Dehydrogenation process utilizing a pillared layered silicate plus a
base metal or noble metal
    41.
    发明授权
    Dehydrogenation process utilizing a pillared layered silicate plus a base metal or noble metal 失效
    使用柱状层状硅酸盐加贱金属或贵金属的脱氢方法

    公开(公告)号:US4956517A

    公开(公告)日:1990-09-11

    申请号:US459215

    申请日:1989-12-29

    IPC分类号: C07C5/32 C07C5/333

    CPC分类号: C07C5/325 C07C5/3337

    摘要: There is provided a process for the dehydrogenation of saturated hydrocarbons having from 2 to 5 carbon atoms. The feed is contacted with a catalyst which includes a base metal or noble metal which is incorporated into or onto a pillared layered silicate. A preferred pillared layered silicate is kenyaite containing interspathic silica, and a preferred base metal or noble metal is chromium.

    摘要翻译: 提供了具有2至5个碳原子的饱和烃脱氢的方法。 进料与催化剂接触,催化剂包括引入到柱状层状硅酸盐中或其上的贱金属或贵金属。 优选的柱状层状硅酸盐是含有间隙二氧化硅的肯尼亚,优选的贱金属或贵金属是铬。

    Xylene isomerization process to exhaustively convert ethylbenzene and
non-aromatics
    42.
    发明授权
    Xylene isomerization process to exhaustively convert ethylbenzene and non-aromatics 失效
    二甲苯异构化方法彻底转化乙苯和非芳族化合物

    公开(公告)号:US4899011A

    公开(公告)日:1990-02-06

    申请号:US819072

    申请日:1986-01-15

    CPC分类号: C07C5/2724 Y02P20/52

    摘要: A new xylene isomerization process which is capable of converting ethylbenzene and non-aromatic exhaustively while selectively converting xylenes to thermal equilibrium in mixed EB/xylene feeds is proposed. The new process employs a two component catalyst system; each of the components contains a strong hydrogenation metal and a zeolite. The zeolite of each of the two components differs from the other in its selectivity for xylene isomerization and its capacity to deethylete ethylbenzene. That selectivity for xylene isomerization is described by xylene diffusion properties of the zeolite. In one embodiment of the invention, ZSM-5 of greater than 1 micron crystal size and an alpha value of greater than 100 in a first component and ZSM-5 of less than 1 micron crystal size and an alpha of less than 100 in a second catalyst component satisfy the diffusion properties which allow for the exhaustive conversion of ethyl benzene and non-aromatics and the selectivity for xylene isomerization of typical xylene isomerization feeds. In a preferred embodiment, the feed is cascaded over the first component and then the aforementioned second component.

    摘要翻译: 提出了一种新的二甲苯异构化方法,其能够在选择性地将二甲苯转化为混合的EB /二甲苯进料中的热平衡的同时彻底转化乙苯和非芳族。 新工艺采用双组分催化剂体系; 每种组分含有强氢化金属和沸石。 两种组分中的每一种的沸石在二甲苯异构化的选择性及其对乙酸乙酯的能力方面彼此不同。 对二甲苯异构化的选择性由沸石的二甲苯扩散性质描述。 在本发明的一个实施方案中,大于1微米晶体尺寸的ZSM-5和第一组分中的大于100的α值和小于1微米晶体尺寸的ZSM-5和在一秒钟内小于100的α 催化剂组分满足允许乙苯和非芳族化合物的彻底转化以及典型的二甲苯异构化进料的二甲苯异构化的选择性的扩散性质。 在优选实施方式中,进料在第一组分上然后上述第二组分级联。

    Separately supported polymetallic reforming catalyst
    43.
    发明授权
    Separately supported polymetallic reforming catalyst 失效
    单独支撑的多金属重整催化剂

    公开(公告)号:US4493764A

    公开(公告)日:1985-01-15

    申请号:US618791

    申请日:1984-06-08

    CPC分类号: C10G35/09 B01J23/6565

    摘要: There is provided, in accordance with the present invention, a catalyst composition made up of a mixture of two components, one component comprising a minor proportion of platinum and rhenium on a support and the second component comprising a minor proportion of iridium and rhenium on a separate support. A process for reforming a charge stock, such as naphtha, utilizing such catalyst is also provided.

    摘要翻译: 根据本发明,提供了由两种组分的混合物组成的催化剂组合物,一种在载体上包含少量铂和铼的组分,第二组分包含少量的铱和铼 单独支持。 还提供了利用这种催化剂重整电荷原料如石脑油的方法。

    Thermally stable, high surface area, modified mesoporous aluminophosphate material
    44.
    发明授权
    Thermally stable, high surface area, modified mesoporous aluminophosphate material 有权
    热稳定,高表面积,改性介​​孔磷酸铝材料

    公开(公告)号:US06447741B1

    公开(公告)日:2002-09-10

    申请号:US09468451

    申请日:1999-12-21

    IPC分类号: C01B2536

    摘要: A mesoporous aluminophosphate material includes a solid aluminophosphate composition modified with at least one element selected from zirconium, cerium, lanthanum, manganese, cobalt, zinc, and vanadium. This mesoporous aluminophosphate material has a specific surface area of at least 100 m2/g, an average pore size less than or equal to 100 Å, and a pore size distribution such that at least 50% of the pores have a pore diameter less than 100 Å. The material can be used as a support for a catalytic cracking catalyst. Additionally, a method for making such a mesoporous aluminophosphate material is disclosed. The method, which preferably avoids use of organic reagents or solvents, includes providing an aqueous solution containing an inorganic phosphorus component; an inorganic aluminum containing component; and an inorganic modifying component containing at least one element selected from zirconium, cerium, lanthanum, manganese, cobalt, zinc, and vanadium. A solid mesoporous aluminophosphate material is formed in the solution by adjusting the pH of the solution to the range of 7 to 12 and is then recovered.

    摘要翻译: 介孔磷酸铝材料包括用至少一种选自锆,铈,镧,锰,钴,锌和钒的元素改性的固体磷酸铝组合物。 该介孔磷酸铝材料的比表面积为至少100m 2 / g,平均孔径小于或等于100,孔径分布使孔至少50%的孔径小于100 一个。 该材料可用作催化裂化催化剂的载体。 另外,公开了制造这种中孔磷酸铝材料的方法。 优选避免使用有机试剂或溶剂的方法包括提供含有无机磷组分的水溶液; 无机含铝组分; 和含有选自锆,铈,镧,锰,钴,锌和钒中的至少一种元素的无机改性成分。 通过将溶液的pH调节至7至12的范围,在溶液中形成固体介孔磷酸铝材料,然后回收。