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    Zeolite Itq-30
    71.
    发明申请
    Zeolite Itq-30 有权
    沸石Itq-30

    公开(公告)号：US20080027247A1

    公开(公告)日：2008-01-31

    申请号：US11597808

    申请日：2005-05-25

    申请人： Avelino Corma Canos ,  Maria Diaz Cabañas

    发明人： Avelino Corma Canos ,  Maria Diaz Cabañas

    IPC分类号： C01B39/48 ,  B01J29/70 ,  C10G11/02

    CPC分类号： C01B39/48 ,  B01J29/035 ,  B01J29/70 ,  C01B37/02 ,  C10G11/05 ,  C10G49/08 ,  C10G2300/1092 ,  C10G2300/1096 ,  C10G2400/30

    摘要： The invention relates to a laminar microporous crystalline zeolite material known as ITQ-30 which, as when synthesized, has a chemical composition in the anhydrous state with the following molar relations: x (M1/n XO2):y YO2:SiO2:z R, wherein: x represents a value less than 0.1, which can be equal to zero; y has a value of less than 0.1, which can be equal to zero; z has a value of less than 0.1; M is selected from among H+, NH4+, one or more +n inorganic cations and combinations of same; X represents one or more +3 oxidation state chemical elements; Y represents one or more +4 oxidation state chemical elements; and R represents one or more organic compounds. The invention also relates to the method of preparing said zeolite, involving the use of one or more organic additives in a reaction mixture which is crystallized by means of heating, and to the use thereof in processes for the separation and transformation of organic compounds.

    摘要翻译： 本发明涉及一种称为ITQ-30的层状微孔结晶沸石材料，其当合成时具有以下摩尔关系的无水状态的化学组成：x（M 1 / n X 0） z 2，其中：x表示小于0.1的值，其可以等于零; y的值小于0.1，可以等于零; z的值小于0.1; M选自H +，N + 4 +，一种或多种+ n种无机阳离子及其组合; X表示一种或多种+3氧化态化学元素; Y表示一个或多个+4氧化态化学元素; R表示一种或多种有机化合物。 本发明还涉及制备所述沸石的方法，涉及在通过加热结晶的反应混合物中使用一种或多种有机添加剂，以及其用于分离和转化有机化合物的方法中的用途。

    Microporous crystalline material (ITQ-15), method for the preparation thereof and its use in processes for separating and transforming organic compounds
    72.
    发明授权
    Microporous crystalline material (ITQ-15), method for the preparation thereof and its use in processes for separating and transforming organic compounds 失效
    微孔结晶材料（ITQ-15），其制备方法及其用于分离和转化有机化合物的方法

    公开(公告)号：US06797254B2

    公开(公告)日：2004-09-28

    申请号：US10412115

    申请日：2003-04-11

    申请人： Avelino Corma Canos ,  María José Diaz Cabañas ,  Fernando Rey García

    发明人： Avelino Corma Canos ,  María José Diaz Cabañas ,  Fernando Rey García

    IPC分类号： C01B3948

    CPC分类号： C01B39/12 ,  B01J29/04 ,  B01J29/70 ,  C01B39/06 ,  C01B39/08 ,  C01B39/48

    摘要： A microporous crystalline material of a zeolitic nature that, in a calcinated and anhydrous state, has a chemical composition represented by the formula: x(M1/nXO2):yYO2:zGeO2:(1−z)TO2 wherein x has a value below 0.2, y has a value below 0.1, z has a value below 1, with at least one of x, z and y being above zero; M is H+ or at least an inorganic cation with a +n charge; X is at least one chemical element with a +3 oxidation status; Y is at least one chemical element with a + oxidation status; and T is at least one chemical element with a +4 oxidation status (Si, Ti, Sn, V), this material having a specific X-ray diffraction pattern. A method for preparation of the material and its use as a catalyst in organic compound separation and transformation processes is also described.

    摘要翻译： 沸石性质的微孔结晶材料，其在煅烧和无水状态下具有由下式表示的化学组成：其中x具有低于0.2的值，y具有低于0.1的值，z具有低于1的值，其中在 x，z和y中的至少一个高于零; M是H +或至少一个具有+ n电荷的无机阳离子; X是至少一种具有+3氧化状态的化学元素; Y是具有+氧化状态的至少一种化学元素; 并且T是具有+4氧化状态（Si，Ti，Sn，V）的至少一种化学元素，该材料具有特定的X射线衍射图。 还描述了用于制备材料的方法及其在有机化合物分离和转化过程中作为催化剂的用途。

    Process for the obtainment of a light paraffin isomerization catalyst
    75.
    发明授权
    Process for the obtainment of a light paraffin isomerization catalyst 失效
    获得轻链烷烃异构化催化剂的方法

    公开(公告)号：US5264648A

    公开(公告)日：1993-11-23

    申请号：US742602

    申请日：1991-08-08

    申请人： Jesus J. Lazaro Munoz ,  Avelino Corma Canos ,  Juana M. Frontela Delgado

    发明人： Jesus J. Lazaro Munoz ,  Avelino Corma Canos ,  Juana M. Frontela Delgado

    IPC分类号： B01J29/20 ,  C07C5/27 ,  C07C5/13

    CPC分类号： B01J29/20 ,  C07C5/2791 ,  B01J2229/16 ,  B01J2229/36 ,  B01J2229/37

    摘要： The invention refers to a process for the obtainment of a catalyst useful in the isomerization of light paraffins, fundamentally based on acid treatment of a synthetic mordenite at temperatures between 40.degree. and 100.degree. C. followed by treatment with steam-air at temperatures between 300.degree. and 600.degree. C. which make it possible to optimize the SiO.sub.2 /Al.sub.2 O.sub.3 framework ratio and the amount of extraframework aluminum of the zeolite. The mordenite thus obtained is mixed with an inorganic refractory oxide such as Al.sub.2 O.sub.3 and a metal of group VIII, basically Pt, is added in an amount between 0.1 and 0.5% by weight referred to the final catalyst.The catalyst has been tested in the isomerization of light refinery fractions (C.sub.5 and C.sub.6) and has a high activity and selectivity of branched isomers with a low production of gases and a high octane number for the light gasoline obtained.

    摘要翻译： 本发明涉及获得可用于轻链烷烃异构化的催化剂的方法，其基本上是基于在40℃至100℃之间的合成丝光沸石的酸处理，然后在300℃的温度下用蒸汽 - 空气处理 DEG和600℃，这使得可以优化SiO 2 / Al 2 O 3骨架比和沸石的粉末铝量。 由此获得的丝光沸石与无机耐火氧化物如Al 2 O 3和基本上Pt的金属基本上相加，以与最终催化剂相关的0.1至0.5重量％的量加入。 催化剂已经在轻馏分馏分（C5和C6）的异构化中进行了测试，并且具有高分子异构体的活性和选择性，其中所得到的轻质汽油具有低产气和高辛烷值。

    Sinter Resistant Metal Species In Zeolites
    76.
    发明申请
    Sinter Resistant Metal Species In Zeolites 有权

    公开(公告)号：US20220016611A1

    公开(公告)日：2022-01-20

    申请号：US17311516

    申请日：2020-01-14

    申请人： Lichen Liu ,  Avelino Corma Canos

    发明人： Lichen Liu ,  Avelino Corma Canos

    IPC分类号： B01J29/74 ,  B01J37/04 ,  B01J37/08 ,  B01J35/02 ,  C07C5/333

    摘要： The invention relates to a medium or large pore synthetic zeolite comprising at least 0.02 wt %, based on the weight of the zeolite, of a catalytic metal selected from the group consisting of Ru, Rh, Pd, Ag, Os, Ir, Pt, Au, Mo, W, Re, Co, Ni, Zn, Cr, Mn, Ce, Ga, Cu and combinations thereof, which is present as catalytic metal particles, wherein at least 60% by number of said catalytic metal particles have a particle size of 2.0 nm or less, and at least 0.005 wt %, based on the weight of the zeolite, of an alkali metal or alkaline earth metal selected from the group consisting of Li, Na, K, Cs, Ca, Mg, Ba and Sr and combinations thereof, wherein, if the zeolite comprises in the zeolite framework a trivalent element Y selected from the group consisting of Al, B, Ga Fe and combinations thereof, the SiO2:Y2O3 ratio is greater than 200:1.