公开(公告)号：US20080009574A1

公开(公告)日：2008-01-10

申请号：US11780926

申请日：2007-07-20

Applicant: Daniel Huenefeld ,  Carl Nichols

Inventor： Daniel Huenefeld ,  Carl Nichols

IPC: C08G63/183 ,  C08K5/13

CPC classification number: C08G63/183 ,  C08G63/6886 ,  C08K5/13 ,  C08K2201/008 ,  C08L67/02 ,  C08L77/06 ,  C08L2666/20

Abstract: The present invention relates to polyamide-polyester barrier blends that possess improved gas barrier, clarity, and organoleptic properties, as well as containers (e.g., bottles), sheets, and films formed from such barrier resins. The invention further relates to polyamide-compatible polyethylene terephthalate resins that are useful in forming these improved polyamide-polyester polymer blends. The invention still further relates to cost-effective recycling of articles formed from polyamide-polyester polymer blends.

Abstract translation: 本发明涉及具有改善的气体屏障，透明度和感官特性的聚酰胺 - 聚酯阻隔共混物，以及由这种阻隔树脂形成的容器（例如瓶子），片材和薄膜。 本发明还涉及可用于形成这些改进的聚酰胺 - 聚酯聚合物共混物的聚酰胺相容的聚对苯二甲酸乙二醇酯树脂。 本发明还涉及由聚酰胺 - 聚酯聚合物共混物形成的制品的成本有效的回收。

公开(公告)号：US20070270529A1

公开(公告)日：2007-11-22

申请号：US11751452

申请日：2007-05-21

Applicant: H. HARALD LUTZMANN ,  JAMES D. IDOL ,  GERALD W. MILLER

Inventor： H. HARALD LUTZMANN ,  JAMES D. IDOL ,  GERALD W. MILLER

IPC: C08K5/15

CPC classification number: C08L33/06 ,  C08K5/05 ,  C08K5/09 ,  C08K5/435 ,  C08K2201/008 ,  C08L23/06 ,  C08L33/20 ,  C08L35/06 ,  C08L39/06 ,  C08L69/00 ,  C08L71/02 ,  C08L71/12 ,  C08L77/00 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2205/08 ,  C08L2666/02

Abstract: Thermoplastic compositions comprising polyacrylonitriles that contain greater than 90% acrylonitrile as monomer, or copolymers of such polyacrylonitriles with an olefinic unsaturated co-monomer, can be formed by the use of certain compatibilizers and/or thermal stabilizers. Other thermoplastic compositions comprising the high nitrile polyacrylonitriles can be obtained by melt blending the polyacrylonitriles with certain aromatic engineering thermoplastic polymers in the presence of compatibilizers and thermal stabilizers. All of the foregoing high nitrile compositions have been found to possess good optical and gas barrier properties, and good stress crack resistance.

Abstract translation: 包含大于90％丙烯腈作为单体的聚丙烯腈或这种聚丙烯腈与烯属不饱和共聚单体的共聚物的热塑性组合物可以通过使用某些相容剂和/或热稳定剂形成。 包含高腈聚丙烯腈的其它热塑性组合物可以通过在相容剂和热稳定剂的存在下将聚丙烯腈与某些芳族工程热塑性聚合物熔融共混来获得。 已经发现所有上述高腈组合物具有良好的光学和气体阻隔性能，以及良好的抗应力开裂性。

公开(公告)号：US20070138707A1

公开(公告)日：2007-06-21

申请号：US11618437

申请日：2006-12-29

Applicant: Edwin Sisson ,  Arianna Giovannini ,  Simone Ferrero

Inventor： Edwin Sisson ,  Arianna Giovannini ,  Simone Ferrero

IPC: B29C49/00

CPC classification number: B29C49/06 ,  B29C2049/069 ,  B32B1/02 ,  B32B27/08 ,  B32B27/18 ,  B32B27/20 ,  B32B27/302 ,  B32B27/304 ,  B32B27/306 ,  B32B27/34 ,  B32B27/36 ,  B32B27/365 ,  B32B2250/02 ,  B32B2307/4026 ,  B32B2307/412 ,  B32B2307/7242 ,  B32B2327/06 ,  B32B2331/04 ,  B32B2367/00 ,  B32B2369/00 ,  B32B2377/00 ,  B32B2439/00 ,  B32B2439/60 ,  B65D1/0207 ,  B65D1/0215 ,  B65D25/54 ,  C08K3/013 ,  C08K5/0041 ,  C08K5/005 ,  C08K2201/008 ,  C08L67/02 ,  C08L77/06 ,  C08L77/10 ,  C08L2201/10 ,  C08L2203/10 ,  G02B1/04 ,  G02B5/22 ,  Y10T428/1352 ,  Y10T428/1372 ,  Y10T428/1379 ,  Y10T428/1383 ,  Y10T428/139 ,  Y10T428/1393 ,  Y10T428/1397 ,  Y10T428/25 ,  Y10T428/31736 ,  Y10T428/31786 ,  C08L2666/20

Abstract: A transparent article includes a continuous polyester matrix having at least one incompatible filler dispersed therein. The incompatible filler provides domains in the polyester matrix, each domain having a particular dimension, thus providing a range of dimensions for the domains in the article. To create haze, the dimensions are within the range of from about 380 nm to about 720 nm. Once the range of dimensions is determined, a light absorbent composition can be found which absorbs light at a range of wavelengths that at least substantially covers the range of dimensions of the domains. In doing so, it has been found that the haze of the article can be substantially masked. Method for producing the article and for masking the haze are also provided.

Abstract translation: 透明制品包括具有分散在其中的至少一种不相容填料的连续聚酯基质。 不相容的填料在聚酯基质中提供结构域，每个结构域具有特定的维度，从而为制品中的结构域提供一定范围的尺寸。 为了产生雾度，尺寸在约380nm至约720nm的范围内。 一旦确定了尺寸范围，就可以发现吸光组合物，其吸收至少基本上覆盖畴的尺寸范围的波长范围的光。 在这样做时，已经发现制品的雾度可以基本上被遮蔽。 还提供了制造物品和掩蔽雾度的方法。

公开(公告)号：US20070087145A1

公开(公告)日：2007-04-19

申请号：US10567360

申请日：2004-07-06

Applicant: Misa Hanita ,  Atsushi Kikuchi ,  Yoshihiro Kitano ,  Toshiki Yamada

Inventor： Misa Hanita ,  Atsushi Kikuchi ,  Yoshihiro Kitano ,  Toshiki Yamada

IPC: B32B27/08

CPC classification number: C08L67/02 ,  C08K5/098 ,  C08K2201/008 ,  C08L77/00 ,  Y10T428/1352 ,  C08L2666/20

Abstract: A packing container having oxygen absorbing layers comprising a base material resin component (component A) and an oxygen absorbing functional component (component B), the oxygen absorbing layers having an islands-in-the-sea structure in which the base material resin component (component A) is forming a sea portion and the oxygen absorbing functional component (component B) is forming island portions, wherein the ratio (N/M). of the whole surface area (N cm2) of the island portions of the oxygen absorbing functional component (component B) in the oxygen absorbing layers to the volume (M cm3) of the packing container is not smaller than 20 (cm−1). The packing container exhibits excellent gas barrier property and oxygen absorbing property from the beginning of filling the content and continuously works to lower the initial concentration of oxygen in the content from the beginning of filling.

Abstract translation: 具有氧吸收层的包装容器包括基材树脂组分（组分A）和氧吸收功能组分（组分B），氧吸收层具有海岛结构，其中基材树脂组分 组分A）形成海水部分，氧吸收功能组分（组分B）形成岛部分，其中比例（N / M）。 氧吸收层中氧吸收功能组分（组分B）的岛部分的整个表面积（N cm 2）的体积（M cm 3） ）不小于20（cm -1）以上。 包装容器从填充内容开始时显示出优异的阻气性和氧吸收性，并且连续地起作用以从填充开始降低含量中的氧初始浓度。

公开(公告)号：US07157147B2

公开(公告)日：2007-01-02

申请号：US10490162

申请日：2002-09-13

Applicant: Yoji Inui ,  Naoto Mochizuki ,  Isao Masada ,  Ryuji Ishimoto ,  Hideki Umekawa ,  Hironori Honda ,  Yoshihiro Kimura

Inventor： Yoji Inui ,  Naoto Mochizuki ,  Isao Masada ,  Ryuji Ishimoto ,  Hideki Umekawa ,  Hironori Honda ,  Yoshihiro Kimura

IPC: B32B27/30 ,  C08J7/04 ,  C09D129/04

CPC classification number: B32B27/08 ,  B32B27/06 ,  C08J7/047 ,  C08J2429/00 ,  C08K3/34 ,  C08K2201/008 ,  C08L29/04 ,  C08L71/02 ,  C09D129/04 ,  Y10T428/31667 ,  Y10T428/31909 ,  C08L2666/14 ,  C08L2666/54

Abstract: Provided are a gas-barrier film which is a laminate comprising a substrate layer comprising a thermoplastic resin film and a gas-barrier layer comprising a hydrolysate of a silicon alkoxide, a stratified silicate and a polyvinyl alcohol base resin, wherein a radius (Rg) of gyration of a scattering matter which is measured by light scattering in the gas-barrier layer described above is 2.4 μm or less, and the silicon alkoxide and/or the hydrolysate thereof are present between the layers of the stratified silicate present in the above gas-barrier layer. The above film shows an excellent gas-barrier property even under such a high humidity as exceeding 90% RH.

Abstract translation: 提供一种阻气膜，其是包含由热塑性树脂膜构成的基材层和包含硅醇盐的水解物，层状硅酸盐和聚乙烯醇基础树脂的阻气层的层压体，其中半径（Rg） 在上述阻气层中通过光散射测量的散射物质的回转为2.4μm以下，硅烷醇盐和/或其水解物存在于上述气体中存在的层状硅酸盐层之间 - 屏障层。 即使在超过90％RH的高湿度下，上述膜也具有优异的阻气性。

公开(公告)号：US20060293448A1

公开(公告)日：2006-12-28

申请号：US11513147

申请日：2006-08-31

Applicant: Katsunori Nishiura ,  Kazuyuki Fukuda ,  Toshihiko Takaki

Inventor： Katsunori Nishiura ,  Kazuyuki Fukuda ,  Toshihiko Takaki

IPC: C08L29/04 ,  C08G63/02

CPC classification number: C09D129/04 ,  B32B27/08 ,  B32B27/28 ,  C08J7/047 ,  C08J2369/00 ,  C08J2429/00 ,  C08K5/3155 ,  C08K5/5415 ,  C08K2201/008 ,  C08L29/04 ,  C08L29/06 ,  C08L33/02 ,  C08L2312/08 ,  C08L2666/04 ,  C09J133/06

Abstract: A composition having gas-barrier properties, which can produce a resin film having gas-barrier properties under high humidity conditions and high abrasion resistance, and a coating film formed by thermally treating a film-like product of the composition having gas-barrier properties and a method for producing the same are provided. A composition having gas-barrier properties, comprising a water-soluble polymer having hydroxyl group (A), a water-soluble polymer having carboxyl group (B), a metal alkoxide and/or a hydrolysis condensate thereof (C), and an esterification catalyst (E), such that the weight ratio of the component (A) and the component (B) is 97/3 to 3/97, and the component (C) is contained in an amount ranging from 1 part by weight to 400 parts by weight, while the component (E) is contained in an amount ranging from 0.01 part by weight to 100 parts by weight, relative to 100 parts by weight of a mixture of the component (A) and the component (B); and a coating film obtained by thermally treating a film-like product of the composition having gas-barrier properties.

公开(公告)号：US20060167167A1

公开(公告)日：2006-07-27

申请号：US10521079

申请日：2003-01-14

Applicant: Tomohiro Ooba ,  Kazuhisa Sakae

Inventor： Tomohiro Ooba ,  Kazuhisa Sakae

IPC: C08K3/04

CPC classification number: C08G18/5072 ,  C08G18/10 ,  C08G18/7642 ,  C08G2190/00 ,  C08K3/013 ,  C08K5/0016 ,  C08K5/5435 ,  C08K5/57 ,  C08K2201/008 ,  C08L75/04

Abstract: A curing composition contains a polymer having two or more thiol groups per molecule, a compound having two or more isocyanate groups per molecule, and carbon black, and further contains a filler of which main ingredient is silicic acid or a silicate, or contains an organic filler of which main ingredient is pulverized coal. The curing composition has satisfactory storage stability of base compound and satisfactory curability event after storage of the base compound and, furthermore, gives a cured compound having sufficient strength at break, hardness, and gas-barrier properties. The curing composition is hence suitable for use as a sealant for insulating glass manufacture, vehicle window frames, etc.

Abstract translation: 固化组合物包含每分子具有两个或更多个硫醇基的聚合物，每分子具有两个或更多个异氰酸酯基的化合物和炭黑，并且还含有主要成分是硅酸或硅酸盐或含有有机物的填料 主要成分是粉煤的填料。 固化组合物具有令人满意的碱性化合物的保存稳定性和储存基础化合物后的令人满意的固化性事件，此外，得到具有足够的断裂强度，硬度和阻气性的固化化合物。 因此，固化组合物适合用作中空玻璃制造用密封剂，车窗框等。

公开(公告)号：US20060122311A1

公开(公告)日：2006-06-08

申请号：US11221182

申请日：2005-09-07

Applicant: Myung Kim ,  Minki Kim ,  Sehyun Kim ,  Youngtock Oh ,  Jaeyong Shin ,  Youngchul Yang

Inventor： Myung Kim ,  Minki Kim ,  Sehyun Kim ,  Youngtock Oh ,  Jaeyong Shin ,  Youngchul Yang

IPC: C08K9/04

CPC classification number: C08L23/06 ,  C08K2201/008 ,  C08L23/0861 ,  C08L29/02 ,  C08L77/00 ,  C08L2666/06

Abstract: An article having barrier properties is provided. The article includes a nanocomposite having barrier properties dispersed in a polyolefin resin to have superior mechanical strength and form a strong barrier to oxygen, organic solvent, and moisture.

Abstract translation: 提供了具有阻隔性的物品。 该制品包括具有分散在聚烯烃树脂中的阻隔性能的纳米复合材料以具有优异的机械强度并形成对氧，有机溶剂和水分的强势垒。

公开(公告)号：US20050282948A1

公开(公告)日：2005-12-22

申请号：US11119425

申请日：2005-04-28

Applicant: Yang Li ,  Hongde Xu ,  Zhanxia Lv ,  Xueqin Zhang ,  Zhenjun Zhang ,  Lina Zhang ,  Ji Zeng ,  Jiedong Zhu ,  Mingyi Liao ,  Dingsheng Yu

Inventor： Yang Li ,  Hongde Xu ,  Zhanxia Lv ,  Xueqin Zhang ,  Zhenjun Zhang ,  Lina Zhang ,  Ji Zeng ,  Jiedong Zhu ,  Mingyi Liao ,  Dingsheng Yu

IPC: C08F2/44 ,  C08F36/04 ,  C08F36/06 ,  C08F36/08 ,  C08F236/06 ,  C08F236/08 ,  C08F236/10 ,  C08F297/04 ,  C08K3/34 ,  C08K9/00 ,  C08K9/04 ,  C08K9/06 ,  C08L9/00 ,  C08L9/06 ,  C08L53/02

CPC classification number: C08F36/04 ,  C08F236/10 ,  C08K3/346 ,  C08K2201/008 ,  C08F2/44 ,  C08L21/00

Abstract: The present invention relates to nanocomposite materials based on a copolymer of at least two monomers selected from the group consisting of butadiene, isoprene and styrene and a clay mineral dispersed therein, and a process for preparing them. By using an organolithium as the initiator, an organic hydrocarbon solvent as the solvent and a polar additive as the microstructure modifier by means of a classical anionic solution polymerization process, at least two monomers selected from the group consisting of butadiene, isoprene and styrene are in-situ intercalation polymerized in the presence of an organoclay, thereby obtaining a delaminated nanocomposite material which is excellent in mechanical properties, heat resistance, barrier property, chemical resistance and is well balanced in its comprehensive properties.

Abstract translation: 本发明涉及基于选自丁二烯，异戊二烯和苯乙烯的至少两种单体和分散在其中的粘土矿物的共聚物的纳米复合材料及其制备方法。 通过使用有机锂作为引发剂，作为溶剂的有机烃溶剂和通过经典的阴离子溶液聚合方法的极性添加剂作为微结构改性剂，选自丁二烯，异戊二烯和苯乙烯中的至少两种单体在 在有机粘土存在下聚合的嵌段，从而获得机械性能，耐热性，阻隔性，耐化学性优异并且其综合性能良好平衡的分层纳米复合材料。

公开(公告)号：US06878774B2

公开(公告)日：2005-04-12

申请号：US10003228

申请日：2001-12-06

Applicant: Atsushi Kikuchi ,  Ikuo Komatsu ,  Toshiki Yamada ,  Yoshihiro Kitano ,  Go Saito

Inventor： Atsushi Kikuchi ,  Ikuo Komatsu ,  Toshiki Yamada ,  Yoshihiro Kitano ,  Go Saito

IPC: C08K5/56 ,  B32B27/08 ,  B32B27/18 ,  B32B27/36 ,  C08F279/00 ,  C08F279/02 ,  C08K5/098 ,  C08L23/08 ,  C08L51/04 ,  C08L77/00

CPC classification number: B32B27/08 ,  B32B27/18 ,  B32B27/306 ,  B32B27/34 ,  B32B27/36 ,  B32B2307/7244 ,  B32B2439/40 ,  C08F279/00 ,  C08F279/02 ,  C08K5/098 ,  C08K2201/008 ,  C08K2201/012 ,  C08L23/0861 ,  C08L51/04 ,  C08L2312/00 ,  C08L2666/24 ,  C08L2666/02 ,  C08L2666/14 ,  C08L2666/04

Abstract: A resin composition obtained by blending a thermoplastic resin that can be melt-extruded at a solubility parameter of not smaller than 9.5 with an organic oxidizing component and with a transition metal catalyst, the organic oxidizing component being a polyene having a functional group on a side chain or at a terminal thereof. The resin composition has excellent moldability and gas shut-off property. A multi-layer container having an oxygen-absorbing layer of this resin composition exhibits excellent gas-barrier property and is capable of favorably preserving the content.

Abstract translation: 将可溶性参数为9.5以上的可熔融挤出的热塑性树脂与有机氧化成分和过渡金属催化剂混合而获得的树脂组合物，有机氧化成分为侧面具有官能团的多烯 链或其末端。 树脂组合物具有优异的成型性和气体切断性。 具有该树脂组合物的氧吸收层的多层容器具有优异的阻气性，能够有利地保持该含量。