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    METHOD FOR CONTINUOUS SYNTHESIS OF METAL OXIDE POWDERS
    33.
    发明申请
    METHOD FOR CONTINUOUS SYNTHESIS OF METAL OXIDE POWDERS 有权
    用于连续合成金属氧化物粉末的方法

    公开(公告)号：US20140363365A1

    公开(公告)日：2014-12-11

    申请号：US14296643

    申请日：2014-06-05

    Applicant: David A. Berry ,  Daniel J. Haynes ,  Dushyant Shekhawat ,  Mark W. Smith

    Inventor： David A. Berry ,  Daniel J. Haynes ,  Dushyant Shekhawat ,  Mark W. Smith

    IPC: C01B13/32

    CPC classification number: C01B13/34 ,  C01P2004/03 ,  C01P2004/32 ,  C01P2004/62

    Abstract: A method for the rapid and continuous production of crystalline mixed-metal oxides from a precursor solution comprised of a polymerizing agent, chelated metal ions, and a solvent. The method discharges solution droplets of less than 500 μm diameter using an atomizing or spray-type process into a reactor having multiple temperature zones. Rapid evaporation occurs in a first zone, followed by mixed-metal organic foam formation in a second zone, followed by amorphous and partially crystalline oxide precursor formation in a third zone, followed by formation of the substantially crystalline mixed-metal oxide in a fourth zone. The method operates in a continuous rather than batch manner and the use of small droplets as the starting material for the temperature-based process allows relatively high temperature processing. In a particular embodiment, the first zone operates at 100-300° C., the second zone operates at 300-700° C., and the third operates at 700-1000° C., and fourth zone operates at at least 700° C. The resulting crystalline mixed-metal oxides display a high degree of crystallinity and sphericity with typical diameters on the order of 50 μm or less.

    Abstract translation: 一种从由聚合剂，螯合金属离子和溶剂组成的前体溶液中快速和连续地生产结晶混合金属氧化物的方法。 该方法使用雾化或喷雾式方法将小于500μm直径的溶液液滴放入具有多个温度区的反应器中。 在第一区域中发生快速蒸发，随后在第二区域中形成混合金属有机泡沫，随后在第三区域中形成无定形和部分结晶的氧化物前体，随后在第四区域中形成基本上结晶的混合金属氧化物 。 该方法以连续而不是间歇的方式操作，并且使用小液滴作为基于温度的方法的起始材料允许相对较高的温度处理。 在特定实施例中，第一区域在100-300℃下操作，第二区域工作在300-700℃，第三区域在700-1000℃下操作，第四区域在至少700° 所得到的结晶混合金属氧化物显示出高度的结晶度和球形度，典型直径为50μm以下。

    Dark quenchers, probes and other conjugates incorporating the same, and their use
    35.
    发明授权
    Dark quenchers, probes and other conjugates incorporating the same, and their use 有权
    暗猝灭剂，探针和其它掺合物的共轭物及其用途

    公开(公告)号：US07879986B2

    公开(公告)日：2011-02-01

    申请号：US11346688

    申请日：2006-02-03

    Applicant: David A. Berry ,  William H. Pearson

    Inventor： David A. Berry ,  William H. Pearson

    IPC: C09B31/153 ,  C07H19/04 ,  C12Q1/68

    CPC classification number: C07H19/073 ,  C07D455/04 ,  C07F9/6561 ,  C07H19/04 ,  C09B35/039

    Abstract: The specification discloses quenchers of excited state energy, probes and other conjugates comprising the same, and methods for their use. The quenchers of excited state energy have a structure comprising at least one reactive functional group for linking the quencher to a carrier molecule and at least three radicals covalently linked via exocyclic diazo bonds, the at least three radicals including at least one comprising a julolidine of the nominal formula: and the remainder of the at least three radicals being selected from the group of substituted and unsubstituted aryls, substituted and unsubstituted heteroaryls, and combinations thereof.

    Abstract translation: 该说明书公开了激发态能量的猝灭剂，探针和包含其的共轭物，以及它们的使用方法。 激发态能的猝灭剂具有包含至少一个用于将猝灭剂与载体分子连接的至少一个反应性官能团和至少三个通过环外重氮键共价连接的基团的结构，所述至少三个基团包括至少一个基团， 所述至少三个基团的其余部分选自取代和未取代的芳基，取代和未取代的杂芳基，及其组合。

    Methods to Enhance Carbon Monoxide Dehydrogenase Activity and Uses Thereof
    38.
    发明申请
    Methods to Enhance Carbon Monoxide Dehydrogenase Activity and Uses Thereof 审中-公开
    增强一氧化碳脱氢酶活性的方法及其用途

    公开(公告)号：US20090155875A1

    公开(公告)日：2009-06-18

    申请号：US11884522

    申请日：2006-02-16

    Applicant: David A. Berry ,  Robert S. Langer ,  Richard J. Resnick

    Inventor： David A. Berry ,  Robert S. Langer ,  Richard J. Resnick

    IPC: C12P3/00 ,  C12N9/02 ,  C12N1/21

    CPC classification number: C12P3/00 ,  C12N9/0008 ,  C12Y102/99002

    Abstract: This invention relates, in part, to methods and compositions for modulating the water-gas shift reaction (e.g., promoting the water-gas shift forward reaction) or in which the water-gas shift reaction has been modulated. The methods and compositions, therefore, also relate, in part, to increasing the oxidation rate of carbon monoxide (CO), for increasing the availability of CO (e.g., to the carbon monoxide dehydrogenase (CODH) enzyme complex), for removing and/or promoting the release of hydrogen and/or carbon dioxide (CO2), for regulating the redox potential of cells, for preventing free radical damage and/or promoting cell survivability, etc. The invention also relates, in part, to methods and compositions for modulating CODH activity, such as increasing CODH activity. Methods and compositions are also provided for modulating the PSII reaction (e.g., promoting the PSII forward reaction) or in which the PSII reaction has been modulated. The modulation of the PSII reaction can be in conjunction with the modulation of the water-gas shift reaction. The invention also relates, in part, to methods and compositions for modulating PSII activity, such as increasing PSII activity. The invention further relates to uses of the aforementioned methods and compositions. For example, methods and compositions are provided for the production of hydrogen and/or for the elimination of CO. The methods and compositions provided can be used for a variety of industrial and medical applications, and such applications are also provided as part of the invention.

    Abstract translation: 本发明部分地涉及用于调节水煤气变换反应（例如促进水煤气前进反应）的方法和组合物，或其中水煤气变换反应被调制的方法和组合物。 因此，方法和组合物还部分地涉及提高一氧化碳（CO）的氧化速率，以增加CO（例如，一氧化碳脱氢酶（CODH）酶复合物）的可用性，用于除去和/ 或促进氢和/或二氧化碳（CO 2）的释放，用于调节细胞的氧化还原电位，用于防止自由基损伤和/或促进细胞存活力等。本发明还部分涉及用于 调节CODH活性，如增加CODH活性。 还提供了用于调节PSII反应（例如，促进PSII正向反应）或其中已经调节PSII反应的方法和组合物。 PSII反应的调节可以与水煤气变换反应的调节相结合。 本发明还部分涉及用于调节PSII活性的方法和组合物，例如增加PSII活性。 本发明还涉及上述方法和组合物的用途。 例如，提供了用于生产氢和/或消除CO的方法和组合物。所提供的方法和组合物可用于各种工业和医疗应用，并且这些应用也作为本发明的一部分提供 。

    Aminoalkyl-substituted cycloalkylamine platinum (II) complexes
    39.
    发明授权
    Aminoalkyl-substituted cycloalkylamine platinum (II) complexes 失效
    氨基烷基取代的环烷基胺铂（II）络合物

    公开(公告)号：US5116831A

    公开(公告)日：1992-05-26

    申请号：US560394

    申请日：1990-07-31

    Applicant: James D. Hoeschele ,  David A. Berry ,  Luigi G. Marzilli

    Inventor： James D. Hoeschele ,  David A. Berry ,  Luigi G. Marzilli

    IPC: C07F15/00

    CPC classification number: C07F15/0093

    Abstract: Square-planar four-coordinate complexes of cis-platinum (II) with neutral bidentate aminoalkyl-substituted cycloalkylamine ligands and bromo-, chloro-, iodo-, nitrato-, oxalato-, or malanato-ligands possess antimicrobial activity as well as activity against transplanted L1210 and P388 murine leukemia cell lines.

    Abstract translation: 顺式铂（II）与中性二齿氨基烷基取代的环烷基胺配体和溴 - ，氯 - ，碘 - ，硝基 - ，草酸 - 或马拉那那 - 配体的平面四坐标络合物具有抗菌活性和抗 移植L1210和P388鼠白血病细胞系。

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