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公开(公告)号：US07229548B2
公开(公告)日：2007-06-12
申请号：US10677697
申请日：2003-10-02
申请人： Kenneth L. Riley , Stuart L. Soled , Sabato Miseo , Frans L. Plantenga , Marinus Bruce Cerfontain , Sonja Eijsbouts , Eelko Brevoord
发明人： Kenneth L. Riley , Stuart L. Soled , Sabato Miseo , Frans L. Plantenga , Marinus Bruce Cerfontain , Sonja Eijsbouts , Eelko Brevoord
CPC分类号： C10G65/12 , B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G2400/10 , C10G2400/14 , C08F240/00
摘要： A method for upgrading a naphtha feed to a naphtha product containing less than about 10 wppm of nitrogen and less than about 15 wppm sulfur, the method comprising contacting said naphtha feed with hydrogen in the presence of a bulk multimetallic catalyst under effective reactor conditions to hydrodesulfurize and hydrodenitrogenize said naphtha feed to produce said naphtha product, wherein said bulk multimetallic catalyst comprises at least one Group VIII non-noble metal and at least two Group VIB metals.
摘要翻译： 一种将石脑油进料升级成含有小于约10wppm氮和小于约15wppm硫的石脑油产品的方法，所述方法包括在有效反应器条件下在大量多金属催化剂存在下使所述石脑油进料与氢气接触以加氢脱硫 并且对所述石脑油进料进行加氢脱氮以产生所述石脑油产品，其中所述本体多金属催化剂包含至少一种第VIII族非贵金属和至少两种VIB族金属。
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32.发明授权Group IVB oxide addition to noble metal on rare earth modified silica alumina as hydrocarbon conversion catalyst 失效第IVB族氧化物添加到稀土改性二氧化硅氧化铝上的贵金属作为烃转化催化剂
公开(公告)号：US5254518A
公开(公告)日：1993-10-19
申请号：US916759
申请日：1992-07-22
IPC分类号： B01J21/12 , B01J23/10 , B01J23/62 , B01J23/63 , B01J23/656 , C10G35/09 , C10G45/10 , C10G45/12 , C10G45/62 , C10G45/64 , B01J23/12 , B01J23/16
CPC分类号： B01J23/10 , B01J23/626 , B01J23/63 , B01J23/6567 , C10G35/09
摘要： By this invention there is provided a catalyst composition comprising a Group IVB oxide, an amorphous silica-alumina support having dispersed thereon a rare earth oxide, which as herein used also includes yttrium oxide, and a metal(s) selected from the group consisting of Group VIII noble metal(s), mixtures of Group VIII noble metal(s) and tin, mixtures of Group VIII noble metal(s) and rhenium, and mixtures of Group VIII noble metal(s), tin and rhenium. The amorphous silica-alumina support contains at least about 50% silica by weight. The catalyst can function as a hydrocarbon conversion catalyst in reactions where platinum on halided (Cl,F)-alumina is typically used.
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公开(公告)号：US5113034A
公开(公告)日：1992-05-12
申请号：US740251
申请日：1991-08-05
IPC分类号： B01J21/06 , B01J23/30 , B01J27/047 , B01J27/053 , C07B61/00 , C07C2/08 , C07C2/10 , C07C11/02 , C07C11/107
CPC分类号： B01J21/066 , B01J21/063 , B01J23/30 , B01J27/053 , C07C2/10 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12
摘要： A solid, acid catalyst, supported or unsupported, comprised of an anion modified Group IVB oxide is used to dimerize C.sub.3 or C.sub.4 containing feedstreams.
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公开(公告)号：US09708548B2
公开(公告)日：2017-07-18
申请号：US12315272
申请日：2008-12-02
申请人： Stuart L. Soled , Sabato Miseo , Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Paul Joseph Maria Lebens , Frans Lodewijk Plantenga , Bob Gerardus Oogjen , Henk-Jan Tromp
发明人： Stuart L. Soled , Sabato Miseo , Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Paul Joseph Maria Lebens , Frans Lodewijk Plantenga , Bob Gerardus Oogjen , Henk-Jan Tromp
IPC分类号： C10G45/10 , C10G49/04 , B01J21/16 , B01J23/85 , B01J23/888 , B01J35/00 , B01J37/20 , B01J37/00
CPC分类号： C10G45/10 , B01J21/16 , B01J23/85 , B01J23/8885 , B01J35/0013 , B01J37/0009 , B01J37/20 , C10G49/04 , C10G2300/301 , C10G2300/4018
摘要： The invention relates to a method for hydroprocessing hydrocarbon feedstocks, said process comprising contacting a hydrocarbon feedstock under hydroprocessing conditions with a bulk catalyst composition comprising bulk metal particles that comprise at least one Group VIII non-noble metal, at least one Group VIB metal and nanoparticles. The bulk metal catalyst composition comprises bulk metal particles that may be prepared by a manufacturing process comprising the steps of combining in a reaction mixture (i) dispersible nanoparticles having a dimension of less than about 1 μm upon being dispersed in a liquid, (ii) at least one Group VIII non-noble metal compound, (iii) at least one Group VIB metal compound, and (iv) a protic liquid; and reacting the at least one Group VIII non-noble metal compound and the at least one Group VIB metal in the presence of the nanoparticles.
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公开(公告)号：US08784647B2
公开(公告)日：2014-07-22
申请号：US12967354
申请日：2010-12-14
IPC分类号： C10G45/00
CPC分类号： C10G45/08 , B01J23/8885 , B01J27/0515 , B01J33/00 , B01J35/002 , B01J35/0046 , B01J37/04 , B01J37/10 , B01J37/14 , B01J37/20 , C10G45/10 , C10G49/04 , C10G49/06 , C10G2300/202 , C10G2300/70
摘要： In a process for producing a hydroprocessing catalyst, a particulate metal oxide composition comprising an oxide of at least one first metal selected from Group 6 of the Periodic Table of the Elements can be mixed with particles of a sulfide of at least one second metal selected from Groups 8 to 10 of the Periodic Table of the Elements to produce a particulate catalyst precursor. The particulate catalyst precursor can then be sulfided under conditions sufficient to at least partially convert the particulate catalyst precursor into a layered metal sulfide having defect sites associated with the second metal sulfide.
摘要翻译： 在制备加氢处理催化剂的方法中，包含选自元素周期表第6族的至少一种第一金属的氧化物的颗粒状金属氧化物组合物可与选自以下的至少一种第二金属的硫化物颗粒混合： 元素周期表第8至10族，以产生颗粒催化剂前体。 然后可以在足以至少部分地将颗粒状催化剂前体转化成具有与第二金属硫化物相关的缺陷位点的层状金属硫化物的条件下将颗粒状催化剂前体硫化。
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36.发明授权Bulk metal hydrotreating catalyst used in the production of low sulfur diesel fuels 有权用于生产低硫柴油燃料的散装金属加氢处理催化剂公开(公告)号：US07709412B2
公开(公告)日：2010-05-04
申请号：US11096501
申请日：2005-04-01
申请人： Stuart S. Shih , Stuart L. Soled , Sabato Miseo
发明人： Stuart S. Shih , Stuart L. Soled , Sabato Miseo
CPC分类号： B01J23/8877 , B01J23/28 , B01J23/8474 , B01J23/882 , C10G45/08
摘要： The invention relates to a bulk metal hydrotreating catalyst, suitable for the production of low sulfur diesel fuels, said bulk metal hydrotreating catalyst being in the oxide state and having a composition of MoxCoyNbz, excluding the oxygen, wherein x, y, and z represent about 0.1 to about 2 moles of Mo, about 0.5 to about 2 moles of Co, and about 0.1 to about 2 moles Nb and wherein Nb is present in amounts from about 2 to about 45 wt. %, Mo is present in amounts from about 1 to about 50 wt. %, and Co is present in amounts from about 10 to about 45 wt. %.
摘要翻译： 本发明涉及适用于生产低硫柴油燃料的本体金属加氢处理催化剂，所述本体金属加氢处理催化剂处于氧化态，并且具有不包括氧的MoxCoyNbz组成，其中x，y和z表示约 0.1至约2摩尔Mo，约0.5至约2摩尔Co和约0.1至约2摩尔Nb，其中Nb以约2至约45重量％的量存在。 ％，Mo的存在量为约1至约50wt。 ％，Co以约10至约45重量％的量存在。 ％。
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37.发明授权Bulk bimetallic catalysts, method of making bulk bimetallic catalysts and hydroprocessing using bulk bimetallic catalysts 有权散装双金属催化剂，制造块状双金属催化剂的方法和使用散装双金属催化剂的加氢处理公开(公告)号：US07648941B2
公开(公告)日：2010-01-19
申请号：US11586399
申请日：2006-10-25
CPC分类号： C10G45/08 , B01J23/883 , B01J23/888 , B01J23/8885 , B01J35/1014 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/038 , B01J37/20
摘要： The invention relates to a process for upgrading hydrocarbonaceous feedstreams by hydroprocessing using bulk bimetallic catalysts. More particularly, the invention relates to a catalytic hydrotreating process for the removal of sulfur and nitrogen from a hydrocarbon feed such as a fuel or a lubricating oil feed. The catalyst is a bulk catalyst comprising a Group VIII metal and a Group VIB metal.
摘要翻译： 本发明涉及通过使用大量双金属催化剂的加氢处理来改质含烃原料流的方法。 更具体地说，本发明涉及一种用于从诸如燃料或润滑油进料的烃进料中除去硫和氮的催化加氢处理方法。 该催化剂是包含VIII族金属和VIB族金属的本体催化剂。
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38.发明授权Bulk Ni-Mo-W catalysts made from precursors containing an organic agent 有权由含有有机试剂的前体制成的大量Ni-Mo-W催化剂公开(公告)号：US07544632B2
公开(公告)日：2009-06-09
申请号：US11227727
申请日：2005-09-14
申请人： Stuart L. Soled , Sabato Miseo , Zhiguo Hou
发明人： Stuart L. Soled , Sabato Miseo , Zhiguo Hou
IPC分类号： B01J31/00 , B01J27/24 , B01J27/047 , B01J27/051 , B01J27/049 , B01J27/043
CPC分类号： C10G65/12 , B01J23/8885 , B01J27/24 , B01J35/002 , B01J35/1014 , B01J35/1038 , B01J37/0018 , B01J37/03 , B01J37/20 , C10G45/08 , C10G45/48 , C10G45/60 , C10G47/02 , C10G47/06 , C10G49/04 , C10G65/02
摘要： Novel bulk tri-metallic catalysts for use in the hydroprocessing of hydrocarbon feeds, as well as a method for preparing such catalysts. The catalysts are prepared from a catalyst precursor containing an organic agent.
摘要翻译： 用于烃进料加氢处理的新型大体三金属催化剂，以及制备这种催化剂的方法。 催化剂由含有有机试剂的催化剂前体制备。
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39.发明授权Method for producing olefins from H.sub.2 and CO.sub.2 using an iron carbide based catalyst 失效使用碳化铁基催化剂从H2和CO2生产烯烃的方法
公开(公告)号：US5140049A
公开(公告)日：1992-08-18
申请号：US698232
申请日：1991-05-06
申请人： Rocco A. Fiato , Stuart L. Soled , Gary W. Rice , Sabato Miseo
发明人： Rocco A. Fiato , Stuart L. Soled , Gary W. Rice , Sabato Miseo
IPC分类号： C07C1/12
CPC分类号： C07C1/12 , C07C2527/22
摘要： This invention relates to a process for producing C.sub.2 -C.sub.20 olefins from a feed stream consisting of H.sub.2 and CO.sub.2 using an iron-carbide based catalyst.
摘要翻译： 本发明涉及一种使用铁碳化物基催化剂从由H 2和CO 2组成的进料流中生产C 2 -C 20烯烃的方法。
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公开(公告)号：US20110190557A1
公开(公告)日：2011-08-04
申请号：US12967354
申请日：2010-12-14
IPC分类号： C07C5/02 , B01J27/051 , B01J37/20 , B01J37/04
CPC分类号： C10G45/08 , B01J23/8885 , B01J27/0515 , B01J33/00 , B01J35/002 , B01J35/0046 , B01J37/04 , B01J37/10 , B01J37/14 , B01J37/20 , C10G45/10 , C10G49/04 , C10G49/06 , C10G2300/202 , C10G2300/70
摘要： In a process for producing a hydroprocessing catalyst, a particulate metal oxide composition comprising an oxide of at least one first metal selected from Group 6 of the Periodic Table of the Elements can be mixed with particles of a sulfide of at least one second metal selected from Groups 8 to 10 of the Periodic Table of the Elements to produce a particulate catalyst precursor. The particulate catalyst precursor can then be sulfided under conditions sufficient to at least partially convert the particulate catalyst precursor into a layered metal sulfide having defect sites associated with the second metal sulfide.
摘要翻译： 在制备加氢处理催化剂的方法中，包含选自元素周期表第6族的至少一种第一金属的氧化物的颗粒状金属氧化物组合物可与选自以下的至少一种第二金属的硫化物颗粒混合： 元素周期表第8至10族，以产生颗粒催化剂前体。 然后可以在足以至少部分地将颗粒状催化剂前体转化成具有与第二金属硫化物相关的缺陷位点的层状金属硫化物的条件下将颗粒状催化剂前体硫化。
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