摘要:
Organosilica materials, which are a polymer of at least one independent monomer of Formula [Z1OZ2OSiCH2]3 (I), wherein each Z1 and Z2 independently represent a hydrogen atom, a C1-C4 alkyl group or a bond to a silicon atom of another monomer and at least one other trivalent metal oxide monomer are provided herein. Methods of preparing and processes of using the organosilica materials, e.g., for catalysis etc., are also provided herein.
摘要:
A method for creating work by adsorption end desorption of a working fluid on an fiber sorption system which has a plurality of tubular hollow fibers within a vessel which is connected to a work device. Each fiber is in the form of a tubular, elongated body composed of a sorbent material capable of adsorbing a working fluid such as carbon dioxide. The fibers have an inner surface adjacent the hollow interior and an outer surface, one of which has a coating layer which is impermeable to both a working fluid and thermal fluid. The system is operated by passing a thermal cooling fluid in contact with the fibers to cool the fibers and passing the working fluid over the fibers in contact with the surface of the cooled fibers which does not have the coating layer so that the working fluid is adsorbed on the fibers, the adsorbed working fluid is then desorbed from the fibers by passing a thermal heating fluid in contact with the fibers to heat the fibers; the pressurized, desorbed working fluid is then passed to a work device connected to the vessel.
摘要:
Management of a pond for algae growth and harvesting is facilitated by use of a cover system. The cover system can include one or more types of cover portions for management of various interactions between a pond and an ambient environment, such as management of incident light, thermal management, facilitating product recovery, and management of gas diffusion. The cover system can be used in conjunction with both active and passive mixing devices.
摘要:
A process for preparing α-olefins from ethylene wherein the α-olefins are substantially free of olefins having greater than 12 carbon atoms comprises contacting ethylene under oligomerization conditions with a 2,6-bis(phenylimino) pyridyl metal halide catalyst in which the metal is Fe, Ni, Co or Pd.
摘要:
This invention relates to a catalyst and process for selectively hydrodesulfurizing naphtha feedstreams using a catalyst comprising at least one hydrodesulfurizing metal supported on a low acidity, ordered mesoporous support material.
摘要:
Waxy feeds are converted to a basestock using a unitized mixed powdered pellet catalyst comprising a metal hydrogenation component on a support having a frist dewaxing component and a second isomerization component, wherein the first component is selected from 10 and 12 ring molecular sieves and mixtures thereof and the second component is an amorphous inorganic oxide. The first and second components are present in a ratio sufficient to promote wax isomerization and naphthene distractions without substantial decrease in VI.
摘要:
A method for hydroisomerizing a waxy feed to favor one of VI or yield is described. The method uses a unitized pellet powder catalyst comprising a metal hydrogeneration component, a first catalytic component selected from 8, 10 and 12 ring moleular sieves and mixtures thereof, and a second amorphous isomerization component which is an amorphous inorganic oxide. Importantly, the ratio of feed and second components are present in a predetermined ratio to provide a preselected acidity favoring one of VI or yield resulting from the hydroisomerization.
摘要:
The present invention comprises a mixing system that provides improved mixing of quench gas and process fluids in a height constrained interbed space while not increasing pressure drop. In particular, the device improves the effectiveness of an existing mixing volume in mixing the gas phase of two-phase systems. The mixing system includes a horizontal collection tray, a mixing chamber positioned below the collection tray, at least one passageway extending through the collection tray into the mixing chamber, and a vapor slipstream passageway extending through the collection tray into the mixing chamber for directing a vapor slipstream from above the collection tray into the mixing chamber. The mixing chamber and the collection tray define a two-phase mixing volume. The passageway conducts fluid containing at least some vapor from above the collection tray into the mixing chamber. The mixing chamber preferably includes at least one outlet opening for the downward passage of fluid. The vapor slipstream passageway, optionally, comprises a plurality of inlets arranged to impart rotational movement to the vapor phase at a location within the mixing chamber where the vapor phase has substantially expended the kinetic energy of its initial entry into the mixing chamber. As a result of providing at least one additional passageway for a vapor slipstream, and optionally, including one or more baffles as described above, significant re-acceleration of the vapor phase is achieved in the mixing chamber resulting in improvements in mixing efficiency of both the vapor and liquid phases.
摘要:
This invention is to a method and system for controlling withdrawal of liquid from pipelines. The system includes intercommunicating analyzers, control applications and controllers for analyzing and controlling flow of a liquid from a pipeline system. Pipeline systems with which this invention can be used include any type of pipeline system capable of transporting and distributing liquid fluids, particularly hydrocarbon liquids.
摘要:
Methods are provided for hydrotreating a feed to generate a product with a reduced or minimized aromatics content and/or an increased distillate product yield. A distillate boiling range feed having an elevated content of sulfur and/or nitrogen can be hydrotreated using at least two hydrotreating stages with intermediate separation to produce a hydrotreated distillate boiling range product with a reduced or minimized aromatics content. Additionally or alternately, a mixed metal catalyst formed from a suitable precursor can be used during the hydrotreating. A mixed metal catalyst formed from a suitable precursor can provide an unexpectedly superior activity for aromatic saturation. A still further unexpected benefic can be achieved by combining a multi-stage hydrotreating process with intermediate separation with hydrotreating in the presence of a mixed metal catalyst formed from a suitable precursor.