Hydrothermally-Stable Silica-Based Composite Membranes for Hydrogen Separation
    21.
    发明申请
    Hydrothermally-Stable Silica-Based Composite Membranes for Hydrogen Separation 有权
    用于氢分离的水热稳定二氧化硅复合膜

    公开(公告)号:US20070251388A1

    公开(公告)日:2007-11-01

    申请号:US11381088

    申请日:2006-05-01

    Inventor: S. Oyama Yunfeng Gu

    Abstract: Thin layers of a mixed composition are deposited on a porous substrate by chemical vapor deposition in an inert atmosphere at high temperature. The resulting membrane has excellent stability to water vapor at high temperatures. An exemplary membrane comprises an amorphous mixed-element surface layer comprising silica and at least one oxide of additional element, an optional porous substrate on which said surface layer is deposited, and a porous support on which said substrate or mixed-element surface layer is deposited, wherein the permeance of the membrane is higher than 1×10−7 mol m−2 s−1 Pa−1 and the selectivity of H2 over CO, CO2, and CH4 is larger than 100, and wherein the H2 permeance of the membrane after exposure to a stream containing 60 mol % water vapor at 673 K for 120 h is at least 50% of its initial H2 permeance.

    Abstract translation: 将混合组合物的薄层通过化学气相沉积在高温下在惰性气氛中沉积在多孔基材上。 所得的膜在高温下对水蒸气具有优异的稳定性。 示例性膜包括非晶混合元件表面层,其包含二氧化硅和至少一种另外的元素的氧化物,其上沉积有所述表面层的任选的多孔基材和沉积所述基材或混合元件表面层的多孔载体 ,其中所述膜的渗透性高于1×10 -7摩尔/秒。 并且H 2 CO 2,CO 2和CH 4的选择性大于100,并且其中H 2 暴露于含有60摩尔%水蒸汽的流在673K下120小时的膜的渗透性是其初始H 2 O 2渗透性的至少50%。

    Chemical modification of shaped hydrogels in non-aqueous medium
    22.
    发明授权
    Chemical modification of shaped hydrogels in non-aqueous medium 失效
    非水介质中形状水凝胶的化学改性

    公开(公告)号:US5530111A

    公开(公告)日:1996-06-25

    申请号:US296171

    申请日:1994-08-29

    CPC classification number: C08B3/00 C08B3/14

    Abstract: A method is described for the chemical modification of pre-shaped hydrogels in non-aqueous medium. The conditions permit the reaction of highly expanded, porous hydrogel particles, such as spherical beads, using pseudo homogeneous reaction conditions in the absence of water. The method involves a three step procedure in which the porous gels are solvent exchanged int a water-free solvent (step 1) with minimal change in gel dimension and porosity; followed by reaction under non-aqueous condition (step 2); and followed by solvent exchange into water (step 3). Many different types of reactions requiring non-aqueous conditions may be carried out using these conditions. The method has particularly been demonstrated for crosslinking fluorinating beads, and for esterifying beads in a reaction involving multifunctional free carboxylic acids in the presence of dicyclohexylcarbodiimide (DCC).

    Abstract translation: 描述了一种用于非水介质中预形状水凝胶的化学改性的方法。 该条件允许在不存在水的情况下使用假均匀反应条件使高度膨胀的多孔水凝胶颗粒如球形珠的反应。 该方法涉及三步法,其中多孔凝胶在无水溶剂(步骤1)中溶剂交换,凝胶尺寸和孔隙率变化最小; 然后在非水条件下反应(步骤2); 然后进行与水的溶剂交换(步骤3)。 可以使用这些条件进行需要非水性条件的许多不同类型的反应。 特别是在二环己基碳化二亚胺(DCC)的存在下,涉及氟化珠的交联以及涉及多官能游离羧酸的反应中的酯化珠粒的方法。

    Metalorganic chemical vapor deposition of layered structure oxides
    23.
    发明授权
    Metalorganic chemical vapor deposition of layered structure oxides 失效
    层状结构氧化物的金属有机化学气相沉积

    公开(公告)号:US5478610A

    公开(公告)日:1995-12-26

    申请号:US300339

    申请日:1994-09-02

    Abstract: A method of fabricating high quality layered structure oxide ferroelectric thin films. The deposition process is a chemical vapor deposition process involving chemical reaction between volatile metal organic compounds of various elements comprising the layered structure material to be deposited, with other gases in a reactor, to produce a nonvolatile solid that deposits on a suitably placed substrate such as a conducting, semiconducting, insulating, or complex integrated circuit substrate. The source materials for this process may include organometallic compounds such as alkyls, alkoxides, .beta.-diketonates or metallocenes of each individual element comprising the layered structure material to be deposited and oxygen. Preferably, the reactor in which the deposition is done is either a hot wall or a cold wall reactor and the vapors are introduced into this reactor either through a set of bubblers or through a direct liquid injection system. The ferroelectric films can be used for device applications such as in capacitors, dielectric resonators, heat sensors, transducers, actuators, nonvolatile memories, optical waveguides and displays.

    Abstract translation: 一种制造高品质层状结构氧化物铁电薄膜的方法。 沉积工艺是一种化学气相沉积工艺,其涉及包括待沉积的层状结构材料的各种元素的挥发性金属有机化合物与反应器中的其它气体的化学反应,以产生沉积在合适放置的基底上的非挥发性固体,例如 导电,半导体,绝缘或复合集成电路基板。 该方法的原料可以包括有机金属化合物,例如包含待沉积的层状结构材料和氧气的每个单独元素的烷基,烷氧基化物,β-二酮化合物或金属茂。 优选地,其中进行沉积的反应器是热壁或冷壁反应器,并且通过一组起泡器或通过直接液体注入系统将蒸气引入该反应器。 铁电薄膜可用于诸如电容器,介质谐振器,热传感器,换能器,致动器,非易失性存储器,光波导和显示器中的器件应用。

    Method for recovery of cathode materials, cathode materials and electric vehicles

    公开(公告)号:US20250007021A1

    公开(公告)日:2025-01-02

    申请号:US18215191

    申请日:2023-06-28

    Abstract: The main purpose of the invention is to provide a method for recovery of cathode materials, cathode materials and electric vehicles. The method for recovery of cathode materials comprises the following steps: step 1, adding cathode materials and a metal reducing agent (MRA) to a molten salt (MS), the cathode materials and the MRA performing a reduction reaction in MS to obtain precipitates and MS solutions. By using the method for recovery of cathode materials of the present invention, main metal elements in cathode materials of a secondary battery are effectively recovered, and compared with pyrometallurgical or hydrometallurgical methods in the prior art, the recovery rate of a metal mixture can reach unexpected 90% or more. Furthermore, the method of the present invention is environmentally friendly, all raw materials can be recycled and reused and no exhaust gases or waste liquids contaminating the environment are discharged.

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