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    Fluorine-containing polymer having acid-reactive group and chemically amplifying type photoresist composition prepared from same
    22.
    发明授权
    Fluorine-containing polymer having acid-reactive group and chemically amplifying type photoresist composition prepared from same 有权
    具有酸反应性基团的含氟聚合物和由其制备的化学放大型光致抗蚀剂组合物

    公开(公告)号：US06908724B2

    公开(公告)日：2005-06-21

    申请号：US10262893

    申请日：2002-10-03

    申请人： Takayuki Araki ,  Meiten Koh ,  Yoshito Tanaka ,  Takuji Ishikawa ,  Hirokazu Aoyama ,  Tetsuo Shimizu

    发明人： Takayuki Araki ,  Meiten Koh ,  Yoshito Tanaka ,  Takuji Ishikawa ,  Hirokazu Aoyama ,  Tetsuo Shimizu

    IPC分类号： G03F7/004 ,  G03F7/038 ,  G03F7/039 ,  G03F7/075

    CPC分类号： G03F7/039 ,  G03F7/0045 ,  G03F7/0046 ,  G03F7/0382 ,  G03F7/0392 ,  G03F7/0395 ,  G03F7/0397 ,  G03F7/0758 ,  Y10S430/106 ,  Y10S430/108

    摘要： There is provided a novel fluorine-containing polymer having an acid-reactive group which has a high transparency against energy rays (radioactive rays) in a vacuum ultraviolet region (157 nm), and further there are provided a material for fluorine-containing base polymer prepared from the polymer and suitable for a photoresist and a chemically amplifying type resist composition obtained therefrom.The polymer has a number average molecular weight of from 1,000 to 1,000,000 and represented by the formula: —(M1)—(M2)—(A)—, wherein M1 is a structural unit having an acid-labile or acid-degradable functional group, M2 is a structural unit of fluorine-containing acryl ester, A is a structural unit derived from other copolymerizable monomer, the percent by mole ratio M1/M2 is 1 to 99/99 to 1 and the polymer comprises from 1 to 99% by mole of the structural unit M1, from 1 to 99% by mole of the structural unit M2 and from 0 to 98% by mole of the structural unit A1. The material for fluorine-containing base polymer comprises a fluorine-containing polymer having an acid-reactive group such as the above-mentioned polymer and is suitable for a photoresist, and the chemically amplifying type resist composition is obtained from those polymer and material.

    摘要翻译： 提供了一种具有酸反应性基团的新型含氟聚合物，其具有对真空紫外区域（157nm）中的能量射线（放射线）的高透明性，并且还提供了含氟基础聚合物 由聚合物制备并适用于由其获得的光致抗蚀剂和化学放大型抗蚀剂组合物。 聚合物的数均分子量为1,000〜1,000,000，由下式表示： - （M1） - （M2） - （A） - ，其中M1是具有酸不稳定性或酸可降解官能团的结构单元 M2是含氟丙烯酸酯的结构单元，A是来自其它可共聚单体的结构单元，M1 / M2的摩尔比为1〜99/99〜1，聚合物的含量为1〜99％ 结构单元M1的摩尔数，结构单元M2的1〜99摩尔％和结构单元A1的0〜98摩尔％。 含氟基础聚合物的材料包括具有酸反应性基团的含氟聚合物如上述聚合物，并且适用于光致抗蚀剂，化学放大型抗蚀剂组合物由那些聚合物和材料获得。

    Molding material for ozone-resistant articles and ozone-resistant injection-molded articles
    23.
    发明申请
    Molding material for ozone-resistant articles and ozone-resistant injection-molded articles 有权
    耐臭氧制品成型材料和耐臭氧注塑制品

    公开(公告)号：US20050020792A1

    公开(公告)日：2005-01-27

    申请号：US10497586

    申请日：2002-12-04

    申请人： Takahisa Aoyama ,  Katsuhide Ohtani ,  Hitoshi Imamura ,  Tetsuo Shimizu

    发明人： Takahisa Aoyama ,  Katsuhide Ohtani ,  Hitoshi Imamura ,  Tetsuo Shimizu

    IPC分类号： C08F8/22 ,  C08F16/24

    CPC分类号： C08F8/22 ,  C08F214/262

    摘要： The present invention provides highly ozone-resistant molding/shaped articles inclusive of piping materials and joints for use in semiconductor production lines, molding materials for ozone-resistant molding/shaped articles which are suited for the production of said molding/shaped articles, and ozone-resistant injection-molded articles and relevant injection-molding materials. The present invention is directed to a molding material for ozone-resistant molding/shaped articles comprising a copolymer (A) and having a melt flow rate of 0.1-50 g/10 minutes, wherein said copolymer (A) is a copolymer comprising tetrafluoroethylene and a perfluorovinylether, and has not less than 3.5 mass % of a perfluorovinylether unit, a melting point of not less than 295° C., and not more than 50 of unstable terminal groups per 1×106 carbon atoms in said copolymer (A)

    摘要翻译： 本发明提供高度耐臭氧的成型制品，其中包括用于半导体生产线的管道材料和接头，适用于生产所述成型制品的耐臭氧成型/成型制品的成型材料和臭氧 耐注射成型制品和相关的注射成型材料。 本发明涉及一种包含共聚物（A），熔体流动速率为0.1-50g / 10分钟的耐臭氧成型制品的成型材料，其中所述共聚物（A）是包含四氟乙烯和 全氟乙烯基醚，并且在所述共聚物（A）中具有不小于3.5质量％的全氟乙烯基单元，熔点不低于295℃，不超过50个不稳定的端基，每1×10 6个碳原子，

    Methods for providing low-molecular radicals, radical-carrying molecules, a polymerization catalyst containing them and processes for polymerization and polymers produced thereby
    25.
    发明授权
    Methods for providing low-molecular radicals, radical-carrying molecules, a polymerization catalyst containing them and processes for polymerization and polymers produced thereby 有权
    提供低分子基团，自由基携带分子，含有它们的聚合催化剂和聚合方法以及由此制备的聚合物的方法

    公开(公告)号：US06818800B2

    公开(公告)日：2004-11-16

    申请号：US10291650

    申请日：2002-11-12

    申请人： Taizo Ono ,  Eiji Hayashi ,  Haruhiko Fukaya ,  Tetsuo Shimizu

    发明人： Taizo Ono ,  Eiji Hayashi ,  Haruhiko Fukaya ,  Tetsuo Shimizu

    IPC分类号： C07C2118

    CPC分类号： C07C17/04 ,  C07C17/263 ,  C07C17/32 ,  C08F4/00 ,  C07C19/08 ,  C07C21/18 ,  C07C22/08

    摘要： The present invention is to provide a method for providing a low-molecular radical which comprises releasing a radical having a lower molecular weight from a super-stable perfluoroalkyl-based radical followed by generating the above super-stable perfluoroalkyl-based radical. The invention is a method for providing a low-molecular radical which comprises a super-stable radical generating reaction for generating a super-stable perfluoroalkyl-based radical from a radical-carrying molecule and a radical releasing reaction for releasing the low-molecular radical from said super-stable perfluoroalkyl-based radical, said radical-carrying molecule being generated as a result of said radical releasing reaction.

    摘要翻译： 本发明提供一种提供低分子量基团的方法，其包括从超稳定的全氟烷基基团释放具有较低分子量的基团，然后产生上述超稳定的全氟烷基基团。本发明是 一种提供低分子量的方法，其包括用于从自由基携带分子产生超稳定全氟烷基基团的超稳定自由基产生反应和用于从所述超分子自由基释放低分子量的自由基释放反应， 稳定的全氟烷基基团，所述自由基携带分子是由于所述自由基释放反应产生的。

    High-ductility steel sheet excellent in press formability and strain age hardenability, and method for manufacturing the same
    26.
    发明授权
    High-ductility steel sheet excellent in press formability and strain age hardenability, and method for manufacturing the same 失效
    压制成形性和应变时效淬透性优异的高延展性钢板及其制造方法

    公开(公告)号：US06818074B2

    公开(公告)日：2004-11-16

    申请号：US10163728

    申请日：2002-06-06

    申请人： Saiji Matsuoka ,  Tetsuo Shimizu ,  Kei Sakata ,  Osamu Furukimi

    发明人： Saiji Matsuoka ,  Tetsuo Shimizu ,  Kei Sakata ,  Osamu Furukimi

    IPC分类号： C22C3802

    CPC分类号： C22C38/02 ,  C21D8/0226 ,  C21D8/0236 ,  C21D8/0273 ,  C21D8/0278 ,  C22C38/04 ,  C22C38/12 ,  C22C38/16 ,  C23C2/02 ,  C23C2/28 ,  Y10T428/12799

    摘要： A steel sheet composition contains appropriate amounts of C, Si, Mn, P, S, Al and N and 0.5 to 3.0% Cu. A composite structure of the steel sheet has a ferrite phase or a ferrite phase and a tempered martensite phase as a primary phase, and a secondary phase containing retained austenite in a volume ratio of not less than 1%. In place of the Cu, at least one of Mo, Cr, and W may be contained in a total amount of not more than 2.0%. This composition is useful in production of a high-ductility hot-rolled steel sheet, a high-ductility cold-rolled steel sheet and a high-ductility hot-dip galvanized steel sheet having excellent press formability and excellent stain age hardenability as represented by a &Dgr;TS of not less than 80 MPa, in which the tensile strength increases remarkably through a heat treatment at a relatively low temperature after press forming.

    摘要翻译： 钢板组合物含有适量的C，Si，Mn，P，S，Al和N以及0.5〜3.0％的Cu。 钢板的复合结构具有铁素体相或铁素体相，回火马氏体相作为主相，第二相含有体积比为1％以上的残留奥氏体。 代替Cu，Mo，Cr和W中的至少一种可以含有不超过2.0％的总量。 该组合物可用于生产高延展性热轧钢板，高延展性冷轧钢板和高延展性热浸镀锌钢板，其具有优异的压制成形性和优异的耐老化淬透性，如 通过压制成形后的较低温度下的热处理，拉伸强度不大于80MPa的ΔTS值。

    Composite materials for cookware
    28.
    发明授权
    Composite materials for cookware 失效
    炊具复合材料

    公开(公告)号：US06737164B2

    公开(公告)日：2004-05-18

    申请号：US09380499

    申请日：1999-09-03

    申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Hisato Sanemasa ,  Tetsuo Shimizu

    发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Hisato Sanemasa ,  Tetsuo Shimizu

    IPC分类号： B32B2708

    CPC分类号： A47J36/02 ,  C08F214/20 ,  C08F216/04 ,  C08F220/00 ,  C09D127/12 ,  C09D127/18 ,  Y10T428/3154 ,  Y10T428/31544

    摘要： Composite materials for cooking apparatuses which are produced by applying, to a substrate, a material comprising a fluorine-containing polymer having an excellent adhesive property to the substrate without necessitating complicated steps and are excellent in heat resistance, non-sticking property, stain-proofing property, water- and oil-repelling property, stain-removing property, chemical resistance, rust-preventing property, antibacterial property, resistance to energy ray and abrasion resistance. The composite materials for cooking apparatuses are produced by applying, to the substrate, the material comprising a fluorine-containing ethylenic polymer having functional group which is prepared by copolymerizing (a) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, and (b) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers having no functional group mentioned above.

    摘要翻译： 用于烹饪设备的复合材料是通过向衬底施加包含具有优异粘合性的含氟聚合物的材料而制成的，而不需要复杂的步骤，并且具有优异的耐热性，不粘附性，防污染性 性能，防油和排斥性能，去污性，耐化学腐蚀性，防锈性，抗菌性，耐光能和耐磨性。 用于烹饪设备的复合材料是通过向基材施加含有具有官能团的含氟乙烯性聚合物的材料制造的，所述官能团通过使（a）0.05〜30摩尔％的含氟乙烯性聚合物中的至少一种 具有选自羟基，羧基，羧酸盐基，羧酸酯基和环氧基中的至少一种官能团的单体，和（b）70〜99.95摩尔％的至少一种含氟乙烯性单体， 没有上述功能组。

    Antireflection article
    30.
    发明授权
    Antireflection article 失效
    防反射制品

    公开(公告)号：US06383620B1

    公开(公告)日：2002-05-07

    申请号：US09242344

    申请日：1999-03-15

    申请人： Takahisa Aoyama ,  Tetsuo Shimizu ,  Norihito Otsuki ,  Norio Nagahama

    发明人： Takahisa Aoyama ,  Tetsuo Shimizu ,  Norihito Otsuki ,  Norio Nagahama

    IPC分类号： B32B502

    CPC分类号： G02B1/14 ,  G02B1/105 ,  G02B1/111 ,  Y10T428/24942 ,  Y10T428/265 ,  Y10T428/3154 ,  Y10T428/31935

    摘要： An antiglare-treated article comprising an acrylic resin substrate and a fluorine-containing polymer coating formed on the surface of the substrate, wherein the thickness of the coating is in the range between 0.03 and 0.5 &mgr;m, and the fluorine-containing polymer has a refractive index in the range between 1.30 and 1.40 and comprises a block which is compatible with the acrylic resin and a block comprising a fluorine-containing elastomer. This treated article can be stably produced at low costs although it has the same abrasion resistance and antiglare effects as those of conventional antiglare-treated articles, or it has better antiglare effects than conventional antiglare films while maintaining abrasion resistance.

    摘要翻译： 一种抗眩光处理制品，其包含丙烯酸树脂基材和形成在基材表面上的含氟聚合物涂层，其中涂层的厚度在0.03-0.5μm之间，含氟聚合物具有折射率 指数在1.30和1.40之间的范围内，并且包括与丙烯酸树脂相容的块和包含含氟弹性体的嵌段。 该处理品能够以低成本稳定地制造，但是与传统的防眩光处理制品具有相同的耐磨性和防眩光效果，或者在保持耐磨性的同时具有比常规防眩光膜更好的防眩光效果。