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公开(公告)号:US09827179B2
公开(公告)日:2017-11-28
申请号:US14902616
申请日:2014-07-08
Applicant: Stepan Company
Inventor: Irene Shapiro , Dave Allen , Aaron Brown
Abstract: Personal cleansers and surfactant blends useful therein are disclosed. The cleansers comprise a primary anionic surfactant, a saturated C8-C-14 alkyl N,N-dialkylamide, and water. The cleansers have good foaming properties and improved viscosity build profiles compared with cleansers that rely on alkanolamides or betaines as the secondary surfactant. The saturated C8-C14 alkyl N,N-dialkylamides are water-white liquids that solubilize cleanser components well, including high levels of fragrances, and can be formulated easily without heating at any actives level up to 100%. Importantly, the surfactant blends build viscosity with less added salt compared with alkanolamide or betaine-based blends, even with more challenging anionic surfactants. Moisturizing cleansers disclosed herein have excellent flash foaming character, foam volume, and foam feel and provide a luxurious, lotion-like after-feel. The personal cleansers include, among others, shampoos, body washes, facial cleansers, shower gels, liquid soaps, hand soaps, baby liquid cleansers, pet shampoos, and bubble baths. The fatty N,N-dialkylamides are also valuable for formulating oil-in-water emulsions with good stability.
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公开(公告)号:US20170267946A1
公开(公告)日:2017-09-21
申请号:US15606285
申请日:2017-05-26
Applicant: Stepan Company
Inventor: David R. Allen , Randal J. Bernhardt , Aaron Brown , Gregory P. Dado , Xue Min Dong , Wilma Gorman , Ronald Masters , Patti Skelton
IPC: C11D1/14 , C07C305/10 , A01N25/00 , A01N25/30
CPC classification number: C11D1/146 , A01N25/00 , A01N25/30 , C07C305/10
Abstract: Surfactant compositions comprising an alkoxylate, a sulfate, or ether sulfate of a C10-C12 monounsaturated alcohol are disclosed. The alkoxylate, sulfate, or ether sulfate may derive from undecylenic acid or undecylenic alcohol. Compared with their saturated analogs, the monounsaturated alkoxylates, sulfates, and ether sulfates are less irritating, making them valuable for personal care, laundry, cleaners, and other household applications. Microscopy studies show that the alkoxylates, sulfates, and ether sulfates have favorable phase behavior over a wide range of actives levels, expanding opportunities for products with greater compaction. When combined with cationic surfactants, the alkoxylates, sulfates, and ether sulfates exhibit synergy, and they have improved solubility compared with their saturated analogs. The surfactants find value for the personal care, laundry and cleaning, emulsion polymerization, agricultural products, oilfield applications, and specialty foams industries.
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公开(公告)号:US20160175213A1
公开(公告)日:2016-06-23
申请号:US14902616
申请日:2014-07-08
Applicant: STEPAN COMPANY
Inventor: Irene Shapiro , Dave Allen , Aaron Brown
Abstract: Personal cleansers and surfactant blends useful therein are disclosed. The cleansers comprise a primary anionic surfactant, a saturated C8-C-14 alkyl N,N-dialkylamide, and water. The cleansers have good foaming properties and improved viscosity build profiles compared with cleansers that rely on alkanolamides or betaines as the secondary surfactant. The saturated C8-C14 alkyl N,N-dialkylamides are water-white liquids that solubilize cleanser components well, including high levels of fragrances, and can be formulated easily without heating at any actives level up to 100%. Importantly, the surfactant blends build viscosity with less added salt compared with alkanolamide or betaine-based blends, even with more challenging anionic surfactants. Moisturizing cleansers disclosed herein have excellent flash foaming character, foam volume, and foam feel and provide a luxurious, lotion-like after-feel. The personal cleansers include, among others, shampoos, body washes, facial cleansers, shower gels, liquid soaps, hand soaps, baby liquid cleansers, pet shampoos, and bubble baths. The fatty N,N-dialkylamides are also valuable for formulating oil-in-water emulsions with good stability.
Abstract translation: 公开了可用于其中的个人清洁剂和表面活性剂混合物。 清洁剂包括主阴离子表面活性剂,饱和C 8 -C 14烷基N,N-二烷基酰胺和水。 与依赖于链烷醇酰胺或甜菜碱作为第二表面活性剂的清洁剂相比,清洁剂具有良好的起泡性能和改进的粘度构型。 饱和的C8-C14烷基N,N-二烷基酰胺是水白色液体,可以很好地溶解清洁剂组分,包括高水平的香料,并且可以在任何高达100%的活性水平下轻松配制而不加热配制。 重要的是,即使使用更具挑战性的阴离子表面活性剂,与烷醇酰胺或甜菜碱基混合物相比,表面活性剂共混物的添加盐也较少。 本文公开的保湿清洁剂具有优异的闪光发泡特性,泡沫体积和泡沫感,并提供了豪华的洗剂般的后感。 个人清洁剂包括洗发水,身体洗涤剂,面部清洁剂,沐浴露,液体肥皂,手肥皂,婴儿液体清洁剂,宠物洗发剂和泡泡浴。 脂肪N,N-二烷基酰胺对于配制具有良好稳定性的水包油乳液也是有价值的。
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公开(公告)号:US20160032218A1
公开(公告)日:2016-02-04
申请号:US14867041
申请日:2015-09-28
Applicant: Stepan Company
Inventor: Dave R. Allen , Marcos Alonso , Randal J. Bernhardt , Aaron Brown , Kelly Buchek , Gary Luebke , Renee Luka , Andrew D. Malec , Ronald A. Masters , Lawrence A. Munie , Dennis S. Murphy , Irene Shapiro , Patti Skelton , Brian Sook , Michael R. Terry , Laura Lee Whitlock , Michael Wiester , Patrick Shane Wolfe
IPC: C11D1/66 , A01N57/20 , C11D1/75 , C11D1/28 , A61K8/42 , A62D1/02 , A61Q19/10 , C09K8/584 , C09K8/54 , C04B24/12 , C04B24/16 , A01N25/02 , A61K8/46
CPC classification number: C11D1/66 , A01N25/02 , A01N25/04 , A01N25/30 , A01N33/12 , A01N37/18 , A01N37/44 , A01N41/04 , A01N57/20 , A61K8/41 , A61K8/416 , A61K8/42 , A61K8/44 , A61K8/466 , A61K8/92 , A61Q5/12 , A61Q19/10 , A62D1/0071 , B01F17/0028 , B01F17/0057 , C04B24/121 , C04B24/124 , C04B24/16 , C04B28/02 , C04B28/14 , C04B38/10 , C07C6/04 , C07C41/03 , C07C43/11 , C07C67/26 , C07C69/533 , C07C69/593 , C07C209/12 , C07C211/21 , C07C219/08 , C07C231/12 , C07C237/16 , C07C303/18 , C07C309/69 , C08G65/2615 , C08K5/01 , C08K5/17 , C08K5/20 , C08K5/32 , C08K5/42 , C09D5/00 , C09D7/63 , C09K8/00 , C09K8/54 , C09K8/584 , C09K15/28 , C09K2208/32 , C11C3/00 , C11C3/08 , C11D1/002 , C11D1/04 , C11D1/28 , C11D1/62 , C11D1/652 , C11D1/74 , C11D1/75 , C11D1/83 , C11D1/90 , C11D1/92 , C11D1/94 , C11D3/48 , C07C211/63 , C07C211/64 , C07C233/38 , C07C309/14 , A01N33/18 , A01N39/04 , A01N43/653 , A01N51/00 , A01N43/40 , A01N43/56 , A01N53/00 , C07C11/02
Abstract: Fatty amine compositions made from a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives are disclosed. In another aspect, fatty amidoamines made by reacting a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with an aminoalkyl-substituted tertiary amine are disclosed. The fatty amines or amidoamines are advantageously sulfonated, sulfitated, oxidized, or reduced. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin.
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公开(公告)号:US10745347B2
公开(公告)日:2020-08-18
申请号:US14395835
申请日:2013-03-13
Applicant: Stepan Company
Inventor: David R. Allen , Marcos Alonso , Mary Beddaoui , Randal J. Bernhardt , Aaron Brown , Scott Dillavou , Xue Min Dong , Wilma Gorman , John C. Hutchison , Gary Luebke , Renee Luka , Franz Luxem , Andrew D Malec , Ronald A. Masters , Dennis S. Murphy , Nicholas Pendleton , Irma Ryklin , Patti Skelton , Brian Sook , Chris Spaulding , Krista Turpin , Gregory Wallace , Michael Wiester , Patrick Shane Wolfe
IPC: C07C309/10 , C07C29/147 , C07C309/08 , A01N25/30 , B01F17/00 , C11D1/37 , C04B38/10 , C07C303/32 , C07C303/14 , C09D7/63 , A61K8/46 , C11D1/14 , C11D1/29 , C07C41/06 , C11D1/66
Abstract: Sulfate and sulfonate derivatives of unsaturated fatty alcohols, processes for making them, and methods of using them are disclosed. In one aspect, a monounsaturated fatty alcohol composition is made by reducing a metathesis-derived monounsaturated alkyl ester. The fatty alcohol composition is then converted to a sulfate or sulfonate derivative by one or more of alkoxylation, sulfation, sulfonation, and sulfitation. Of particular interest are the sulfate and ether sulfate derivatives.
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公开(公告)号:US20190225915A1
公开(公告)日:2019-07-25
申请号:US16374819
申请日:2019-04-04
Applicant: Stepan Company
Inventor: David R. Allen , Randal J. Bernhardt , Aaron Brown , Gregory P. Dado , Xue Min Dong , Wilma Gorman , Ronald Masters , Patti Skelton
IPC: C11D1/14 , A01N25/00 , A01N25/30 , C07C305/10
Abstract: Surfactant compositions comprising an alkoxylate, a sulfate, or ether sulfate of a C10-C12 monounsaturated alcohol are disclosed. The alkoxylate, sulfate, or ether sulfate may derive from undecylenic acid or undecylenic alcohol. Compared with their saturated analogs, the monounsaturated alkoxylates, sulfates, and ether sulfates are less irritating, making them valuable for personal care, laundry, cleaners, and other household applications. Microscopy studies show that the alkoxylates, sulfates, and ether sulfates have favorable phase behavior over a wide range of actives levels, expanding opportunities for products with greater compaction. When combined with cationic surfactants, the alkoxylates, sulfates, and ether sulfates exhibit synergy, and they have improved solubility compared with their saturated analogs. The surfactants find value for the personal care, laundry and cleaning, emulsion polymerization, agricultural products, oilfield applications, and specialty foams industries.
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公开(公告)号:US10322994B2
公开(公告)日:2019-06-18
申请号:US15403288
申请日:2017-01-11
Applicant: Stepan Company
Inventor: Dave R. Allen , Marcos Alonso , Randal J. Bernhardt , Aaron Brown , Kelly Buchek , Sangeeta Ganguly-Mink , Brian Holland , Gary Luebke , Renee Luka , Andrew D. Malec , Ronald A. Masters , Dennis S. Murphy , Irene Shapiro , Patti Skelton , Brian Sook , Michael R. Terry , Gregory Wallace , Laura Lee Whitlock , Michael Wiester , Patrick Shane Wolfe , Lena Titievsky
IPC: C11D3/32 , C07C233/09 , A01N25/02 , A01N25/04 , A01N25/30 , A01N33/12 , A01N37/18 , A01N37/44 , A01N41/04 , A61K8/41 , A61K8/42 , A61K8/44 , A61K8/46 , A61K8/92 , A61Q5/12 , A61Q19/10 , A62D1/02 , B01F17/00 , C07C69/533 , C07C69/593 , C07C209/12 , C07C211/21 , C07C219/08 , C07C231/12 , C07C237/16 , C07C303/18 , C08G65/26 , C08K5/01 , C08K5/20 , C09K8/00 , C09K15/28 , C11C3/00 , C11C3/08 , C11D1/00 , C11D1/04 , C11D1/28 , C11D1/62 , C11D1/65 , C11D1/74 , C11D1/83 , C11D1/90 , C11D1/92 , C11D1/94 , C11D3/48 , A61Q5/02 , C07C233/20 , C07C233/38 , C07C309/15 , C07D233/24 , C09K8/54 , C11D1/66 , A61Q17/00 , C07C309/70 , C09K8/524 , C11D11/00 , C09D7/45 , C09D7/63 , C08K5/42
Abstract: Fatty amide compositions and their derivatives are disclosed. The fatty amides comprise a reaction product of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with a primary or secondary amine. Derivatives made by reducing, quaternizing, sulfonating, alkoxylating, sulfating, and sulfitating the fatty amide are also included. The amine reactant can be diethylenetriamine or (2-aminoethyl)ethanolamine, which provide imidazoline amides or esters, respectively. In one aspect, the ester derivative of the C10-C17 monounsaturated acid or octadecene-1,18-dioic acid is a lower alkyl ester. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin. The compositions are valuable for cleaners, fabric treatment, hair conditioning, personal care, antimicrobial compositions, agricultural uses, and oil field applications.
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公开(公告)号:US20170342354A1
公开(公告)日:2017-11-30
申请号:US15674608
申请日:2017-08-11
Applicant: STEPAN COMPANY
Inventor: Aaron Brown , Wilma Gorman , Ronald A. Masters
IPC: C11D11/00 , B43K29/05 , C11D3/32 , C11D3/20 , C11D3/18 , C11D1/46 , C11D1/94 , C11D1/835 , C11D1/83 , C11D1/65 , C11D1/645 , C11D1/52 , C11D17/04 , C11D3/10
CPC classification number: C11D11/0023 , B43K29/05 , C11D1/02 , C11D1/38 , C11D1/46 , C11D1/521 , C11D1/528 , C11D1/645 , C11D1/65 , C11D1/66 , C11D1/83 , C11D1/835 , C11D1/94 , C11D3/10 , C11D3/188 , C11D3/2037 , C11D3/2062 , C11D3/30 , C11D3/32 , C11D3/50 , C11D11/0052 , C11D17/041 , C11D17/046
Abstract: Aqueous hard surface cleaner compositions useful for removing permanent ink are disclosed. The compositions comprise 75 to 99 wt. % of water; 0.1 to 5 wt. % of a monoterpene; 0.1 to 5 wt. % of a C10-C17 fatty acid derivative; and 0.1 to 5 wt. % of one or more surfactants. The fatty acid derivative is selected from N,N-dialkyl amides, N,N-dialkyl esteramines, and N,N-dialkyl amidoamines. Preferably, a base such as sodium carbonate or monoethanolamine is also included. The invention includes concentrates comprising the non-aqueous components recited above, as well as other applications for the cleaners and concentrates such as graffiti removers and permanent ink erasers. The combination of a monoterpene and certain fatty acid derivatives, especially fatty N,N-dialkyl amides, unexpectedly enables even dilute aqueous compositions to rapidly decolorize black permanent marker from hard, non-porous surfaces.
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公开(公告)号:US09796662B2
公开(公告)日:2017-10-24
申请号:US14873113
申请日:2015-10-01
Applicant: Stepan Company
Inventor: Dave R Allen , Randal J Bernhardt , Aaron Brown , Anatoliy A Dameshek , Brian Holland , Andrew D Malec , Ronald A Masters , Marshall J Nepras , Patti Skelton , Laura Lee Whitlock , Patrick Shane Wolfe
IPC: C07C209/12 , C07C211/21 , C07C219/08 , C07C237/12 , C07C237/16 , C07C303/18 , C07C41/03 , C07C43/11 , C07C6/04 , C07C67/26 , C07C69/533 , C07C69/593 , A01N25/02 , A01N25/04 , A01N25/30 , A01N33/12 , A01N37/18 , A01N37/44 , A01N41/04 , A61K8/41 , A61K8/42 , A61K8/44 , A61K8/46 , A61K8/92 , A61Q5/12 , A61Q19/10 , A62D1/02 , B01F17/00 , C07C231/12 , C07C237/18 , C08G65/26 , C08K5/01 , C08K5/20 , C09K15/28 , C11C3/00 , C11C3/08 , C11D1/00 , C11D1/04 , C11D1/28 , C11D1/62 , C11D1/65 , C11D1/74 , C11D1/83 , C11D1/90 , C11D1/92 , C11D1/94 , C11D3/48 , A61Q5/02 , C09K8/00
CPC classification number: C07C219/08 , A01N25/02 , A01N25/04 , A01N25/30 , A01N33/12 , A01N37/18 , A01N37/44 , A01N41/04 , A61K8/416 , A61K8/42 , A61K8/44 , A61K8/466 , A61K8/92 , A61K8/922 , A61K2800/805 , A61Q5/02 , A61Q5/12 , A61Q19/10 , A62D1/0071 , B01F17/0028 , B01F17/0057 , C07C6/04 , C07C41/03 , C07C43/11 , C07C67/26 , C07C69/533 , C07C69/593 , C07C209/12 , C07C211/21 , C07C231/12 , C07C237/16 , C07C237/18 , C07C303/18 , C08G65/2615 , C08K5/01 , C08K5/20 , C09K8/00 , C09K15/28 , C11C3/00 , C11C3/08 , C11D1/002 , C11D1/04 , C11D1/28 , C11D1/62 , C11D1/652 , C11D1/74 , C11D1/83 , C11D1/90 , C11D1/92 , C11D1/94 , C11D3/48 , C07C211/63 , C07C211/64 , C07C233/38 , C07C309/14 , A01N33/18 , A01N39/04 , A01N43/653 , A01N51/00 , A01N57/20 , A01N43/40 , A01N43/56 , A01N53/00
Abstract: Esteramine compositions and their derivatives are disclosed. The esteramines comprise a reaction product of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with a tertiary alkanolamine. Derivatives made by quaternizing, sulfonating, alkoxylating, sulfating, and/or sulfitating the esteramines are also disclosed. In one aspect, the ester derivative of the C10-C17 monounsaturated acid or octadecene-1,18-dioic acid is a lower alkyl ester. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin. The esteramines and derivatives are valuable for a wide variety of end uses, including cleaners, fabric treatment, hair conditioning, personal care (liquid cleansing products, conditioning bars, oral care products), antimicrobial compositions, agricultural uses, and oil field applications.
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公开(公告)号:US09695385B2
公开(公告)日:2017-07-04
申请号:US14770912
申请日:2014-03-05
Applicant: Stepan Company
Inventor: David R Allen , Randal J Bernhardt , Aaron Brown , Gregory P Dado , Xue Min Dong , Wilma Gorman , Ronald Masters , Patti Skelton
IPC: A01N25/00 , A01N25/30 , C07C305/10 , C11D1/14
CPC classification number: C11D1/146 , A01N25/00 , A01N25/30 , C07C305/10
Abstract: Surfactant compositions comprising an alkoxylate, a sulfate, or ether sulfate of a C10-C12 monounsaturated alcohol are disclosed. The alkoxylate, sulfate, or ether sulfate may derive from undecylenic acid or undecylenic alcohol. Compared with their saturated analogs, the monounsaturated alkoxylates, sulfates, and ether sulfates are less irritating, making them valuable for personal care, laundry, cleaners, and other household applications. Microscopy studies show that the alkoxylates, sulfates, and ether sulfates have favorable phase behavior over a wide range of actives levels, expanding opportunities for products with greater compaction. When combined with cationic surfactants, the alkoxylates, sulfates, and ether sulfates exhibit synergy, and they have improved solubility compared with their saturated analogs. The surfactants find value for the personal care, laundry and cleaning, emulsion polymerization, agricultural products, oilfield applications, and specialty foams industries.
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