METHOD OF MANUFACTURING A CATALYST
    3.
    发明申请
    METHOD OF MANUFACTURING A CATALYST 失效
    制备催化剂的方法

    公开(公告)号:US20080167180A1

    公开(公告)日:2008-07-10

    申请号:US11924441

    申请日:2007-10-25

    IPC分类号: B01J23/00 B29C33/44 B29C47/12

    摘要: A method of manufacturing a catalyst, a catalyst precursor, or a catalyst support comprising: (a) mixing a refractory metal oxide or precursor thereof with a liquid to form a paste; (b) adding said paste to an extruder, the extruder having a die plate comprising one or more dies, each die having a plurality of apertures, the outlet of each aperture having a cross sectional area of 6 mm2 or less; (c) extruding the paste through the apertures to form catalyst support extrudates;wherein the inlet of the apertures has a greater cross sectional area than the outlet of said apertures; and wherein for at least one die the combined cross sectional area of all apertures at the inlet relative to the total cross sectional area of the die at the inlet is higher than 50%.

    摘要翻译: 一种制造催化剂,催化剂前体或催化剂载体的方法,包括:(a)将难熔金属氧化物或其前体与液体混合以形成糊状物; (b)将所述糊料加入到挤出机中,所述挤出机具有包括一个或多个模具的模板,每个模具具有多个孔,每个孔的出口的横截面积为6mm 2 / >以下; (c)通过所述孔挤出所述浆料以形成催化剂载体挤出物; 其中所述孔的入口具有比所述孔的出口更大的横截面面积; 并且其中对于至少一个模具,入口处的所有孔的相对于入口处的模具的总横截面面积的组合横截面面积高于50%。

    System for the preparation of multiple solid state samples, in particular for spectroscopic and microscopic analysis
    4.
    发明授权
    System for the preparation of multiple solid state samples, in particular for spectroscopic and microscopic analysis 失效
    用于制备多个固态样品的系统,特别是用于光谱和显微镜分析

    公开(公告)号:US07375807B2

    公开(公告)日:2008-05-20

    申请号:US10521081

    申请日:2002-07-15

    IPC分类号: G01N1/10 B01L3/00

    摘要: A system for the preparation and handling of multiple solid state samples, in particular for spectroscopic and microscopic analysis. The system comprises a sample holder assembly for multiple solid-state samples. The sample holder assembly comprises a sample holding body having first and second sides (3a, 4a), provided with multiple sample receiving open-ended bores (5) extending through said body between said first and second sides, each bore (5) having a first opening at the first side and a second opening at the second side. Furthermore a closure body (10) is provided adapted to be mounted against the second side of the sample holding body, said closure body (10) having a closure side adapted to rest against the second side of the sample holding body for closing off the second openings of the bores (5) in said sample holding body. Compacting (23) means are provided for compacting samples filled in bores (5) of the sample holding body as these bores are closed off on the second side by the closure body.

    摘要翻译: 一种用于制备和处理多个固态样品的系统,特别是用于光谱和显微镜分析。 该系统包括用于多个固态样品的样品保持器组件。 样品保持器组件包括具有第一和第二侧面(3a,4a)的样品保持体,所述第一和第二侧面(3a,4a)设置有多个样品接收在所述第一和第二侧之间延伸穿过所述主体的开口孔(5),每个孔(5) 在第一侧具有第一开口,在第二侧具有第二开口。 此外,闭合体(10)被设置为适于抵靠样品保持体的第二侧安装,所述封闭体(10)具有适合于抵靠样品保持体的第二侧的闭合侧,用于封闭第二 所述样品保持体中的孔(5)的开口。 提供压实(23)装置,用于压实样品保持体的孔(5)中的样品,因为这些孔在第二侧被封闭体封闭。

    Process for the hydrogenation of a lactone or of a carboxylic acid or an ester having a gamma-carbonyl group
    9.
    发明授权
    Process for the hydrogenation of a lactone or of a carboxylic acid or an ester having a gamma-carbonyl group 有权
    内酯或具有γ-羰基的羧酸或酯的氢化方法

    公开(公告)号:US08003818B2

    公开(公告)日:2011-08-23

    申请号:US11314404

    申请日:2005-12-21

    IPC分类号: C07C69/34 C07C69/52

    CPC分类号: C07C51/377 C07C53/126

    摘要: The invention provides a process for the hydrogenation of a reactant selected from the group consisting of: at the ring-closing carbon atom and has a proton at a (a) a 5- or 6-membered lactone that is substituted carbon atom adjacent to the ring-closing carbon atom; (b) an ester of a carboxylic acid having a gamma-carbonyl group and a proton at a carbon atom adjacent to the carbon atom of the carbonyl group; and (c) a carboxylic acid having a gamma-carbonyl group and a proton at a carbon atom adjacent to the carbon atom of the carbonyl group, wherein the reactant is contacted with a strongly acidic heterogeneous catalyst comprising a hydrogenating metal, in the presence of hydrogen, at a temperature in the range of from 100 to 350° C. and a pressure in the range of from 1 to 150 bar (absolute). The invention further provides a fuel composition, preferably a diesel composition, comprising di-alkyl 4-methylnonanedioate or di-alkyl 3-ethyl-4-methylheptanedioate.

    摘要翻译: 本发明提供了一种用于氢化反应物的方法,所述反应物选自:在闭环碳原子处,并且在(a)5-或6-元内酯上具有质子,该内酯是与 闭环碳原子; (b)在与羰基的碳原子相邻的碳原子处具有γ-羰基和质子的羧酸的酯; 和(c)在与羰基的碳原子相邻的碳原子处具有γ-羰基和质子的羧酸,其中反应物与包含氢化金属的强酸性多相催化剂在存在下, 氢气,温度范围为100至350℃,压力范围为1至150巴(绝对)。 本发明还提供一种燃料组合物,优选含有4-甲基壬二酸二烷基酯或3-乙基-4-甲基庚二酸二烷基酯的柴油组合物。