公开(公告)号：US20140235914A1

公开(公告)日：2014-08-21

申请号：US13770288

申请日：2013-02-19

Applicant: BASF CORPORATION

Inventor： Joseph C. Dellamorte

IPC: B01J23/30 ,  C07C6/04

CPC classification number: B01J23/30 ,  B01J35/002 ,  B01J35/008 ,  B01J37/02 ,  C07C6/04 ,  C07C2521/08 ,  C07C2523/30 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/107

Abstract: Provided are catalyst composites useful for the production of olefins during a metathesis reaction, as well as methods of making and using the same. Certain methods comprise a support comprising at least about 90% by weight silica; and an eggshell layer on the support comprising about 0.25 to about 10 wt. % tungsten in the form of tungsten oxide or tungsten oxide hydrate, based on the total weight of the catalyst composite.

Abstract translation: 提供了在复分解反应期间可用于生产烯烃的催化剂复合材料，以及制备和使用它们的方法。 某些方法包括包含至少约90重量％的二氧化硅的载体; 并且载体上的蛋壳层包含约0.25至约10wt。 基于催化剂复合材料的总重量，以氧化钨或氧化钨水合物形式的钨的％。

公开(公告)号：US11684906B2

公开(公告)日：2023-06-27

申请号：US16972867

申请日：2019-05-30

Applicant: BASF Corporation

Inventor： Ibrahim Ilgaz Soykal ,  Burcu Bayram ,  Knut Wassermann ,  Joseph C. Dellamorte

IPC: B01J21/10 ,  B01J35/10 ,  B01J35/02 ,  B01J35/00 ,  B01J37/08 ,  C07C6/04 ,  C07C5/25 ,  B28B3/20

CPC classification number: B01J21/10 ,  B01J35/002 ,  B01J35/026 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/082 ,  C07C5/2512 ,  C07C6/04 ,  B28B3/20 ,  C07C2521/04 ,  C07C2521/10 ,  C07C2523/02

Abstract: A catalyst composition comprising MgO, Al2O3 and one or more further alkaline earth metal oxides, provides for outstanding catalytic production of propylene when employed together with a metathesis catalyst.

公开(公告)号：US20140005449A1

公开(公告)日：2014-01-02

申请号：US14020442

申请日：2013-09-06

Applicant: BASF Corporation ,  Chevron Phillips Chemical Company LP

Inventor： Tin-Tack Peter Cheung ,  Joseph Bergmeister, III ,  Stephen L. Kelly ,  Michael Joseph Breen ,  Joseph C. Dellamorte ,  Danna Rehms Mooney

IPC: B01J27/13

CPC classification number: B01J23/50 ,  B01J21/04 ,  B01J23/44 ,  B01J23/56 ,  B01J27/13 ,  B01J35/002 ,  B01J35/008 ,  B01J35/08 ,  B01J35/10 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/06 ,  B01J37/08 ,  B01J37/18 ,  B01J37/24 ,  C07C5/09 ,  C07C7/167 ,  C10G45/40 ,  Y02P20/52 ,  Y10T428/2982 ,  C07C11/04

Abstract: A composition comprising a support formed from a high surface area alumina and having a low angularity particle shape; and at least one catalytically active metal, wherein the support has pores, a total pore volume, and a pore size distribution; wherein the pore size distribution displays at least two peaks of pore diameters, each peak having a maximum; wherein a first peak has a first maximum of pore diameters of equal to or greater than about 200 nm and a second peak has a second maximum of pore diameters of less than about 200 nm; and wherein greater than or equal to about 5% of a total pore volume of the support is contained within the first peak of pore diameters.

Abstract translation: 一种组合物，其包含由高表面积氧化铝形成并具有低角度颗粒形状的载体; 和至少一种催化活性金属，其中所述载体具有孔，总孔体积和孔径分布; 其中孔径分布显示至少两个孔径的峰，每个峰具有最大值; 其中第一峰具有等于或大于约200nm的孔径的第一最大值，并且第二峰具有小于约200nm的孔径的第二最大值; 并且其中所述载体的总孔体积的大于或等于约5％包含在所述第一孔径范围内。

公开(公告)号：US20210245138A1

公开(公告)日：2021-08-12

申请号：US16972867

申请日：2019-05-30

Applicant: BASF Corporation

Inventor： Ibrahim Ilgaz Soykal ,  Burcu Bayram ,  Knut Wassermann ,  Joseph C. Dellamorte

IPC: B01J21/10 ,  B01J35/10 ,  B01J35/02 ,  B01J35/00 ,  B01J37/08 ,  C07C6/04 ,  C07C5/25

Abstract: A catalyst composition comprising MgO, Al2O3 and one or more further alkaline earth metal oxides, provides for outstanding catalytic production of propylene when employed together with a metathesis catalyst.

公开(公告)号：US09556100B2

公开(公告)日：2017-01-31

申请号：US13932233

申请日：2013-07-01

Applicant: BASF Corporation

Inventor： Joseph C. Dellamorte ,  Ronald T. Mentz

IPC: B01J21/00 ,  C07C51/25 ,  B01J37/02 ,  B01J37/06 ,  B01J37/18 ,  B01J23/56 ,  B01J23/58 ,  B01J35/00 ,  B01J35/10 ,  C07C67/055

CPC classification number: C07C67/04 ,  B01J21/12 ,  B01J23/52 ,  B01J23/56 ,  B01J23/58 ,  B01J35/008 ,  B01J35/023 ,  B01J35/08 ,  B01J35/1019 ,  B01J37/0203 ,  B01J37/0234 ,  B01J37/06 ,  B01J37/18 ,  C07C51/25 ,  C07C67/055 ,  C07C69/15

Abstract: Provided are catalyst composites useful for the production of vinyl acetate monomer, as well as methods of making using same. The catalyst composites may comprise a support comprising silica and about 1 to about 3 wt-% alumina, wherein the support has a surface area of about 175 to about 300 m2/g; and an eggshell layer on the support comprising Pd and Au.

Abstract translation: 提供了可用于生产乙酸乙烯酯单体的催化剂复合物，以及使用它们的制备方法。 催化剂复合材料可以包含包含二氧化硅和约1至约3重量％的氧化铝的载体，其中载体的表面积为约175至约300m 2 / g; 和在包含Pd和Au的载体上的蛋壳层。

公开(公告)号：US20230249160A1

公开(公告)日：2023-08-10

申请号：US18013613

申请日：2021-06-24

Applicant: BASF CORPORATION

Inventor： Jian-Ping Chen ,  Arunabha Kundu ,  Joseph C. Dellamorte

IPC: B01J23/889 ,  B01J23/72 ,  B01J23/34 ,  B01J21/04 ,  B01J23/00 ,  B01J35/10 ,  B01J35/02 ,  B01J35/00 ,  B01J37/04 ,  B01J37/03 ,  B01J37/02 ,  B01J37/08 ,  B01J37/00 ,  B01J37/18 ,  C07C29/149

CPC classification number: B01J23/8892 ,  B01J23/72 ,  B01J23/34 ,  B01J21/04 ,  B01J23/005 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/026 ,  B01J35/006 ,  B01J37/04 ,  B01J37/031 ,  B01J37/0236 ,  B01J37/088 ,  B01J37/009 ,  B01J37/18 ,  C07C29/149

Abstract: A method of preparing a calcined hydrogenolysis/hydrogenation catalyst includes mixing a copper-containing material, manganese-containing material, sodium aluminate, and water to obtain an aqueous slurry; contacting the aqueous slurry with a caustic material to form a precipitate in a caustic aqueous slurry; removing the precipitate from the caustic aqueous slurry; and removing residual water from the precipitate to form a dried precipitate; calcining the dried precipitate to form the calcined hydrogenolysis/hydrogenation catalyst exhibiting a Brunauer-Emmett-Teller (“BET”) surface area of about 5 m2/g to about 75 m2/g. The calcined hydrogenolysis/hydrogenation catalyst may include a spinel structure crystallite size of about 15 nm or less. The calcined hydrogenolysis/hydrogenation catalyst may include a tenorite crystallite size of about 20 nm to 30 nm.

公开(公告)号：US20230149908A1

公开(公告)日：2023-05-18

申请号：US17913512

申请日：2021-02-19

Applicant: BASF CORPORATION ,  THE REGENTS OF THE UNIVERSITY OF CALIFORNIA

Inventor： Joseph C. Dellamorte ,  Enrique Iglesia ,  Biswanath Dutta ,  Miao Guang

IPC: B01J23/89 ,  B01J23/75 ,  B01J23/86 ,  B01J23/825 ,  B01J21/08 ,  B01J21/04 ,  B01J35/00 ,  B01J35/10 ,  B01J35/02 ,  B01J37/02 ,  C07C5/48 ,  C07C5/333

CPC classification number: B01J23/8913 ,  B01J23/75 ,  B01J23/864 ,  B01J23/825 ,  B01J21/08 ,  B01J21/04 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/026 ,  B01J37/0203 ,  C07C5/48 ,  C07C5/3332 ,  C07C2523/75 ,  C07C2523/89 ,  C07C2523/86 ,  C07C2523/825 ,  C07C2521/08 ,  C07C2521/04

Abstract: Disclosed are catalyst compositions containing cobalt II cations (Co2+) on a support. In embodiments, the catalyst compositions are free of chromium and/or a precious metal. Also disclosed are methods of preparing such catalyst compositions and methods of using such catalyst compositions, for example, to dehydrogenate light alkane and/or light alkene gas.

公开(公告)号：US20230090704A1

公开(公告)日：2023-03-23

申请号：US17800803

申请日：2021-02-08

Applicant: BASF CORPORATION ,  THE REGENTS OF THE UNIVERSITY OF CALIFORNIA

Inventor： Joseph C. Dellamorte ,  Enrique Iglesia ,  Teng Fu ,  Biswanath Dutta

IPC: B01J21/06 ,  B01J23/10 ,  B01J35/10 ,  B01J35/02 ,  B01J35/08 ,  B01J37/18 ,  C01G25/02 ,  C07C5/333

Abstract: Disclosed are methods of dehydrogenating a light alkane gas (and/or light alkene gas), which include adding hydrogen (H2) to the light alkane gas (and/or light alkene gas) in the presence of a catalyst composition containing zirconium oxide. Also disclosed are catalyst compositions containing zirconium oxide and methods of preparation thereof, where the catalyst compositions are useful in methods of dehydrogenating light alkane gas.

公开(公告)号：US20140039218A1

公开(公告)日：2014-02-06

申请号：US13932233

申请日：2013-07-01

Applicant: BASF Corporation

Inventor： Joseph C. Dellamorte ,  Ronald T. Mentz

IPC: C07C51/25

CPC classification number: C07C67/04 ,  B01J21/12 ,  B01J23/52 ,  B01J23/56 ,  B01J23/58 ,  B01J35/008 ,  B01J35/023 ,  B01J35/08 ,  B01J35/1019 ,  B01J37/0203 ,  B01J37/0234 ,  B01J37/06 ,  B01J37/18 ,  C07C51/25 ,  C07C67/055 ,  C07C69/15

Abstract: Provided are catalyst composites useful for the production of vinyl acetate monomer, as well as methods of making using same. The catalyst composites may comprise a support comprising silica and about 1 to about 3 wt-% alumina, wherein the support has a surface area of about 175 to about 300 m2/g; and an eggshell layer on the support comprising Pd and Au.

Abstract translation: 提供了可用于生产乙酸乙烯酯单体的催化剂复合物，以及使用它们的制备方法。 催化剂复合材料可以包含包含二氧化硅和约1至约3重量％的氧化铝的载体，其中载体的表面积为约175至约300m 2 / g; 和在包含Pd和Au的载体上的蛋壳层。