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公开(公告)号：US06992153B1
公开(公告)日：2006-01-31
申请号：US09936111
申请日：2000-03-06
CPC分类号： C08L23/0815 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08F297/06 , C08F2410/05 , C08L23/142 , C08L2308/00 , C08L2314/08 , C08F2/42 , C08F2/001 , C08F4/027 , C08L2666/04 , C08L2666/06 , C08F2500/17 , C08F2500/12 , C08F2500/10 , C08F2500/09 , C08F210/14 , C08F210/08 , C08F4/7042 , C08F4/7006 , C08F4/7004 , C08F4/7021
摘要： Multi-stage process for the polymerization of olefins CH2═CHR, where R is hydrogen or a C1–C10 alkyl, cycloalkyl or aryl radical, comprising: (I) a first polymerization stage carried out in the presence of a catalyst comprising the product of the reaction between an alkyl-Al compound and a solid component comprising at least one compound of transition metal M1 not containing M1-π bonds, thus obtaining a porous polymer, (II) a treatment stage, wherein said porous polymer is contacted with a compound capable of deactivating the catalyst used in stage (I) and with a late transition metal complex; and (III) a second stage of polymerization, carried out in the presence of the product obtained from treatment stage (II).
摘要翻译： 用于烯烃CH 2 CO 2的聚合的多阶段方法，其中R是氢或C 1 -C 10烷基，环烷基或 芳基，其包含：（I）在催化剂存在下进行的第一聚合阶段，所述催化剂包含烷基Al化合物和包含至少一种过渡金属化合物M 1的固体组分之间的反应的产物， / SUP>不含M 1 -pi键，从而获得多孔聚合物，（II）处理阶段，其中所述多孔聚合物与能够使阶段（I）中使用的催化剂失活的化合物接触 ）和后期过渡金属络合物; 和（III）在得自治疗阶段（II）的产物存在下进行第二阶段聚合。
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公开(公告)号：US06613915B1
公开(公告)日：2003-09-02
申请号：US09417323
申请日：1999-10-13
申请人： Lynda Kaye Johnson , Alison Margaret Anne Bennett , Lin Wang , Anju Parthasarathy , Elisabeth Hauptman , Robert D. Simpson , Jerald Feldman , Edward Bryan Coughlin , Steven Dale Ittel
发明人： Lynda Kaye Johnson , Alison Margaret Anne Bennett , Lin Wang , Anju Parthasarathy , Elisabeth Hauptman , Robert D. Simpson , Jerald Feldman , Edward Bryan Coughlin , Steven Dale Ittel
IPC分类号： C07F1504
CPC分类号： C08F4/26 , C07C225/22 , C07C251/86 , C07D207/335 , C07F15/04 , C08F10/00 , C08F12/04 , C08F110/02 , C08F110/14 , C08F210/02 , C08F210/16 , C08F2410/03 , C08F2500/02 , C08F2500/03 , C08F2500/12 , C08F2500/04 , C08F220/10 , C08F2500/10 , C08F210/14 , C08F4/80 , C08F210/06 , C08F4/7006 , C08F4/7004 , C08F4/7021 , C08F4/7019 , C08F4/7026
摘要： Selected olefins such as ethylene and &agr;-olefins are polymerized by nickel [II] complexes of certain monoanionic ligands. The polyolefins are useful in many applications such as molding resins, film, fibers and others. Also described are many novel nickel compounds and their precursors, as well a novel ligands.
摘要翻译： 选择的烯烃如乙烯和α-烯烃由某些单阴离子配体的镍[II]络合物聚合。 聚烯烃可用于许多应用中，例如模制树脂，薄膜，纤维等。 还描述了许多新型的镍化合物及其前体，以及新的配体。
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公开(公告)号：US20100324237A1
公开(公告)日：2010-12-23
申请号：US12852081
申请日：2010-08-06
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65922 , C08F110/02 , C08F2410/04 , C08F4/61904 , C08F2500/10 , C08F2500/03 , C08F2500/04 , C08F2500/08 , C08F4/7042 , C08F4/7006
摘要： Mixtures of different polyolefins may be made by direct, preferably simultaneous, polymerization of one or more polymerizable olefins using two or more transition metal containing active polymerization catalyst systems, at least one of which contains cobalt or iron complexed with selected ligands. The polyolefin products may have polymers that vary in molecular weight, molecular weight distribution, crystallinity, or other factors, and are useful as molding resins and for films.
摘要翻译： 不同聚烯烃的混合物可以通过使用两种或更多种含过渡金属的活性聚合催化剂体系的一种或多种可聚合烯烃的直接，优选同时聚合来制备，其中至少一种含有与所选择的配体络合的钴或铁。 聚烯烃产品可以具有分子量，分子量分布，结晶度等因素变化的聚合物，并且可用作模制树脂和薄膜。
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公开(公告)号：US06265507B1
公开(公告)日：2001-07-24
申请号：US09132293
申请日：1998-08-11
申请人： Lin Wang , Edward Bryan Coughlin , Zhen-Yu Yang
发明人： Lin Wang , Edward Bryan Coughlin , Zhen-Yu Yang
IPC分类号： C08F1418
CPC分类号： C08F210/00 , C08F4/6592 , C08F4/65922 , C08F210/02 , C08F210/06 , C08F4/65912 , C08F210/14 , C08F2500/03 , C08F210/16
摘要： Selected partially fluorinated olefins containing terminal unfluorinated vinyl groups, and optionally containing other functional groups, may be copolymerized with other olefins such as ethylene and/or propylene using metallocene or Ziegler-Natta type polymerization catalyst systems. The resulting polymers may be used as molding resins, elastomers, for films and in coatings.
摘要翻译： 使用金属茂或齐格勒 - 纳塔型聚合催化剂体系，可以将含有末端未氟化乙烯基和任选含有其它官能团的选择性部分氟化烯烃与其它烯烃如乙烯和/或丙烯共聚。 所得聚合物可用作模制树脂，弹性体，用于薄膜和涂料。
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公开(公告)号：US6034259A
公开(公告)日：2000-03-07
申请号：US891398
申请日：1997-07-10
申请人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
发明人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
IPC分类号： B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号： C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要： Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译： 本文公开了聚合乙烯，无环烯烃和/或选择的环烯烃，和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物，有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性，因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的，特别是在它们的微结构方面，这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂，以及一些制备它们的新方法。 制备的聚合物可用作弹性体，模塑树脂，粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃，将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸，或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号：US5714556A
公开(公告)日：1998-02-03
申请号：US671392
申请日：1996-06-27
申请人： Lynda Kaye Johnson , Jerald Feldman , Kristina Ann Kreutzer , Stephan James McLain , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Dennis Scott Donald , Lissa Taka Jennings Nelson , Anju Parthasarathy , Xing Shen , Wilson Tam , Yueli Wang
发明人： Lynda Kaye Johnson , Jerald Feldman , Kristina Ann Kreutzer , Stephan James McLain , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Dennis Scott Donald , Lissa Taka Jennings Nelson , Anju Parthasarathy , Xing Shen , Wilson Tam , Yueli Wang
IPC分类号： C07F15/04 , C08F4/06 , C08F4/70 , C08F10/00 , C08F10/02 , C08F12/00 , C08F12/04 , C08F12/08 , C08F32/08 , C08F36/00 , C08F36/20 , C08F110/02 , C08F210/02
CPC分类号： C08F32/08 , C07F15/04 , C08F10/00 , C08F10/02 , C08F12/08 , C08F110/02 , C08F210/02
摘要： Disclosed herein is a process for the polymerization of ethylene, norbornenes and styrenes, by contacting in solution a selected nickel compound and a selected compound which is or can coordinated to the nickel with the olefin(s). The polymers produced are useful for films and molding resins.
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7.发明申请公开(公告)号：US20120270979A1
公开(公告)日：2012-10-25
申请号：US13456146
申请日：2012-04-25
申请人： Shaw Ling Hsu , Sahas Rathi , Edward Bryan Coughlin , Xiaolang Chen , Charles S. Golub , Michael J. Tzivanis , Michael A. Zimmerman , Nicholas Orf , Choung H. Lai
发明人： Shaw Ling Hsu , Sahas Rathi , Edward Bryan Coughlin , Xiaolang Chen , Charles S. Golub , Michael J. Tzivanis , Michael A. Zimmerman , Nicholas Orf , Choung H. Lai
CPC分类号： C08L67/04 , B29C2045/0091 , C08K5/103 , C08L101/12 , C08L101/16 , C08L2205/02
摘要： A composition includes a blend of (a) a multi-block copolymer including at least one block of an elastomeric polymer and at least one block of a first polymer including a chiral polymer having a stereo isomeric configuration; and (b) a second polymer including an anti-chiral polymer corresponding to the chiral polymer in (a), wherein the second polymer includes an opposite handed stereo isomeric configuration to the chiral polymer in (a); wherein the blend of the chiral polymer and the anti-chiral polymer form stereo complex sites. A flexible tubing material further includes the blend. In an embodiment, a method of making the blend material is also provided.
摘要翻译： 组合物包括（a）包含弹性体聚合物的至少一个嵌段和至少一个第一聚合物嵌段的多嵌段共聚物的混合物，所述第一聚合物包括具有立体异构构型的手性聚合物; 和（b）包含对应于（a）中的手性聚合物的抗手性聚合物的第二聚合物，其中所述第二聚合物包含与（a）中的手性聚合物相反的立体异构构型; 其中手性聚合物和抗手性聚合物的共混物形成立体复合物位点。 柔性管材料还包括该混合物。 在一个实施方案中，还提供了制备共混材料的方法。
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公开(公告)号：US06506920B2
公开(公告)日：2003-01-14
申请号：US09824072
申请日：2001-04-02
IPC分类号： C07F700
CPC分类号： C08F10/00 , C07F7/003 , C08F110/02 , C08F110/06 , C08F110/14 , C08F210/16 , C08F232/00 , C08F2410/04 , C08F4/69465 , C08F4/64186 , C08F4/68465 , C08F4/54 , C08F2500/20 , C08F2500/10 , C08F2500/12 , C08F2500/05 , C08F2500/04 , C08F210/14 , C08F2500/01 , C08F4/7042
摘要： Olefins such as ethylene and propylene may be polymerized by using as catalysts novel selected transition metal complexes of bis(carboximidamidatonates) in which the carboximidamidatonate groups are connected together through covalent bonds by a bridging group. The resulting polymers are useful as molding and extrusion resins.
摘要翻译： 烯烃如乙烯和丙烯可以通过使用作为催化剂的新型选择的双（羧甲基脒基化合物）的过渡金属络合物来聚合，其中通过桥连基团通过共价键将甲脒基酰胺基团连接在一起。 所得聚合物可用作模制和挤出树脂。
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公开(公告)号：US06310163B1
公开(公告)日：2001-10-30
申请号：US08899002
申请日：1997-07-10
申请人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
发明人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
IPC分类号： C08F22010
CPC分类号： C08F110/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/06 , C08F110/14 , C08F210/02 , C08F210/14 , C08F210/16 , C08F232/00 , C08L23/02 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要： Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear &agr;-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected &agr;-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected &agr;-diimine nickel complexes with ethylene.
摘要翻译： 本文公开了聚合乙烯，无环烯烃和/或选择的环烯烃，和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物，有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性，因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的，特别是关于它们的微观结构，这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂，以及一些制备它们的新方法。 制备的聚合物可用作弹性体，模塑树脂，粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚法合成线性α-烯烃，将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸，或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号：US06174975B1
公开(公告)日：2001-01-16
申请号：US09006536
申请日：1998-01-13
申请人： Lynda Kaye Johnson , Alison Margaret Anne Bennett , Lin Wang , Anju Parthasarathy , Elisabeth Hauptman , Robert D. Simpson , Jerald Feldman , Edward Bryan Coughlin , Steven Dale Ittel
发明人： Lynda Kaye Johnson , Alison Margaret Anne Bennett , Lin Wang , Anju Parthasarathy , Elisabeth Hauptman , Robert D. Simpson , Jerald Feldman , Edward Bryan Coughlin , Steven Dale Ittel
IPC分类号： C08F426
CPC分类号： C08F4/26 , C07C225/22 , C07C251/86 , C07D207/335 , C07F15/04 , C08F10/00 , C08F12/04 , C08F110/02 , C08F110/14 , C08F210/02 , C08F210/16 , C08F2410/03 , C08F2500/02 , C08F2500/03 , C08F2500/12 , C08F2500/04 , C08F220/10 , C08F2500/10 , C08F210/14 , C08F4/80 , C08F210/06 , C08F4/7006 , C08F4/7004 , C08F4/7021 , C08F4/7019 , C08F4/7026
摘要： Selected olefins such as ethylene and &agr;-olefins are polymerized by nickel [II] complexes of certain monoanionic ligands. The polyolefins are useful in many applications such as molding resins, film, fibers and others. Also described are many novel nickel compounds and their precursors, as well a novel ligands.
摘要翻译： 选择的烯烃如乙烯和α-烯烃由某些单阴离子配体的镍[II]络合物聚合。 聚烯烃可用于许多应用中，例如模制树脂，薄膜，纤维等。 还描述了许多新型的镍化合物及其前体，以及新的配体。
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