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公开(公告)号：US07906681B2
公开(公告)日：2011-03-15
申请号：US12924048
申请日：2010-09-20
IPC分类号： C07F9/02 , B01J27/188 , B01J27/00 , B01J31/00 , C07C2/02
CPC分类号： C07F9/46 , B01J31/189 , B01J2231/20 , B01J2531/007 , B01J2531/62 , C07C2/32 , C07C2/36 , C07C2531/14 , C07C2531/22 , C07C2531/24 , C08F4/69 , C08F10/00 , C08F110/02 , C08F2500/02 , C08F4/69146 , C08F4/69267
摘要： A new P—N—P ligand is useful in ethylene oligomerizations. In combination with i) a source of chromium and ii) an activator such as methylalumoxane; the ligand of this invention may be used to prepare an oligomer product that contains a mixture of hexenes and octenes. The hexenes and octenes produced with this ligand contain very low levels of internal olefins when produced under preferred reaction conditions.
摘要翻译： 新的P-N-P配体可用于乙烯低聚。 与i）铬源和ii）活化剂如甲基铝氧烷; 本发明的配体可用于制备含有己烯和辛烯的混合物的低聚物产物。 当在优选的反应条件下产生时，用该配体产生的己烯和辛烯含有非常低水平的内烯烃。
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公开(公告)号：US20110015061A1
公开(公告)日：2011-01-20
申请号：US12924048
申请日：2010-09-20
CPC分类号： C07F9/46 , B01J31/189 , B01J2231/20 , B01J2531/007 , B01J2531/62 , C07C2/32 , C07C2/36 , C07C2531/14 , C07C2531/22 , C07C2531/24 , C08F4/69 , C08F10/00 , C08F110/02 , C08F2500/02 , C08F4/69146 , C08F4/69267
摘要： A new P—N—P ligand is useful in ethylene oligomerizations. In combination with i) a source of chromium and ii) an activator such as methylalumoxane; the ligand of this invention may be used to prepare an oligomer product that contains a mixture of hexenes and octenes. The hexenes and octenes produced with this ligand contain very low levels of internal olefins when produced under preferred reaction conditions.
摘要翻译： 新的P-N-P配体可用于乙烯低聚。 与i）铬源和ii）活化剂如甲基铝氧烷; 本发明的配体可用于制备含有己烯和辛烯的混合物的低聚物产物。 当在优选的反应条件下产生时，用该配体产生的己烯和辛烯含有非常低水平的内烯烃。
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83.发明申请SELECTIVE OLEFIN DIMERIZATION WITH SUPPORTED METAL COMPLEXES ACTIVATED BY ALKYLALUMINUM COMPOUNDS OR IONIC LIQUIDS 有权具有支持的金属络合物的选择性烯化二烯化合物由ALKYLALUMINUM化合物或离子液体公开(公告)号：US20110004039A1
公开(公告)日：2011-01-06
申请号：US12828797
申请日：2010-07-01
IPC分类号： C07C2/32
CPC分类号： C07C2/34 , B01J21/08 , B01J31/0231 , B01J31/0272 , B01J31/0275 , B01J31/0295 , B01J37/0207 , B01J37/0209 , B01J2231/20 , B01J2531/842 , C07C2/32 , C07C2521/08 , C07C2531/14 , C07C2531/22
摘要： Methods for dimerizing alpha-olefins utilizing immobilized buffered catalysts wherein the catalytic component is of the form: where X is a halogen, n=2 or 3, M=Ti, V, Cr, Mn, Fe, Co and Ni and R1, R2, R3 and R4 are selected from the group consisting of hydrogen, alkyl, aryl, alkenyl, alkinyl, alkyloxy, substituted aryl, and X are provided. A method for dimerizing alpha-olefins utilizing the immobilized buffered catalysts and a co-catalyst is also provided.
摘要翻译： 使用固定化缓冲催化剂二聚α-烯烃的方法，其中催化组分的形式为：其中X是卤素，n = 2或3，M = Ti，V，Cr，Mn，Fe，Co和Ni以及R1，R2 ，R3和R4选自氢，烷基，芳基，烯基，炔基，烷氧基，取代的芳基和X。 还提供了利用固定化缓冲催化剂和助催化剂二聚α-烯烃的方法。
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84.发明申请OLIGOMERIZATION OF ALPHA OLEFINS USING METALLOCENE-SSA CATALYST SYSTEMS AND USE OF THE RESULTANT POLYALPHAOLEFINS TO PREPARE LUBRICANT BLENDS 有权使用金属 - SSA催化剂体系的ALPHA烯烃的低级化和用于制备润滑剂混合物的成分聚合物的使用公开(公告)号：US20100317904A1
公开(公告)日：2010-12-16
申请号：US12816077
申请日：2010-06-15
申请人： Brooke L. Small , Kenneth D. Hope , Albert P. Masino , Max P. McDaniel , Richard M. Buck , William B. Beaulieu , Qing Yang , Eduardo J. Baralt , Eric J. Netemeyer , Bruce Kreischer
发明人： Brooke L. Small , Kenneth D. Hope , Albert P. Masino , Max P. McDaniel , Richard M. Buck , William B. Beaulieu , Qing Yang , Eduardo J. Baralt , Eric J. Netemeyer , Bruce Kreischer
CPC分类号： C07C2/32 , B01J21/04 , B01J21/12 , B01J27/053 , B01J27/08 , B01J31/143 , B01J37/24 , B01J37/26 , B01J2231/20 , B01J2531/48 , C07C2/30 , C07C5/05 , C07C2531/14 , C07C2531/22 , C08F4/65912 , C08F4/65916 , C08F10/14 , C08F110/14 , C08F2410/01 , C10G2300/1088 , C10G2300/302 , C10G2300/304 , C10G2300/703 , C10G2400/22 , C10M105/04 , C10M107/08 , C10M107/10 , C10M143/08 , C10M2203/024 , C10M2205/026 , C10M2205/0265 , C10M2205/028 , C10M2205/0285 , C10N2220/021 , C10N2220/022 , C10N2220/023 , C10N2220/028 , C10N2220/032 , C10N2230/02 , C10N2230/10 , C10N2230/34 , C10N2230/74 , C10N2270/00 , Y02P20/52 , C08F4/65922 , C08F2500/02 , C08F2500/17
摘要： This disclosure provides for alpha olefin oligomers and polyalphaolefins (or PAOs) and methods of making the alpha olefin oligomers and PAOs. This disclosure encompasses metallocene-based alpha olefin oligomerization catalyst systems, including those that include at least one metallocene and an activator comprising a solid oxide chemically-treated with an electron withdrawing anion. The alpha olefin oligomers and PAOs prepared with these catalyst systems can have a high viscosity index combined with a low pour point, making them particularly useful in lubricant compositions and as viscosity modifiers.
摘要翻译： 本公开提供了α-烯烃低聚物和聚α-烯烃（或PAO）以及制备α-烯烃低聚物和PAO的方法。 本公开内容包括基于茂金属的α-烯烃低聚催化剂体系，包括至少一种金属茂和包含用吸电子阴离子化学处理的固体氧化物的活化剂的催化剂体系。 用这些催化剂体系制备的α-烯烃低聚物和PAO可以具有与低倾点相结合的高粘度指数，使得它们在润滑剂组合物和粘度调节剂中特别有用。
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公开(公告)号：US20100298618A1
公开(公告)日：2010-11-25
申请号：US12734770
申请日：2008-11-05
申请人： Vugar Aliyev , Mohammed Al-Hazmi , Fuad Mosa , Peter M. Fritz , Heinz Bölt , Anina Wöhl , Wolfgang Müller , Florian Winkler , Anton Wellenhofer , Uwe Rosenthal , Bernd H. Müller , Marko Hapke , Normen Peulecke
发明人： Vugar Aliyev , Mohammed Al-Hazmi , Fuad Mosa , Peter M. Fritz , Heinz Bölt , Anina Wöhl , Wolfgang Müller , Florian Winkler , Anton Wellenhofer , Uwe Rosenthal , Bernd H. Müller , Marko Hapke , Normen Peulecke
CPC分类号： B01J31/189 , B01J31/143 , B01J31/188 , B01J2231/20 , B01J2531/0258 , B01J2531/62 , C07C2/36 , C07C2531/14 , C07C2531/24
摘要： The present invention relates to a catalyst composition comprising: (a) a binuclear chromium(II) complex; (b) a ligand of the general structure (A) R1R2P—N(R3)—P(R4)—N(R5)—H or (B) R1R2P—N(R3)—P(R4)—N(R5)—PR6R7, wherein R1, R2, R3, R4, R5, R6 and R7 are independently selected from halogen, amino, trimethylsilyl, C1-C10-alkyl, aryl and substituted aryl, wherein the PNPN- or PNPNP-unit is optionally part of a ring system; and (c) an activator or co-catalyst, as well as to a process for oligomerization of ethylene.
摘要翻译： 本发明涉及一种催化剂组合物，其包含：（a）双核铬（II）络合物; （R）R（R）-N（R 5）-H或（B）R 1 R 2 P -N（R 3）-P（R 4）-N（R 5） -PR 6 R 7，其中R 1，R 2，R 3，R 4，R 5，R 6和R 7独立地选自卤素，氨基，三甲基甲硅烷基，C 1 -C 10 - 烷基，芳基和取代的芳基，其中PNPN-或PNPNP-单元任选地是 环系; 和（c）活化剂或助催化剂，以及乙烯低聚方法。
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86.发明申请CATALYST COMPOSITION FOR OLIGOMERIZATION OF ETHYLENE OLIGOMERIZATION PROCESS AND METHOD FOR ITS PREPARATION 有权用于乙烯低聚化方法低级化的催化组合物及其制备方法公开(公告)号：US20100292423A1
公开(公告)日：2010-11-18
申请号：US12735072
申请日：2008-11-13
申请人： Vugar Aliyev , Fuad Mosa , Mohammed Al-Hazmi
发明人： Vugar Aliyev , Fuad Mosa , Mohammed Al-Hazmi
IPC分类号： C08F4/54
CPC分类号： B01J31/04 , B01J31/128 , B01J31/143 , B01J2231/20 , C07C2/30 , C07C2531/04 , C07C2531/14 , Y02P20/52
摘要： Catalyst composition for the oligomerization of ethylene, comprising (i) an at least partially hydrolyzed transition metal compound, obtainable by controlled addition of water to a transition metal compound having the general formula MXm(OR′)4-m or MXm(OOCR′)4-m, wherein R′ is an alkyl, alkenyl, aryl, aralkyl or cycloalkyl group, X is halogen, preferably Cl or Br, and m is from 0 to 4; preferably 0-3; and (ii) an organoaluminum compound as a cocatalyst, wherein the molar ratio of water and transition metal compound is within a range of between about (0.01-3):1; a process for oligomerization of ethylene and a method for preparing the catalyst composition.
摘要翻译： 用于乙烯低聚的催化剂组合物，其包含（i）至少部分水解的过渡金属化合物，其可通过将具有通式MX m（OR'）4-m或MX m（OOCR'）的过渡金属化合物控制加入而获得， 4-m，其中R'是烷基，烯基，芳基，芳烷基或环烷基，X是卤素，优选Cl或Br，m是0-4; 优选0-3; 和（ii）作为助催化剂的有机铝化合物，其中水和过渡金属化合物的摩尔比在约（0.01-3）：1之间的范围内; 乙烯低聚方法和制备催化剂组合物的方法。
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公开(公告)号：US07829749B2
公开(公告)日：2010-11-09
申请号：US12584170
申请日：2009-09-01
CPC分类号： C07F9/46 , B01J31/189 , B01J2231/20 , B01J2531/007 , B01J2531/62 , C07C2/32 , C07C2/36 , C07C2531/14 , C07C2531/22 , C07C2531/24 , C08F4/69 , C08F10/00 , C08F110/02 , C08F2500/02 , C08F4/69146 , C08F4/69267
摘要： A new P-N-P ligand is useful in ethylene oligomerizations. In combination with i) a source of chromium and ii) an activator such as methylalumoxane; the ligand of this invention may be used to prepare an oligomer product that contains a mixture of hexenes and octenes. The hexenes and octenes produced with this ligand contain very low levels of internal olefins when produced under preferred reaction conditions.
摘要翻译： 新的P-N-P配体可用于乙烯低聚。 与i）铬源和ii）活化剂如甲基铝氧烷; 本发明的配体可用于制备含有己烯和辛烯的混合物的低聚物产物。 当在优选的反应条件下产生时，用该配体产生的己烯和辛烯含有非常低水平的内烯烃。
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88.发明申请METHOD FOR PRODUCING ORGANOMETALLIC FRAMEWORK MATERIALS CONTAINING MAIN GROUP METAL IONS 有权生产含有主要金属离子的有机骨架材料的方法公开(公告)号：US20100166644A1
公开(公告)日：2010-07-01
申请号：US12063522
申请日：2006-08-18
申请人： Markus Schubert , Ulrich Mueller , Markus Tonigold , Roger Ruetz
发明人： Markus Schubert , Ulrich Mueller , Markus Tonigold , Roger Ruetz
CPC分类号： C01B3/0026 , B01D53/02 , B01D2253/204 , B01J20/226 , B01J20/28014 , B01J20/28057 , B01J31/1691 , B01J31/1805 , B01J31/2239 , B01J31/226 , B01J2231/12 , B01J2231/20 , B01J2531/21 , B01J2531/22 , B01J2531/23 , B01J2531/25 , B01J2531/31 , B01J2531/32 , B01J2531/33 , C07C51/418 , C07F5/069 , F17C11/007 , Y02E60/321 , Y02E60/327 , C07C55/24 , C07C63/28 , C07C63/307 , C07C63/38
摘要： The present invention relates to a process for preparing a porous metal-organic framework by reacting at least one metal compound in which the metal is Be, Mg, Ca, Sr, Ba, Al, Ga or In with at least one at least bidentate organic compound and also the use of such porous metal-organic frameworks.
摘要翻译： 本发明涉及通过使金属为Be，Mg，Ca，Sr，Ba，Al，Ga或In的至少一种金属化合物与至少一种至少二齿有机的金属化合物来制备多孔金属 - 有机骨架的方法 化合物以及这种多孔金属 - 有机骨架的使用。
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公开(公告)号：US07691180B2
公开(公告)日：2010-04-06
申请号：US10564258
申请日：2004-07-16
CPC分类号： C07D213/20 , B01J31/0224 , B01J31/0278 , B01J31/0288 , B01J31/26 , B01J2231/20 , B01J2231/4205 , B01J2231/52 , C07D233/56 , C07F5/069 , C07F15/025
摘要： Ionic liquids comprising a mixture of one or more triflate or bis(trifluoromethylsulfonyl)imide salt(s) with one or more Lewis acids(s), wherein the total of the molar contents of the Lewis acid(s) in the mixture is from about 0.01-98%, are provided, that are useful as catalysts in Lewis acid catalyzed reactions.
摘要翻译： 包含一种或多种三氟甲磺酸酯或双（三氟甲基磺酰基）酰亚胺盐与一种或多种路易斯酸的混合物的离子液体，其中混合物中路易斯酸的摩尔含量的总和为约 0.01-98％，可用作路易斯酸催化反应中的催化剂。
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公开(公告)号：US20090216015A1
公开(公告)日：2009-08-27
申请号：US11794712
申请日：2006-01-04
申请人： Martyn J. Earle , Ute Frohlich , Susanne Huq , Suhas Katdare , Rafal Marcin Lukasik , Ewa Bogel , Natalia Vladimirovna Plechkova , Kenneth Richard Seddon
发明人： Martyn J. Earle , Ute Frohlich , Susanne Huq , Suhas Katdare , Rafal Marcin Lukasik , Ewa Bogel , Natalia Vladimirovna Plechkova , Kenneth Richard Seddon
IPC分类号： C07C213/08 , C07D265/30 , C07D471/08 , C07D213/72 , C07D231/10 , C07D241/38 , C07C215/20 , C07C49/115 , C07C49/11
CPC分类号： B01J31/0288 , B01J31/0202 , B01J31/0204 , B01J31/0224 , B01J31/0225 , B01J31/0227 , B01J31/0237 , B01J31/0277 , B01J31/0278 , B01J31/0279 , B01J31/0282 , B01J31/0284 , B01J31/0285 , B01J31/0298 , B01J2231/10 , B01J2231/20 , B01J2231/30 , B01J2231/341 , B01J2231/342 , B01J2231/346 , B01J2231/348 , B01J2231/40 , B01J2231/4261 , B01J2231/50 , B01J2231/60 , B01J2231/70 , B01J2531/90 , C07C45/66 , C07C45/67 , C07C45/72 , C07C45/73 , C07C45/74 , C07C211/63 , C07C215/40 , C07C217/08 , C07C221/00 , C07C2601/14 , C07D211/14 , C07D231/12 , C07D487/04 , Y02P20/542 , Y02P20/582 , C07C49/637 , C07C49/203 , C07C49/647 , C07C49/603 , C07C49/597 , C07C49/17 , C07C49/493 , C07C49/497 , C07C49/403 , C07C225/12
摘要： The present invention relates to novel base stable ionic liquids and uses thereof as solvents in chemical reactions, especially base catalysed chemical reactions and reactions comprising the use of strong basis.
摘要翻译： 本发明涉及新型碱稳定离子液体及其作为化学反应中的溶剂的用途，特别是碱催化的化学反应和包括使用强碱的反应。
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