摘要:
Heavy asphaltenic oils are converted to lighter fractions by(a) Deasphalting the asphaltenic oil with an aliphatic C.sub.5 -C.sub.7 hydrocarbon,(b) Maintaining the oil with hydrogen at 440.degree.-530.degree. C. and 40-140 bars in a non-catalytic conversion zone, and(c) Feeding the product of step (b) to a catalytic conversion zone at 320.degree.-430.degree. C. and 40-140 bars, the catalyst in said zone comprising at least one molybdenum and/or tungsten compound and at least one nickel and/or cobalt compound.
摘要:
Process for reducing the viscosity of a highly viscous hydrocarbon charge containing 10-30% b.w. of constituents distilling above 375.degree. C., said treatment comprising hydrovisbreaking said charge to such an extent as to convert 10 to 30% of the 375.degree. C..sup.+ fraction to a 375.degree. C..sup.- fraction, fractionating the hydrovisbreaked product to separate a fraction comprising at least 90% of the constituents boiling below 375.degree. C. from a distillation residue, deasphalting said distillation residue and admixing at least a portion of the deasphalted distillation residue with at least a portion of said fraction comprising at least 90% of the constituents boiling below 375.degree. C.
摘要:
Process for deasphalting a hydrocarbon charge by means of a deasphalting solvent.The charge (1) is introduced, at 100.degree.-200.degree. C., in admixture with a deasphalting solvent (3and 4), into a settler (7). The deasphalted oil (24) is separated from the solvent (23). Asphalt (9) is washed in a column and then separated from the washing liquid (21).
摘要:
Hydrorefining of a hydrocarbon charge of high metal content with a catalyst containing alumina, a metal from group VI and a metal from the iron group, of a specific surface from 120 to 200 m.sup.2 /g, a total pore volume from 0.8 to 1.2 cc/g and a pore distribution as follows:0 to 10% of pores smaller than 100 A35 to 60% of pores from 100 to 600 A35 to 55% of pores greater than 600 A,including 10 to 25% of pores greater than 10,000 A, said catalyst optionally containing additionally an alkaline-earth metal.
摘要:
The invention relates to an alkylation process, in which a charge incorporating at least one isoparaffin and at least one olefin containing 2 to 6 carbon atoms per molecule, is treated in the presence of a solid alkylation catalyst. In the process, catalyst present in a reaction R is contacted with the charge, recycled liquid effluent discharged from reaction zone R and liquid effluent discharged from an isobutane/n-butane/alkylate separation zone S. The process uses a specific catalyst, e.g., sulfuric acid impregnated on a porous support.
摘要:
A reaction-distillation apparatus is provided comprising at least one reaction-distillation zone including at least one bed of solid elements disposed on a fluid-permeable perforated support having perforations small enough to retain the elements wherein the bed of solid elements includes loose solid catalytic particles and at least one receptacle, containing at least one distillation packing body, the external jacket of which is permeable to fluids and the impermeable to the solid catalytic particles and packing body. The apparatus can be used for carrying out chemical reaction and concomitant fractionation of the reaction mixture, for example, to synthesize ethers from olefins and alcohols.
摘要:
The invention relates to a process for catalytic treatment of heavy hydrocarbons, in a fixed or moving bed, over a catalyst containing an alumina carrier and at least one catalytic metal or compound of metal from groups VB, VI B and VIII of the periodic classification of elements, characterized by the direct injection into the charge, continuously or periodically, of at least one metal compound selected from the group consisting of halides, oxyhalides, oxides, polyacids and polyacid salts of metals from groups VI B, VII B and VIII, before introducing the charge into the hydrotreatment zone.
摘要:
Hydrocarbon cuts of high olefin content are desulfurized, without substantial loss in octane number, by reaction with hydrogen in the presence of a catalyst comprising (a) a specified non-acidic carried and (b) cobalt and at least one of tungsten and molybdenum, the atomic ratio ##EQU1## being higher than 0.55.
摘要:
Process for upgrading an olefinic C.sub.4 cut issued from a cracking or steam cracking unit, comprising subjecting said cut to isomerization conditions so as to convert at least 80% of its 1-butene content to 2-butenes, subjecting the so-treated C.sub.4 cut to polymerization conditions so as to convert at least 90% of its isobutene content to isobutene dimers and trimers without substantially converting the normal butenes, separating the isobutene dimers and trimers, alkylating the remaining fraction and fractionating the latter to an alkylate, L P G and an isobutane containing fraction.
摘要:
Process for polymerizing olefinic hydrocarbons at a temperature from 0.degree. to 90.degree. C., preferably from 20.degree. to 80.degree. C. in the presence of a catalyst containing aluminum oxide and, per part by weight thereof, boron oxide in a proportion of 0.01 to 1, preferably 0.07 to 0.15 part by weight and halogen in a proportion of 0.5 to 20%, preferably 4 to 12%, said catalyst resulting from the reaction of an aluminum compound of formula AlX.sub.y R.sub.(3-y) where X is halogen, R is a hydrocarbon radical and y is selected from 1, 3/2, 2 and 3, with a carrier containing aluminum oxide and boron oxide in a proportion to aluminum oxide from 1 to 100%.