公开(公告)号：US09295945B2

公开(公告)日：2016-03-29

申请号：US13356203

申请日：2012-01-23

Applicant: Satoshi Matsueda ,  Akimasa Hirai ,  Kenichi Taki ,  Keiichi Narita ,  Asuka Hori ,  Masahiro Kusaka

Inventor： Satoshi Matsueda ,  Akimasa Hirai ,  Kenichi Taki ,  Keiichi Narita ,  Asuka Hori ,  Masahiro Kusaka

IPC: B01J23/00 ,  B01J25/00 ,  B01J21/00 ,  B01J29/00 ,  B01J31/00 ,  B01J23/10 ,  B01D53/94 ,  B01J23/63 ,  B01J35/00 ,  B01J37/00 ,  B01J37/03 ,  F01N3/08 ,  F01N3/10

CPC classification number: B01D53/945 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/2068 ,  B01D2255/407 ,  B01D2255/908 ,  B01J23/002 ,  B01J23/63 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/031 ,  B01J2523/00 ,  F01N3/0864 ,  F01N3/10 ,  F01N2370/02 ,  Y02T10/20 ,  Y02T10/22 ,  B01J2523/36 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/822 ,  B01J2523/47 ,  B01J2523/824 ,  B01J2523/828 ,  B01J2523/3725 ,  B01J2523/69 ,  B01J2523/41

Abstract: An exhaust gas-purifying catalyst includes first particles of oxygen storage material, second particles of one or more rare-earth elements other than cerium and/or compounds thereof interposed between the first particles, and third particles of one or more precious metal elements interposed between the first particles, wherein a spectrum of a characteristic X-ray intensity for one of the rare-earth element(s) and a spectrum of a characteristic X-ray intensity for one of the precious metal element(s) that are obtained by performing a line analysis using energy-dispersive X-ray spectrometry along a length of 500 nm have a correlation coefficient of 0.68 or more.

Abstract translation: 废气净化催化剂包括第一颗粒的储氧材料，一个或多个除铈之外的稀土元素的第二颗粒和/或介于第一颗粒之间的化合物，以及介于第一颗粒之间的一种或多种贵金属元素的第三颗粒 第一颗粒，其中稀土元素之一的特征X射线强度的光谱和贵金属元素之一的特征X射线强度的光谱是通过执行 使用沿着500nm长度的能量色散X射线光谱法的线分析具有0.68以上的相关系数。

公开(公告)号：US08741799B2

公开(公告)日：2014-06-03

申请号：US13305255

申请日：2011-11-28

Applicant: Satoshi Matsueda ,  Akimasa Hirai ,  Kenichi Taki ,  Yuji Yabuzaki

Inventor： Satoshi Matsueda ,  Akimasa Hirai ,  Kenichi Taki ,  Yuji Yabuzaki

IPC: B01J27/053 ,  B01J23/26 ,  B01D53/94 ,  B01J23/58 ,  B01J35/02 ,  B01J37/02

CPC classification number: B01D53/944 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/204 ,  B01D2255/2042 ,  B01D2255/2092 ,  B01D2255/407 ,  B01D2255/9022 ,  B01D2255/908 ,  B01D2255/9202 ,  B01J23/58 ,  B01J27/053 ,  B01J31/26 ,  B01J35/023 ,  B01J37/0215 ,  B01J37/0219 ,  B01J37/0244 ,  F01N2370/02 ,  F01N2510/06 ,  F01N2510/0684 ,  Y02T10/22

Abstract: An exhaust gas-purifying catalyst includes a substrate, and a catalytic layer facing the substrate and including a precious metal, alumina, an oxygen storage material, and a sulfate of an alkaline-earth metal having an average particle diameter falling within a range of 0.01 to 0.70 μm, the average particle diameter being obtained by observation using a scanning electron microscope. Another exhaust gas-purifying catalyst includes a substrate, and a catalytic layer formed on the substrate using slurry containing a precious metal, alumina, an oxygen storage material, and a sulfate of an alkaline-earth metal having an average particle diameter falling within a range of 0.01 to 0.70 μm, the average particle diameter being obtained by observation using a scanning electron microscope.

Abstract translation: 废气净化催化剂包括基材和面向基材的催化剂层，并且包含贵金属，氧化铝，储氧材料和平均粒径在0.01以下的碱土金属的硫酸盐 通过使用扫描型电子显微镜观察得到的平均粒径为0.70μm。 另一种废气净化催化剂包括基材和使用含有贵金属，氧化铝，储氧材料和平均粒径落在一定范围内的碱土金属硫酸盐的浆料在基材上形成的催化剂层 为0.01〜0.70μm，通过使用扫描型电子显微镜观察得到的平均粒径。

公开(公告)号：US08569198B2

公开(公告)日：2013-10-29

申请号：US13402770

申请日：2012-02-22

Applicant: Sho Hoshino ,  Akimasa Hirai ,  Kenichi Taki ,  Keiichi Narita ,  Satoshi Matsueda ,  Asuka Hori ,  Masahiro Kusaka

Inventor： Sho Hoshino ,  Akimasa Hirai ,  Kenichi Taki ,  Keiichi Narita ,  Satoshi Matsueda ,  Asuka Hori ,  Masahiro Kusaka

IPC: B01J27/053

CPC classification number: B01D53/9422 ,  B01D2255/10 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/2042 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/908 ,  B01D2257/404 ,  B01J23/002 ,  B01J23/58 ,  B01J23/63 ,  B01J35/002 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0009 ,  B01J37/031 ,  B01J2523/00 ,  F01N3/10 ,  B01J2523/36 ,  B01J2523/3712 ,  B01J2523/48

Abstract: An exhaust gas-purifying catalyst includes first particles of oxygen storage material, second particles of one or more alkaline-earth metal elements and/or compounds thereof interposed between the first particles, and third particles of one or more precious metal elements interposed between the first particles. A spectrum of a first characteristic X-ray intensity for one of the one or more alkaline-earth metal elements and a spectrum of a second characteristic X-ray intensity for one of the one or more precious metal elements that are obtained by performing a line analysis using energy-dispersive X-ray spectrometry along a length of 500 nm have a correlation coefficient σ(AE,PM) of 0.70 or more.

Abstract translation: 废气净化催化剂包括第一颗粒的储氧材料，介于第一颗粒之间的一种或多种碱土金属元素和/或其化合物的第二颗粒和介于第一颗粒之间的一种或多种贵金属元素的第三颗粒 粒子。 一种或多种碱土金属元素之一的第一特征X射线强度的光谱和通过执行线获得的一种或多种贵金属元素之一的第二特征X射线强度的光谱 使用能量色散X射线光谱分析法，沿着500nm的长度，相关系数σ（AE，PM）为0.70以上。

公开(公告)号：US20100093526A1

公开(公告)日：2010-04-15

申请号：US12449104

申请日：2008-01-15

Applicant: Hirohisa Tanaka ,  Mari Uenishi ,  Masashi Taniguchi ,  Ryouhei Iwasaki ,  Mareo Kimura ,  Satoshi Matsueda

Inventor： Hirohisa Tanaka ,  Mari Uenishi ,  Masashi Taniguchi ,  Ryouhei Iwasaki ,  Mareo Kimura ,  Satoshi Matsueda

IPC: B01J23/745 ,  B01J23/44

CPC classification number: B01J23/8946 ,  B01D53/945 ,  B01D2255/1023 ,  B01D2255/2047 ,  B01D2255/20738 ,  B01D2255/2092 ,  B01J23/002 ,  B01J23/005 ,  B01J23/78 ,  B01J37/03 ,  B01J37/036 ,  B01J37/08 ,  B01J37/16 ,  B01J2523/00 ,  Y02T10/22

Abstract: Disclosed is a catalyst composition containing a composite oxide. The composite oxide contains a transition element (excluding platinum group elements) which is transformed into a solid solution in the composite oxide under an oxidizing atmosphere and is precipitated from the composite oxide under a reducing atmosphere.

Abstract translation: 公开了含有复合氧化物的催化剂组合物。 复合氧化物含有在氧化气氛下转变成复合氧化物中的固溶体的过渡元素（不含铂族元素），并在还原气氛下从复合氧化物中析出。

公开(公告)号：US07625836B2

公开(公告)日：2009-12-01

申请号：US11792832

申请日：2005-12-13

Applicant: Satoshi Matsueda ,  Mareo Kimura ,  Naoto Miyoshi ,  Yoshinori Ishii ,  Hirohisa Tanaka ,  Isao Tan ,  Mari Uenishi ,  Masashi Taniguchi

Inventor： Satoshi Matsueda ,  Mareo Kimura ,  Naoto Miyoshi ,  Yoshinori Ishii ,  Hirohisa Tanaka ,  Isao Tan ,  Mari Uenishi ,  Masashi Taniguchi

IPC: B01J21/00 ,  B01J21/02 ,  B01J21/06 ,  B01J21/10 ,  B01J23/00 ,  B01J23/02 ,  B01J23/10 ,  B01J23/38 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/54 ,  B01J23/56 ,  B01J23/58 ,  B01J23/63 ,  B01J37/08 ,  C01F3/00 ,  C01F5/00 ,  C01F7/00 ,  C01F11/00 ,  C01F17/00 ,  C01G25/00 ,  C01G25/02 ,  C01G55/00 ,  C01G57/00

CPC classification number: C01G25/006 ,  B01J23/002 ,  B01J23/63 ,  B01J2523/00 ,  C01P2002/52 ,  C01P2006/37 ,  C04B35/486 ,  C04B2235/3205 ,  C04B2235/3213 ,  C04B2235/3217 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3229 ,  C04B2235/3289 ,  C04B2235/3418 ,  C04B2235/441 ,  C04B2235/443 ,  C04B2235/444 ,  F01N3/2803 ,  F01N2370/02 ,  B01J2523/36 ,  B01J2523/48 ,  B01J2523/822 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/37

Abstract: To provide a heat-resistant oxide which is excellent in heat resistance and durability at high temperature and has high activity, a heat-resistant oxide which has an oxide crystal structure and in which a rate of a solid solution of a noble metal in the oxide crystal structure is 50% or more is obtained by heat-treating (secondarily baking) a precursor composition comprising zirconia, at least one coordinative element selected from the group consisting of rare earth elements, alkaline earth elements, aluminum and silicon, and at least one noble metal selected from the group consisting of platinum, rhodium and palladium at 650° C. or higher.

Abstract translation: 为了提供耐热性和耐高温性优异且活性高的耐热氧化物，具有氧化物结晶结构的耐热氧化物，其中贵金属在氧化物中的固溶率 通过对包含氧化锆的前体组合物进行热处理（二次焙烧），至少一种选自稀土元素，碱土金属元素，铝和硅的配位元素和至少一种配位元素获得的晶体结构为50％以上 选自铂，铑和钯在650℃以上的贵金属。

公开(公告)号：US20090131251A1

公开(公告)日：2009-05-21

申请号：US12343451

申请日：2008-12-23

Applicant: Satoshi Matsueda ,  Mareo Kimura ,  Akimasa Hirai ,  Keiichi Narita ,  Hirohisa Tanaka ,  Isao Tan ,  Mari Uenishi ,  Masashi Taniguchi

Inventor： Satoshi Matsueda ,  Mareo Kimura ,  Akimasa Hirai ,  Keiichi Narita ,  Hirohisa Tanaka ,  Isao Tan ,  Mari Uenishi ,  Masashi Taniguchi

IPC: B01J23/10 ,  B01J23/58

CPC classification number: B01D53/945 ,  B01D2255/102 ,  B01D2255/402 ,  B01D2255/405 ,  B01J21/10 ,  B01J23/002 ,  B01J23/02 ,  B01J23/58 ,  B01J23/894 ,  B01J23/8946 ,  B01J35/0006 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/033 ,  B01J2523/00 ,  Y02T10/22 ,  B01J2523/23 ,  B01J2523/47 ,  B01J2523/822 ,  B01J2523/3706 ,  B01J2523/824 ,  B01J2523/842

Abstract: An exhaust gas-purifying catalyst is less prone to cause a decrease in its activity even when used in a high temperature atmosphere containing oxygen at a high concentration. The exhaust gas-purifying catalyst includes a composite oxide and Pd or a second solid solution of a composite and Rh and/or Pt. The first and second solid solutions have perovskite structure and are represented by ABO3 and CDO3, respectively. The composite oxide catalyst is supported by a composite oxide support including a composite oxide of spinel structure represented by EF2O4 or a composite oxide represented by GAl12O19. A and B represent a rare-earth element and a transition element, respectively. C and G represent an alkaline-earth element. D represents one or more of Ti, Zr, Hf and Ce. E represents an alkaline-earth element and/or a transition element. F represents one or more of Al, Mg and transition elements.

Abstract translation: 废气净化催化剂即使在高浓度氧气的高温气氛中使用也不易引起其活性降低。 废气净化催化剂包括复合氧化物和Pd或复合材料和Rh和/或Pt的第二固溶体。 第一和第二固溶体具有钙钛矿结构，分别由ABO 3和CDO 3表示。 复合氧化物催化剂由包含由EF 2 O 4表示的尖晶石结构的复合氧化物或由GA122019表示的复合氧化物的复合氧化物载体负载。 A和B分别表示稀土元素和过渡元素。 C和G表示碱土元素。 D表示Ti，Zr，Hf和Ce中的一种或多种。 E表示碱土元素和/或过渡元素。 F表示Al，Mg和过渡元素中的一种或多种。

公开(公告)号：US20090011932A1

公开(公告)日：2009-01-08

申请号：US12204647

申请日：2008-09-04

Applicant: Satoshi MATSUEDA ,  Mareo Kimura ,  Hirohisa Tanaka ,  Mari Uenishi

Inventor： Satoshi MATSUEDA ,  Mareo Kimura ,  Hirohisa Tanaka ,  Mari Uenishi

IPC: B01J23/58

CPC classification number: B01J23/58 ,  B01D2255/1021 ,  B01D2255/40 ,  B01J21/005 ,  B01J23/002 ,  B01J23/005 ,  B01J35/0006 ,  B01J37/04 ,  B01J2523/00 ,  B01J2523/23 ,  B01J2523/31 ,  B01J2523/22

Abstract: An object of the present invention is to provide an exhaust gas-purifying catalyst that is less prone to cause a decrease in its activity even when used at high temperatures in an atmosphere whose oxygen concentration is high. An exhaust gas-purifying catalyst of the present invention includes a composite oxide of alkaline-earth metal and aluminum, and platinum, wherein at least a part of the composite oxide and at least a part of the platinum forms a solid solution.

Abstract translation: 本发明的目的是提供即使在氧浓度高的气氛中在高温下使用时也不易引起其活性降低的废气净化用催化剂。 本发明的废气净化催化剂包括碱土金属和铝的复合氧化物和铂，其中至少一部分复合氧化物和至少一部分铂形成固溶体。

公开(公告)号：US20070297971A1

公开(公告)日：2007-12-27

申请号：US11792832

申请日：2005-12-13

Applicant: Satoshi Matsueda ,  Mareo Kimura ,  Naoto Miyoshi ,  Yoshinori Ishii ,  Hirohisa Tanaka ,  Isao Tan ,  Mari Uenishi ,  Masashi Taniguchi

Inventor： Satoshi Matsueda ,  Mareo Kimura ,  Naoto Miyoshi ,  Yoshinori Ishii ,  Hirohisa Tanaka ,  Isao Tan ,  Mari Uenishi ,  Masashi Taniguchi

IPC: C01G25/02

CPC classification number: C01G25/006 ,  B01J23/002 ,  B01J23/63 ,  B01J2523/00 ,  C01P2002/52 ,  C01P2006/37 ,  C04B35/486 ,  C04B2235/3205 ,  C04B2235/3213 ,  C04B2235/3217 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3229 ,  C04B2235/3289 ,  C04B2235/3418 ,  C04B2235/441 ,  C04B2235/443 ,  C04B2235/444 ,  F01N3/2803 ,  F01N2370/02 ,  B01J2523/36 ,  B01J2523/48 ,  B01J2523/822 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/37

Abstract: To provide a heat-resistant oxide which is excellent in heat resistance and durability at high temperature and has high activity, a heat-resistant oxide which has an oxide crystal structure and in which a rate of a solid solution of a noble metal in the oxide crystal structure is 50% or more is obtained by heat-treating (secondarily baking) a precursor composition comprising zirconia, at least one coordinative element selected from the group consisting of rare earth elements, alkaline earth elements, aluminum and silicon, and at least one noble metal selected from the group consisting of platinum, rhodium and palladium at 650° C. or higher.

Abstract translation: 为了提供耐热性和耐高温性优异且活性高的耐热氧化物，具有氧化物结晶结构的耐热氧化物，其中贵金属在氧化物中的固溶率 通过对包含氧化锆的前体组合物进行热处理（二次焙烧），至少一种选自稀土元素，碱土金属元素，铝和硅的配位元素和至少一种配位元素获得的晶体结构为50％以上 选自铂，铑和钯在650℃以上的贵金属。

公开(公告)号：US09073048B2

公开(公告)日：2015-07-07

申请号：US12301011

申请日：2007-05-31

Applicant: Hiroki Nagashima ,  Akiya Chiba ,  Satoshi Matsueda

Inventor： Hiroki Nagashima ,  Akiya Chiba ,  Satoshi Matsueda

IPC: B01J23/10 ,  B01J23/38 ,  B01J37/08 ,  B01D53/94 ,  B01J21/10 ,  B01J23/00 ,  B01J23/63 ,  B01J37/02 ,  B01J35/00 ,  B01J37/03

CPC classification number: B01J37/08 ,  B01D53/945 ,  B01D2255/206 ,  B01D2255/2092 ,  B01D2255/407 ,  B01J21/10 ,  B01J23/002 ,  B01J23/63 ,  B01J35/002 ,  B01J37/0215 ,  B01J37/0244 ,  B01J37/03 ,  B01J2523/00 ,  Y02T10/22 ,  B01J2523/25 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/828 ,  B01J2523/22 ,  B01J2523/31

Abstract: An exhaust gas-purifying catalyst whose activity is less prone to be decreased even in the case where used in a high-temperature atmosphere containing oxygen at a high concentration can be realized. The catalytic layer of the catalyst includes an oxide particle, a simple oxide of alkaline-earth element or rare-earth element, and alumina and/or aluminum hydroxide. The oxide particle contains an oxide of rare-earth element and/or zirconium, a composite oxide and a precious metal. The composite oxide contains an alkaline-earth element and at least one of the rare-earth element and zirconium. The composite oxide and a part of the precious metal form a solid solution.

Abstract translation: 即使在高浓度氧气的高温气氛中使用的情况下，即使能够实现活性也不易降低的废气净化用催化剂。 催化剂的催化剂层包括氧化物颗粒，碱土金属或稀土元素的简单氧化物，以及氧化铝和/或氢氧化铝。 氧化物颗粒包含稀土元素和/或锆的氧化物，复合氧化物和贵金属。 复合氧化物含有碱土元素和稀土元素和锆中的至少一种。 复合氧化物和贵金属的一部分形成固溶体。

公开(公告)号：US08546296B2

公开(公告)日：2013-10-01

申请号：US13327375

申请日：2011-12-15

Applicant: Yuji Yabuzaki ,  Akimasa Hirai ,  Kenichi Taki ,  Tomohito Mizukami ,  Satoshi Matsueda

Inventor： Yuji Yabuzaki ,  Akimasa Hirai ,  Kenichi Taki ,  Tomohito Mizukami ,  Satoshi Matsueda

IPC: B01J23/10 ,  B01J23/42 ,  B01J23/44 ,  B01J23/56 ,  B01J8/00 ,  B01J8/02 ,  B32B3/12 ,  B01D53/56 ,  B01D53/86 ,  B01D53/94 ,  C01B21/00 ,  C01B23/00 ,  C01B25/00 ,  C01B31/00 ,  C01B33/00 ,  C01B35/00 ,  C01G28/00 ,  C01G30/00

CPC classification number: B01J23/58 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/2027 ,  B01D2255/204 ,  B01D2255/2042 ,  B01D2255/2045 ,  B01D2255/2092 ,  B01D2255/407 ,  B01D2255/9022 ,  B01D2255/908 ,  B01J23/63 ,  B01J27/053 ,  B01J35/002 ,  B01J37/0215 ,  B01J37/0244 ,  B01J37/0248 ,  Y02T10/22 ,  Y10T428/24149 ,  Y10T428/24157 ,  Y10T428/24165

Abstract: An exhaust gas-purifying catalyst includes a substrate, and a catalytic layer supported by the substrate. The catalytic layer includes a support made of alumina, an oxygen storage material, an alkaline earth metal and/or a compound of alkaline-earth metal selectively supported by a surface of the support and dispersed on the surface of the support, and a precious metal supported by the surface of the support. A ratio of a number of moles of the alkaline-earth metal in the catalytic layer with respect to a volumetric capacity of the exhaust gas-purifying catalyst falls within a range of 0.0004 mol/L to 0.35 mol/L.

Abstract translation: 废气净化催化剂包括基板和由基板支撑的催化剂层。 催化剂层包括由氧化铝制成的载体，储氧材料，碱土金属和/或由载体表面选择性地分散在载体表面上的碱土金属的化合物和贵金属 由支撑体的表面支撑。 催化剂层中的碱土类金属的摩尔数相对于排气净化催化剂的体积容量的比例在0.0004mol / L〜0.35mol / L的范围内。