Glass sizing composition
    32.
    发明授权
    Glass sizing composition 失效
    玻璃施胶组合物

    公开(公告)号:US07087302B2

    公开(公告)日:2006-08-08

    申请号:US10372370

    申请日:2003-02-24

    Abstract: The present invention relates to a sizing composition for use on glass fibers which are used to reinforce plastic resins used in the formation of fiber-reinforced plastics (FRPs). The sizing composition comprises a copolymer formed from at least one functional monomer that is selected from the group consisting of hydroxy, phenyl and alkoxylated functional groups. The glass fibers sized with the sizing composition of the invention have excellent computability with resins used in forming FRPs, as seen by a low level of white glass.

    Abstract translation: 本发明涉及一种用于玻璃纤维的上胶组合物,其用于增强用于形成纤维增强塑料(FRP)的塑料树脂。 上胶组合物包含由选自羟基,苯基和烷氧基化官能团的至少一种官能单体形成的共聚物。 用本发明的施胶组合物尺寸的玻璃纤维与用于形成FRP的树脂具有优异的可计算性,如低白度玻璃所见。

    Cationic coating for printable surfaces
    33.
    发明申请
    Cationic coating for printable surfaces 审中-公开
    可印刷表面的阳离子涂层

    公开(公告)号:US20050075445A1

    公开(公告)日:2005-04-07

    申请号:US10963965

    申请日:2004-10-13

    CPC classification number: B41M5/5245 B41M5/5218 B41M5/5254 Y10T428/31855

    Abstract: The present invention relates to a coating composition for fibrous substrates made up of 0.5 to 25 percent by weight of a water-insoluble emulsion polymer comprising from greater than 0.4 to 3 mole percent of one or more cationic monomer units and at least 50 mole percent of at least one vinyl ester monomer; 25 to 75 percent by weight pigment; cationic surfactant; and water. The coating is useful on fibrous substrates on which liquid inks will be fixed. The cationic nature of the coating provides the substrate with an excellent point of attachment for anionic inks and dyes, resulting in bright, crisp printed images. The coating is especially useful for ink-jet printing on paper, paperboard, textiles, non-wovens, and wood.

    Abstract translation: 本发明涉及一种用于纤维基材的涂料组合物,其由0.5至25重量%的水不溶性乳液聚合物组成,所述水不溶性乳液聚合物包含大于0.4至3摩尔%的一种或多种阳离子单体单元和至少50摩尔% 至少一种乙烯基酯单体; 25〜75重量%的颜料; 阳离子表面活性剂; 和水。 该涂层可用于固定液体油墨的纤维基材上。 涂料的阳离子性质为底物提供了阴离子油墨和染料的极好的附着点,从而产生明亮,清晰的印刷图像。 该涂料对于在纸,纸板,纺织品,无纺布和木材上的喷墨印刷特别有用。

    Star polymer colloidal stabilizers
    34.
    发明授权
    Star polymer colloidal stabilizers 失效
    星状胶体稳定剂

    公开(公告)号:US06420479B1

    公开(公告)日:2002-07-16

    申请号:US09752897

    申请日:2000-12-29

    Abstract: A colloid composition is presented which contains an amphiphilic star polymer having potentially crosslinkable sites on the polymer backbone. The potentially crosslinkable site is either a sterically hindered silane monomer or an acetoacetoxy-containing monomer. When the crosslinkable site is a sterically hindered silane monomer the star polymer also contains an internal catalyst, and when the crosslinkable site is an acetoacetoxy group the colliod composition also contains a non-polymeric polyfunctional amine. The star polymer can be either a random or heteroarm star polymer. The colloid composition is useful in the formation and stabilization of emulsion polymers, as a replacement for surfactants currently used for this purpose. Emulsion polymers formulated with the colloid composition are especially useful for one-part coatings such as paints and adhesives.

    Abstract translation: 提出了一种胶体组合物,其包含在聚合物主链上具有潜在可交联位点的两亲性星形聚合物。 潜在可交联的位点是空间位阻硅烷单体或含乙酰乙酰氧基的单体。 当可交联位置是空间位阻硅烷单体时,星形聚合物还含有内部催化剂,并且当可交联位点是乙酰乙酰氧基时,该絮状组合物还含有非聚合多官能胺。 星形聚合物可以是无规或星形聚合物。 胶体组合物可用于形成和稳定乳液聚合物,作为目前用于此目的的表面活性剂的替代物。 用胶体组合物配制的乳液聚合物特别适用于一部分涂料如油漆和粘合剂。

    Coating compositions prepared with a sterically hindered alkoxylated silane
    35.
    发明授权
    Coating compositions prepared with a sterically hindered alkoxylated silane 失效
    用空间位阻烷氧基化硅烷制备的涂料组合物

    公开(公告)号:US06258460B1

    公开(公告)日:2001-07-10

    申请号:US09227756

    申请日:1999-01-08

    CPC classification number: C09D201/10 Y10T428/31663

    Abstract: A coating composition having increased block resistance comprising a polymer prepared by emulsion polymerizing at least one ethylenically unsaturated non-carboxy functional monomer, from 0.01 to 2 pphm of a sterically hindered alkoxylated silane monomer, and at least one anionic surfactant, wherein the polymer is crosslinked during film formation. The sterically hindered alkoxylated silane monomer has the structure R′—Si—(OR2)n(R3)3-n wherein R1 is selected from the group consisting of an alkylene, arylene, and aralkylene group; R2 is independently a sterically hindered alkyl group having 3 to 10 carbon atoms in a straight or branched chain configuration; R3 is a monovalent alkyl group having 1 to 10 carbon atoms; and n is an integer of from 1 to 3.

    Abstract translation: 具有增加的抗阻性的涂料组合物包括通过乳液聚合至少一种烯属不饱和非羧基官能单体,0.01至2pphm的空间位阻烷氧基化硅烷单体和至少一种阴离子表面活性剂制备的聚合物,其中聚合物交联 在成膜期间。 空间位阻烷氧基化硅烷单体具有结构R'-Si-(OR2)n(R3)3-n,其中R1选自亚烷基,亚芳基和亚芳基; R2独立地为直链或支链构型的具有3-10个碳原子的空间位阻烷基; R3是具有1-10个碳原子的一价烷基; n为1〜3的整数。

    Ethylene/vinyl acetate latex binders and paints which are free of
volatile coalescents and freeze-thaw additives
    36.
    发明授权
    Ethylene/vinyl acetate latex binders and paints which are free of volatile coalescents and freeze-thaw additives 失效
    乙烯/乙酸乙烯酯胶乳粘合剂和不含挥发性聚结剂和冻融添加剂的涂料

    公开(公告)号:US6087437A

    公开(公告)日:2000-07-11

    申请号:US722817

    申请日:1996-09-27

    CPC classification number: C09D131/04 C08F210/02 C08F218/08

    Abstract: The invention is directed to aqueous coating compositions which are freeze-thaw stable in the absence of conventional volatile coalescing solvents and volatile freeze-thaw (F/T) additives and which utilize a latex binder which contains an EVA thermoplastic interpolymer which is prepared by emulsion polymerization of ethylene, vinyl acetate and a monomer represented by structure (I) ##STR1## where R is hydrogen or a methyl group, X is O or NH, and n is an integer from 1 to 11 and to the latex binder which contains the EVA interpolymer.

    Abstract translation: 本发明涉及在不存在常规挥发性聚结溶剂和挥发性冻融(F / T)添加剂的情况下冻融稳定的水性涂料组合物,其使用含有通过乳液制备的EVA热塑性共聚体的胶乳粘合剂 乙烯,乙酸乙烯酯和由R为氢或甲基,X为O或NH,n为1至11的整数的结构(I)表示的单体与含有EVA互聚物的胶乳粘合剂的聚合反应。

    Ethylene/vinyl acetate latex binders and paints prepared with
surface-active initiators
    37.
    发明授权
    Ethylene/vinyl acetate latex binders and paints prepared with surface-active initiators 失效
    乙烯/乙酸乙烯酯胶乳粘合剂和用表面活性引发剂制备的油漆

    公开(公告)号:US6028139A

    公开(公告)日:2000-02-22

    申请号:US929971

    申请日:1997-09-16

    CPC classification number: C09D131/04

    Abstract: The invention is directed to aqueous coating compositions which are freeze-thaw stable in the absence of conventional volatile coalescing solvents and volatile freeze-thaw (F/T) additives and which utilize a latex binder which contains an EVA thermoplastic interpolymer which is prepared by emulsion polymerization of ethylene, vinyl acetate and a surface active initiator having an azo group as radical generating functionality and an anionic substituent, and to latex binders which contain the EVA interpolymer.

    Abstract translation: 本发明涉及在不存在常规挥发性聚结溶剂和挥发性冻融(F / T)添加剂的情况下冻融稳定的水性涂料组合物,其使用含有通过乳液制备的EVA热塑性共聚体的胶乳粘合剂 乙烯,乙酸乙烯酯和具有作为自由基产生官能团的偶氮基团的表面活性引发剂和阴离子取代基的聚合,以及含有EVA互聚物的胶乳粘合剂。

    Latex polymers for pigments coatings prepared in the presence of
acetoacetonate moiety
    38.
    发明授权
    Latex polymers for pigments coatings prepared in the presence of acetoacetonate moiety 失效
    用于在乙酰丙酮化物部分存在下制备的颜料涂料的胶乳聚合物

    公开(公告)号:US5455298A

    公开(公告)日:1995-10-03

    申请号:US281388

    申请日:1994-07-27

    CPC classification number: C08F2/44 C08L33/062 C09D133/062

    Abstract: The invention relates to an acrylic polymer latex comprising the polymerization product of an acetoacetate moiety of the structure ##STR1## wherein R.sub.1 and R.sub.2 are the same or different and are selected from the group consisting of C.sub.1 -C.sub.22 alkyl groups and X is a halogen, in amounts effective to improve the water resistance of the acrylic latex; and at least one monomer(s) selected from the group consisting of C.sub.3 -C.sub.6 monocarboxylic acids, C.sub.4 -C.sub.6 dicarboxylic acids and their C.sub.1 -C.sub.4 half esters, C.sub.1 -C.sub.10 alkyl esters of acrylic acid, C.sub.1 C.sub.10 alkyl esters of methacrylic acid, styrene, halogenated styrene and substituted styrene and latex compositions containing the novel latexes. The invention also relates to methods of improving the water resistance of the coating compositions which include adding to the coating composition the latex which contains an amount of the acetoacetate moiety effective to improve the water resistance of the coating compositions.

    Abstract translation: 本发明涉及丙烯酸聚合物胶乳,其包含结构为“IMAGE”的乙酰乙酸酯部分的聚合产物,其中R 1和R 2相同或不同,并且选自C 1 -C 22烷基,X为卤素, 有效提高丙烯酸胶乳的耐水性; 和至少一种选自C 3 -C 6单羧酸,C 4 -C 6二羧酸及其C 1 -C 4半酯,丙烯酸C1-C10烷基酯,甲基丙烯酸C 1 -C 10烷基酯,苯乙烯 ,卤代苯乙烯和取代的苯乙烯和含有新胶乳的胶乳组合物。 本发明还涉及提高涂料组合物的耐水性的方法,包括向涂料组合物中加入含有一定量乙酰乙酸酯部分的胶乳,其有效地改善涂料组合物的耐水性。

    Polymer hydrogenation process
    39.
    发明授权
    Polymer hydrogenation process 失效
    聚合物加氢工艺

    公开(公告)号:US4816525A

    公开(公告)日:1989-03-28

    申请号:US70023

    申请日:1987-07-06

    CPC classification number: C08C19/02

    Abstract: Selective hydrogenation of the carbon-carbon double bonds of conjugated diene copolymers is effective homogeneous solution in an organic solvent in the presence of certain divalent ruthenium carbonyl complex catalysts. The ruthenium catalysts have the general formula:Ru(CO)HA(Z).sub.3 ( 1)wherein A is a halogen atom, most preferably chlorine, or a hydrogen atom and Z is -PR.sub.1 R.sub.2 R.sub.3 in which R.sub.1, R.sub.2 and R.sub.3 are the same or different and are selected from alkyl and aryl groups, preferably all the phenyl group, or have the general formula:Ru(CO)XY(Z).sub.2 ( 2)wherein X is a carboxylate group, particularly ClCH.sub.2 COO--, Cl.sub.2 CHCOO--, Cl.sub.3 CCOO--, F.sub.3 CCOO--, CH.sub.3 COO--, C.sub.6 H.sub.5 COO-- or p--ClC.sub.6 H.sub.4 COO--, y is a halogen atom, preferably a chlorine atom or a bromine atom, or a hydrogen atom or a carboxylate group, Z is as defined above.

    Aqueous latex coating compositions
    40.
    发明授权
    Aqueous latex coating compositions 有权
    水性胶乳涂料组合物

    公开(公告)号:US09090793B2

    公开(公告)日:2015-07-28

    申请号:US13990550

    申请日:2010-12-17

    Abstract: Disclosed are aqueous latex-based coating compositions which comprise a blend of an ethylene-vinyl acetate emulsion copolymer component and a selected type of acrylic emulsion copolymer component. The acrylic copolymer component comprises primarily acrylate ester co-monomers or acrylic ester co-monomers and vinyl aromatic, e.g., styrene, co-monomers. The blend of these two emulsion copolymer types also contains a specific type of hydrazine-based, water-soluble cross-linking agent which can eventually react with the acrylic emulsion copolymer component. The acrylic emulsion copolymer is one which contains minor amounts of both 1) carboxy functional co-monomers such as itaconic and/or (meth)acrylic acids, and 2) keto- or aldehyde-containing co-monomers such as diacetone acrylamide. Such latex-based coating compositions can be formulated in the form of water-based paint compositions. These paint products provide paint coatings that exhibit desirable dry and wet adhesion characteristics and desirable resistance to blocking.

    Abstract translation: 公开了含有乙烯 - 乙酸乙烯酯乳液共聚物组分和所选类型的丙烯酸乳液共聚物组分的共混物的水性胶乳基涂料组合物。 丙烯酸共聚物组分主要包括丙烯酸酯共聚单体或丙烯酸酯共聚单体和乙烯基芳族化合物,例如苯乙烯共聚单体。 这两种乳液共聚物类型的共混物也含有特定类型的肼类水溶性交联剂,其可以最终与丙烯酸乳液共聚物组分反应。 丙烯酸乳液共聚物是含有少量两种1)羧基官能共聚单体如衣康酸和/或(甲基)丙烯酸的共聚物,和2)含有酮或醛的共聚单体如双丙酮丙烯酰胺。 这种胶乳基涂料组合物可以以水基涂料组合物的形式配制。 这些涂料产品提供涂料涂料,其表现出所需的干和湿粘合特性和所需的阻断性。

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