Ion-exchange composition employing resin attachment to dispersant and
method for forming the same
    33.
    发明授权
    Ion-exchange composition employing resin attachment to dispersant and method for forming the same 失效
    使用树脂附着于分散剂的离子交换组合物及其形成方法

    公开(公告)号:US5324752A

    公开(公告)日:1994-06-28

    申请号:US518293

    申请日:1990-05-03

    CPC classification number: B01J20/3221 B01J39/26 B01J41/20 B01J47/006

    Abstract: In accordance with the present invention, an ion-exchange composition has been formed which comprises synthetic resin support particles, dispersant capable of suspending the support particles in an aqueous medium to inhibit or prevent agglomeration, and fine synthetic resin layering particles. In a preferred embodiment, the complex can be formed by contacting a suitable dispersant with monomer in an aqueous solution in which the monomer is insoluble. Under suitable conditions for suspension polymerization, the monomer will polymerize to form resin support particles having dispersant irreversibly attached to those particles. The dispersant is irreversibly attached to the synthetic resin support particles, either by covalent bonding or permanent physical entanglement. The dispersant is also attached to the fine layering particles, either by covalent bonding or electrostatic forces. The result is formation of a support particle-dispersant-layering particle complex.

    Abstract translation: 根据本发明,已经形成了一种离子交换组合物,其包括合成树脂载体颗粒,能够将载体颗粒悬浮在水性介质中以抑制或防止附聚的分散剂和细小的合成树脂层压颗粒。 在优选的实施方案中,络合物可以通过使合适的分散剂与单体在单体不溶的水溶液中接触来形成。 在合适的悬浮聚合条件下,单体将聚合形成具有分散剂不可逆地连接到这些颗粒上的树脂载体颗粒。 分散剂通过共价键或永久性物理缠结不可逆地附着在合成树脂载体颗粒上。 分散剂也通过共价键或静电力连接到细分层颗粒上。 结果是形成载体颗粒 - 分散剂分层颗粒复合物。

    Process for preparation of .alpha.-acetoxy-.alpha.-methyl-N,N'-diacetyl
malonamide
    36.
    发明授权
    Process for preparation of .alpha.-acetoxy-.alpha.-methyl-N,N'-diacetyl malonamide 失效
    制备α-乙酰氧基-α-甲基-N,N'-二乙酰丙酰胺的方法

    公开(公告)号:US4943654A

    公开(公告)日:1990-07-24

    申请号:US819985

    申请日:1986-01-15

    CPC classification number: C07C255/00

    Abstract: Process for the preparation of .alpha.-acetoxy-.alpha.-methyl-N,N'-diacetylmalonamide wherein hydrocyanic acid or a cyanide is reacted in a first step with acetic anhydride and then in a second step the reaction mixture so obtained is treated with acetic acid in the presence of an acid catalyst, wherein the first step is carried out in the presence of a catalyst based on anion exchange resins in which the functional groups are quaternary ammonium or tertiary amine, such .alpha.-acetoxy-.alpha.-methyl-N,N'-diacetylmalonamides being very useful as activators in bleaching and cleaning compositions which are thus active at lower temperatures.

    Abstract translation: 制备α-乙酰氧基-α-甲基-N,N'-二乙酰基丙二酰胺的方法,其中氢氰酸或氰化物在第一步中与乙酸酐反应,然后在第二步中,如此获得的反应混合物用乙酸 在酸催化剂存在下,其中第一步是在催化剂存在下进行的,该催化剂基于阴离子交换树脂,其中官能团是季铵或叔胺,如α-乙酰氧基-α-甲基-N,N ' - 二乙酰基马来酰胺作为漂白和清洁组合物中的活化剂非常有用,因此在较低温度下活性较高。

    Shaped composite adsorbent and a process for preparing the same
    39.
    发明授权
    Shaped composite adsorbent and a process for preparing the same 失效
    成型复合吸附剂及其制备方法

    公开(公告)号:US4414111A

    公开(公告)日:1983-11-08

    申请号:US385410

    申请日:1982-05-17

    Abstract: A shaped composite adsorbent made of a shaped porous material of a skin-core structure comprising a powdery ion-exchange type adsorbent and an ionic group-containing acrylonitrile polymer and wherein said shaped porous material has a semi-permeable skin layer of 0.01 to 1.mu. in thickness and a void volume rate of 50 to 90%, which is capable of adsorbing solutes present at low concentration with high selectivity and high yield. The shaped composite adsorbent of the present invention can be obtained by a process comprising dissolving an ionic group-containing acrylonitrile polymer in and dispersing a powdery ion exchange type adsorbent in an inorganic solvent for said acrylonitrile polymer, extruding the resultant into a coagulating liquid bath to effect coagulation-shaping thereof. The adsorption capacity and mechanical strength of the shaped composite adsorbent of the present invention can be further improved by subjecting the above-obtained coagulation-shaped material to heat treatment in a wet state, without drying.

    Abstract translation: PCT No.PCT / JP81 / 00379 Sec。 371日期1982年5月17日 102(e)日期1982年5月17日PCT提交1981年12月15日PCT公布。 公开号WO82 / 02006 日本1982年6月24日。一种由包含粉末状离子交换型吸附剂和含离子性基团的丙烯腈聚合物的皮肤芯结构的成形多孔材料制成的成形复合吸附剂,其中所述成形多孔材料具有半渗透性 表皮层的厚度为0.01〜1μm,空隙体积率为50〜90%,能够以高选择性和高收率吸附低浓度的溶质。 本发明的成形复合吸附剂可以通过以下方法获得,该方法包括将含离子基团的丙烯腈聚合物溶解并分散在用于所述丙烯腈聚合物的无机溶剂中并将粉末状离子交换型吸附剂分散,将所得物挤出到凝固液浴中 其凝固成型。 本发明的成型复合吸附剂的吸附能力和机械强度可以通过对上述得到的凝固形状的材料进行湿润处理而不干燥而进一步改善。

    Method of preparing a mixture of ion exchange resins
    40.
    发明授权
    Method of preparing a mixture of ion exchange resins 失效
    制备离子交换树脂混合物的方法

    公开(公告)号:US4252905A

    公开(公告)日:1981-02-24

    申请号:US055166

    申请日:1979-07-06

    Applicant: Walter C. Bass

    Inventor: Walter C. Bass

    CPC classification number: B01J47/04 B01J47/126

    Abstract: A method of preparing a mixture of cation and anion exchange resins in the size range of about 10 to 250 microns, comprising combining cation exchange resins and anion exchange resins of a size larger than 60 mesh and grinding the combination of anion and cation exchange resins to a size range of about 10 to 250 microns.

    Abstract translation: 制备大约10至250微米尺寸范围的阳离子和阴离子交换树脂的混合物的方法,包括将阳离子交换树脂和尺寸大于60目的阴离子交换树脂组合并研磨阴离子和阳离子交换树脂的组合, 尺寸范围约为10至250微米。

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