PROCESS FOR PRODUCTION OF HEXAMETHYLENEDIAMINE FROM CARBOHYDRATE-CONTAINING MATERIALS AND INTERMEDIATES THEREFOR
    24.
    发明申请
    PROCESS FOR PRODUCTION OF HEXAMETHYLENEDIAMINE FROM CARBOHYDRATE-CONTAINING MATERIALS AND INTERMEDIATES THEREFOR 有权
    含碳酸酯材料及其中间体生产十六烷二胺的方法

    公开(公告)号:US20170050906A1

    公开(公告)日:2017-02-23

    申请号:US15195349

    申请日:2016-06-28

    Applicant: Rennovia, Inc.

    Abstract: Processes are disclosed for the conversion of a carbohydrate source to hexamethylenediamine (HMDA) and to intermediates useful for the production of hexamethylenediamine and other industrial chemicals. HMDA is produced by direct reduction of a furfural substrate to 1,6-hexanediol in the presence of hydrogen and a heterogeneous reduction catalyst comprising Pt or by indirect reduction of a furfural substrate to 1,6-hexanediol wherein 1,2,6-hexanetriol is produced by reduction of the furfural substrate in the presence of hydrogen and a catalyst comprising Pt and 1,2,6-hexanediol is then converted by hydrogenation in the presence of a catalyst comprising Pt to 1,6 hexanediol, each process then proceding to the production of HMDA by known routes, such as amination of the 1,6 hexanediol. Catalysts useful for the direct and indirect production of 1,6-hexanediol are also disclosed.

    Abstract translation: 公开了用于将碳水化合物源转化为六亚甲基二胺(HMDA)的方法和用于生产六亚甲基二胺和其它工业化学品的中间体。 HMDA通过在氢存在下将糠醛底物直接还原为1,6-己二醇和通过Pt的多相还原催化剂或通过将糠醛底物间接还原成1,6-己二醇来制备,其中1,2,6-己三醇 通过在氢气存在下还原糠醛底物而制备,然后在包含Pt至1,2,6-己二醇的催化剂存在下,通过氢化转化包含Pt和1,2,6-己二醇的催化剂,然后每个过程进行 通过已知途径生产HMDA,如1,6己糖胺的胺化。 还公开了用于直接和间接生产1,6-己二醇的催化剂。

    Process for the separation of mono- and di-carboxylic acid compounds
    25.
    发明授权
    Process for the separation of mono- and di-carboxylic acid compounds 有权
    分离单羧酸和二羧酸化合物的方法

    公开(公告)号:US09487465B2

    公开(公告)日:2016-11-08

    申请号:US13691611

    申请日:2012-11-30

    Applicant: Rennovia, Inc.

    Abstract: The present disclosure relates to processes for the separation of at least one di-carboxylic acid compound and/or at least one mono-carboxylic acid compound from a mixture. The separation processes involve contacting the mixture with an ion exchange medium to cause at least one of the mono- and/or di-carboxylic acid compounds to be retained by the medium, eluting at least one of the mono-carboxylic acid compound or the di-carboxylic acid compound using an eluent to form an eluate, wherein the eluate is enriched in at least one of the mono-carboxylic acid compound or di-carboxylic acid relative to the concentration of such eluted acid in the mixture having contacted the medium and wherein the eluent comprises an organic acid. The process has particular utility in the production of di-carboxylic acid compounds from glucose.

    Abstract translation: 本公开涉及从混合物中分离至少一种二羧酸化合物和/或至少一种单羧酸化合物的方法。 分离过程包括使混合物与离子交换介质接触以使至少一种单羧酸化合物和/或二羧酸化合物由介质保留,至少一种单羧酸化合物或二 - 羧酸化合物,使用洗脱液形成洗脱液,其中洗脱液相对于接触培养基的混合物中这种洗脱酸的浓度富含至少一种单羧酸化合物或二羧酸,并且其中 洗脱液含有机酸。 该方法在从葡萄糖生产二羧酸化合物中具有特殊的用途。

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