METHANOL SYNTHESIS PROCESS
    56.
    发明申请
    METHANOL SYNTHESIS PROCESS 有权
    甲醇合成方法

    公开(公告)号:US20120165418A1

    公开(公告)日:2012-06-28

    申请号:US13378595

    申请日:2010-05-24

    IPC分类号: C07C27/00

    摘要: A methanol synthesis process includes reacting a process gas containing hydrogen, carbon dioxide and carbon monoxide over a catalyst including shaped units formed from a reduced and passivated catalyst powder the powder including copper in the range 10-80% by weight, zinc oxide in the range 20-90% by weight, alumina in the range 5-60% by weight and optionally one or more oxidic promoter compounds selected from compounds of Mg, Cr, Mn, V, Ti, Zr, Ta, Mo, W, Si and rare earths in the range 0.01-10% by weight, to form a product gas, and condensing methanol, water and oxygenate by-products therefrom, wherein the total oxygenate by-product level in the condensate is below 500 ppm.

    摘要翻译: 甲醇合成方法包括使含有氢气,二氧化碳和一氧化碳的工艺气体在催化剂上反应,所述催化剂包括由还原和钝化的催化剂粉末形成的成形单元,该粉末包括10-80重量%的铜,范围为10-80重量%的氧化锌 20-90重量%,氧化铝在5-60重量%范围内,以及任选的一种或多种选自Mg,Cr,Mn,V,Ti,Zr,Ta,Mo,W,Si和稀有金属的氧化促进剂化合物 地球在0.01-10重量%的范围内,以形成产物气体,并从其中冷凝甲醇,水和含氧化合物副产物,其中冷凝物中的总含氧化合物副产物水平低于500ppm。