摘要:
A particulate matter purifying material is used for a filter catalyst for purifying particulate matter that is disposed in an exhaust gas flow path of an internal combustion engine, traps the particulate matter in exhaust gas generated in the internal combustion engine, and burns the particulate matter to be deposited, so as to be regenerated. The particulate matter purifying material includes an oxide containing cerium (Ce) having an oxygen storage-release capacity, and at least one metal (Me) selected from the group consisting of Zr, Y, La, Pr, Sr, Nb and Nd, wherein a content ratio (Ce:Me) of cerium to the metal is 6:4 to 9:1 in terms of an atomic ratio, and a degree of crystallinity (CR) represented by the following formula (1) is within a range of 25 to 60%: Degree of crystallinity(CR)=I/I0×100(%) (1) wherein I represents an X-ray diffraction peak intensity with regard to a (111) plane of a CeO2 phase in the particulate matter purifying material, and I0 represents the X-ray diffraction peak intensity with regard to the (111) plane of the CeO2 phase after the particulate matter purifying material is baked in air at 1000° C.
摘要:
An oxidation catalyst is disclosed, which contains Ce and Ga, and a Ce—Ga composite oxide containing a solid solution in which a part of Ce is substituted with Ga. This oxidation catalyst is obtained in such a manner that pH of a mixed solution obtained by mixing a Ce-containing solution and a Ga-containing solution together is adjusted, and a precipitate obtained by coprecipitating Ce and Ga is dried and baked.
摘要:
A lean NOx trap type exhaust gas purifying catalyst having a catalyst noble metal selected from a group consisting of platinum, palladium and rhodium, an inorganic oxide that carries the catalyst noble metal, and at least one NOx adsorbent one selected from a group of magnesium, barium, sodium, potassium and cesium. The inorganic oxide carrying palladium containing cerium in a CeO2-equivalent quantity in a range of 1 to 20 wt %, and at least one of aluminum and zirconium.
摘要:
A catalyst supporting body has a porous honeycomb base body having a porosity within a range of 40 to 60 vol. %. The body has a plurality of cells partitioned by cell walls arranged in a lattice-like shape. A coated catalyst layer made of a porous body having a void fraction of void spaces within a range of 53 to 63 vol. % is particularly supported on surfaces of the cell walls and in pores formed in the cell walls by a filling rate of not less than 40 vol. %. In an immersing step of a manufacturing method, a combination of a kind of catalyst slurry and the porous honeycomb base body is selected so that a cumulative-frequency at an intersection point between a pore distribution map and a particle size distribution map becomes not less than 80%. The pore distribution map indicates a relationship between pore sizes of pores in the porous honeycomb base body and a cumulative-frequency of the pores. The particle size distribution map indicates a relationship between particle size in the catalyst slurry and a cumulative-frequency of the particles.
摘要:
An exhaust gas purifying system for an automotive internal combustion engine includes a NOx treating catalyst for reducing NOx disposed in an exhaust gas passageway of a combustion device, to reduce NOx in presence of reducing components in exhaust gas. Additionally, a hydrogen enriching device is disposed upstream of said NOx treating catalyst with respect to flow of exhaust gas from the combustion device and arranged to increase a ratio of hydrogen to total reducing components in at least one of combustion gas and exhaust gas so as to meet relations represented by following formulae (1) and (2), when reduction of NOx is carried out by the NOx treating catalyst: [H2/TR]d>[H2/TR]u (1) [H2/TR]d≧0.3 (2) where [H2/TR]u is a ratio between a concentration [H2]u of hydrogen and a concentration [TR]u of total reducing components in at least one of exhaust gas in the exhaust gas passageway upstream of the hydrogen enriching device and combustion gas in a state before undergoing the hydrogen ratio increasing by said hydrogen enriching means; and [H2/TR]d is a ratio between a concentration [H2]d of hydrogen and a concentration [TR]d of total reducing components in exhaust gas in the exhaust gas passageway upstream of the NOx treating catalyst and downstream of the hydrogen enriching device.
摘要:
An oxidation catalyst is disclosed, which contains Ce and Ga, and a Ce—Ga composite oxide containing a solid solution in which a part of Ce is substituted with Ga. This oxidation catalyst is obtained in such a manner that pH of a mixed solution obtained by mixing a Ce-containing solution and a Ga-containing solution together is adjusted, and a precipitate obtained by coprecipitating Ce and Ga is dried and baked.
摘要:
An exhaust gas purifying system for an internal combustion engine mounted on an automotive vehicle. The exhaust gas purifying system may include an exhaust gas component concentration regulating device disposed in an exhaust gas passageway of the engine, for regulating concentrations of gas components in exhaust gas discharged from the engine such that the concentrations of carbon monoxide and hydrogen are respectively not more than 2.0% by volume and not less than 0.5 by volume and such that a volume concentration ratio of hydrogen/carbon monoxide is not smaller than 0.5, in a first exhaust gas condition in which air/fuel ratio of exhaust gas is within a range of from a rich value and a stoichiometric value. Additionally, a NOx adsorbing and reducing catalyst is disposed in the exhaust gas passageway downstream of the exhaust gas component concentration regulating device, for adsorbing nitrogen oxides in a second exhaust gas condition in which the air/fuel ratio of exhaust gas is at a lean value, and reducing the nitrogen oxides into nitrogen in the first exhaust gas condition.
摘要:
A particulate matter purifying material is used for a filter catalyst for purifying particulate matter that is disposed in an exhaust gas flow path of an internal combustion engine, traps the particulate matter in exhaust gas generated in the internal combustion engine, and burns the particulate matter to be deposited, so as to be regenerated. The particulate matter purifying material includes an oxide containing cerium (Ce) having an oxygen storage-release capacity, and at least one metal (Me) selected from the group consisting of Zr, Y, La, Pr, Sr, Nb and Nd, wherein a content ratio (Ce:Me) of cerium to the metal is 6:4 to 9:1 in terms of an atomic ratio, and a degree of crystallinity (CR) represented by the following formula (1) is within a range of 25 to 60%: Degree of crystallinity (CR)=I/I0×100(%) (1) wherein I represents an X-ray diffraction peak intensity with regard to a (111) plane of a CeO2 phase in the particulate matter purifying material, and I0 represents the X-ray diffraction peak intensity with regard to the (111) plane of the CeO2 phase after the particulate matter purifying material is baked in air at 1000° C.
摘要:
A lean NOx trap type exhaust gas purifying catalyst having a catalyst noble metal selected from a group consisting of platinum, palladium and rhodium, an inorganic oxide that carries the catalyst noble metal, and at least one NOx adsorbent one selected from a group of magnesium, barium, sodium, potassium and cesium. The inorganic oxide carrying palladium containing cerium in a CeO2-equivalent quantity in a range of 1 to 20 wt %, and at least one of aluminum and zirconium.