摘要:
A process for improving the operation of combustors includes the steps of burning a carbonaceous fuel in a combustor system and determining combustion conditions within the combustor system that can benefit from a targeted treatment additive, wherein the determinations are made by calculation including computational fluid dynamics and observation. The process further includes locating introduction points in the combustor system where introduction of the targeted treatment additive could be accomplished. Based on the previous steps, a treatment regimen for introducing the targeted treatment additive to locations within the combustor system results in one or more benefits selected from the group consisting of reducing the opacity of plume, improving combustion, reducing slag, reducing LOI and/or unburned carbon, reducing corrosion, and improving electrostatic precipitator performance. The targeted treatment additive comprises an alloy represented by the following generic formula (Aa)n(Bb)n(Cc)n(Dd)n(. . .)n, wherein each capital letter and (. . .) is a metal, wherein A is a combustion modifier, B is a deposit modifier; C is a corrosion inhibitor; and D is a combustion co-modifier/electrostatic precipitator enhancer, wherein each subscript letter represents compositional stoichiometry, wherein n is greater than or equal to zero and the sum of n's is greater than zero, and wherein the alloy comprises at least two different metals, with the proviso that if the metal is cerium, then its compositional stoichiometry is less than about 0.7.
摘要:
A process for improving the operation of combustors includes the steps of burning a carbonaceous fuel in a combustor system and determining combustion conditions within the combustor system that can benefit from a targeted treatment additive, wherein the determinations are made by calculation including computational fluid dynamics and observation The process further includes locating introduction points in the combustor system where introduction of the targeted treatment additive could be accomplished. Based on the previous steps, a treatment regimen for introducing the targeted treatment additive to locations within the combustor system results in one or more benefits selected from the group consisting of reducing the opacity of plume, improving combustion, reducing slag, reducing LOI and/or unburned carbon, reducing corrosion, and improving electrostatic precipitator performance. The targeted treatment additive comprises an alloy represented by the following generic formula (Aa)n(Bb)n(Cc)n(Dd)n( . . . )n, wherein each capital letter and ( . . . ) is a metal, wherein A is a combustion modifier, B is a deposit modifier; C is a corrosion inhibitor; and D is a combustion co-modifier/electrostatic precipitator enhancer, wherein each subscript letter represents compositional stoichiometry, wherein n is greater than or equal to zero and the sum of n's is greater than zero, and wherein the alloy comprises at least two different metals, with the proviso that if the metal is cerium, then its compositional stoichiometry is less than about 0.7.
摘要:
Deposits and soot formation in a direct injection gasoline engine are reduced by providing as fuel for the operation of said direct injection engine a fuel composition comprising a fuel-soluble cyclopentadienyl manganese tricarbonyl compound.
摘要:
In a specific embodiment of this invention, deposits and soot formation in a direct injection engine are reduced by passivating the injectors to within 0.1 mm of the injector nozzle. The fuel used with the inventive injectors comprises fuel-soluble additives.
摘要:
The present invention relates to an apparatus and method for delivering tungsten from a to a fuel combustion system or to the exhaust therefrom. By the present invention, tungsten from the lubricant or the fuel will interact with iron from the combustion process. In this manner, the tungsten scavenges or inactivates iron that can otherwise poison catalytic converters, sensors and/or automotive on-board diagnostic devices and/or reduce the operation of spark plugs. The present invention can also lead to improved durability of exhaust after treatment systems. Supplying tungsten acts to change the characteristics of iron deposits formed by combusting a fuel with iron.
摘要:
The present invention relates to an apparatus and method for delivering tungsten from a to a fuel combustion system or to the exhaust therefrom. By the present invention, tungsten from the lubricant or the fuel will interact with iron from the combustion process. In this manner, the tungsten scavenges or inactivates iron that can otherwise poison catalytic converters, sensors and/or automotive on-board diagnostic devices and/or reduce the operation of spark plugs. The present invention can also lead to improved durability of exhaust after treatment systems. Supplying tungsten acts to change the characteristics of iron deposits formed by combusting a fuel with iron.
摘要:
A nanoalloy catalyst, dual catalyst and methods for improving the efficiency and output of a biomass gasification process are provided where the catalysts comprise a volatile organometallic compound(s) and/or a nanoalloy catalyst. The subject nanoalloy catalyst cracks and gasifies lignin, which is generally inert in conventional gasification, at relatively low gasification temperatures. The subject disclosure also provides a means to increase gas yields and lower lignin content in the resulting product relative to conventional gasification. Alternatively, oil production may be increased, if desired. Moreover, the resulting gas may achieve a Fischer-Tropsch reactor favorable H2:CO ratio of up to about 9:1. The energy input to the gasification is correspondingly reduced to reduce costs and the environmental impact associated with the gasification process.
摘要:
A safe, metal-containing combustion additive and a method of formulation is directed for use in connection with utility and industrial furnaces. The additive includes a metal-containing catalyst, a ligand for complexing with the catalyst and a solvent for carrying the catalyst/ligand complex. The vapor pressure of the additive is less than about 200×10−5 Torr at 100° F.
摘要:
A hydrocarbonaceous fuel additive, fuel composition, and method all lower both carbon particulate emissions and improve slag properties in combustion systems including, for instance, utility furnaces and boiler systems. The mixed metal catalyst may include a transition metal-containing compound, an alkali metal compound, and a magnesium-containing compound.
摘要:
The present invention relates to an apparatus and method for delivering tungsten into a fuel combustion system or to the exhaust therefrom. By the present invention, tungsten from the lubricant or the fuel will interact with combustion products and, in particular, phosphorus, sulfur, and/or lead from the combustion products. In this manner, the tungsten scavenges or inactivates harmful materials which have migrated into the fuel or combustion products, and which can otherwise poison catalytic converters, sensors and/or automotive on-board diagnostic devices The present invention can also lead to improved durability of exhaust after treatment systems. A lubricant in accordance with the present invention is also disclosed.