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1.发明授权
公开(公告)号：US5049536A
公开(公告)日：1991-09-17
申请号：US345142
申请日：1989-04-28
IPC分类号： B01J21/12 , B01J37/00 , C01B33/12 , C01B33/26 , C07B61/00 , C07C1/00 , C07C2/10 , C07C2/58 , C07C5/25 , C07C11/02 , C07C67/00
CPC分类号： B01J21/12 , C07C2/10 , C07C2521/12
摘要： A silica and alumina gel is disclosed, which is amorphous at X-rays, has a molar ratio of SiO.sub.2 /Al.sub.2 O.sub.3 comprised within the range of from 30/1 to 500/1, a surface area comprised within the range of from 500 to 1000 m.sup.2 /g, a total volume of pores comprised within the range of from 0.3 to 0.6 ml/g, an average diameter of the pores of the order of magnitude of 10 .ANG. or less and which is free, or substantially free, from pores having a diameter larger than 30 .ANG..Such a silica and alumina gel is catalytically active in reactions of conversion of the hydrocarbons, such as: oligomerization, alkylation, isomerization and dewaxing.Also a process for preparing such a silica and alumina gel is disclosed.
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公开(公告)号：US5110570A
公开(公告)日：1992-05-05
申请号：US627635
申请日：1990-12-14
CPC分类号： B01J29/86 , C01B35/1009 , Y10S423/27
摘要： A novel method for preparing crystalline, porous boro-silicates and boron-metal-silicates isostructural with beta zeolite is disclosed.This method makes it possible the times required by the synthesis of such zeolites to be reduced, and said preparations to be carried out with larger reaction volumes.
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公开(公告)号：US5149896A
公开(公告)日：1992-09-22
申请号：US715786
申请日：1991-06-14
IPC分类号： C08F4/12 , C07C2/08 , C07C2/10 , C07C2/12 , C07C9/14 , C08F4/06 , C08F4/18 , C08F10/00 , C08F10/06 , C10G50/00
CPC分类号： C07C2/10 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/12 , Y02P20/52
摘要： A process for oligomerizing propylene is described, consisting of reacting said olefin in the presence of an X-ray amorphous alumina-silica gel catalyst with a silica/alumina molar ratio of between 30/1 and 500/1, a surface area of between 500 and 1000 m.sup.2 /g, a total pore volume of between 0.3 and 0.6 ml/g, an average pore diameter of the order of 10 .ANG. or less, and free or substantially free of pores with a diameter greater than 30 .ANG..
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4.发明申请ORGANIC-INORGANIC HYBRID SILICATES AND METAL-SILICATES HAVING AN ORDERED STRUCTURE 有权有机无机混合硅酸盐和具有订购结构的金属硅酸盐公开(公告)号：US20100191009A1
公开(公告)日：2010-07-29
申请号：US12376704
申请日：2007-08-03
申请人： Giuseppe Bellussi , Angela Carati , Caterina Rizzo , Urbano Diaz Morales , Stefano Zanardi , Wallace O'Neil Parker , Roberto Millini
发明人： Giuseppe Bellussi , Angela Carati , Caterina Rizzo , Urbano Diaz Morales , Stefano Zanardi , Wallace O'Neil Parker , Roberto Millini
IPC分类号： C07F7/08
CPC分类号： C09C1/3081 , C01B33/44 , C01B37/00 , C01B39/00 , C01B39/02 , C01P2002/72 , C01P2002/74 , C01P2002/86 , C01P2006/17 , C07F7/1804
摘要： The present invention relates to new organic-inorganic hybrid silicates and metal-silicates called ECS, characterized by an X-ray powder diffraction pattern with reflections exclusively at angular values higher than 4.0° of 2Θ, preferably at angular values higher than 4.7°, and an ordered structure containing structural units having formula (a) wherein R is an organic group: Formula (a) and possibly containing one or more elements T selected from groups III B, IV B, V B and transition metals, with a Si/(Si+T) molar ratio in said structure higher than 0.3 and lower than or equal to 1, wherein Si is the silicon contained in the structural unit (a). A process is also described, starting from disilanes, for the preparation of these materials, which does not include the use of templates or surfactants. These materials can be used as molecular sieves, adsorbents, in the field of catalysis, in the field of electronics, in the field of sensors, in the field of nanotechnologies.
摘要翻译： 本发明涉及称为ECS的新的有机 - 无机杂化硅酸盐和金属硅酸盐，其特征在于具有专门在高于4.0°的角度值为2θ，优选高于4.7°的角度值的反射的X射线粉末衍射图，以及 含有具有式（a）的结构单元的有序结构，其中R是有机基团：式（a）并且可能含有选自IIIB，IVB，VB族和过渡金属的一种或多种元素T，其中Si /（Si + T）的摩尔比高于0.3且小于或等于1，其中Si是结构单元（a）中所含的硅。 还描述了从二硅烷开始制备这些材料的方法，其不包括使用模板或表面活性剂。 这些材料可用作纳米技术领域的电子领域，传感器领域的催化剂领域的分子筛，吸附剂。
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公开(公告)号：US07018595B2
公开(公告)日：2006-03-28
申请号：US10315022
申请日：2002-12-10
CPC分类号： C01B37/005 , B01J29/06 , B01J29/40 , B01J2229/32 , C01B37/02 , C01B39/40 , Y10S423/22 , Y10S423/29
摘要： A process is described for the preparation of zeolitic catalysts in the form of microspheres, comprising zeolite and oligomeric silica, characterized by a high mechanical resistance. The process consists in subjecting to rapid drying the suspension, to which tetra-alkylorthosilicate is optionally added, resulting from the synthesis of zeolite by hydrothermal treatment at autogenous pressure of the reagent mixture containing tetra-alkylammoniumhydroxide as templating agent, and subjecting the product resulting from the drying to calcination.
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公开(公告)号：US09278339B2
公开(公告)日：2016-03-08
申请号：US13499452
申请日：2010-09-23
申请人： Giuseppe Bellussi , Angela Carati , Maria Federica Gagliardi , Stefano Zanardi , Marcello Marella , Roberto Scattolin , Michele Tomaselli
发明人： Giuseppe Bellussi , Angela Carati , Maria Federica Gagliardi , Stefano Zanardi , Marcello Marella , Roberto Scattolin , Michele Tomaselli
IPC分类号： B01J21/00 , B01J23/00 , B01J29/00 , B01J31/00 , B01J27/049 , B01J27/051 , B01J35/10 , B01J37/03 , B01J37/20 , C10G45/08
CPC分类号： B01J27/0515 , B01J23/002 , B01J23/883 , B01J23/8885 , B01J27/049 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/033 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G2300/1044 , C10G2300/1062 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2400/04 , C10G2400/06 , B01J2523/31 , B01J2523/68 , B01J2523/69 , B01J2523/845 , B01J2523/847 , B01J2523/41
摘要： New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) XaYbZcOd.pC (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, O is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) RIRIIRIIIRIVNOH (I) wherein the groups RI-RIV, the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R1R2R3N (II) wherein R1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R2 and R3, the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R1, a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b)/c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d=(2a+6b+Hc)/2 wherein H=4 when Z=Si H=3 when Z=Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.
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7.发明授权Hybrid, organic-inorganic, crystalline, porous silicates and metal-silicates 有权混合有机 - 无机，结晶，多孔硅酸盐和金属硅酸盐公开(公告)号：US08809561B2
公开(公告)日：2014-08-19
申请号：US13254999
申请日：2010-02-25
CPC分类号： C01B37/00 , C01P2002/72
摘要： The present invention relates to new hybrid, organic-inorganic hybrid silicates and metal-silicates characterized by a crystalline structure containing structural units having formula (a), wherein R is an organic group possibly containing one or more element T selected from Group IIIB, IVB, VB and from transition metals. A process starting from cyclic trisilanes for the preparation of said materials, is also described. These materials can be used as molecular sieves, adsorbents, in the field of catalysis, in the field of electronics, in the field of sensors, in the area of nanotechnology.
摘要翻译： 本发明涉及新型混合有机 - 无机杂化硅酸盐和金属硅酸盐，其特征在于含有具有式（a）的结构单元的晶体结构，其中R是可能含有一种或多种选自IIIB族，IVB族元素的有机基团 ，VB和过渡金属。 还描述了从用于制备所述材料的环状三硅烷开始的方法。 这些材料可用作催化领域的分子筛，吸附剂，电子领域，传感器领域，纳米技术领域。
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公开(公告)号：US20120261311A1
公开(公告)日：2012-10-18
申请号：US13499452
申请日：2010-09-23
申请人： Giuseppe Bellussi , Angela Carati , Maria Federica Gagliardi , Stefano Zanardi , Marcello Marella , Roberto Scattolin , Michele Tomaselli
发明人： Giuseppe Bellussi , Angela Carati , Maria Federica Gagliardi , Stefano Zanardi , Marcello Marella , Roberto Scattolin , Michele Tomaselli
IPC分类号： B01J21/08 , C10G29/16 , C10G29/20 , B01J27/051 , C10G45/00
CPC分类号： B01J27/0515 , B01J23/002 , B01J23/883 , B01J23/8885 , B01J27/049 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/033 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G2300/1044 , C10G2300/1062 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2400/04 , C10G2400/06 , B01J2523/31 , B01J2523/68 , B01J2523/69 , B01J2523/845 , B01J2523/847 , B01J2523/41
摘要： New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) XaYbZcOd.pC (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, 0 is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) RIRIIRIIIRIVNOH (I) wherein the groups RI-RIV, the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R1R2R3N (II) wherein R1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R2 and R3, the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R1, a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b)/c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d=(2a+6b+Hc)/2 wherein H=4 when Z=Si H=3 when Z=Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.
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公开(公告)号：US06524984B2
公开(公告)日：2003-02-25
申请号：US09159751
申请日：1998-09-24
IPC分类号： B01J2906
CPC分类号： C01B37/005 , B01J29/06 , B01J29/40 , B01J2229/32 , C01B37/02 , C01B39/40 , Y10S423/22 , Y10S423/29
摘要： A process is described for the preparation of zeolitic catalysts in the form of microspheres, comprising zeolite and oligomeric silica, characterized by a high mechanical resistance. The process consists in subjecting to rapid drying the suspension, to which tetra-alkylorthosilicate is optionally added, resulting from the synthesis of zeolite by hydrothermal treatment at autogenous pressure of the reagent mixture containing tetra-alkylammoniumhydroxide as templating agent, and subjecting the product resulting from the drying to calcination.
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公开(公告)号：US09765266B2
公开(公告)日：2017-09-19
申请号：US12996782
申请日：2009-06-08
IPC分类号： C10G45/04 , B01J29/04 , B01J23/16 , C10G47/02 , C10G47/26 , B01J23/882 , B01J23/883 , B01J27/051 , B01J29/06 , B01J29/072 , B01J29/16 , B01J29/70 , B01J29/76 , B01J35/00 , B01J37/20 , C10G45/08 , C10G45/12 , C10G45/46 , C10G45/50 , C10G45/54 , C10G47/20
CPC分类号： C10G45/04 , B01J23/882 , B01J23/883 , B01J27/051 , B01J29/041 , B01J29/061 , B01J29/072 , B01J29/166 , B01J29/7007 , B01J29/7615 , B01J35/0006 , B01J37/20 , C10G45/08 , C10G45/12 , C10G45/46 , C10G45/50 , C10G45/54 , C10G47/20 , C10G2300/1003 , C10G2300/1011 , C10G2300/1033 , C10G2300/1074 , Y02P30/20
摘要： Catalytic system which can be used in processes for the hydroconversion of heavy oils by means of hydrotreatment in slurry phase, characterized in that it comprises: a catalyst, having the function of hydrogenating agent, containing MoS2 or WS2 or mixtures thereof in lamellar form or an oil-soluble precursor thereof; a co-catalyst, having nanometric or micronic particle-sizes, selected from cracking and/or denitrogenation catalysts. The co-catalyst preferably consists of zeolites having small-sized crystals and with a low aggregation degree between the primary particles, and/or oxides or sulfides or precursors of sulfides of Ni and/or Co in a mixture with Mo and/or W.
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