Partially crosslinked polymer composition
    2.
    发明授权
    Partially crosslinked polymer composition 失效
    部分交联聚合物组合物

    公开(公告)号:US5244976A

    公开(公告)日:1993-09-14

    申请号:US847403

    申请日:1992-03-06

    IPC分类号: C08F255/02

    CPC分类号: C08F255/02

    摘要: A partially crosslinked polymer composition having a melt flow index of from 0.1 to 50 g/10 min at 230.degree. C. under a weight of 2.16 kg and comprisinga) a polymer comprising from 25 to 95% by weight of polypropylene and 5 to 75% by weight of a propylene copolymer with copolymerized C.sub.2 -C.sub.10 -alk-1-enes, the comonomer content being from 1 to 45% by weight, based on the total polymer,b) an organosilane compound of the formula (I)A.sub.4-n SiR.sub.n (i) where A are identical or different acrylates or methacrylates or vinyl groups, R are identical or different C.sub.1 -C.sub.8 -alkoxy or C.sub.1 -C.sub.8 -acetoxy groups, and n is 1, 2 or 3, obtainable by reacting the polymer a) with the organosilane compound b) in the presence of a free-radical initiator and in the presence of a condensation catalyst at from 180.degree. to 280.degree. C., and at from 1 to 100 bar and at a mean residence time of the reaction mixture of from 0.2 to 10 minutes,has, in particular, high notched impact strength, increased puncture resistance and improved weld line strength.

    摘要翻译: 一种部分交联的聚合物组合物,其熔体流动指数为0.1至50g / 10min,在230℃,重量为2.16kg,并包含a)包含25至95重量%的聚丙烯和5至75的聚合物 重量%的具有共聚的C 2 -C 10 - 烷-1-烯的丙烯共聚物,基于总聚合物的共聚单体含量为1至45重量%,b)式(I)的有机硅烷化合物, nSiRn(i)其中A是相同或不同的丙烯酸酯或甲基丙烯酸酯或乙烯基,R是相同或不同的C 1 -C 8 - 烷氧基或C 1 -C 8 - 乙酰氧基,n是1,2或3,可通过使聚合物a )与有机硅烷化合物b)在自由基引发剂的存在下,在缩合催化剂存在下,在180-280℃,和1-100巴,反应的平均停留时间 0.2〜10分钟的混合物,特别是具有高缺口冲击强度,抗穿刺性提高 焊线强度。

    Shock-absorbing propylene polymer composite moldings
    3.
    发明授权
    Shock-absorbing propylene polymer composite moldings 失效
    阻聚丙烯聚合物复合材料

    公开(公告)号:US5180628A

    公开(公告)日:1993-01-19

    申请号:US822263

    申请日:1992-01-17

    摘要: A shock-absorbing propylene polymer composite molding containsa. a layer with a thickness of from 0.5 to 10 mm which contains a propylene polymer having a melting point of from 130.degree. to 165.degree. C.,b. an intermediate layer with a thickness of from 0.05 to 0.5 mm comprising a hot-melt adhesive based on an olefin copolymer having a melting point of from 90.degree. to 140.degree. C.,c. a foam layer with a thickness of from 3 to 200 mm and a density of from 0.015 to 0.1 g/cm.sup.3 based on a propylene copolymer having a melting point of from 125.degree. to 155.degree. C.,d. an intermediate layer with a thickness of from 0.05 to 0.5 mm comprising a hot-melt adhesive based on an olefin copolymer having a melting point of from 90.degree. to 140.degree. C.,e. a layer with a thickness of from 0.5 to 10 mm which contains a propylene polymer having a melting point of from 130.degree. to 165.degree. C.

    摘要翻译: 减震丙烯聚合物复合成型体包含a。 b。厚度为0.5至10毫米的层,其含有熔点为130至165℃的丙烯聚合物,b。 c)厚度为0.05至0.5mm的中间层,包括基于熔点为90-140℃的烯烃共聚物的热熔粘合剂,c。 d。基于熔点为125-155℃的丙烯共聚物,厚度为3至200mm,密度为0.015至0.1g / cm 3的泡沫层。 厚度为0.05至0.5mm的中间层,包括基于熔点为90°至140℃的烯烃共聚物的热熔粘合剂, 厚度为0.5〜10mm的层,其含有熔点为130〜165℃的丙烯聚合物。

    Thermoplastic polypropylene/polyamide molding composition
    4.
    发明授权
    Thermoplastic polypropylene/polyamide molding composition 失效
    热塑性聚丙烯/聚酰胺成型组合物

    公开(公告)号:US5179164A

    公开(公告)日:1993-01-12

    申请号:US668701

    申请日:1991-03-08

    摘要: Polypropylene/polyamide molding compositions, suitable in particular for producing moldings, advantageously consist of, in each case based on 100 parts by weight of the molding composition,A) from 10 to 89.5 parts by weight of one or more polypropylene homopolymers and/or copolymers,B) from 10 to 89.5 parts by weight of one or more polyamides,C) from 0.5 to 30 parts by weight of an ethylene copolymer as adhesion promoter,D) from 0 to 30 parts by weight of an impact modifier andE) from 0 to 60 parts by weight of a reinforcing agent and/or additive,the ethylene copolymer (C) advantageously being polymerized from, in each case based on (C),a) from 50 to 98% by weight of ethylene,b) from 1 to 45% by weight of one or more alkyl (meth)acrylates having 1 to 8 carbon atoms in the alkyl, but not tert-butyl (meth)acrylate, andc) from 1 to 40% by weight of one or more further monomers containing in bonded form a group which is reactive toward the polyamide, for example a carboxyl, carboxylic anhydride, tert-butyl carboxylate, sulfo, sulfonyl, oxazolinyl or epoxide group,and are produced by melting together components (A) to (C) and any (D) and/or (E) at from 200.degree. to 300.degree. C.

    摘要翻译: 适合于特别用于生产模制品的聚丙烯/聚酰胺模塑组合物有利地包括在每种情况下基于100重量份的模塑组合物A)10至89.5重量份的一种或多种聚丙烯均聚物和/或共聚物 ,B)10至89.5重量份的一种或多种聚酰胺,C)0.5至30重量份的作为粘合促进剂的乙烯共聚物,D)0至30重量份的抗冲改性剂,E) 0至60重量份的增强剂和/或添加剂,乙烯共聚物(C)有利地在每种情况下基于(C)聚合,a)50至98重量%的乙烯,b)从 1〜45重量%的一种或多种烷基中具有1-8个碳原子的(甲基)丙烯酸烷基酯,但不是(甲基)丙烯酸叔丁酯,和c)1至40重量%的一种或多种 含有键合形式的对聚酰胺具有反应性的基团的单体,例如羧基,羧基 通过将组分(A)至(C)和(200)至(300)的任何(D)和/或(E))熔融在一起而制备, 。

    Thermoplastic polypropylene-polyamide molding compositions of high
toughness, rigidity and heat-distortion resistance, and the preparation
thereof
    5.
    发明授权
    Thermoplastic polypropylene-polyamide molding compositions of high toughness, rigidity and heat-distortion resistance, and the preparation thereof 失效
    热塑性聚丙烯 - 聚酰胺模塑组合物的高韧性,刚性和耐热性及其制备

    公开(公告)号:US5162422A

    公开(公告)日:1992-11-10

    申请号:US534883

    申请日:1990-06-08

    摘要: Novel polypropylene-polyamide molding compositions which comprise, based on 100 parts by weight of the molding compositions,A) 10 to 89.9 parts by weight of one or more polypropylene homopolymer and/or copolymer,B) 10 to 89.9 parts by weight of one or more polyamide,C) 0.1 to 5.0 parts by weight of one or more olefinically unsaturated carboxylic acid and/or one or more olefinically unsaturated carboxylic acid derivate,D) 0 to 3.0 parts by weight of an impact modifier, andE) 0 to 60.0 parts by weight of a reinforcing agent and/or additive,are prepared by melting together components (A), (C) and, if desired (D) at from 200.degree. to 300.degree. C. in a first reaction step and then, in a second reaction step, introducing component (B) and, if appropriate, components (D) and/or (E) into the modified melt obtained, and melting together the components.The molding compositions obtained are used for the production of moldings.

    摘要翻译: 基于100重量份成型组合物的新型聚丙烯 - 聚酰胺模塑组合物,A)10至89.9重量份的一种或多种聚丙烯均聚物和/或共聚物,B)10至89.9重量份的一种或多种 更多的聚酰胺,C)0.1至5.0重量份的一种或多种烯属不饱和羧酸和/或一种或多种烯属不饱和羧酸衍生物,D)0-3.0重量份抗冲改性剂,E)0-60.0 通过在第一反应步骤中将组分(A),(C)和(如果需要的话)(D)在200℃至300℃下熔融在一起制备增强剂和/或添加剂的重量份,然后在 第二反应步骤,将组分(B)和(如果合适的话)将组分(D)和/或(E)引入所获得的改性熔体中并将组分一起熔化。 得到的成型组合物用于制造模制品。

    Graft copolymers based on methyl methacrylate polymers
    7.
    发明授权
    Graft copolymers based on methyl methacrylate polymers 失效
    基于甲基丙烯酸甲酯聚合物的接枝共聚物

    公开(公告)号:US4002703A

    公开(公告)日:1977-01-11

    申请号:US603857

    申请日:1975-08-12

    IPC分类号: C08G81/02 C08L33/04

    CPC分类号: C08G81/025

    摘要: This invention relates to a process for the manufacture of graft copolymers based on methyl methacrylate polymers. The methyl methacrylate polymer is reacted with a high molecular weight organic compound containing at least one alkylene oxide unit having an alkali metal alcoholate end group, during which reaction transesterification occurs to eliminate alkali metal methoxide and cause chain joining. The graft copolymers may be used for the production of shaped articles or coating compositions and as additives, antistatic agents or adhesion promoters for plastics materials.

    摘要翻译: 本发明涉及一种制备基于甲基丙烯酸甲酯聚合物的接枝共聚物的方法。 甲基丙烯酸甲酯聚合物与含有至少一个具有碱金属醇化物端基的烯化氧单元的高分子量有机化合物反应,在此期间进行反应酯交换以除去碱金属甲醇盐并引起链接。 接枝共聚物可用于生产成形制品或涂料组合物,以及用作塑料材料的抗静电剂或粘合促进剂的添加剂。

    Polypropylene molding materials
    9.
    发明授权
    Polypropylene molding materials 失效
    聚丙烯成型材料

    公开(公告)号:US5641821A

    公开(公告)日:1997-06-24

    申请号:US418607

    申请日:1995-04-07

    摘要: Molding materials comprisingA) polymers of propylene and up to 20% by weight of further monomers, containingB) from 0.05 to 0.4% by weight of a monofunctional or polyfunctional carboxamide or of a carboxamide mixture having a molecular weight of from 150 to 600 andc) from 0.1 to 3.0% by weight of an ethylene polymer with up to 20% by weight of comonomers, having a density of from 0.890 to 0.945 g/cm.sup.3 and an MFI of from 10 to 100 g/10 min, measured according to ISO 1133 at 190.degree.C./2.16 kg.The films and moldings produced using the novel molding materials have particularly good frictional properties.

    摘要翻译: 包括A)丙烯聚合物和至多20重量%的其它单体的聚合物,其包含B)0.05至0.4重量%的单官能或多官能羧酰胺或分子量为150至600的羧酰胺混合物,以及 c)0.1至3.0重量%的具有至多20重量%共聚单体的乙烯聚合物,密度为0.890至0.945g / cm 3,MFI为10至100g / 10min,根据 ISO 1133在190℃/2.16kg。 使用新型成型材料制造的薄膜和模制品具有特别好的摩擦性能。

    Thermoplastic molding materials based on polyphenylene ethers and
polyesters
    10.
    发明授权
    Thermoplastic molding materials based on polyphenylene ethers and polyesters 失效
    基于聚苯醚和聚酯的热塑性成型材料

    公开(公告)号:US5180778A

    公开(公告)日:1993-01-19

    申请号:US574073

    申请日:1990-08-29

    IPC分类号: C08L67/00 C08L67/02 C08L71/12

    摘要: Thermoplastic molding materials containA) not less than 5% by weight of a polymer component consisting of from 50 to 100% by weight of polyphenylene ethers and from 0 to 50% by weight of a styrene polymer differing from component C),B) not less than 5% by weight of a polyester,C) not less than 0.1% by weight of a copolymer consisting ofC.sub.1) not less than 20% by weight of .alpha.-olefins of 2 to 8 carbon atoms, styrene or substituted styrenes of the general formula I ##STR1## where R and R.sup.1 is alkyl of 1 to 8 carbon atoms, hydrogen and/or halogen and n is 0, 1 or 2, or a mixture of these monomers,C.sub.2) not less than 0.5% by weight of a polymerizable monomer containing epoxide groups, and/orC.sub.3) not less than 0.05% by weight of a halobenzyl-containing polymerizable monomer having the structural unit (II) ##STR2## where X is halogen and R.sup.2 and R.sup.3 are each alkyl of 1 to 8 carbon atoms or hydrogen and n is 1, 2 or 3, and/orC.sub.4) not less than 0.05% by weight of a polymerizable monomer containing oxazoline groups, andC.sub.5) from 0 to 65% by weight of acrylonitrile, methacrylonitrile and further nonionic comonomers, andD) from 0 to 40% by weight of a rubber impact modifier.

    摘要翻译: 热塑性成型材料包含A)不小于5重量%的由50至100重量%的聚苯醚和0至50重量%的不同于组分C)的苯乙烯聚合物组成的聚合物组分,B)不 小于5重量%的聚酯,C)不小于0.1重量%的由C1组成的共聚物,不少于20重量%的碳原子数2〜8的α-烯烃,苯乙烯或苯乙烯的取代苯乙烯 通式I其中R和R 1是1至8个碳原子的烷基,氢和/或卤素,n是0,1或2,或这些单体的混合物,C2)不小于0.5% 重量的含有环氧基的可聚合单体和/或C3)不少于0.05重量%的具有结构单元(II)的卤代苄基的可聚合单体(II),其中X是卤素,R 2和R 3 各自为1至8个碳原子的烷基或氢,n为1,2或3,和/或C 4)不小于0.05重量%的可聚合单体 r为0〜65重量%的丙烯腈,甲基丙烯腈和其它非离子共聚单体,和D)0〜40重量%的橡胶抗冲改性剂。