摘要:
A copolymer comprised of at least one monomer having ethylenic unsaturation and a carboxylic acid group, optionally at least one monomer having ethylenic unsaturation and not having a carboxylic acid group, at least one oxyalkylated monomer having ethylenic unsaturation and terminated by a fatty hydrophobic chain having at least 26 C atoms, and optionally at least one monomer having at least two sites of ethylenic unsaturation. The copolymer is employed as a modifier of rheological properties, stabilizing agent, and/or an antisedimentation or suspension agent for coarse mineral of organic materials, in applications such as drilling muds, textile printing pies, cosmetics, detergents, plant protection, and paints and coatings.
摘要:
An associative thickening copolymer, water-soluble in a neutral or alkaline medium, for charged and/or pigmented, white or colored aqueous compositions is disclosed. The copolymer is composed of (a) at least one monomer with ethylenic unsaturation having at least one carboxylic function, (b) at least one other monomer with ethylenic unsaturation without a carboxylic function, (c) at least one surfactant monomer having at least one urethane function resulting from the reaction of an isocyanate with ethylenic unsaturation with a surfactant compound having a hydroxyl function which is reactive with regard to the --NCO group, wherein said copolymer belongs to the group composed of those which, by definition, placed in aqueous solution with 2% by weight of dry material, brought to a pH of 9 by the addition of ammonia and at a temperature of 20.degree. C., have a Brookfield viscosity at 100 revolutions per minute of at most equal to 220 centipoises.The copolymer may be is used in charged and/or pigmented aqueous compositions such as coating compositions and, more particularly, coating colors, printing pastes, leather finishing products, cosmetic and detergent compositions and drilling fluids.
摘要:
A granular polymer composition having increased water absorption and desorption capability, resistance to photogradation and increased life span, comprising a water-insoluble but swellable cross-linked polymer material formed of at least one polymer and/or copolymer prepared from at least one unsaturated ethylene monomer having at least one carboxylic, amide, sulfuric, sulfonic, phosphoric, phosphonic, or hydroxyl functional group and at least one powdered mineral charge well dispersed in and intimately bonded to said polymer as a result of its introduction into the mixture of monomers of the same type or of a different type before their polymerization into said polymer or copolymer.
摘要:
The invention consists of formulations based on compounds of platinum encapsulated by associative and water-soluble polymers. These formulations are in aqueous form or in the form of granulates. The invention further pertains to pharmaceutical preparations which contain these formulations, and their implementation in the fabrication of an orally administered medication, in polychemotherapy treatments.
摘要:
A method of obtaining homopolymers and/or copolymers in aqueous solution by the use of phosphorous acid and/or its salts or sodium hypophosphite and by neutralization during the polymerisation of the ethylenically unsaturated monomers by the continuous addition, first of all, of bases such as sodium hydroxide, potassium hydroxide or lithium hydroxide and then bases of alkaline earths such as calcium hydroxide, magnesium hydroxide, calcium oxide or magnesium oxide.The polymers obtained by the said method and uses thereof.
摘要:
A stable aqueous liquid polymer composition, which comprises: (i) at least one polyvinyl alcohol (PVA) which has an Ostwald viscosity less than 5 mPanulls corresponding to a degree of polymerization less than 600 and a molar percentage of hydrolysis ranging from 70 to 100 measured from the ester value (DIN 53401), corresponding to a molar percentage of vinyl acetate units from 30 to 0, and (ii) at least one water-soluble polymer at neutral or alkaline pH, the composition controlling the activation of optical brighteners, water retention and viscosities of paper coating colors.
摘要:
A method of dispersing mineral substances in aqueous media, comprising combining:water,at least one mineral substance, anda copolymer which comprises the following monomers in polymerized form:(a) at least one ethylenically unsaturated monomer having at least one carboxyl function,(b) optionally, at least one ethylenically unsaturated monomer having at least one sulphonyl function and/or phosphoryl function,(c) optionally, at least one ethylenically unsaturated monomer having no carboxyl function, and(d) at least one ethylenically unsaturated oxyalkylated monomer terminating with a hydrophobic chain represented by a specified formula,where the sum of the weight percent of (a), (b), (c) and (d) in the copolymer is 100%, and the copolymer has a specific viscosity of at most 50. Mineral substances may be effectively dispersed according to the invention, regardless of the surface properties thereof.
摘要:
Homopolymers and/or copolymers are manufactured by polymerizing ethylenically monounsaturated monomer(s) in an aqueous solution in a reaction vessel containing compounds which contain a phosphorus atom of degree of oxidation less than 5, phosphorous compounds being introduced in amounts of 0.005-0.49 gram-atom phosphorus per mol of unsaturation in said ethylenically unsaturated monomer(s) in the presence of hydrogen peroxide and in the absence of any agent(s) which decomposes hydrogen peroxide thereby forming free radicals, in the absence of any other generator of free radicals, and in the absence of any per salt and/or any other transfer agent.
摘要:
A grinding agent containing polymers and/or copolymers partially neutralized by magnesium, for aqueous suspensions of mineral substances to be used in pigmentary applications is disclosed.A grinding agent composed of polymers and/or copolymers obtained by polymerization and/or copolymerization of acrylic and/or vinyl monomers containing acid groups, and in which the active acid sites are completely or partially neutralized to a degree of 40% to 60%, including terminals, using a neutralizing agent containing magnesium ions, and to a degree of up to 60% using a neutralizing agent containing monovalent ions is disclosed.A procedure for grinding in an aqueous suspension using said agent, as well as the aqueous suspensions produced using said procedure and their applications to the fields of weight fillers, paper coating, paints, and plastics is also disclosed.
摘要:
A stable aqueous zeolite suspension containing, as stabilizing agent, a copolymer comprising units of (i) at least one acrylic monomer having a carboxylic acid group, (ii) at least one acrylic and/or vinyl monomer not having a carboxylic acid group, and (iii) at least one oxyalkylated monomer having ethylenic unsaturation, and terminated by a fatty hydrophobic chain having 12-40 C atoms.