公开(公告)号：US20120022279A1

公开(公告)日：2012-01-26

申请号：US13057846

申请日：2009-07-21

申请人： Amandine Cabiac ,  Nicolas Cadran ,  Emmanuelle Guillon ,  Vincent Lecocq ,  Sylvie Maury

发明人： Amandine Cabiac ,  Nicolas Cadran ,  Emmanuelle Guillon ,  Vincent Lecocq ,  Sylvie Maury

IPC分类号： C11C3/10 ,  B01J29/70 ,  C07C5/52 ,  C07C2/24 ,  C07C2/66 ,  B01J29/04 ,  C07C1/24

CPC分类号： C11C3/003 ,  B01J29/70 ,  B01J29/7049 ,  B01J2229/20 ,  C07C1/24 ,  C07C2/66 ,  C07C11/02 ,  C10G45/12 ,  C10G50/00 ,  C10G2300/1088 ,  C10G2300/1096 ,  C10G2400/20 ,  C10G2400/22 ,  C10G2400/30 ,  Y02P30/42 ,  C07C15/107

摘要： A catalyst is described which comprises at least one IZM-2 zeolite and at least one matrix, said zeolite having a chemical composition expressed as the anhydrous base in terms of moles of oxides by the following general formula: XO2: aY2O3: bMnO, in which X represents at least one tetravalent element, Y represents at least one trivalent element and M is at least one alkali metal and/or alkaline-earth metal, a and b respectively representing the number of moles of Y2O3 and MnO; and a is in the range 0.001 to 0.5, b is in the range 0 to 1 and n is in the range 1 to 2. Said catalyst is used in various processes for the transformation of hydrocarbon feeds.

摘要翻译： 描述了包含至少一种IZM-2沸石和至少一种基质的催化剂，所述沸石具有以氧化物的摩尔数表示为无水碱的化学组成，通过以下通式：XO 2：aY 2 O 3：bMnO，其中 X表示至少一种四价元素，Y表示至少一种三价元素，M表示至少一种碱金属和/或碱土金属，a和b分别表示Y 2 O 3和MnO的摩尔数; a在0.001至0.5的范围内，b在0至1的范围内，n在1至2的范围内。所述催化剂用于烃进料转化的各种方法中。

公开(公告)号：US20110182790A1

公开(公告)日：2011-07-28

申请号：US13057911

申请日：2009-10-13

申请人： Guy Richard Chandler ,  Neil Robert Collins ,  Rodney Foo Kok Shin ,  Alexander Nicholas Michael Green ,  Paul Richard Phillips ,  Raj Rao Rajaram ,  Stuart David Reid

发明人： Guy Richard Chandler ,  Neil Robert Collins ,  Rodney Foo Kok Shin ,  Alexander Nicholas Michael Green ,  Paul Richard Phillips ,  Raj Rao Rajaram ,  Stuart David Reid

IPC分类号： B01D53/94 ,  B01J29/072 ,  B01J29/06 ,  B01J29/068 ,  B01J29/076 ,  B01J29/74 ,  B01J29/76 ,  B01J29/78 ,  B01J29/54 ,  B01J29/56 ,  B01J29/58 ,  B01D53/56 ,  B01D53/34

CPC分类号： B01J29/7015 ,  B01D53/9418 ,  B01D53/9431 ,  B01D2251/206 ,  B01D2251/2062 ,  B01D2255/20723 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01J23/22 ,  B01J23/72 ,  B01J23/745 ,  B01J29/061 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J29/56 ,  B01J29/7049 ,  B01J29/74 ,  B01J29/76 ,  B01J29/763 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/10 ,  B01J37/0018 ,  B01J37/0203 ,  B01J37/0236 ,  B01J37/04 ,  B01J37/08 ,  B01J37/086 ,  B01J37/10 ,  B01J2229/186 ,  F01N3/2066 ,  F01N2370/04 ,  Y02A50/2325 ,  Y02T10/24

摘要： A synthetic alumino silicate zeolite catalyst containing at least one catalytically active transition metal selected from the group consisting of Cu, Fe, Hf, La, Au, In, V, lanthanides and Group VIII transition metals, which alumino silicate zeolite is a small pore aluminosilicate zeolite having a maximum ring size of eight tetrahedral atoms, wherein the mean crystallite size of the aluminosilicate zeolite determined by scanning electron microscope is >0.50 micrometer.

摘要翻译： 含有选自Cu，Fe，Hf，La，Au，In，V，镧系元素和第Ⅷ族过渡金属中的至少一种催化活性过渡金属的合成铝硅酸盐沸石催化剂，该铝硅酸盐沸石是小孔硅铝酸盐 沸石的最大环尺寸为八面体原子，其中通过扫描电子显微镜测定的硅铝酸盐沸石的平均微晶尺寸> 0.50微米。

公开(公告)号：US07468126B2

公开(公告)日：2008-12-23

申请号：US11467093

申请日：2006-08-24

申请人： Stacey I. Zones ,  Guang Zhang ,  Kamala Krishna ,  Joseph A. Biscardi ,  Paul Marcantonio ,  Euthimios Vittoratos

发明人： Stacey I. Zones ,  Guang Zhang ,  Kamala Krishna ,  Joseph A. Biscardi ,  Paul Marcantonio ,  Euthimios Vittoratos

IPC分类号： C10G45/64 ,  B01J29/06

CPC分类号： C01B39/04 ,  B01J29/70 ,  B01J29/7049 ,  B01J29/74 ,  B01J37/0009 ,  B01J2229/42 ,  C01B39/48 ,  C10G45/64

摘要： The invention is directed to a method of making a small crystal SSZ-32 zeolite, known as SSZ-32X. The catalyst is suitable for use in a process whereby a feed including straight chain and slightly branched paraffins having 10 or more carbon atoms is dewaxed to produce an isomerized product, with increased yield of isomerized material and decreased production of light ends.

摘要翻译： 本发明涉及制备称为SSZ-32X的小晶体SSZ-32沸石的方法。 该催化剂适合用于将包含具有10个或更多个碳原子的直链和轻度支化链烷烃的进料脱蜡以产生异构化产物，同时异构化材料的产率增加和轻馏分产生减少的方法。

公开(公告)号：US07390763B2

公开(公告)日：2008-06-24

申请号：US10698250

申请日：2003-10-31

申请人： Stacey I. Zones ,  Guang Zhang ,  Kamala R. Krishna ,  Joseph A. Biscardi ,  Paul Marcantonio ,  Euthimios Vittoratos

发明人： Stacey I. Zones ,  Guang Zhang ,  Kamala R. Krishna ,  Joseph A. Biscardi ,  Paul Marcantonio ,  Euthimios Vittoratos

IPC分类号： B01J29/06

CPC分类号： C01B39/04 ,  B01J29/70 ,  B01J29/7049 ,  B01J29/74 ,  B01J37/0009 ,  B01J2229/42 ,  C01B39/48 ,  C10G45/64

摘要： The invention is directed to a method of making a small crystal SSZ-32 zeolite, known as SSZ-32X. The catalyst is suitable for use in a process whereby a feed including straight chain and slightly branched paraffins having 10 or more carbon atoms is dewaxed to produce an isomerized product, with increased yield of isomerized material and decreased production of light ends.

公开(公告)号：US07141529B2

公开(公告)日：2006-11-28

申请号：US10393817

申请日：2003-03-21

申请人： Joseph A. Biscardi ,  Darren P. Fong ,  Paul Marcantonio

发明人： Joseph A. Biscardi ,  Darren P. Fong ,  Paul Marcantonio

IPC分类号： B01J27/182

CPC分类号： B01J29/74 ,  B01J29/7049 ,  B01J29/78 ,  B01J37/0009 ,  B01J2229/20 ,  B01J2229/42 ,  C10G45/64 ,  C10G65/043 ,  C10G2300/1022 ,  C10G2300/1059 ,  C10G2300/1062 ,  C10G2300/4018

摘要： The invention is directed to a method of making a catalyst comprising an intermediate pore size molecular sieve, preferably a zeolite of the MTT or TON type. SSZ-32 and ZSM-22 are examples of such molecular sieves. This catalyst is modified with a metal or metals selected from the group consisting of Ca, Cr, Mg, La, Ba, Pr, Sr, K and Nd. The catalyst is additionally loaded with a Group VII metal or metals for hydrogenation purposes. The catalyst is suitable for use in a process whereby a feed including straight chain and slightly branched paraffins having 10 or more carbon atoms is isomerized.

摘要翻译： 本发明涉及制备包含中等孔径分子筛，优选MTT或TON型沸石的催化剂的方法。 SSZ-32和ZSM-22是这种分子筛的实例。 该催化剂用选自Ca，Cr，Mg，La，Ba，Pr，Sr，K和Nd的金属或金属进行改性。 催化剂另外装有用于氢化目的的第VII族金属或金属。 该催化剂适合用于含有具有10个或更多碳原子的直链和轻链烷烃的进料异构化的方法。

公开(公告)号：US20060229193A1

公开(公告)日：2006-10-12

申请号：US11449421

申请日：2006-06-07

申请人： Joseph Biscardi ,  Darren Fong ,  Paul Marcantonio

发明人： Joseph Biscardi ,  Darren Fong ,  Paul Marcantonio

IPC分类号： B01J29/04

CPC分类号： B01J29/74 ,  B01J29/7049 ,  B01J29/78 ,  B01J37/0009 ,  B01J2229/20 ,  B01J2229/42 ,  C10G45/64 ,  C10G65/043 ,  C10G2300/1022 ,  C10G2300/1059 ,  C10G2300/1062 ,  C10G2300/4018

摘要： The invention is directed to a method of making a catalyst comprising an intermediate pore size molecular sieve, preferably a zeolite of the MTT or TON type. SSZ-32 and ZSM-22 are examples of such molecular sieves. This catalyst is modified with a metal or metals selected from the group consisting of Ca, Cr, Mg, La, Ba, Pr, Sr, K and Nd. The catalyst is additionally loaded with a Group VIII metal or metals for hydrogenation purposes. The catalyst is suitable for use in a process whereby a feed including straight chain and slightly branched paraffins having 10 or more carbon atoms is isomerized.

摘要翻译： 本发明涉及制备包含中等孔径分子筛，优选MTT或TON型沸石的催化剂的方法。 SSZ-32和ZSM-22是这种分子筛的实例。 该催化剂用选自Ca，Cr，Mg，La，Ba，Pr，Sr，K和Nd的金属或金属进行改性。 催化剂另外装载有第VIII族金属或用于氢化目的的金属。 该催化剂适合用于含有具有10个或更多碳原子的直链和轻链烷烃的进料异构化的方法。

公开(公告)号：US07081237B2

公开(公告)日：2006-07-25

申请号：US10928104

申请日：2004-08-30

申请人： Ulrich Mueller ,  Friedrich Hill ,  Norbert Rieber

发明人： Ulrich Mueller ,  Friedrich Hill ,  Norbert Rieber

IPC分类号： C01B39/40

CPC分类号： C01G23/04 ,  B01J20/18 ,  B01J29/7049 ,  B01J29/89 ,  C01B37/00 ,  C01B37/005 ,  C01B39/026 ,  C01B39/04 ,  C01B39/36 ,  Y02P20/125 ,  Y10S423/22

摘要： Process for the preparation of a crystalline solid comprising at least one zeolitic material, in which the solid is crystallized from at least one precursor compound and the reaction discharge of the crystallization is fed directly to a drying stage.

摘要翻译： 制备包含至少一种沸石材料的结晶固体的方法，其中固体从至少一种前体化合物结晶并将结晶的反应放出直接进料到干燥阶段。

公开(公告)号：US20050155907A1

公开(公告)日：2005-07-21

申请号：US11012051

申请日：2004-12-13

申请人： Joseph Biscardi ,  Darren Fong ,  Paul Marcantonio

发明人： Joseph Biscardi ,  Darren Fong ,  Paul Marcantonio

IPC分类号： B01J29/70 ,  B01J29/74 ,  B01J29/78 ,  B01J37/00 ,  C10G45/64 ,  C10G65/04 ,  C10G73/38

CPC分类号： B01J29/74 ,  B01J29/7049 ,  B01J29/78 ,  B01J37/0009 ,  B01J2229/20 ,  B01J2229/42 ,  C10G45/64 ,  C10G65/043 ,  C10G2300/1022 ,  C10G2300/1059 ,  C10G2300/1062 ,  C10G2300/4018

摘要： The invention is directed to a method of making a catalyst comprising an intermediate pore size molecular sieve, preferably a zeolite of the MTT or TON type. SSZ-32 and ZSM-22 are examples of such molecular sieves. This catalyst is modified with a metal or metals selected from the group consisting of Ca, Cr, Mg, La, Ba, Pr, Sr, K and Nd. The catalyst is additionally loaded with a Group VIII metal or metals for hydrogenation purposes. The catalyst is suitable for use in a process whereby a feed including straight chain and slightly branched paraffins having 10 or more carbon atoms is isomerized.

摘要翻译： 本发明涉及制备包含中等孔径分子筛，优选MTT或TON型沸石的催化剂的方法。 SSZ-32和ZSM-22是这种分子筛的实例。 该催化剂用选自Ca，Cr，Mg，La，Ba，Pr，Sr，K和Nd的金属或金属进行改性。 催化剂另外装载有第VIII族金属或用于氢化目的的金属。 该催化剂适合用于含有具有10个或更多碳原子的直链和轻链烷烃的进料异构化的方法。

公开(公告)号：US5545788A

公开(公告)日：1996-08-13

申请号：US350308

申请日：1994-12-06

申请人： Jane C. Cheng ,  Tracy J. Huang

发明人： Jane C. Cheng ,  Tracy J. Huang

IPC分类号： B01J29/06 ,  B01J29/70 ,  C01B39/06 ,  C01B39/48 ,  C07C2/66 ,  C07C15/02 ,  C10G29/20 ,  C10G50/00 ,  C10G59/02 ,  C10L1/16

CPC分类号： B01J29/7049 ,  B01J29/70 ,  C01B39/065 ,  C01B39/48 ,  C10G29/205 ,  C10G50/00 ,  C10G59/02 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  Y02P20/52

摘要： The present invention relates to a process for alkylating a reformate feedstream containing benzene, toluene, xylenes, and ethylbenzene, said process comprising:1) contacting said reformate feedstream with a hydrocarbon stream comprising C.sub.2 -C.sub.5 olefins in the presence of a catalyst comprising an active form of synthetic porous crystalline MCM-49 under benzene alkylation conditions whereby an effluent stream is produced having a benzene content at least 50 wt % less than that of said feedstream, an octane rating no less than that of said feedstream, and a total liquid product greater than that of said feedstream; and2) collecting the gasoline boiling range fraction of said effluent stream.

摘要翻译： 本发明涉及一种用于烷基化含有苯，甲苯，二甲苯和乙苯的重整油进料流的方法，所述方法包括：1）在催化剂存在下，使所述重整油进料流与包含C 2 -C 5烯烃的烃流接触， 在苯烷基化条件下合成多孔结晶MCM-49的形式，由此产生苯含量低于所述原料流的至少50重量％的流出物流，辛烷值不低于所述原料流的辛烷值，以及总液体产物 大于所述进料流的流量; 和2）收集所述流出物流的汽油沸程级分。

公开(公告)号：US4300013A

公开(公告)日：1981-11-10

申请号：US158807

申请日：1980-06-12

申请人： Thomas V. Whittam

发明人： Thomas V. Whittam

IPC分类号： C07C4/12 ,  B01J29/00 ,  B01J29/70 ,  B01J29/76 ,  B01J29/80 ,  C01B33/38 ,  C01B39/04 ,  C01B39/48 ,  C07C1/00 ,  C07C4/06 ,  C07C5/27 ,  C07C15/02 ,  C07C67/00 ,  C10G11/05

CPC分类号： C10G11/05 ,  B01J29/70 ,  B01J29/7049 ,  B01J29/76 ,  B01J29/80 ,  C01B39/48 ,  C07C4/06 ,  C07C5/2708 ,  C07C5/2737 ,  B01J2229/36 ,  B01J2229/37 ,  C07C2529/70 ,  Y02P20/52 ,  Y10S208/02 ,  Y10S585/94

摘要： A silica-containing material related to zeolites and referred to hereinafter as FU-1 has the composition 0.6 to 1.4 R.sub.2 O.Al.sub.2 O.sub.3.over 5 SiO.sub.2.O to 40 H.sub.2 O, (where R is a monovalent cation or 1/n of a cation of valency n) and is characterized inter alia by its X-ray diffraction pattern. It can be made by hydrothermal synthesis in presence of methylated quaternary onium compounds. It is useful as a catalyst for hydrocarbon conversion reactions, especially isomerization of xylenes.

摘要翻译： 与沸石相关并且以下称为FU-1的含二氧化硅的材料具有组成为0.6至1.4的R2O.Al2O3.O 5 SiO 2 O至40 H 2 O（其中R为单价阳离子或1 / n的阳离子 化合价n），其特征在于其X射线衍射图。 在甲基化季铵化合物存在下，可以通过水热合成制得。 它可用作烃转化反应的催化剂，特别是二甲苯的异构化。