公开(公告)号：US5525322A

公开(公告)日：1996-06-11

申请号：US322874

申请日：1994-10-12

Applicant: R. Scott Willms

Inventor： R. Scott Willms

IPC: B01J4/04 ,  B01J8/00 ,  B01J19/24 ,  B01J35/06 ,  C01B3/16 ,  C01B3/26 ,  C01B3/38 ,  C01B3/50 ,  C01B3/12

CPC classification number: C01B3/501 ,  B01J19/2475 ,  B01J35/065 ,  B01J4/04 ,  C01B3/16 ,  C01B3/26 ,  C01B3/38 ,  C01B2203/0233 ,  C01B2203/0277 ,  C01B2203/0283 ,  C01B2203/041 ,  C01B2203/0475 ,  C01B2203/0816 ,  C01B2203/1052 ,  C01B2203/1241 ,  C01B2203/1614 ,  C01B2203/1695 ,  Y02P20/52

Abstract: Method for simultaneous recovery of hydrogen and hydrogen isotopes from water and from hydrocarbons. A palladium membrane, when utilized in cooperation with a nickel catalyst in a reactor, has been found to drive reactions such as water gas shift, steam reforming and methane cracking to substantial completion by removing the product hydrogen from the reacting mixture. In addition, ultrapure hydrogen is produced, thereby eliminating the need for an additional processing step.

Abstract translation: 从水和烃同时回收氢和氢同位素的方法。 已经发现当与反应器中的镍催化剂配合使用时，钯膜通过从反应混合物中除去产物氢来驱动诸如水煤气变换，蒸汽重整和甲烷裂解的反应来达到基本完成。 此外，产生超纯氢，从而不再需要额外的加工步骤。

公开(公告)号：US5424180A

公开(公告)日：1995-06-13

申请号：US996866

申请日：1992-12-15

Applicant: Mitsuo Saitou

Inventor： Mitsuo Saitou

IPC: B01F5/00 ,  B01F5/06 ,  B01J4/04 ,  G03C1/015

CPC classification number: B01F5/0659 ,  B01F5/0602 ,  B01F5/0682 ,  B01J4/04 ,  G03C1/015 ,  B01F2005/0008

Abstract: An apparatus for producing a highly uniform mixture of a first solution with two or more solute-containing solutions comprises a reaction vessel with a porous member located therein. The porous member, whic may be a membrane or a plurality of fine tubes, is located within the vessel below the surface of the first solution. One or more solute-containing solutions are rapidly and uniformly introduced into the first solution through the porous member. The solute containing solutions diffuse rapidly into the first solution through the openings in the porous member, mixing evenly to produce a uniform composition.

Abstract translation: 用于生产具有两种或多种含溶质溶液的第一溶液的高度均匀混合物的装置包括具有位于其中的多孔构件的反应容器。 多孔构件可以是膜或多个细管，位于第一溶液表面下方的容器内。 通过多孔构件将一种或多种含溶质的溶液快速均匀地引入第一溶液中。 含有溶质的溶液通过多孔构件中的开口快速扩散到第一溶液中，混合均匀以产生均匀的组成。

公开(公告)号：US5380496A

公开(公告)日：1995-01-10

申请号：US130391

申请日：1993-10-01

Applicant: Yoshiyuki Hashiguchi ,  Masakiti Kishi ,  Takehiko Yagyu

Inventor： Yoshiyuki Hashiguchi ,  Masakiti Kishi ,  Takehiko Yagyu

IPC: B01J4/04 ,  B01J19/18 ,  C08F2/18 ,  C08F2/00 ,  B01F13/00

CPC classification number: B01J4/04 ,  B01J19/1862 ,  B01J19/1881 ,  C08F2/18 ,  B01J2219/00103 ,  B01J2219/0011 ,  B01J2219/00164 ,  B01J2219/182

Abstract: There is provided an apparatus for suspension polymerization to produce polymer particles having uniform size. The apparatus has a droplet forming device with at least one orifice and a recycle line which recycles the aqueous dispersion medium through the droplet forming device, a first reactor and a second reactor. The apparatus can produce polymer particles having uniform particle size.

Abstract translation: 提供了一种用于制备具有均匀尺寸的聚合物颗粒的悬浮聚合装置。 该装置具有液滴形成装置，其具有至少一个孔口和再循环管线，该再循环管线通过液滴形成装置，第一反应器和第二反应器再循环水分散介质。 该装置可以生产具有均匀粒度的聚合物颗粒。

公开(公告)号：US5306411A

公开(公告)日：1994-04-26

申请号：US618792

申请日：1990-11-27

Applicant: Terry J. Mazanec ,  Thomas L. Cable ,  John G. Frye, Jr. ,  Wayne R. Kliewer

Inventor： Terry J. Mazanec ,  Thomas L. Cable ,  John G. Frye, Jr. ,  Wayne R. Kliewer

IPC: B01D53/32 ,  B01D71/02 ,  B01J4/04 ,  B01J8/00 ,  B01J12/00 ,  B01J19/00 ,  B01J19/24 ,  C01B3/36 ,  C01B3/38 ,  C01B13/02 ,  C01C3/02 ,  C01G45/00 ,  C01G49/00 ,  C01G51/00 ,  C25B3/02 ,  C25B5/00 ,  H01M8/12 ,  C25B1/02 ,  C25B13/04

CPC classification number: H01M8/1246 ,  B01D53/326 ,  B01D67/0046 ,  B01D67/0072 ,  B01D69/12 ,  B01D69/141 ,  B01D69/145 ,  B01D71/02 ,  B01D71/022 ,  B01D71/024 ,  B01J12/007 ,  B01J19/2475 ,  B01J8/009 ,  C01B13/0255 ,  C01B13/0288 ,  C01B3/36 ,  C01B3/386 ,  C01C3/0216 ,  C01C3/0225 ,  C01C3/0233 ,  C01G37/006 ,  C01G41/00 ,  C01G45/006 ,  C01G45/1264 ,  C01G49/0063 ,  C01G51/006 ,  C01G51/68 ,  C25B3/02 ,  C25B5/00 ,  H01M8/12 ,  H01M8/1231 ,  H01M8/124 ,  B01D2325/26 ,  B01J2208/00044 ,  B01J2208/00106 ,  B01J2208/00309 ,  B01J2208/00336 ,  B01J2208/00345 ,  B01J2208/00548 ,  B01J2208/00628 ,  B01J2219/00058 ,  B01J2219/00117 ,  B01J2219/00123 ,  B01J2219/00126 ,  B01J2219/00164 ,  B01J2219/00186 ,  C01B2203/0261 ,  C01B2203/1035 ,  C01B2203/1241 ,  C01B2203/1258 ,  C01B2210/0003 ,  C01B2210/0012 ,  C01B2210/0071 ,  C01B2210/0075 ,  C01P2002/34 ,  C01P2002/54 ,  C01P2004/03 ,  C01P2004/80 ,  C01P2006/12 ,  C01P2006/40 ,  Y02E60/525 ,  Y02P70/56

Abstract: Solid membranes comprising an intimate, gas-impervious, multi-phase mixture of an electronically-conductive material and an oxygen ion-conductive material and/or a mixed metal oxide of a perovskite structure are described. Electrochemical reactor components, such as reactor cells, and electrochemical reactors are also described for transporting oxygen from any oxygen-containing gas to any gas or mixture of gases that consume oxygen. The reactor cells generally comprise first and second zones separated by an element having a first surface capable of reducing oxygen to oxygen ions, a second surface capable of reacting oxygen ions with an oxygen-consuming gas, an electron-conductive path between the first and second surfaces and an oxygen ion-conductive path between the first and second surfaces. The element may further comprise (1) a porous substrate, (2) an electron-conductive metal, metal oxide or mixture thereof and/or (3) a catalyst. The reactor cell may further comprise a catalyst in the zone which comprises a passageway from an entrance end to an exit end of the element. Processes described which may be conducted with the disclosed reactor cells and reactors include, for example, the partial oxidation of methane to produce unsaturated compounds or synthesis gas, the partial oxidation of ethane, substitution of aromatic compounds, extraction of oxygen from oxygen-containing gases, including oxidized gases, ammoxidation of methane, etc. The extraction of oxygen from oxidized gases may be used for flue or exhaust gas cleanup.

Abstract translation: 描述了包含电子导电材料和氧离子传导材料和/或钙钛矿结构的混合金属氧化物的紧密，不透气的多相混合物的固体膜。 还描述了电化学反应器组分，例如反应器电池和电化学反应器，用于将氧气从任何含氧气体输送到消耗氧气的任何气体或气体混合物。 反应器电池通常包括由具有能够将氧还原成氧离子的第一表面的元件隔开的第一和第二区，能够使氧离子与耗氧气体反应的第二表面，第一和第二之间的电子传导路径 表面和在第一和第二表面之间的氧离子传导路径。 元件还可以包括（1）多孔基底，（2）电子传导金属，金属氧化物或其混合物和/或（3）催化剂。 反应器电池还可以包括在该区域中的催化剂，其包括从元件的入口端到出口端的通道。 可以使用所公开的反应器电池和反应器进行的方法包括例如甲烷的部分氧化以产生不饱和化合物或合成气，乙烷的部分氧化，芳族化合物的取代，从含氧气体中提取氧 包括氧化气体，甲烷的氨氧化等。氧化气体中的氧气可用于烟气或废气净化。

公开(公告)号：US5087270A

公开(公告)日：1992-02-11

申请号：US549624

申请日：1990-07-09

Applicant: Paul Gateau ,  Michel Maute ,  Alain Feugier ,  Edmond Perthuis

Inventor： Paul Gateau ,  Michel Maute ,  Alain Feugier ,  Edmond Perthuis

IPC: C01B3/34 ,  B01J4/04 ,  B01J7/00 ,  C01B3/36 ,  C01B3/38

CPC classification number: B01J4/04 ,  C01B3/363 ,  C01B3/386 ,  C01B2203/0255 ,  C01B2203/0261 ,  C01B2203/1035 ,  C01B2203/1041 ,  C01B2203/1241 ,  Y02P20/52

Abstract: A method and device are provided for producing synthetic gas by combustion of a fuel in a combustive agent deficient atmosphere, said combustive agent being gaseous, said device including first means for feeding the fuel and a part of the combustive gas into the reactor, and second means for feeding a second part of the combustive gas into the reactor, said second means including a porous wall defining at least a part of said reactor.

Abstract translation: 提供了一种用于通过在燃烧剂不足气氛中燃烧燃料来生产合成气体的方法和装置，所述燃烧剂是气态的，所述装置包括用于将燃料和一部分可燃气体进料到反应器中的第一装置，第二 用于将第二部分可燃气体进料到反应器中的装置，所述第二装置包括限定所述反应器的至少一部分的多孔壁。

公开(公告)号：US5037619A

公开(公告)日：1991-08-06

申请号：US507507

申请日：1990-04-11

Applicant: Jacques Alagy ,  Christian Busson

Inventor： Jacques Alagy ,  Christian Busson

IPC: B01J4/04 ,  B01J12/00 ,  B01J19/00 ,  B01J19/24 ,  C01B3/34 ,  C01B3/38

CPC classification number: C01B3/34 ,  B01J12/005 ,  B01J19/2415 ,  B01J4/04 ,  B01J2219/00085 ,  B01J2219/00155 ,  B01J2219/00159 ,  B01J2219/0263

Abstract: An oxidizable charge is oxidized in a gaseous phase reaction. The oxidizable charge and an oxidizing gas flow simultaneously and separately through a distribution zone made of a ceramic material. In at least a part of the distribution zone, the oxidizable charge and the oxidizing gas flow through a multiplicity of passages of a dimension so small that any flame resulting from oxidation of the oxidizable charge will be quenched. The oxidizable charge and oxidizing gas are then mixed in a mixing zone made from a ceramic material defining a multiplicity of spaces with passages having a dimension comparable to the dimension of the passages in the distribution zone. The mixture of gases then flows through a reaction zone made from a ceramic material defining another multiplicity of passages having dimensions comparable to those in the distribution zone. The distance between each of the distribution, mixing and reaction zones is also so small that any flame resulting from oxidation of the oxidizable charge will be quenched.

Abstract translation: 可氧化的电荷在气相反应中被氧化。 可氧化的电荷和氧化性气体流动同时且分开地通过由陶瓷材料制成的分布区域。 在分配区域的至少一部分中，可氧化电荷和氧化气体流过多个尺寸小的通道，使得由可氧化电荷的氧化产生的任何火焰都将被淬灭。 然后将可氧化的电荷和氧化气体在由限定多个空间的陶瓷材料制成的混合区中混合，通道具有与分配区中的通道的尺寸相当的尺寸。 气体混合物然后流过由陶瓷材料制成的反应区，该反应区限定了与分配区相当的尺寸的多个通道。 分配，混合和反应区域之间的距离也很小，使得可氧化的电荷的氧化产生的任何火焰都将被淬火。

公开(公告)号：US4971770A

公开(公告)日：1990-11-20

申请号：US264393

申请日：1988-10-31

Applicant: Jacques Alagy ,  Christian Busson

Inventor： Jacques Alagy ,  Christian Busson

IPC: C10J3/00 ,  B01J4/04 ,  B01J12/00 ,  B01J19/00 ,  B01J19/24 ,  C01B3/38 ,  C07C29/152 ,  B01J8/04

CPC classification number: B01J19/2485 ,  B01J12/005 ,  B01J19/242 ,  B01J4/004 ,  B01J4/04 ,  C07C29/152 ,  B01J2219/00155 ,  B01J2219/00159 ,  B01J2219/00265 ,  B01J2219/0263

Abstract: A new technique for oxidizing a gaseous phase oxidizable feed involves a process wherein a gas mixture containing at least one oxidizing gas is placed in contact with an oxidizable feed inside a mixing contact zone situated between at least one first zone passed through by the feed and at least one second zone passed through by the oxidation reaction products. The first and second zones define a multiplicity of multidirectional spaces exhibiting passages having, along at least one direction, a dimension at most equal to the jamming distance of the flame possibly resulting from oxidations of feed. The contact zone comprises an oxidizing gas mixture supply means comprising a plurality of parallel pipes with porous walls situated at a distance from the first and second zones which is at most equal to the jamming distance.

Abstract translation: 用于氧化气相可氧化进料的新技术涉及一种方法，其中将含有至少一种氧化气体的气体混合物置于与位于至少由进料通过的至少一个第一区域之间的混合接触区域内， 至少一个第二区域被氧化反应产物穿过。 第一和第二区域限定多个多向空间，其显示通道，沿着至少一个方向具有最大等于可能由进料氧化引起的火焰的干扰距离的尺寸。 所述接触区包括氧化气体混合物供应装置，所述氧化气体混合物供应装置包括多个平行的管道，所述多个平行管道具有位于距离所述第一和第二区域一定距离的多孔壁，所述第一和第二

公开(公告)号：US4908114A

公开(公告)日：1990-03-13

申请号：US117298

申请日：1987-11-06

Applicant: William Ayers

Inventor： William Ayers

IPC: B01J4/04 ,  B01J19/24 ,  C01B15/029 ,  C01B21/16 ,  C01C1/04 ,  C07C45/00 ,  C07C45/49 ,  C25B3/04 ,  C25B13/08

CPC classification number: C25B3/04 ,  B01J19/2475 ,  B01J4/04 ,  C01B15/029 ,  C01B21/16 ,  C01C1/04 ,  C01C1/0405 ,  C07C45/00 ,  C07C45/49 ,  C25B13/08 ,  B01J2219/00177 ,  B01J2219/00186 ,  Y02P20/52

Abstract: Disclosed is a method of carrying out a mobile atom insertion reaction, such as a hydrogen insertion reaction, for the synthesis of reduced, hydrogenated compounds. Such reactions include the production of ammonia and hydrazine from nitrogen, formic acid and methanol from carbon dioxide, and hydrogen peroxide from oxygen. The insertion reactions are carried out at a bipolar mobile atom transmissive membrane comprising a membrane formed of a mobile atom pump material, as a hydrogen pump material, conductive atom transmissive means on one surface of the membrane and conductive atom transmissive means on the opposite surface of the membrane. The mobile atom, such as hydrogen, diffuses across the membrane, to provide a source of hydrogen on the insertion reaction side of the membrane. The insertion reaction side of the membrane is positively biased with respect to a counterelectrode so that a reactant molecule, such as carbon dioxide, is electrosorbed on that surface of the membrane. The electrosorbed reactant molecular chemically reacts with the surface hydrogen by the insertion reaction to form a reduced, hydrogenated product such as formic acid. Also disclosed is a chemical reactor, containing the membrane, and several electrical field assisted chemical reactions utilizing the membrane and reactor.

Abstract translation: 公开了用于合成还原的氢化化合物的进行诸如氢插入反应的可移动的原子插入反应的方法。 这样的反应包括从氮气中生成氨和肼，从二氧化碳生成甲酸和甲醇，以及从氧气生产过氧化氢。 插入反应在双极移动原子透射膜上进行，该双极移动原子透射膜包括由移动原子泵材料形成的膜，作为氢泵材料，在膜的一个表面上的导电原子透射装置和在膜的相对表面上的导电原子透射装置 膜。 诸如氢的移动原子扩散到膜上，以在膜的插入反应侧提供氢源。 膜的插入反应侧相对于反电极被正偏置，使得诸如二氧化碳的反应物分子在膜的表面上被电泳。 电泳反应物分子通过插入反应与表面氢化学反应形成还原的氢化产物如甲酸。 还公开了含有膜的化学反应器和利用膜和反应器的几个电场辅助化学反应。

公开(公告)号：US4865630A

公开(公告)日：1989-09-12

申请号：US942799

申请日：1986-12-17

Applicant: Fumio Abe

Inventor： Fumio Abe

IPC: B01D53/22 ,  B01D69/00 ,  B01D71/02 ,  B01J4/04 ,  B01J8/00 ,  B01J15/00 ,  B01J19/24 ,  B01J35/06

CPC classification number: B01J35/065 ,  B01J15/005 ,  B01J19/2475 ,  B01J35/06 ,  B01J8/009

Abstract: A porous membrane adapted for use in a chemical reaction process, the porous membrane being formed with interconnected micropores having an average pore size less than 100am (1000 .ANG.) and containing a catalytic component such as molybdenum sulfide, platinum-alumina, palladium-silica-alumina or the like uniformly distributed therein.

Abstract translation: 一种适用于化学反应过程的多孔膜，多孔膜由平均孔径小于100am（1000）的相互连接的微孔形成并含有催化组分如硫化钼，铂 - 氧化铝，钯 - 二氧化硅 - 氧化铝等均匀分布在其中。

公开(公告)号：US4652449A

公开(公告)日：1987-03-24

申请号：US546015

申请日：1983-10-27

Applicant: Claude Ropars ,  Yves C. Nicolau ,  Maurice Chassaigne

Inventor： Claude Ropars ,  Yves C. Nicolau ,  Maurice Chassaigne

IPC: A61J3/07 ,  A61K9/48 ,  A61K9/50 ,  A61K31/66 ,  A61K31/70 ,  A61K35/14 ,  A61K35/18 ,  A61K38/16 ,  A61K38/21 ,  A61K38/28 ,  A61M1/16 ,  A61M1/36 ,  B01J4/04 ,  C12M1/12

CPC classification number: B01D61/28 ,  A61K35/18 ,  A61K9/5068 ,  A61M1/36 ,  A61M1/16 ,  B01D2311/04 ,  B01D2313/243

Abstract: This invention relates to a process for the encapsulation in human or animal erythrocytes of at least one substance having a biological activity, characterized in that the primary compartment of at least one dialysis element is continuously supplied with an aqueous suspension of erythrocytes, the secondary compartment of the dialysis element contains an aqueous solution which is hypotonic with respect to the erythrocyte suspension in order to lyse the erythrocytes, the erythrocyte lysate is in contact with said substance having a biological activity and, in order to reseal the membrane of the erythrocytes, the osmotic and/or oncotic pressure of the erythrocyte lysate is increased after it has been brought into contact with said substance having a biological activity.

Abstract translation: 本发明涉及一种用于在人或动物红细胞中包封具有生物活性的至少一种物质的方法，其特征在于至少一种透析元件的初级隔室连续地供应红细胞的水性悬浮液，第二隔室 透析元件含有相对于红细胞悬液低渗的水溶液，以溶解红细胞，红细胞裂解物与具有生物活性的所述物质接触，为了重新密封红细胞膜，渗透 在与所述具有生物活性的物质接触后，红细胞溶解产物的和/或肿瘤的压力增加。