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公开(公告)号:US20190233660A1
公开(公告)日:2019-08-01
申请号:US15880830
申请日:2018-01-26
IPC分类号: C09D5/16 , C09D5/14 , C09D133/14 , C08F220/06 , C09D125/16 , C08F212/14 , C08F220/58 , C09D133/26 , C23C18/40
摘要: A water-soluble composition includes reducible copper ions or copper nanoparticles complexed with a reactive polymer. The reactive polymer can be crosslinked using suitable irradiation to provide copper-containing water-insoluble complexes. The water-soluble composition can be used to provide various articles and electrically-conductive materials that can be assembled in electronic devices. The reactive polymer has greater than 1 mol % of recurring units comprising sulfonic acid or sulfonate groups, at least 5 mol % of recurring units comprising a pendant group capable of crosslinking via [2+2] photocycloaddition, and optionally at least 1 mol % of recurring units comprising a pendant amide, amine, hydroxyl, lactam, phosphonic acid, or carboxylic acid group.
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公开(公告)号:US10351720B2
公开(公告)日:2019-07-16
申请号:US15729714
申请日:2017-10-11
IPC分类号: C08G18/06 , C09D11/30 , C08G18/76 , C08G18/32 , C08G18/34 , C09D175/08 , C08G18/62 , C08G18/66 , C09D11/102 , C08G18/48
摘要: A non-crosslinked, crosslinkable polyurethane has an acid number of 20-40 and a glass transition temperature of up to and including 40° C. It can be derived from an aromatic diisocyanate; and a diol mixture of at least D1, D2, D3, and D4 diols. D1 has a C3 to C7 aliphatic group and at least one pendant carboxy group or pendant neutralized carboxy group. D2 has a chain of repeating C2 to C6 alkylene oxide groups and a molecular weight of 250-3000. D3 is an alkoxylated bisphenol A or aliphatic cyclic diol present in an amount of at least 5 mol %. D4 is a hydroxy-terminated polybutadiene having a molecular weight of at least 1000, and is present in an amount of at least 0.1-5 mol %.
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公开(公告)号:US10745570B2
公开(公告)日:2020-08-18
申请号:US15880830
申请日:2018-01-26
IPC分类号: C09D5/14 , C09D133/14 , C08F220/06 , C09D125/16 , C08F220/58 , C09D133/26 , C23C18/40 , C08F212/14 , C08F2/60 , C08F220/36 , C09D5/16 , C08K3/08
摘要: A water-soluble composition includes reducible copper ions or copper nanoparticles complexed with a reactive polymer. The reactive polymer can be crosslinked using suitable irradiation to provide copper-containing water-insoluble complexes. The water-soluble composition can be used to provide various articles and electrically-conductive materials that can be assembled in electronic devices. The reactive polymer has greater than 1 mol % of recurring units comprising sulfonic acid or sulfonate groups, at least 5 mol % of recurring units comprising a pendant group capable of crosslinking via [2+2] photocycloaddition, and optionally at least 1 mol % of recurring units comprising a pendant amide, amine, hydroxyl, lactam, phosphonic acid, or carboxylic acid group.
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公开(公告)号:US10513622B2
公开(公告)日:2019-12-24
申请号:US15729736
申请日:2017-10-11
发明人: Catherine A. Falkner , John Leonard Muehlbauer , Peter John Ghyzel , Valerie Lynn Kuykendall , Thomas B. Brust
摘要: Individual aqueous inks or inks in ink sets haves a non-crosslinked, crosslinkable polyurethane having an acid number of 20-40 and is derived from an aromatic diisocyanate; and a diol mixture of D1 and D2 diols, and optionally including D3 diol, D4 diol, or both D3 and D4 diols. D1 has a C3 to C7 aliphatic group and a pendant carboxy group or neutralized carboxy group. D2 has a chain of repeating C2 to C6 alkylene oxide groups. D3 is an alkoxylated bisphenol A or an aliphatic cyclic diol, present at least 5 mol %. D4 is a hydroxy-terminated polybutadiene having a molecular weight of at least 1000 and is present in an amount of 0.1-5 mol %. The ink also contains a dispersed pigment colorant; a humectant or organic co-solvent, and optionally, a crosslinking agent.
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公开(公告)号:US20190106587A1
公开(公告)日:2019-04-11
申请号:US15729882
申请日:2017-10-11
发明人: Valerie Lynn Kuykendall , Peter John Ghyzel , Catherine A. Falkner , John Leonard Muehlbauer , Thomas B. Brust
IPC分类号: C09D11/322 , C09D11/326 , C09D11/40
CPC分类号: C09D11/322 , B41J2/21 , B41M5/0041 , C08G18/0823 , C08G18/10 , C08G18/246 , C08G18/3206 , C08G18/3212 , C08G18/3215 , C08G18/348 , C08G18/4854 , C08G18/6588 , C08G18/6692 , C08G18/69 , C08G18/724 , C08G18/755 , C08G18/7671 , C09D11/102 , C09D11/106 , C09D11/326 , C09D11/38 , C09D11/40
摘要: An inkjet printing method uses an aqueous inkjet ink composition having a non-crosslinked, crosslinkable polyurethane having an acid number of 20-40 and is derived from an aromatic diisocyanate; and a diol mixture of D1 and D2 diols, and optionally including D3 diol, D4 diol, or both D3 and D4 diols. D1 has a C3 to C7 aliphatic group and a pendant carboxy group or neutralized carboxy group. D2 has a chain of repeating C2 to C6 alkylene oxide groups. D3 is an alkoxylated bisphenol A or aliphatic cyclic diol, present at least 5 mol %. D4 is a hydroxy-terminated polybutadiene having a molecular weight of at least 1000 and is present in an amount of 0.1-5 mol %. The ink composition also contains a dispersed pigment colorant; a humectant or organic co-solvent, and optionally, a crosslinking agent.
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公开(公告)号:US20170306121A1
公开(公告)日:2017-10-26
申请号:US15133295
申请日:2016-04-20
IPC分类号: C08J7/16 , B05D3/06 , H01B1/12 , G03F7/40 , G03F7/004 , H05K3/02 , B05D3/10 , C08J7/12 , C08J7/04 , C08G73/02 , C08F212/14 , B05D7/00 , B05D7/04 , H05K3/10
CPC分类号: C08J7/16 , B05D3/067 , B05D3/101 , B05D7/04 , B05D7/544 , B05D7/584 , C08F12/30 , C08F212/14 , C08G73/0266 , C08J7/047 , C08J7/123 , C08J2367/02 , C08J2425/08 , C09D125/18 , G03F7/004 , G03F7/0047 , G03F7/038 , G03F7/40 , H01B1/128 , H05K3/02 , H05K3/105 , H05K2203/1136 , C08F2220/302 , C08F220/06
摘要: A method is used to provide an electrically-conductive polyaniline pattern by providing a uniform layer of a photocurable composition on a substrate. The photocurable composition comprises a water-soluble reactive polymer comprising (a) greater than 40 mol % of recurring units comprising sulfonic acid or sulfonate groups, and (b) at least 5 mol % of recurring units comprising a pendant group capable of crosslinking via [2+2] photocycloaddition. The photocurable composition is exposed to cause crosslinking via [2+2] photocycloaddition of the (b) recurring units, thereby forming a crosslinked polymer. Any remaining water-soluble reactive polymer is removed. The crosslinked polymer is contacted with an aniline reactive composition having aniline monomer and up to 0.5 molar of an aniline oxidizing agent, thereby forming an electrically-conductive polyaniline disposed either within, on top of, or both within and on top of, the crosslinked polymer.
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公开(公告)号:US20160274460A1
公开(公告)日:2016-09-22
申请号:US14661235
申请日:2015-03-18
IPC分类号: G03F7/06
CPC分类号: G03F7/06 , B05D7/04 , C08F8/42 , C08K2003/0806 , C09D5/14 , C09D7/67 , C09D7/68 , C23C18/1608 , C23C18/1851 , C23C18/1889 , C23C18/1893 , C23C18/2006 , C23C18/208 , C23C18/2086 , C23C18/30 , C23C18/36 , C23C18/38 , C23C18/40 , C23C18/44 , G03F7/0388 , G03F7/20 , G03F7/40
摘要: Silver-containing compositions contain a water-soluble complex of a reactive polymer with either reducible silver ions or silver nanoparticles, the reactive polymer comprising: (a) greater than 1 mol % of recurring units comprising sulfonic acid or sulfonate groups, (b) at least 5 mol % of recurring units comprising a pendant group capable of crosslinking via [2+2] photocycloaddition, and optionally (c) at least mol % of recurring units comprising a pendant amide, hydroxyl, lactam, phosphoric acid, or carboxylic acid group, all amounts based on the total recurring units in the reactive polymer. Other silver-containing compositions contain a water-insoluble complex of a reacted polymer with either reducible silver ions or silver nanoparticles. The reacted polymers are derived from the reactive polymers.
摘要翻译: 含银组合物含有反应性聚合物与可还原银离子或银纳米颗粒的水溶性络合物,反应性聚合物包含:(a)大于1mol%的包含磺酸或磺酸盐基团的重复单元,(b) 至少5摩尔%的包含能够通过[2 + 2]光环加成交联的侧基的重复单元,以及任选地(c)至少含有酰胺,羟基,内酰胺,磷酸或羧酸基团的重复单元的摩尔% ,基于反应性聚合物中的总重复单元的所有量。 其它含银组合物含有反应聚合物与可还原银离子或银纳米颗粒的水不溶性络合物。 反应的聚合物衍生自反应性聚合物。
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公开(公告)号:US09963614B2
公开(公告)日:2018-05-08
申请号:US14714422
申请日:2015-05-18
IPC分类号: C09D133/24 , C08F220/38 , C08K5/00 , C09D133/14 , C09D135/00
CPC分类号: C09D133/02 , C08F220/06 , C08F220/20 , C08F220/38 , C08F220/58 , C08K5/00 , C09D133/14 , C09D135/00 , C08F2220/382 , C08F2220/303 , C08F2220/585 , C08F212/14
摘要: A water-soluble composition includes reducible copper ions or copper nanoparticles complexed with a reactive polymer. The reactive polymer can be crosslinked using suitable irradiation to provide copper-containing water-insoluble complexes. The water-soluble composition can be used to provide various articles and electrically-conductive materials that can be assembled in electronic devices. The reactive polymer has greater than 1 mol % of recurring units comprising sulfonic acid or sulfonate groups, at least 5 mol % of recurring units comprising a pendant group capable of crosslinking via [2+2] photocycloaddition, and optionally at least 1 mol % of recurring units comprising a pendant amide, amine, hydroxyl, lactam, phosphonic acid, or carboxylic acid group.
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公开(公告)号:US09644112B1
公开(公告)日:2017-05-09
申请号:US15133583
申请日:2016-04-20
摘要: Articles are designed with a substrate and have either a uniform layer or pattern of electrically-conductive polyaniline on one or both supporting sides of the substrate. The electrically-conductive polyaniline is disposed either within, on top of, or both within and on top of, a uniform or pattern of a crosslinked polymer that is derived from a photocurable composition comprising water-soluble reactive polymer comprising (a) greater than 40 mol % of recurring units comprising sulfonic acid or sulfonate groups, (b) at least 5 mol % of recurring units comprising a pendant group capable of crosslinking via [2+2] photocycloaddition, and optionally (c) at least 1 mol % of recurring units comprising a pendant amide, hydroxyl, lactam, phosphonic acid, phosphonate, carboxylic acid, or carboxylate group, all amounts based on the total recurring units in the water-soluble reactive polymer.
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公开(公告)号:US10457824B2
公开(公告)日:2019-10-29
申请号:US15729882
申请日:2017-10-11
发明人: Valerie Lynn Kuykendall , Peter John Ghyzel , Catherine A. Falkner , John Leonard Muehlbauer , Thomas B. Brust
IPC分类号: B41J2/21 , B41M5/00 , C08G18/08 , C08G18/10 , C08G18/24 , C08G18/32 , C08G18/34 , C08G18/48 , C08G18/65 , C08G18/66 , C08G18/69 , C08G18/72 , C08G18/75 , C08G18/76 , C09D11/322 , C09D11/326 , C09D11/40 , C09D11/102 , C09D11/38 , C09D11/106
摘要: An inkjet printing method uses an aqueous inkjet ink composition having a non-crosslinked, crosslinkable polyurethane having an acid number of 20-40 and is derived from an aromatic diisocyanate; and a diol mixture of D1 and D2 diols, and optionally including D3 diol, D4 diol, or both D3 and D4 diols. D1 has a C3 to C7 aliphatic group and a pendant carboxy group or neutralized carboxy group. D2 has a chain of repeating C2 to C6 alkylene oxide groups. D3 is an alkoxylated bisphenol A or aliphatic cyclic diol, present at least 5 mol %. D4 is a hydroxy-terminated polybutadiene having a molecular weight of at least 1000 and is present in an amount of 0.1-5 mol %. The ink composition also contains a dispersed pigment colorant; a humectant or organic co-solvent, and optionally, a crosslinking agent.
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