Cross-linked composition and method of forming the same

    公开(公告)号:US09822221B2

    公开(公告)日:2017-11-21

    申请号:US14912174

    申请日:2014-10-29

    摘要: A cross-linked composition comprises the reaction product of a first reactant having at least one hydroxyl or amine (functional) group, a second reactant having at least one hydroxyl or amine (functional) group, and a siloxane having at least two terminal anhydride groups reactive with the functional groups of the first and second reactants. The first reactant is selected from the group of first siloxanes having at least one hydroxyl or amine group, a first organic alcohol having at least one hydroxyl group, a first organic amine having at least one amine group, or combinations thereof. The second reactant is selected from the group of second siloxanes having at least one hydroxyl or amine group, a second organic alcohol having at least one hydroxyl group, a second organic amine having at least one amine group, or combinations thereof. If utilized, the first siloxanes and/or second siloxanes are different from the siloxane.

    Resin-linear organosiloxane block copolymers
    79.
    发明授权
    Resin-linear organosiloxane block copolymers 有权
    树脂线性有机硅氧烷嵌段共聚物

    公开(公告)号:US08957147B2

    公开(公告)日:2015-02-17

    申请号:US13822113

    申请日:2011-09-21

    摘要: Organosiloxane block copolymers, curable compositions, and solid compositions derived from these block copolymers are disclosed. The organosiloxane block copolymers comprise: 40 to 90 mole percent disiloxy units of the formula [R12—SiO2/2] 10 to 60 mole percent trisiloxy units of the formula [R2SiO3/2] 0.5 to 35 mole percent silanol groups [≡SiOH] where R1 is independently a C1 to C30 hydrocarbyl, R2 is independently a C1 to C20 hydrocarbyl, wherein; the disiloxy units [R12SiO2/2] are arranged in linear blocks having an average of from 10 to 400 disiloxy units [R12SiO2/2] per linear block, the trisiloxy units [R2SiO3/2] are arranged in non-linear blocks having a molecular weight of at least 500 g/mol, and at least 30% of the non-linear blocks are crosslinked with each other, each linear block is linked to at least one non-linear block, and the organosiloxane block copolymer has a molecular weight (Mw) of at least 20,000 g/mole.

    摘要翻译: 公开了有机硅氧烷嵌段共聚物,可固化组合物和衍生自这些嵌段共聚物的固体组合物。 有机硅氧烷嵌段共聚物包含:40至90摩尔%的式[R 12 -SiO 2/2] 10至60摩尔%的式[R 2 SiO 3/2]的3-甲硅烷氧基单元为0.5至35摩尔%的硅烷醇基[≡SiOH] R 1独立地为C 1至C 30烃基,R 2独立地为C 1至C 20烃基,其中: 二甲硅烷氧基单元[R 12 SiO 2/2]排列成每线性嵌段平均为10〜400个二甲硅烷基单元[R 12 SiO 2/2]的线性嵌段,三硅氧烷单元[R 2 SiO 3/2]排列在具有分子 至少500g / mol的重量,至少30%的非线性嵌段彼此交联,每个直链嵌段连接至少一个非线性嵌段,有机硅氧烷嵌段共聚物的分子量( Mw)至少为20,000g / mol。