摘要:
A chiral inorganic mesoporous material characterized by having a chiral twisted structure and being mesoporous; a process for producing the material; and a method of using the material. The process for inorganic mesoporous material production is a method in which one or more polymerizable inorganic monomers selected from the group consisting of polymerizable inorganic monomers and polymerizable inorganic monomers having a functional group capable of having a charge are polymerized in the presence of a solvent using as a template a self-assembly of a chiral surfactant such as an N-(higher alkanoyl)amino acid salt. Examples of the use of the inorganic mesoporous material include the separation of racemates and reaction fields for asymmetric syntheses.
摘要:
A divider comprising a first and second normalizing circuits (5, 6) each which holds a hexadecimal-normalized mantissa data of a dividend and divisor respectively, a selector (7) which inputs the mantissa outputted from the first normalizing circuit (5), a remainder data outputted from a latch (13), a borrow signal (16) of a subtracter (8) which subtracts the mantissa data of the divisor from the mantissa of the dividend data of the remainder data, and control signals 21, 22, 23 respectively indicating a first, second and third and after third division cycles, through-outputs the mantissa data of the dividend in the first division cycle, shifts the mantissa data outputted from the first normalizing circuit (5) to the right by three bits and outputs it when the borrow signal (16) indicates "0" in the second division cycle, shifts the mantissa data outputted from the first normalizing circuit (5) to the left by one bit when the borrow signal (16) indicates "1", and through-outputs the remainder data outputted from the latch (13) in the third division cycle, and a dividing circuit. (100) which calculates a quotient data and a remainder data by using data outputted from the selector (7) and the mantissa data outputted from the second normalizing circuit (6).
摘要:
A portable terminal computer is adapted for connection to an optional unit and a host computer. The optional unit (6) includes a connector (15) for electrical connection to the main body (1) of the portable computer, guides (8), a lock pawl (9) for coupling the optional unit (6) to the main body (1), and a lock release (17). The main body (1) includes guide inserting slots (10) in which guides (8) are inserted, a pawl inserting slot (11) in which the lock pawl (9) is inserted, and an engagement member (30) for engaging the lock pawl (9). The above-described structure allows smooth attachment and detachment of the main body (1) to and from the optional unit (6), thereby preventing malfunction.
摘要:
A valve operating mechanism for an internal combustion engine having a crankshaft and a plurality of intake or exhaust valves normally biased in a valve closing direction includes a rocker shaft, a cam rotatable in synchronism with the crankshaft, a plurality of rocker arms swingably supported on the rocker shaft in association with the valves, respectively, and swingable by the cam, a coupling device for selectively connecting and disconnecting adjacent ones of the rocker arms under hydraulic pressure, and a hydraulic circuit openable and closable according to a rotational speed of the engine for selectively supplying hydraulic pressure to the coupling device. The opening and closing of the hydraulic circuit are controlled in view of a delay in operation thereof based on an angular displacement of the crankshaft or the cam so that the coupling device will be inoperative when the rocker arms are in a predetermined initial interval of a valve opening stroke thereof. The delay in operation of the hydraulic circuit is determined dependent on operating conditions of the internal combustion engine. The predetermined initial interval is defined such that when a piston of the coupling device is urged to slidably move from one of the rocker arms to the other during the initial interval, the piston is struck by the other rocker arm.
摘要:
The present invention relates to a process for the preparation of a zeolitic material having a BEA framework structure comprising the steps of: (i) providing one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YO2 and X2O3, wherein Y is a tetravalent element, and X is a trivalent element; (ii) subjecting the one or more zeolitic materials provided in step (i) to a procedure for removing at least a portion of X, preferably tetrahedrally coordinated X, from the BEA framework structure; wherein the Y:X molar ratios of the one or more zeolitic materials provided in step (i) are respectively comprised in the range of from 1 to 50.
摘要翻译:本发明涉及一种制备具有BEA骨架结构的沸石材料的方法,包括以下步骤:(i)提供一种或多种具有BEA骨架结构的沸石材料,其中BEA骨架结构包含YO 2和X 2 O 3,其中 Y是四价元素,X是三价元素; (ii)使步骤(i)中提供的一种或多种沸石材料从BEA骨架结构中除去至少一部分X,优选四面体配位的X的步骤; 其中步骤(i)中提供的一种或多种沸石材料的Y:X摩尔比分别在1至50的范围内。
摘要:
The present invention relates to a pillared silicate compound comprising a layered silicate structure, and bridging metal atoms located between adjacent silicate layers of the silicate structure, wherein said bridging metal atoms form at least one covalent bond to each of the adjacent silicate layers, as well as a process for the preparation of a pillared silicate compound, and further includes a pillared silicate compound obtainable and or obtained according to said process, as well as a method of catalyzing a chemical reaction comprising the step of contacting one or more chemical compounds with the any of the aforementioned pillared silicate compounds.
摘要:
A process for the preparation of an isomorphously substituted layered silicate comprising (1) providing a mixture containing silica or a precursor thereof, at least one structure directing agent (SDA) allowing for the crystallization of the layered silicate, and water; (2) heating the mixture obtained according to (1) under hydrothermal conditions; (3) adding at least one source at least one element suitable for isomorphous substitution; (4) heating the mixture obtained according to (3) under hydrothermal conditions.
摘要:
The present invention relates to a process for the preparation of a silicate compound, comprising (1) providing at least one layered silicate; and (2) mixing said layered silicate with water and at least one silicon containing compound according to formula R4-mSi[—(SiR2)n—R]m wherein at least one residue R is a leaving group and none of the residues R contains Si; m is 0, 1, 2, 3, or 4; and n is an integer greater than or equal to 0.
摘要:
A titanosilicate represented by the following compositional formula (1), wherein in the infrared absorption spectrum measured in the dehydrated state, the absorption spectrum has an absorption band having a relative maximum value at 930±15 cm−1: xTiO2.(1−X)SiO2 Compositional Formula (1)(wherein x is from 0.0001 to 0.2).
摘要:
A process for easily synthesizing a zeolite substance containing an element having a large ionic radius in the framework at a high ratio. This process comprises the following first to fourth steps: First Step: a step of heating a mixture containing a template compound, a compound containing a Group 13 element of the periodic table, a silicon-containing compound and water to obtain a precursor (A); Second Step: a step of acid-treating the precursor (A) obtained in the first step; Third Step: a step of heating the acid-treated precursor (A) obtained in the second step together with a mixture containing a template compound and water to obtain a precursor (B); and Fourth Step: a step of calcining the precursor (B) obtained in the third step to obtain a zeolite substance.