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    Synthesis of Chabazite-Containing Molecular Sieves and Their Use in the Conversion of Oxygenates to Olefins
    44.
    发明申请
    Synthesis of Chabazite-Containing Molecular Sieves and Their Use in the Conversion of Oxygenates to Olefins 有权
    含有含异噻唑啉的分子筛的合成及其在烯烃转化中的应用

    公开(公告)号：US20120316312A1

    公开(公告)日：2012-12-13

    申请号：US13589289

    申请日：2012-08-20

    申请人： Machteld M. Mertens ,  Stephen N. Vaughn

    发明人： Machteld M. Mertens ,  Stephen N. Vaughn

    IPC分类号： C07C1/22 ,  C08F210/02 ,  C08F210/06 ,  C08F110/06 ,  C08F110/02

    CPC分类号： C07C1/20 ,  B01J29/85 ,  B01J29/90 ,  B01J2229/42 ,  C01B39/54 ,  C07C2529/85 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/06 ,  C07C11/04

    摘要： In a method of synthesizing a silicoaluminophosphate molecular sieve having 90+% CHA framework-type character, a reaction mixture is prepared comprising sources of water, silicon, aluminum, and phosphorus, as well as an organic template. In one aspect, the reaction mixture is heated at more than 10° C./hour to a crystallization temperature and is retained at the crystallization temperature or within the crystallization temperature range for a crystallization time from 16 hours to 350 hours to produce the silicoaluminophosphate molecular sieve. In another aspect, the reaction mixture is heated at less than 10° C./hour to a crystallization temperature from about 150° C. to about 225° C. and is then retained there for less than 10 hours to produce the silicoaluminophosphate molecular sieve. The molecular sieve can then be recovered from the reaction mixture and, preferably, used in a hydrocarbon conversion process, such as oxygenates to olefins.

    摘要翻译： 在合成具有90 + CHA框架型特征的硅铝磷酸盐分子筛的方法中，制备包含水，硅，铝和磷源以及有机模板的反应混合物。 在一个方面，将反应混合物在大于10℃/小时加热至结晶温度，并保持在结晶温度或结晶温度范围内，结晶时间为16小时至350小时，以产生硅铝磷酸盐分子 筛。 在另一方面，将反应混合物在小于10℃/小时加热至约150℃至约225℃的结晶温度，然后将其保留在少于10小时以产生硅铝磷酸盐分子筛 。 然后可以从反应混合物中回收分子筛，并且优选用于烃转化方法，例如含氧化合物至烯烃。

    Process for manufacturing molecular sieve of MFS framework type and its use
    45.
    发明授权
    Process for manufacturing molecular sieve of MFS framework type and its use 有权
    制造MFS框架型分子筛的工艺及其应用

    公开(公告)号：US08187569B2

    公开(公告)日：2012-05-29

    申请号：US11699166

    申请日：2007-01-29

    申请人： Machteld M. Mertens ,  An Verberckmoes ,  Ivy D. Johnson

    发明人： Machteld M. Mertens ,  An Verberckmoes ,  Ivy D. Johnson

    IPC分类号： C01F7/00 ,  C01B33/36 ,  C01B39/00 ,  C01B39/02 ,  C01B39/04

    CPC分类号： B01J29/7026 ,  C01B39/48 ,  C07C2/12 ,  C10G49/08 ,  C10G2400/20 ,  C10G2400/22 ,  C07C11/02

    摘要： A method of making a crystalline molecular sieve of MFS framework type, said method comprising the steps of (a) adding at least one source of ions of tetravalent element (Y), at least one source of ions of trivalent element (X), at least one hydroxide source (OH−), at least one structure-directing-agent (R), at least one seed source (Seed), and water (H2O) to form a mixture having the following mole composition (expressed in term of oxide): YO2:(n)X2O3:(x)OH−:(y)R:(z)H2O+(m)Seed wherein the m is in the range of from about 10 wtppm to about 2 wt. % (based on total weight of the synthesis mixture), the n is in the range of from about 0.005 to 0.05, the x is in the range of from about 0.01 to about 0.3, the y is in the range of from about 0.03 to about 2; and the z is in the range of from about 3 to about 30; and (b) treating said mixture under crystallization conditions to form said crystalline molecular sieve substantially free of non-MFS material, wherein said crystallization conditions comprise a temperature in the range of from about 150° C. to about 250° C., and crystallization time less than 100 hr, the weight hourly throughput is at least 0.001 hr−1.

    摘要翻译： 一种制备MFS框架型结晶分子筛的方法，所述方法包括以下步骤：（a）将至少一种四价元素（Y）的离子的至少一种源，至少一种三价元素（X）的离子源加入 至少一种氢氧化物源（OH-），至少一种结构导向剂（R），至少一种种子源（Seed）和水（H 2 O），以形成具有以下摩尔组成的混合物 ）：YO 2：（n）X 2 O 3：（x）OH - :( y）R：（z）H 2 O +（m）其中m为约10重量ppm至约2重量％ ％（基于合成混合物的总重量），n在约0.005至0.05的范围内，x在约0.01至约0.3的范围内，y在约0.03至 约2; 并且z在约3至约30的范围内; 和（b）在结晶条件下处理所述混合物以形成基本上不含非MFS材料的所述结晶分子筛，其中所述结晶条件包括在约150℃至约250℃范围内的温度和结晶 时间小于100小时，重量小时产量至少为0.001小时-1。

    Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins
    50.
    发明授权
    Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins 有权
    含有菱沸石的分子筛的合成及其在含氧化合物转化为烯烃的用途

    公开(公告)号：US08268277B2

    公开(公告)日：2012-09-18

    申请号：US12477808

    申请日：2009-06-03

    申请人： Machteld M. Mertens ,  Stephen N. Vaughn

    发明人： Machteld M. Mertens ,  Stephen N. Vaughn

    IPC分类号： C01B37/08

    CPC分类号： C07C1/20 ,  B01J29/85 ,  B01J29/90 ,  B01J2229/42 ,  C01B39/54 ,  C07C2529/85 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/06 ,  C07C11/04

    摘要： In a method of synthesizing a silicoaluminophosphate molecular sieve having 90+% CHA framework-type character, a reaction mixture is prepared comprising sources of water, silicon, aluminum, and phosphorus, as well as an organic template. In one aspect, the reaction mixture is heated at more than 10° C./hour to a crystallization temperature and is retained at the crystallization temperature or within the crystallization temperature range for a crystallization time from 16 hours to 350 hours to produce the silicoaluminophosphate molecular sieve. In another aspect, the reaction mixture is heated at less than 10° C./hour to a crystallization temperature from about 150° C. to about 225° C. and is then retained there for less than 10 hours to produce the silicoaluminophosphate molecular sieve. The molecular sieve can then be recovered from the reaction mixture and, preferably, used in a hydrocarbon conversion process, such as oxygenates to olefins.

    摘要翻译： 在合成具有90 + CHA框架型特征的硅铝磷酸盐分子筛的方法中，制备包含水，硅，铝和磷源以及有机模板的反应混合物。 在一个方面，将反应混合物在大于10℃/小时加热至结晶温度，并保持在结晶温度或结晶温度范围内，结晶时间为16小时至350小时，以产生硅铝磷酸盐分子 筛。 在另一方面，将反应混合物在小于10℃/小时加热至约150℃至约225℃的结晶温度，然后将其保留在少于10小时以产生硅铝磷酸盐分子筛 。 然后可以从反应混合物中回收分子筛，并且优选用于烃转化方法，例如含氧化合物至烯烃。