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    Plasticized sulfonated ionomers
    2.
    发明授权
    Plasticized sulfonated ionomers 失效
    增塑磺化离聚物

    公开(公告)号：US06121356A

    公开(公告)日：2000-09-19

    申请号：US304105

    申请日：1994-09-09

    申请人： Robert Dean Lundberg ,  Dennis George Peiffer ,  Robert Richard Phillips

    发明人： Robert Dean Lundberg ,  Dennis George Peiffer ,  Robert Richard Phillips

    IPC分类号： C08L101/00 ,  C08L5/12

    CPC分类号： C08L101/00

    摘要： In its broadest sense of the present invention comprises an aqueous emulsion containing water, a normally thermoplastic sulfonated polymer and a plasticizer that is substantially miscible in the polymer is, non-volatile and substantially insoluble in the water phase of the emulsion.The aqueous emulsion of the present invention is formed by polymerizing a sulfonate containing monomer with at least one non-sulfonate containing monomer in the aqueous phase in the presence of a free radical initiator and in the presence of a plasticizer that is substantially miscible in the polymer, is non-volatile and substantially water insoluble.

    摘要翻译： 在本发明的最广泛意义上，包括含水，通常热塑性磺化聚合物和在聚合物中基本可混溶的增塑剂的水乳液是非挥发性的并且基本上不溶于乳液的水相中。 本发明的水性乳液是通过在自由基引发剂的存在下在水相中和在聚合物中基本上可混溶的增塑剂的存在下，使含磺酸酯的单体与至少一种含有非磺酸酯的单体聚合而形成的 ，是非挥发性且基本上不溶于水的。

    Polyolefin-substituted amines grafted with poly(aromatic-n-monomers) for olegaginous compositions
    3.
    发明授权
    Polyolefin-substituted amines grafted with poly(aromatic-n-monomers) for olegaginous compositions 失效
    用聚合（芳族 - n-单体）接枝的聚烯烃取代的胺用于olegaginous组合物

    公开(公告)号：US5871554A

    公开(公告)日：1999-02-16

    申请号：US9615

    申请日：1998-01-20

    申请人： Abhimanyu Onkar Patil ,  Robert Dean Lundberg ,  Antonio Gutierrez

    发明人： Abhimanyu Onkar Patil ,  Robert Dean Lundberg ,  Antonio Gutierrez

    IPC分类号： C08F8/30 ,  C08F8/32 ,  C08F271/00 ,  C10L1/22 ,  C10L1/238 ,  C10L1/24 ,  C10L1/30 ,  C10L10/00 ,  C10M143/00 ,  C10M143/12 ,  C10M149/00 ,  C10M159/12 ,  C10M159/16

    CPC分类号： C08F271/00 ,  C08F8/32 ,  C08F8/42 ,  C10L1/221 ,  C10L1/238 ,  C10L1/2475 ,  C10L1/303 ,  C10L10/04 ,  C10M143/00 ,  C10M143/12 ,  C10M149/00 ,  C10M159/12 ,  C10M159/16 ,  C08F2800/10 ,  C10M2205/00 ,  C10M2205/02 ,  C10M2215/04 ,  C10M2215/042 ,  C10M2215/26 ,  C10M2217/00 ,  C10M2217/02 ,  C10M2217/04 ,  C10M2217/042 ,  C10M2217/043 ,  C10M2217/046 ,  C10M2217/06 ,  C10M2227/00

    摘要： Novel polymers comprising polyolefin-substituted amines grafted with aromatic N-containing monomers such as aniline, have been found to provide oil soluble polymers having dispersant and antioxidant properties in oleaginous compositions, including fuel and lubricating oils. The polymers of this invention are further useful in electrical applications. These materials are formed by a process which comprises: (a) contacting an amine compound having at least two reactive nitrogen moieties with at least one long chain hydrocarbon-substituted reactant in an amount and under conditions sufficient to form a N-containing polymer adduct containing reactive amine groups, and (b) contacting the N-containing polymer adduct with at least one aromatic N-containing monomer under polymerization conditions to graft said N-containing polymer adduct with aromatic N-containing polymer segments. The long chain hydrocarbon-substituted reactant can comprise materials such as (i) long chain hydrocarbons substituted with mono- or dicarboxylic acid, anhydride or ester groups; (ii) halogenated long chain hydrocarbons; (iii) mixtures of formaldehyde and a long chain hydrocarbyl substituted phenol; and (iv) mixtures of formaldehyde and a reaction product formed by reaction of long chain hydrocarbons substituted with mono- or dicarboxylic acid, anhydride or ester groups and an amino-substituted, optionally hydrocarbyl-substituted phenol.

    摘要翻译： 已经发现包含与芳族含N单体如苯胺接枝的聚烯烃取代的胺的新型聚合物在含油组合物（包括燃料和润滑油）中提供具有分散剂和抗氧化性能的油溶性聚合物。 本发明的聚合物在电气应用中更有用。 这些材料通过一种方法形成，该方法包括：（a）使具有至少两个反应性氮部分的胺化合物与至少一种长链烃取代的反应物以足以形成含有N的聚合物加合物的量和条件 反应性胺基，和（b）在聚合条件下使含N聚合物加合物与至少一种含芳族N的单体接触，以使含有N的聚合物链段与含N的聚合物链段接枝。 长链烃取代的反应物可以包括以下材料，例如（i）被单或二羧酸，酸酐或酯基取代的长链烃; （ii）卤代长链烃; （iii）甲醛和长链烃基取代的苯酚的混合物; 和（iv）甲醛和通过用单或二羧酸，酸酐或酯基和氨基取代的任选被烃基取代的苯酚取代的长链烃反应形成的反应产物的混合物。

    Polyolefin-substituted amines grafted with poly (aromatic-N-monomers) for oleaginous compositions
    4.
    发明授权
    Polyolefin-substituted amines grafted with poly (aromatic-N-monomers) for oleaginous compositions 失效
    与聚（芳族-N-单体）接枝的聚烯烃取代的胺用于油性组合物

    公开(公告)号：US5756434A

    公开(公告)日：1998-05-26

    申请号：US823259

    申请日：1997-03-24

    申请人： Abhimanyu Onkar Patil ,  Robert Dean Lundberg ,  Antonio Gutierrez

    发明人： Abhimanyu Onkar Patil ,  Robert Dean Lundberg ,  Antonio Gutierrez

    IPC分类号： C08F8/30 ,  C08F8/32 ,  C08F271/00 ,  C10L1/22 ,  C10L1/238 ,  C10L1/24 ,  C10L1/30 ,  C10L10/00 ,  C10M143/00 ,  C10M143/12 ,  C10M149/00 ,  C10M159/12 ,  C10M159/16 ,  C10M149/12

    CPC分类号： C08F271/00 ,  C08F8/32 ,  C08F8/42 ,  C10L1/221 ,  C10L1/238 ,  C10L1/2475 ,  C10L1/303 ,  C10L10/04 ,  C10M143/00 ,  C10M143/12 ,  C10M149/00 ,  C10M159/12 ,  C10M159/16 ,  C08F2800/10 ,  C10M2205/00 ,  C10M2205/02 ,  C10M2215/04 ,  C10M2215/042 ,  C10M2215/26 ,  C10M2217/00 ,  C10M2217/02 ,  C10M2217/04 ,  C10M2217/042 ,  C10M2217/043 ,  C10M2217/046 ,  C10M2217/06 ,  C10M2227/00

    摘要： Novel polymers comprising polyolefin-substituted amines grafted with aromatic N-containing monomers such as aniline, have been found to provide oil soluble polymers having dispersant and antioxidant properties in oleaginous compositions, including fuel and lubricating oils. The polymers of this invention are further useful in electrical applications. These materials are formed by a process which comprises: (a) contacting an amine compound having at least two reactive nitrogen moieties with at least one long chain hydrocarbon-substituted reactant in an amount and under conditions sufficient to form a N-containing polymer adduct containing reactive amine groups, and (b) contacting the N-containing polymer adduct with at least one aromatic N-containing monomer under polymerization conditions to graft said N-containing polymer adduct with aromatic N-containing polymer segments. The long chain hydrocarbon-substituted reactant can comprise materials such as (i) long chain hydrocarbons substituted with mono- or dicarboxylic acid, anhydride or ester groups; (ii) halogenated long chain hydrocarbons; (iii) mixtures of formaldehyde and a long chain hydrocarbyl substituted phenol; and (iv) mixtures of formaldehyde and a reaction product formed by reaction of long chain hydrocarbons substituted with mono- or dicarboxylic acid, anhydride or ester groups and an amino-substituted, optionally hydrocarbyl-substituted phenol.

    摘要翻译： 已经发现包含与芳族含N单体如苯胺接枝的聚烯烃取代的胺的新型聚合物在含油组合物（包括燃料和润滑油）中提供具有分散剂和抗氧化性能的油溶性聚合物。 本发明的聚合物在电气应用中更有用。 这些材料通过一种方法形成，该方法包括：（a）使具有至少两个反应性氮部分的胺化合物与至少一种长链烃取代的反应物以足以形成含有N的聚合物加合物的量和条件 反应性胺基，和（b）在聚合条件下使含N聚合物加合物与至少一种含芳族N的单体接触，以使含有N的聚合物链段与含N的聚合物链段接枝。 长链烃取代的反应物可以包括以下材料，例如（i）被单或二羧酸，酸酐或酯基取代的长链烃; （ii）卤代长链烃; （iii）甲醛和长链烃基取代的苯酚的混合物; 和（iv）甲醛和通过用单或二羧酸，酸酐或酯基和氨基取代的任选被烃基取代的苯酚取代的长链烃反应形成的反应产物的混合物。