与至少一种结构稳定剂或其化合物接触的结晶含水氧化铝前体的方法制备。 结晶含水氧化铝前体优选包括平均微晶尺寸，其选自由期望的耐热热性和所需孔隙率限定的最佳范围。 结晶含水氧化铝前体优选包括平均微晶尺寸不同至少约1nm的氧化铝氢氧化物，例如结晶勃姆石，结晶三羟铝石或其多个。 结晶含水氧化铝前体可以在与结构稳定剂或其化合物接触之前或之后成型。 处理包括在450℃或更高温度下煅烧。 优选的结构稳定剂可包括钴，镁，锰，锰，锆，硼，铝，钡，硅，镧，氧化物或其组合。
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18.发明申请公开(公告)号：US20050096215A1
公开(公告)日：2005-05-05
申请号：US10699018
申请日：2003-10-31
Applicant: Rafael Espinoza , Harold Wright , Tianyan Niu , Kandaswamy Jothimurugesan
Inventor： Rafael Espinoza , Harold Wright , Tianyan Niu , Kandaswamy Jothimurugesan
IPC: B01J23/10 , B01J23/46 , B01J23/63 , B01J35/00 , C01B3/38 , C01B3/40 , B01J21/18 , B01J21/08 , B01J21/12 , C01B3/32
CPC classification number: C01B3/40 , B01J23/10 , B01J23/464 , B01J23/63 , B01J35/0006 , C01B3/386 , C01B2203/0261 , C01B2203/1041 , C01B2203/1047 , C01B2203/1082 , C01B2203/1094 , C01B2203/1241 , Y02P20/52
Abstract: A catalytic partial oxidation process for producing synthesis gas is disclosed which comprises passing a light hydrocarbon and oxygen mixture over a composite catalyst to produce a mixture of carbon monoxide and hydrogen. Preferred composite catalysts are prepared by mixing together discrete particles of catalytic metal and of promoter. The resulting catalyst resists deactivation due to reaction between the active metal and the promoter. A catalyst and method for making a catalyst and a method for making middle distillates from light hydrocarbons are also disclosed.
Abstract translation: 公开了用于生产合成气的催化部分氧化方法，其包括使轻烃和氧混合物在复合催化剂上通过以产生一氧化碳和氢气的混合物。 优选的复合催化剂通过将催化金属和促进剂的离散颗粒混合在一起来制备。 所得催化剂由于活性金属和助催化剂之间的反应而抵抗失活。 还公开了催化剂和制备催化剂的方法以及从轻质烃制备中间馏分的方法。
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19.发明授权Attrition resistant catalysts and sorbents based on heavy metal poisoned FCC catalysts 失效基于重金属中毒FCC催化剂的耐磨催化剂和吸附剂
公开(公告)号：US5928980A
公开(公告)日：1999-07-27
申请号：US795669
申请日：1997-02-06
Applicant: Santosh Gangwal , Kandaswamy Jothimurugesan
Inventor： Santosh Gangwal , Kandaswamy Jothimurugesan
IPC: B01J20/02 , B01J20/06 , B01J20/32 , B01J23/22 , B01J23/755 , B01J23/94 , C10G2/00 , C10G49/02 , C10K1/32 , C10K1/34 , B01J20/34
CPC classification number: C10G2/33 , B01J20/02 , B01J20/06 , B01J20/16 , B01J20/18 , B01J20/28057 , B01J20/3078 , B01J20/3204 , B01J20/3236 , B01J20/3433 , B01J20/3458 , B01J20/3483 , B01J23/22 , B01J23/755 , B01J23/94 , C10G49/02 , C10K1/32 , C10K1/34 , B01J2220/42 , Y02P20/584
Abstract: A heavy metal poisoned, spent FCC catalyst is treated by chemically impregnating the poisoned catalyst with a new catalytic metal or metal salt to provide an attrition resistant catalyst or sorbent for a different catalytic or absorption processes, such as catalysts for Fischer-Tropsh Synthesis, and sorbents for removal of sulfur gasses from fuel gases and flue-gases. The heavy metal contaminated FCC catalyst is directly used as a support for preparing catalysts having new catalytic properties and sorbents having new sorbent properties, without removing or "passivating" the heavy metals on the spent FCC catalyst as an intermediate step.
Abstract translation: 重金属中毒，废FCC催化剂通过用新的催化金属或金属盐化学浸渍中毒的催化剂来处理，以提供用于不同催化或吸收方法的耐磨催化剂或吸附剂，例如用于费 - 托罗合成的催化剂，和 用于从燃料气体和烟道气中去除硫气的吸附剂。 重金属污染的FCC催化剂直接用作制备具有新吸附剂性能的催化剂的载体和具有新的吸附剂性质的吸附剂，而不用去除或“钝化”废催化剂催化剂上的重金属作为中间步骤。
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公开(公告)号：US20160067687A1
公开(公告)日：2016-03-10
申请号：US14482361
申请日：2014-09-10
Applicant: Kandaswamy Jothimurugesan
Inventor： Kandaswamy Jothimurugesan
IPC: B01J27/198 , C10G2/00 , B01J37/02 , B01J37/08 , B01J37/18
CPC classification number: B01J27/198 , B01J33/00 , B01J35/006 , B01J35/023 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0203 , B01J37/024 , B01J37/08 , B01J37/18 , B01J2523/00 , C10G2/331 , C10G2/333 , B01J2523/31 , B01J2523/3706 , B01J2523/828 , B01J2523/845
Abstract: A process has been developed for preparing a Fischer-Tropsch catalyst precursor and a Fischer-Tropsch catalyst made from the precursor. The process includes contacting a gamma alumina catalyst support material with a first solution containing a vanadium compound and a phosphorus compound, to obtain a modified catalyst support material. The modified catalyst support material is calcined at a temperature of at least 500° C. The calcined modified catalyst support has a pore volume of at least 0.4 cc/g. The modified catalyst support is less soluble in acid solutions than an equivalent unmodified catalyst support. The modified catalyst support is contacted with a second solution which includes a precursor compound of an active cobalt catalyst component and an organic compound, preferably glutaric acid, to obtain a catalyst precursor. The catalyst precursor is reduced to activate the catalyst precursor to obtain the Fischer-Tropsch catalyst. The catalyst has enhanced hydrothermal stability as measured by losing no more than 10% of its pore volume when exposed to water vapor. The catalyst has Co3O4 crystallites having an average size of no greater than 20 nm. As a result, the catalyst has good activity.
Abstract translation: 已经开发了制备费 - 托催化剂前体和由前体制备的费 - 托催化剂的方法。 该方法包括使γ氧化铝催化剂载体材料与含有钒化合物和磷化合物的第一溶液接触，以获得改性的催化剂载体材料。 改性的催化剂载体材料在至少500℃的温度下煅烧。煅烧的改性催化剂载体的孔体积至少为0.4cc / g。 改性的催化剂载体在酸溶液中比相当的未改性的催化剂载体更难溶解。 改性的催化剂载体与包含活性钴催化剂组分的前体化合物和有机化合物，优选戊二酸的第二溶液接触，以获得催化剂前体。 催化剂前体被还原以活化催化剂前体以获得费 - 托催化剂。 催化剂具有增强的水热稳定性，当暴露于水蒸气时，其通过损失不超过其孔体积的10％来测量。 催化剂具有平均粒度不大于20nm的Co 3 O 4微晶。 结果，催化剂具有良好的活性。
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