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1.发明申请公开(公告)号：US20070129512A1
公开(公告)日：2007-06-07
申请号：US10581689
申请日：2004-11-04
CPC分类号： B01J19/1818 , B01J4/008 , B01J2219/00094 , B01J2219/00779 , C08F20/12
摘要： The invention relates to a process for the continuous free-radical homogeneous solution polymerization or melt polymerization of (meth)acrylate monomer mixtures.
摘要翻译： 本发明涉及（甲基）丙烯酸酯单体混合物的连续自由基均相溶液聚合或熔融聚合的方法。
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2.发明授权公开(公告)号：US07638094B2
公开(公告)日：2009-12-29
申请号：US10581689
申请日：2004-11-04
CPC分类号： B01J19/1818 , B01J4/008 , B01J2219/00094 , B01J2219/00779 , C08F20/12
摘要： The invention relates to a process for the continuous free-radical homogeneous solution polymerization or melt polymerization of (meth)acrylate monomer mixtures.
摘要翻译： 本发明涉及（甲基）丙烯酸酯单体混合物的连续自由基均相溶液聚合或熔融聚合的方法。
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公开(公告)号：US4268549A
公开(公告)日：1981-05-19
申请号：US56541
申请日：1979-07-11
申请人： Herbert Fink , Norbert Suetterlin , Horst Dinklage , Willi Tilch
发明人： Herbert Fink , Norbert Suetterlin , Horst Dinklage , Willi Tilch
IPC分类号： C09D5/03 , C08J3/12 , C08L33/10 , C09D7/00 , C09D7/12 , C09D133/04 , C09D133/10 , B05D3/02
CPC分类号： C08J3/12 , C09D133/10 , C09D7/125 , C08J2333/10 , C08L2205/02 , C08L33/10 , Y10S428/904 , Y10T428/31928
摘要： What is disclosed is a synthetic resin powder of latex particles having an average particle size between 1 micron and 5 microns, which particles can be partially or completely loosely aggregated to form larger particles, said synthetic resin being a cross-linked copolymer of 75 to 99.5 percent by weight of a monomer mixture of methyl methacrylate and isobutyl methacrylate in a weight ratio of 1:3 to 3:1, 0.5 to 10 percent by weight of a cross-linking comonomer having at least two polymerizable double bonds, and 0 to 24.5 percent by weight of a further different ethylenically-unsaturated comonomer copolymerizable therewith, a coating agent containing a binder dissolved or dispersed therein together with such a resin powder, and a method of coating using such a coating agent to give coatings wherein the presence of the resin powder prevents blocking of the coatings without undue loss of luster therein.
摘要翻译： 公开的是具有1微米至5微米平均粒度的胶乳颗粒的合成树脂粉末，该颗粒可以部分或完全松散聚集形成较大的颗粒，所述合成树脂为75至99.5的交联共聚物 重量比的甲基丙烯酸甲酯和甲基丙烯酸异丁酯的重量比为1:3至3:1的单体混合物，0.5至10重量％的具有至少两个可聚合双键的交联共聚单体，和0至24.5重量％ 可与其共聚的其它不同的烯键式不饱和共聚单体的重量百分数，含有与这种树脂粉末一起溶解或分散在其中的粘合剂的涂布剂以及使用这种涂布剂进行涂布的方法，得到其中存在树脂 粉末可以防止涂层的堵塞，而不会在其中过多的光泽损失。
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4.发明授权Polymer powders of low fines content and method for making the same by spray drying 失效低细粉含量的聚合物粉末及其制备方法
公开(公告)号：US4892910A
公开(公告)日：1990-01-09
申请号：US218808
申请日：1988-07-13
IPC分类号： C08L101/00 , B01D1/18 , C08F6/18 , C08J3/12 , C08J5/00 , C08L25/00 , C08L25/04 , C08L27/06 , C08L33/04 , C08L33/18
摘要： Polymer powders comprising aggregated polymer particles, said powders having a low content of fines and being suitable as processing aids in the manufacture of polyvinyl chloride, are made by spray drying an aqueous dispersion (latex) of two emulsion polymers, one of which has a dynamic glass transition temperature above 90.degree. C. and the other of which has a dynamic glass transition below 105.degree. C., the latter being at least 10 K. degrees below the former.
摘要翻译： 包含聚集的聚合物颗粒的聚合物粉末，所述粉末具有低含量的细粒并且适合作为制造聚氯乙烯的加工助剂，通过喷雾干燥两种乳液聚合物的水性分散体（胶乳）制成，其中一种乳液聚合物具有动态 玻璃化转变温度高于90℃，另一个玻璃化转变温度低于105℃，后者比前者低至少10 K.度。
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公开(公告)号：US4513118A
公开(公告)日：1985-04-23
申请号：US567793
申请日：1984-01-03
申请人： Norbert Suetterlin , Peter J. Arndt , Ernst Heil , Werner Siol , Willi Tilch , Wilhelm Wopker
发明人： Norbert Suetterlin , Peter J. Arndt , Ernst Heil , Werner Siol , Willi Tilch , Wilhelm Wopker
IPC分类号： C09K3/00 , C08F2/22 , C08F285/00 , C08L33/00 , C08L33/02 , C08L33/04 , C08L33/10 , C08L33/12 , C08L51/00 , C08L51/02 , C08L51/06 , C08L33/08
CPC分类号： C08F285/00 , C08L33/12 , C08L51/00
摘要： An emulsion polymer comprising a hard nonelastomeric core, an elastomeric intermediate stage produced in the presence of the core and essentially composed of an acrylic ester and a crosslinking monomer which contains three or more acrylic or methacrylic groups in the molecule, and a hard nonelastomeric final stage produced in the presence of the elastomeric intermediate stage and crosslinked therewith, said polymer being useful as an impact strength modifying agent which, in admixture with a thermoplastic polymethyl methacrylate molding compound for example, yields molded articles exhibiting reduced susceptibility to stress whitening and improved impact strength.
摘要翻译： 一种乳液聚合物，其包含硬非弹性芯，在芯的存在下产生并基本上由丙烯酸酯和在分子中含有三个或更多个丙烯酸或甲基丙烯酸基团的交联单体制备的弹性体中间阶段，以及硬非弹性末端 在弹性体中间阶段的存在下生产并与其交联，所述聚合物可用作冲击强度改性剂，其与热塑性聚甲基丙烯酸甲酯模塑料混合，例如产生对应力增白的敏感性降低和改善的冲击强度的模塑制品 。
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6.发明授权High surface area support having bound latex particles containing oxirane groups for immobilization of substances 失效具有结合的胶体颗粒的高表面积载体含有用于固定物质的环氧乙烷基团
公开(公告)号：US5976527A
公开(公告)日：1999-11-02
申请号：US990554
申请日：1992-12-14
申请人： Werner Siol , Dieter Kraemer , Norbert Suetterlin , Cornelia Scordialo , Gerhard Markert , Erwin Schuster
发明人： Werner Siol , Dieter Kraemer , Norbert Suetterlin , Cornelia Scordialo , Gerhard Markert , Erwin Schuster
IPC分类号： C08F220/18 , A61K38/43 , B01J20/32 , C08F8/30 , C08J9/26 , C08J9/28 , C12N9/00 , C12N11/00 , C12N11/08 , C12Q1/00 , G01N33/543 , C12N11/14 , C07K17/14 , G01N33/551
CPC分类号： G01N33/543 , A61K38/465 , A61K38/47 , A61K38/4826 , B01J20/3204 , B01J20/3208 , B01J20/321 , B01J20/3212 , B01J20/3219 , B01J20/327 , C08J9/26 , C08J9/28 , C12N11/00 , C12N11/08 , C12N9/00 , C12Q1/00 , G01N33/54353 , Y10S530/811 , Y10S530/815
摘要： A high surface area system is provided with latex particles for immobilization of substances containing nucleophilic groups. The high surface area system is formed by aggregating the latex particles or by bonding the latex particles to a porous support of high surface area. The latex particles contain groups such as oxirane groups that react with the nucleophilic groups. The substances containing nucleophilic groups may be enzymes or proteins such as albumin, immunoglobulins, blood-clotting factors, cell-membrane proteins or peptide hormones. The high surface area system may be used as a sorbent in removing pollutants, as a stationary phase in organic synthesis such as peptide synthesis, and in the therapeutic treatment of a patient.
摘要翻译： 高表面积系统提供了用于固定含有亲核基团的物质的胶乳颗粒。 通过聚集胶乳颗粒或通过将胶乳颗粒粘合到高表面积的多孔载体上而形成高表面积体系。 胶乳颗粒含有与亲核基团反应的基团如环氧乙烷基团。 含有亲核基团的物质可以是酶或蛋白质，例如白蛋白，免疫球蛋白，凝血因子，细胞膜蛋白或肽激素。 高表面积系统可用作吸附剂，用于除去有机合成如肽合成中的污染物，以及在患者的治疗中作为固定相。
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7.发明授权
公开(公告)号：US4710525A
公开(公告)日：1987-12-01
申请号：US930023
申请日：1986-11-07
IPC分类号： C08F2/00 , A61K39/00 , C08F2/22 , C08F291/00 , C08J3/05 , C08L33/00 , C08L33/02 , C08L33/24 , C08L33/26 , C08L51/00 , C08L51/02 , C08L57/00 , C08L101/00 , C12N11/02 , G01N33/535 , G01N33/543 , G01N33/545 , G01N33/546 , G01N33/547 , C08L83/00
CPC分类号： G01N33/54313 , C08F291/00 , C12N11/02 , Y10S525/902
摘要： Polymer particles dispersible to form a latex and latices of such polymer particles, said particles being adaptable to the fixing or bonding thereto of a biologically active substance and having a core-shell construction wherein the polymer material of the core determines the stability of the form of the latex particles and their redispersibility, and the material of the shell(1) is so hydrophilic that it would be completely or largely water soluble if it were not anchored to the core material and/or crosslinked,(2) contains functional groups which are suitable for the covalent fixation or bonding of biological active substances, and(3) in an anhydrous condition has a T.sub..lambda.max from 20.degree.-250.degree. C., depending on its composition, and methods for bonding a biologically active substance to such particles, for example to prepare a diagnostic reagent.
摘要翻译： 可分散以形成胶乳的聚合物颗粒和这种聚合物颗粒的胶乳，所述颗粒适于固定或粘合生物活性物质并具有核 - 壳结构，其中芯的聚合物材料决定了 胶乳颗粒及其再分散性，并且壳（1）的材料是亲水性的，如果它不被锚定到芯材料和/或交联的话，它将完全或大部分是水溶性的，（2）包含官能团 适用于生物活性物质的共价固定或结合，（3）在无水状态下，根据其组成，T值为20〜250℃，以及将生物活性物质与该颗粒结合的方法 ，例如制备诊断试剂。
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公开(公告)号：US4542175A
公开(公告)日：1985-09-17
申请号：US522524
申请日：1983-08-12
IPC分类号： A61K8/81 , A61Q19/00 , B01J19/06 , C08F220/34 , C09D7/00 , C11D3/37 , C23C22/08 , C23G1/02 , D06M15/263 , C08J3/06
CPC分类号： A61Q19/00 , A61K8/8152 , B01J19/06 , C08F220/34 , C11D3/3773 , C23C22/08 , C23G1/025 , D06M15/263
摘要： What is disclosed is a method for thickening aqueous systems in the acid range at a pH below 7 by the addition of an aqueous dispersion of a synthetic polymer having a molecular weight of at least 500,000, and which is water soluble or at least colloidally dispersible at a pH below 7, said polymer comprising (A) 5-100 percent by weight of at least one monomer having at least one basic nitrogen atom (B) 0-95 percent by weight of at least one monomer which has at most limited solubility in water, and (C) 0-30 percent by weight of at least one further non-basic, water soluble comonomer.
摘要翻译： 所公开的是通过加入分子量至少为500,000的合成聚合物的水性分散体，在pH低于7的酸性范围内增稠水性体系的方法，其水溶性或至少胶体分散在 所述聚合物包含（A）5-100重量％的至少一种具有至少一个碱性氮原子的单体（B）0-95重量％的至少一种单体，其至少具有在 水，和（C）0-30重量％的至少一种其它非碱性水溶性共聚单体。
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公开(公告)号：US4476182A
公开(公告)日：1984-10-09
申请号：US455661
申请日：1983-01-05
申请人： Herbert Fink , Heiner Kniese , Norbert Suetterlin , Klaus Mueller , Willi Tilch , Werner Siol
发明人： Herbert Fink , Heiner Kniese , Norbert Suetterlin , Klaus Mueller , Willi Tilch , Werner Siol
IPC分类号： D06M15/263 , D04H1/435 , D04H1/587 , D04H1/64 , D06M101/00 , D06M101/16 , D06M101/30 , D06M101/32 , B32B27/08 , B05D3/02
CPC分类号： D04H1/435 , D04H1/587 , D04H1/64 , Y10T442/2344 , Y10T442/2861
摘要： What are disclosed are a method for the reinforcement of a fibrous article with an aqueous dispersion of a resin, free of formaldehyde and acrylonitrile, comprising at least 40 weight percent of alkyl acrylates and/or methacrylates having at least 4 carbon atoms in the alkyl group; up to 57 weight percent of alkyl acrylates or methacrylates having not more than 3 carbon atoms in the alkyl group, or of styrene; less than 1 weight percent of acrylic acid or of methacrylic acid; and from 3 to 15 weight percent of a hydroxyalkyl ester of an unsaturated carboxylic acid, as well as reinforced fibrous articles made by this method and distinguished by high wet strength and by low loss of the resin binder on washing with boiling water.
摘要翻译： 所公开的是使用不含甲醛和丙烯腈的树脂的水性分散体增强纤维制品的方法，其包括至少40重量％的在烷基中具有至少4个碳原子的丙烯酸烷基酯和/或甲基丙烯酸烷基酯 ; 至多57重量％的烷基中具有不超过3个碳原子的丙烯酸烷基酯或甲基丙烯酸烷基酯或苯乙烯; 丙烯酸或甲基丙烯酸少于1重量％; 和3至15重量％的不饱和羧酸的羟烷基酯，以及通过该方法制备的增强纤维制品，其特征在于高湿强度和用沸水冲洗时树脂粘合剂的低损失。
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公开(公告)号：US3937648A
公开(公告)日：1976-02-10
申请号：US370239
申请日：1973-06-15
摘要： Method for making highly resin-filled paper on a paper machine employing a fiber slurry having therein a non-ionic resin in an amount of at least 30 percent (dry resin weight based on dry fiber weight), said resin being combined with the fiber slurry as a dispersion comprising a cationic and a non-ionic dispersing agent.
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