公开(公告)号：US08163969B2

公开(公告)日：2012-04-24

申请号：US12021096

申请日：2008-01-28

Applicant: Emanuel Hermanus Van Broekhoven ,  Mark Hendrikus Harte ,  Gijsbertus Klaver ,  Jan Nieman

Inventor： Emanuel Hermanus Van Broekhoven ,  Mark Hendrikus Harte ,  Gijsbertus Klaver ,  Jan Nieman

IPC: C07C2/58 ,  C07C2/54

CPC classification number: B01J29/126 ,  B01J29/7007 ,  B01J29/90 ,  B01J35/023 ,  B01J38/56 ,  B01J38/58 ,  B01J2229/18 ,  B01J2229/40 ,  B01J2229/42 ,  C07C2/58 ,  C07C2521/04 ,  C07C2529/12 ,  C07C2529/74 ,  C10G2300/703 ,  C10G2300/805 ,  C10G2400/02 ,  Y02P20/584 ,  C07C9/16

Abstract: An improved alkylation process utilizing a solid-acid catalyst comprising a rare earth containing zeolite and a hydrogenation metal is disclosed.

Abstract translation: 公开了一种利用包含含稀土沸石和氢化金属的固体酸催化剂的改进的烷基化方法。

公开(公告)号：US08088354B2

公开(公告)日：2012-01-03

申请号：US10579595

申请日：2004-11-19

Applicant: Erik Jeroen Laheij ,  Paul O'Connor ,  Dennis Stamires ,  Edisson Morgado, Jr. ,  Marco Antonio Santos de Abreu ,  Márcio Fernandes ,  Michael Brady

Inventor： Erik Jeroen Laheij ,  Paul O'Connor ,  Dennis Stamires ,  Edisson Morgado, Jr. ,  Marco Antonio Santos de Abreu ,  Márcio Fernandes ,  Michael Brady

IPC: C01F7/02

CPC classification number: C04B35/6303 ,  B82Y30/00 ,  C01F7/02 ,  C01F7/34 ,  C01F7/448 ,  C01P2002/04 ,  C01P2002/70 ,  C01P2004/62 ,  C01P2004/64 ,  C04B35/62605 ,  C04B35/63 ,  C04B2235/3218 ,  C04B2235/5454 ,  C04B2235/549

Abstract: Process for the preparation of quasi-crystalline boehmite comprising the steps of: (a) preparing an aqueous precursor mixture comprising a water-insoluble aluminum source; (b) decreasing the pH of the precursor mixture of step (a) by at least 2 units; (c) increasing the pH of the mixture of step (b) by at least 2 units, and (d) aging the mixture of step (c) under hydrothermal conditions to form a quasi-crystalline boehmite. This process provides for the hydrothermal preparation of quasi-crystalline boehmites with high peptizability. The invention therefore further relates to quasi-crystalline boehmites with a high peptizability, measured as the Z-average submicron particle size. This Z-average submicron particle size preferably is less than 500 nm, more preferably less than 300 nm, even more preferably less than 200 nm, and most preferably less than 100 nm.

Abstract translation: 制备准晶体勃姆石的方法，包括以下步骤：（a）制备包含水不溶性铝源的水性前体混合物; （b）将步骤（a）的前体混合物的pH降低至少2单位; （c）将步骤（b）的混合物的pH提高至少2单位，和（d）在水热条件下老化步骤（c）的混合物以形成准结晶勃姆石。 该方法提供了具有高可溶性性的准晶体沸石的水热制备。 因此，本发明进一步涉及具有高可溶性性的准晶体沸石，其测量为Z-平均亚微米粒度。 该Z平均亚微米粒径优选小于500nm，更优选小于300nm，甚至更优选小于200nm，最优选小于100nm。

公开(公告)号：US07964528B2

公开(公告)日：2011-06-21

申请号：US12091362

申请日：2006-10-25

Applicant: Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Johannes Cornelis Sitters ,  Marinus Bruce Cerfontain ,  Bob Gerardus Oogjen

Inventor： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Johannes Cornelis Sitters ,  Marinus Bruce Cerfontain ,  Bob Gerardus Oogjen

IPC: C10G45/00

CPC classification number: B01J23/85 ,  B01J23/002 ,  B01J23/881 ,  B01J23/888 ,  B01J23/8885 ,  B01J35/0006 ,  B01J37/0009 ,  B01J37/0027 ,  B01J37/04 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/04 ,  C10G45/08 ,  C10G45/50 ,  C10G45/60 ,  C10G47/02 ,  C10G47/04 ,  C10G2300/202 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/847

Abstract: The invention relates to a process for the preparation of a shaped bulk catalyst comprising metal oxide particles comprising one or more Group VIII metals and two or more Group VIB metals which process comprises the steps of providing first metal oxidic particles comprising one or more first Group VIII metals and one or more first Group VIB metals, providing separately prepared second metal oxidic particles comprising one or more second Group VIII metals and one or more second Group VIB metals, wherein the composition of Group VIB and Group VIII metals in the first and second metal oxidic particles are different, combining the first and second metal oxidic particles before and/or during shaping and shaping the combined first and second metal oxide particles to form a shaped bulk catalyst. The invention further relates to the shaped bulk catalyst obtainable with the process In sulphided or unsulphided form and the use thereof in hydroprocessing.

Abstract translation: 本发明涉及一种制备成形体积催化剂的方法，其包括包含一种或多种第VIII族金属和两种或更多种VIB族金属的金属氧化物颗粒，其包括以下步骤：提供第一金属氧化物颗粒，其包含一个或多个第一VIII族 金属和一种或多种第一族VIB金属，提供单独制备的包含一种或多种第二族VIII族金属和一种或多种第二族VIB金属的第二金属氧化物颗粒，其中第一和第二金属中的VIB族和第VIII族金属的组成 氧化颗粒是不同的，在第一和第二金属氧化物颗粒的成形和成形之前和/或之间组合第一和第二金属氧化物颗粒以形成成型的本体催化剂。 本发明还涉及通过硫化或未硫化形式的方法获得的成型体催化剂及其在加氢处理中的用途。

公开(公告)号：US07951741B2

公开(公告)日：2011-05-31

申请号：US11271679

申请日：2005-11-10

Applicant: Sonja Eijsbouts

Inventor： Sonja Eijsbouts

IPC: B01J38/16

CPC classification number: B01J23/94 ,  B01J21/18 ,  B01J23/85 ,  B01J23/8878 ,  B01J23/8885 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/084 ,  C10G45/08 ,  C10G49/04 ,  C22B7/009 ,  Y02P10/214

Abstract: The present invention pertains to a catalyst composition comprising at least one non-noble Group VIII metal component, at least two Group VIB metal components, and at least about 1 wt. % of a combustible binder material selected from combustible binders and precursors thereof, the Group VIII and Group VIB metal components making up at least about 50 wt. % of the catalyst composition, calculated as oxides. The invention also pertains to a process for preparing the catalyst, to its use in hydroprocessing and to its recycling. The catalyst according to the invention has a higher strength than corresponding binder-free catalysts, and are easier to recycle than catalysts containing a non-combustible binder.

Abstract translation: 本发明涉及一种催化剂组合物，其包含至少一种非贵金属VIII族金属组分，至少两种VIB族金属组分和至少约1wt。 ％的可燃粘合剂材料选自可燃粘合剂及其前体，第VIII族和第VIB族金属组分构成至少约50wt。 催化剂组成的百分比计算为氧化物。 本发明还涉及一种制备该催化剂的方法，其用于加氢处理和其再循环。 根据本发明的催化剂具有比相应的无粘合剂催化剂更高的强度，并且比含有不可燃粘合剂的催化剂更容易循环。

公开(公告)号：US07781619B2

公开(公告)日：2010-08-24

申请号：US11717845

申请日：2007-03-14

Applicant: Eelko Brevoord ,  Stephan Janbroers ,  Francisco René Mas Cabre ,  Mark Hendrikus Harte

Inventor： Eelko Brevoord ,  Stephan Janbroers ,  Francisco René Mas Cabre ,  Mark Hendrikus Harte

IPC: C07C45/41 ,  C07C45/65

CPC classification number: C07C45/48 ,  Y02P20/582 ,  C07C49/04

Abstract: A process for the production of a ketone having a carbon number between about 20 and about 40 comprising contacting fatty acids containing from about 10 to about 21 carbons atoms with a hydrotalcite catalyst under conditions effective to decarboxylate said acids. More particularly said decarboxylation conditions comprise: a temperature in the range between about 300° C. and about 400° C.; a pressure in the range between about 0.01 and about 5 bar; and a weight hourly space velocity (WHSV) of from about 0.1 to about 10 hr−1.

Abstract translation: 一种制备碳数在约20至约40之间的酮的方法，包括使含有约10至约21个碳原子的脂肪酸与水滑石催化剂在有效使所述酸脱羧的条件下接触。 更具体地说，脱羧条件包括：在约300℃和约400℃之间的范围内的温度; 压力在约0.01至约5巴之间的范围内; 和约0.1至约10小时-1的重时空速（WHSV）。

公开(公告)号：US20100111797A1

公开(公告)日：2010-05-06

申请号：US12532317

申请日：2008-03-20

Applicant: Elbert Arjan De Graaf ,  Jorge Alberto Conzalez ,  Julie Ann Francis ,  Maria Margaret Ludvig

Inventor： Elbert Arjan De Graaf ,  Jorge Alberto Conzalez ,  Julie Ann Francis ,  Maria Margaret Ludvig

IPC: B01J21/16 ,  B01D53/50

CPC classification number: B01J35/0006 ,  B01D53/508 ,  B01D53/8609 ,  B01D53/96 ,  B01D2255/20 ,  B01D2255/2047 ,  B01D2255/2092 ,  B01J21/16 ,  B01J23/007 ,  B01J23/06 ,  B01J23/10 ,  B01J23/78 ,  B01J29/084 ,  B01J37/0036 ,  B01J37/0045 ,  C01F7/005 ,  C01P2002/22 ,  C01P2004/88 ,  C09C1/42 ,  C10G11/182

Abstract: A process is disclosed for the preparation of an additive-containing anionic clay generally comprising the steps of: a) milling a physical mixture of a divalent metal compound and a trivalent metal compound, b) calcining the milled physical mixture at a temperature in the range of about 200 to about 8000 C, and c) rehydrating the calcined mixture in aqueous suspension to form the additive-containing anionic clay, wherein an additive is optionally present in the physical mixture of step (a) and present in the aqueous suspension of step (c), and the additive is essentially free of vanadium.

Abstract translation: 公开了一种制备含添加剂的阴离子粘土的方法，通常包括以下步骤：a）研磨二价金属化合物和三价金属化合物的物理混合物，b）在该范围内的温度下煅烧研磨的物理混合物 约200至约8000℃，和c）在水悬浮液中将煅烧的混合物再水化以形成含添加剂的阴离子粘土，其中任选地将添加剂存在于步骤（a）的物理混合物中并存在于步骤 （c），添加剂基本上不含钒。

公开(公告)号：US20100093519A1

公开(公告)日：2010-04-15

申请号：US12636626

申请日：2009-12-11

Applicant: SCOTT MICHAEL BABITZ

Inventor： SCOTT MICHAEL BABITZ

IPC: B01J29/06 ,  B01J29/04

CPC classification number: C10G2/33 ,  B01D53/94 ,  B01J29/06 ,  B01J29/084 ,  B01J35/002 ,  B01J37/0045 ,  B01J2229/42 ,  C01B3/02 ,  C01B2203/1041 ,  C10G1/086 ,  C10G11/05 ,  C10G29/205 ,  C10G35/06 ,  C10G49/02

Abstract: Process for the preparation of a catalyst comprising the steps of (a) preparing a slurry comprising clay, zeolite, and quasi-crystalline boehmite, provided that the slurry does not comprise peptised quasi-crystalline boehmite, (b) adding a monovalent acid to the slurry, (c) adding a silicon source to the slurry, and (d) shaping the slurry to form particles.This process leads to a catalyst with high accessibility and high attrition resistance.

Abstract translation: 制备催化剂的方法包括以下步骤：（a）制备包含粘土，沸石和准结晶勃姆石的浆料，条件是浆料不包含胶体化的准晶勃姆石，（b）将一价酸加入到 浆料，（c）向浆料中加入硅源，和（d）使浆料成形以形成颗粒。 该方法导致具有高可接近性和高抗磨性的催化剂。

公开(公告)号：US20100043278A1

公开(公告)日：2010-02-25

申请号：US11911168

申请日：2007-06-09

Applicant: Eelko Brevoord ,  Robertus Gerardus Leliveld ,  Stephan Janbroers

Inventor： Eelko Brevoord ,  Robertus Gerardus Leliveld ,  Stephan Janbroers

IPC: C10L1/188

CPC classification number: B01J23/85 ,  B01J23/883 ,  B01J35/0026 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/20 ,  C10G45/08 ,  C10G2300/1011 ,  C10G2300/207 ,  C10G2300/4018 ,  C11C3/123 ,  Y02P30/20

Abstract: A method for the hydrodeoxygenation of an oxygenate feedstock comprising contacting the feedstock with a sulphided catalyst composition under hydrodeoxygenation conditions, wherein the catalyst composition comprises: i) a porous carrier substantially comprised of alumina, the carrier comprising between about 0.001 and about 1 wt. % phosphorous and between about 0.001 and about 1 wt. % silicon (both calculated as oxides) and having a mean pore diameter in the range from about 5 nm to about 40 nm; and, ii) from about 1 to about 20 wt. % of an active metal component (calculated as oxides based on the weight of the composition) borne on said porous carrier and which comprises at least one Group VIB metal and at least one Group VIII metal.

Abstract translation: 一种用于含氧化合物原料的加氢脱氧的方法，包括在加氢脱氧条件下使原料与硫化催化剂组合物接触，其中催化剂组合物包含：i）基本上由氧化铝组成的多孔载体，载体包含约0.001至约1wt。 ％磷，约0.001至约1wt。 ％硅（均计算为氧化物），平均孔径在约5nm至约40nm的范围内; 和，ii）约1至约20wt。 ％的活性金属组分（以基于组合物重量的氧化物计算）承载在所述多孔载体上，并且包含至少一种VIB族金属和至少一种第Ⅷ族金属。

公开(公告)号：US07598202B2

公开(公告)日：2009-10-06

申请号：US11313837

申请日：2005-12-20

Applicant: Paul O'Connor ,  William Jones ,  Dennis Stamires

Inventor： Paul O'Connor ,  William Jones ,  Dennis Stamires

IPC: B01J29/06

CPC classification number: B01J23/002 ,  B01J23/007 ,  B01J23/06 ,  B01J27/232 ,  B01J2523/00 ,  C10G2/33 ,  C10G45/00 ,  C10G45/04 ,  C10G45/46 ,  Y10S208/95 ,  B01J2523/27 ,  B01J2523/31 ,  B01J2523/847 ,  B01J2523/17

Abstract: Novel compositions of matter comprising a cationic layered material and a second compound. The second compound has a reflection in its XRD pattern at 18.5 degrees two-theta, and s second reflection at 29 degrees two-theta. The composition of matter may be used in hydrocarbon conversion, purification, and synthesis processes, such as fluid catalytic cracking and hydroprocessing. The materials are especially suitable for the reduction of SOx and NOx emissions and the reduction of the sulfur and nitrogen content in fuels like gasoline and diesel.

Abstract translation: 包含阳离子层状材料和第二化合物的新型组合物。 第二种化合物在其XRD图案上具有18.5度2θ的反射，在29度处具有第二反射2θ。 物质的组成可用于烃转化，纯化和合成过程，如流化催化裂化和加氢处理。 这些材料特别适用于减少SOx和NOx排放以及减少燃料如汽油和柴油中的硫和氮含量。

公开(公告)号：US20090149317A1

公开(公告)日：2009-06-11

申请号：US12093104

申请日：2006-11-07

Applicant: Dennis Stamires ,  Paul O'Connor

Inventor： Dennis Stamires ,  Paul O'Connor

IPC: B01J21/16

CPC classification number: B01J35/0006 ,  B01J21/12 ,  B01J21/16 ,  B01J23/007 ,  B01J23/02 ,  B01J23/06 ,  B01J23/10 ,  B01J27/16 ,  B01J29/061 ,  B01J29/83 ,  B01J37/031 ,  B01J37/28 ,  C10G11/05

Abstract: Process for the preparation of an aluminium phosphate-containing composition wherein an aluminium source is converted partly to aluminium phosphate using a phosphorus-containing compound and partly to (i) an anionic clay and/or a Al-MII mixed metal (hydr)oxide using a divalent metal (MII) source, (ii) an aluminosilicate using a silicon source, and/or (iii) a MII- aluminosilicate using both a divalent metal source and a silicon source.

Abstract translation: 制备含磷酸铝的组合物的方法，其中使用含磷化合物将铝源部分转化成磷酸铝，并且部分地使用（i）阴离子粘土和/或Al-MII混合金属（hydr）氧化物，使用 二价金属（MII）源，（ii）使用硅源的硅铝酸盐和/或（iii）使用二价金属源和硅源的MII-硅铝酸盐。