公开(公告)号：US11440266B2

公开(公告)日：2022-09-13

申请号：US16204141

申请日：2018-11-29

申请人： Carbon, Inc.

发明人： Jason P. Rolland ,  Kai Chen ,  Justin Poelma ,  James Goodrich ,  Robert Pinschmidt ,  Joseph M. DeSimone ,  Lloyd M. Robeson

IPC分类号： C08G18/42 ,  B29C64/129 ,  B29C64/40 ,  C08K3/013 ,  C08K3/01 ,  G03F7/00 ,  G03F7/027 ,  G03F7/038 ,  G03F7/075 ,  G03F7/38 ,  B29C64/124 ,  B29C64/135 ,  B29C64/386 ,  C08G18/81 ,  C08G18/10 ,  C08G18/76 ,  C08F220/34 ,  C08F290/06 ,  C08G18/73 ,  C08G18/48 ,  C08G18/24 ,  C08G18/69 ,  C08G18/75 ,  C08F283/00 ,  C08G18/40 ,  B29C71/00 ,  B33Y10/00 ,  B33Y70/00 ,  B29D11/00 ,  B29C35/08 ,  C08K5/00 ,  C08L75/04 ,  B33Y80/00 ,  C09D135/02 ,  C09D175/04 ,  C09D175/08 ,  B29C64/255 ,  B29C64/106 ,  B29C64/165 ,  B33Y30/00 ,  C08J5/00 ,  C08L75/14 ,  B33Y50/02 ,  B29C33/00 ,  B29K75/00 ,  B29K105/04 ,  B29L11/00 ,  B29L31/10 ,  B29K105/00 ,  B29K105/16 ,  B29K509/00 ,  B29L31/00

摘要： A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.

公开(公告)号：US20210246300A1

公开(公告)日：2021-08-12

申请号：US17053931

申请日：2019-05-09

申请人： Carbon, Inc.

发明人： Justin Poelma ,  Mu San Zhang ,  Xinyu Gu ,  Jason P. Rolland ,  Joseph M. DeSimone

IPC分类号： C08L55/00 ,  C09D175/16 ,  C08J3/12 ,  C08G18/80 ,  C08G18/75 ,  C08G18/48 ,  C08G18/32 ,  C08G18/10 ,  C08G18/08 ,  C08F290/06 ,  C08K5/00 ,  B33Y40/10 ,  B33Y10/00 ,  B33Y70/00 ,  B29C64/165 ,  B29C64/314

摘要： Provided herein are methods of making a reactive particulate material by free radically polymerizing a single-cure resin to produce a polymer, the resin comprising: a reactive blocked polyurethane prepolymer, a reactive blocked polyurea prepolymer, a reactive blocked polyurethane-polyurea copolymer, or a combination thereof, wherein said polymerizing is carried out by dispersive polymerization (e.g., an emulsion, suspension or dispersion polymerization process), to form said reactive particulate material. Methods of use of the reactive particulate material and material sets including the same are also provided.

公开(公告)号：US20210024775A1

公开(公告)日：2021-01-28

申请号：US17068962

申请日：2020-10-13

申请人： Carbon, Inc.

发明人： Jason P. Rolland ,  Kai Chen ,  Justin Poelma ,  James Goodrich ,  Robert K. Pinschmidt, JR. ,  Joseph M. DeSimone ,  Lloyd M. Robeson

IPC分类号： C09D175/08 ,  C08K3/013 ,  C08K3/01 ,  B29C64/129 ,  G03F7/00 ,  G03F7/027 ,  G03F7/038 ,  G03F7/075 ,  G03F7/38 ,  B29C64/124 ,  B29C64/135 ,  B29C64/386 ,  C08G18/81 ,  C08G18/10 ,  C08G18/76 ,  C08F220/34 ,  C08G18/42 ,  C08F290/06 ,  C08G18/73 ,  C08G18/48 ,  C08G18/24 ,  C08G18/69 ,  C08G18/75 ,  C08F283/00 ,  C08G18/40 ,  B33Y10/00 ,  B33Y70/00 ,  B29D11/00 ,  B29C35/08 ,  C08K5/00 ,  C08L75/04 ,  B33Y80/00 ,  C09D135/02 ,  C09D175/04 ,  B29C64/255 ,  B29C64/106 ,  B29C64/165 ,  B33Y30/00 ,  C08J5/00 ,  C08L75/14 ,  B33Y50/02

摘要： A method of forming a three-dimensional object, wherein said three-dimensional object is an insert for use between a helmet and a human body, is described. The method may use a polymerizable liquid, or resin, useful for the production by additive manufacturing of a three-dimensional object, comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component.

公开(公告)号：US10899868B2

公开(公告)日：2021-01-26

申请号：US16803047

申请日：2020-02-27

申请人： Carbon, Inc.

发明人： Jason P. Rolland ,  Kai Chen ,  Justin Poelma ,  James Goodrich ,  Robert K. Pinschmidt, Jr. ,  Joseph M. DeSimone ,  Lloyd M. Robeson

IPC分类号： C08F2/46 ,  C08F2/50 ,  C08G61/04 ,  C08G18/42 ,  C08K3/013 ,  C08K3/01 ,  B29C64/129 ,  G03F7/00 ,  G03F7/027 ,  G03F7/038 ,  G03F7/075 ,  G03F7/38 ,  B29C64/124 ,  B29C64/135 ,  B29C64/386 ,  C08G18/81 ,  C08G18/10 ,  C08G18/76 ,  C08F220/34 ,  C08F290/06 ,  C08G18/73 ,  C08G18/48 ,  C08G18/24 ,  C08G18/69 ,  C08G18/75 ,  C08F283/00 ,  C08G18/40 ,  B33Y10/00 ,  B33Y70/00 ,  B29D11/00 ,  B29C35/08 ,  C08K5/00 ,  C08L75/04 ,  B33Y80/00 ,  C09D135/02 ,  C09D175/04 ,  C09D175/08 ,  B29C64/255 ,  B29C64/106 ,  B29C64/165 ,  B33Y30/00 ,  C08J5/00 ,  C08L75/14 ,  B33Y50/02 ,  B29C33/00 ,  B29K75/00 ,  B29K105/04 ,  B29L11/00 ,  B29L31/10 ,  B29K105/00 ,  B29K105/16 ,  B29K509/00 ,  B29L31/00

摘要： A method of forming a three-dimensional object, wherein said three-dimensional object is a footwear sole, heel, innersole or midsole, is described. The method may use a polymerizable liquid, or resin, useful for the production by additive manufacturing of a three-dimensional object, comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component.

公开(公告)号：US20200070409A1

公开(公告)日：2020-03-05

申请号：US16550592

申请日：2019-08-26

申请人： Carbon, Inc.

发明人： Justin Poelma

IPC分类号： B29C64/124 ,  C08L75/04 ,  C08L33/08 ,  C08L33/10 ,  C08K5/00 ,  C08K3/013

摘要： Provided herein according to embodiments is a prepolymer compound of formula I: and a prepolymer compound of formula II: A polymerizable liquid composition comprising the prepolymer compound, methods of use in forming a three-dimensional object, and objects produced are also provided.

公开(公告)号：US10240066B2

公开(公告)日：2019-03-26

申请号：US15428708

申请日：2017-02-09

申请人： Carbon, Inc.

发明人： Jason P. Rolland ,  Kai Chen ,  Justin Poelma ,  James Goodrich ,  Robert Pinschmidt ,  Joseph M. DeSimone ,  Lloyd M. Robeson

IPC分类号： B29C71/02 ,  B29C71/04 ,  C09D175/08 ,  C08K3/013 ,  C08K3/01 ,  B29C64/129 ,  G03F7/00 ,  B33Y10/00 ,  B33Y70/00 ,  B29D11/00 ,  B29C35/08 ,  C08K5/00 ,  C08L75/04 ,  B33Y80/00 ,  C09D135/02 ,  C09D175/04 ,  G03F7/027 ,  G03F7/038 ,  G03F7/075 ,  G03F7/38 ,  B29C64/255 ,  B29C64/106 ,  B29C64/165 ,  B33Y30/00 ,  C08J5/00 ,  C08L75/14 ,  B33Y50/02 ,  B29C64/124 ,  B29C64/135 ,  B29C64/386 ,  B29C33/00 ,  B29K75/00 ,  B29K105/04 ,  B29L11/00 ,  B29L31/10 ,  B29K105/00 ,  B29K105/16 ,  B29K509/00 ,  B29L31/00

摘要： A method of forming a three-dimensional object of polyurethane, polyurea, or copolymer thereof is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including at least one of: (i) a blocked or reactive blocked prepolymer, (ii) a blocked or reactive blocked diisocyante, or (iii) a blocked or reactive blocked diisocyanate chain extender; (c) irradiating the build region with light through the optically transparent member to form a solid blocked polymer scaffold and advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, with the intermediate containing the chain extender; and then (d) heating or microwave irradiating the three-dimensional intermediate sufficiently to form from the three-dimensional intermediate the three-dimensional object of polyurethane, polyurea, or copolymer thereof.

公开(公告)号：US12042994B2

公开(公告)日：2024-07-23

申请号：US15733556

申请日：2019-02-26

申请人： Carbon, Inc.

发明人： Mu San Zhang ,  Kai Chen ,  Jason P. Rolland ,  Justin Poelma

IPC分类号： B29C64/357 ,  B29B17/00 ,  B29B17/04 ,  B33Y40/00 ,  B33Y40/20 ,  B33Y70/00 ,  C08G18/78 ,  C08L75/04

CPC分类号： B29C64/357 ,  B29B17/0026 ,  B29B17/04 ,  B33Y40/00 ,  B33Y40/20 ,  B33Y70/00 ,  C08G18/7843 ,  C08L75/04 ,  B29B2017/0416

摘要： Provided herein are methods of recycling additively manufactured objects (e.g., stereolithographically produced objects), the additively manufactured objects comprising linear polyurethane, branched polyurethane, linear polyurea, branched polyurea, a copolymer thereof, or a combination thereof. Compositions comprising the same and methods of use thereof are also provided.

公开(公告)号：US11850803B2

公开(公告)日：2023-12-26

申请号：US17655275

申请日：2022-03-17

申请人： Carbon, Inc.

发明人： Jason P. Rolland ,  Kai Chen ,  Justin Poelma ,  James Goodrich ,  Robert Pinschmidt ,  Joseph M. DeSimone ,  Lloyd M. Robeson

IPC分类号： B29C71/02 ,  B29C71/04 ,  B29C64/40 ,  C08K3/013 ,  C08K3/01 ,  B29C64/129 ,  G03F7/00 ,  G03F7/027 ,  G03F7/038 ,  G03F7/075 ,  G03F7/38 ,  B29C64/124 ,  B29C64/135 ,  B29C64/386 ,  C08G18/81 ,  C08G18/10 ,  C08G18/76 ,  C08F220/34 ,  C08G18/42 ,  C08F290/06 ,  C08G18/73 ,  C08G18/48 ,  C08G18/24 ,  C08G18/69 ,  C08G18/75 ,  C08F283/00 ,  C08G18/40 ,  B29C71/00 ,  B29C64/286 ,  B33Y10/00 ,  B33Y70/00 ,  B29D11/00 ,  B29C35/08 ,  C08K5/00 ,  C08L75/04 ,  B33Y80/00 ,  C09D135/02 ,  C09D175/04 ,  C09D175/08 ,  B29C64/255 ,  B29C64/106 ,  B29C64/165 ,  B33Y30/00 ,  C08J5/00 ,  C08L75/14 ,  B33Y50/02 ,  B29C33/00 ,  B29K105/00 ,  B29K75/00 ,  B29K105/04 ,  B29L11/00 ,  B29L31/10 ,  B29K105/16 ,  B29K509/00 ,  B29L31/00

CPC分类号： B29C64/40 ,  B29C35/0805 ,  B29C64/106 ,  B29C64/124 ,  B29C64/129 ,  B29C64/135 ,  B29C64/165 ,  B29C64/255 ,  B29C64/286 ,  B29C64/386 ,  B29C71/0009 ,  B29D11/00009 ,  B29D11/00663 ,  B33Y10/00 ,  B33Y30/00 ,  B33Y50/02 ,  B33Y70/00 ,  B33Y80/00 ,  C08F220/34 ,  C08F283/006 ,  C08F290/067 ,  C08G18/10 ,  C08G18/244 ,  C08G18/40 ,  C08G18/42 ,  C08G18/4825 ,  C08G18/4854 ,  C08G18/69 ,  C08G18/73 ,  C08G18/755 ,  C08G18/758 ,  C08G18/7671 ,  C08G18/81 ,  C08G18/8175 ,  C08J5/00 ,  C08K3/01 ,  C08K3/013 ,  C08K5/0008 ,  C08K5/0041 ,  C08L75/04 ,  C08L75/14 ,  C09D135/02 ,  C09D175/04 ,  C09D175/08 ,  G03F7/00 ,  G03F7/0037 ,  G03F7/027 ,  G03F7/038 ,  G03F7/0757 ,  G03F7/38 ,  B29C2033/0005 ,  B29C2035/0827 ,  B29C2035/0855 ,  B29K2075/00 ,  B29K2075/02 ,  B29K2105/0002 ,  B29K2105/0058 ,  B29K2105/0073 ,  B29K2105/0091 ,  B29K2105/043 ,  B29K2105/16 ,  B29K2105/251 ,  B29K2509/00 ,  B29K2995/0026 ,  B29L2011/00 ,  B29L2011/0016 ,  B29L2011/0075 ,  B29L2031/001 ,  B29L2031/10 ,  C08J2375/14 ,  C08F283/006 ,  C08F222/102 ,  C08F222/1063 ,  C08F290/067 ,  C08F222/102 ,  C08F222/1063 ,  C08F220/1808 ,  C08F290/067 ,  C08F222/102 ,  C08F220/1811 ,  C08G18/672 ,  C08G18/48 ,  C08F290/067 ,  C08F222/102 ,  C08F222/1063

摘要： A method of forming a three-dimensional object (e.g. comprised of polyurethane, polyurea, or copolymer thereof) is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid comprising a mixture of: (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid blocked polymer scaffold and advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, with the intermediate containing the second solidifiable component; and then (d) contacting the three-dimensional intermediate to water to form the three-dimensional object.

公开(公告)号：US20230001634A1

公开(公告)日：2023-01-05

申请号：US17662706

申请日：2022-05-10

申请人： Carbon, Inc.

发明人： Jason P. Rolland ,  Kai Chen ,  Justin Poelma ,  James Goodrich ,  Robert Pinschmidt ,  Joseph M. DeSimone ,  Lloyd M. Robeson

IPC分类号： B29C64/165 ,  B29C64/286 ,  B33Y10/00 ,  B33Y70/00

摘要： A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.

公开(公告)号：US20220118689A1

公开(公告)日：2022-04-21

申请号：US17645538

申请日：2021-12-22

申请人： Carbon, Inc.

发明人： Justin Poelma ,  Jason P. Rolland

IPC分类号： B29C64/124 ,  B29C64/264 ,  B29C64/188

摘要： Provided herein according to some embodiments is polymerizable liquid useful for the production of a three-dimensional object by additive manufacturing, said polymerizable liquid comprising a mixture of: (a) at least one photopolymerizable component; (b) a photoinitiator; (c) at least one heat polymerizable component; and (d) heat expandable microspheres. A method of making a three-dimensional object from such a polymerizable liquid by additive manufacturing and objects so produced are also provided.