公开(公告)号：US20120012504A1

公开(公告)日：2012-01-19

申请号：US13138763

申请日：2010-03-26

申请人： Hideki Minami ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo ,  Shinichiro Yanagawa ,  Kazuaki Hayasaka

发明人： Hideki Minami ,  Yoshishige Sugi ,  Atsushi Fukui ,  Atsuro Nagumo ,  Shinichiro Yanagawa ,  Kazuaki Hayasaka

IPC分类号： C10G35/04

CPC分类号： B01J29/048 ,  B01J29/405 ,  B01J29/87 ,  B01J29/90 ,  B01J37/0201 ,  B01J38/02 ,  C07C4/06 ,  C07C2529/70 ,  C10G35/14 ,  C10G2300/1044 ,  C10G2400/30 ,  Y02P20/584 ,  C07C15/02

摘要： A method for producing aromatic hydrocarbons in which at least one feedstock oil selected from the group consisting of LCO produced from an FCC apparatus, hydrotreated LCO, naphtha and straight-run gas oil is brought into contact with a reforming catalyst inside a fluidized bed reactor, wherein the method includes transporting a reforming catalyst that has been extracted from the fluidized bed reactor to a heating tank, heating the reforming catalyst in the heating tank to a temperature at least as high as the reaction temperature inside the fluidized bed reactor, and following heating, transporting the heated reforming catalyst to the fluidized bed reactor.

摘要翻译： 一种制备芳族烃的方法，其中将至少一种选自FCC装置的LCO，加氢处理的LCO，石脑油和直馏瓦斯油的原料油与流化床反应器内的重整催化剂接触， 其特征在于，将从所述流化床反应器提取的重整催化剂输送到加热槽，将所述加热槽内的重整催化剂加热到与所述流化床反应器内部的反应温度至少一样的温度， 将加热的重整催化剂输送到流化床反应器。

公开(公告)号：US20130030232A1

公开(公告)日：2013-01-31

申请号：US13522867

申请日：2011-01-20

申请人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Kazuaki Hayasaka

发明人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Kazuaki Hayasaka

IPC分类号： B01J29/80 ,  C07C4/06

CPC分类号： C10G11/05 ,  B01J29/084 ,  B01J29/18 ,  B01J29/40 ,  B01J29/405 ,  B01J29/7007 ,  B01J29/7057 ,  B01J29/80 ,  B01J37/0009 ,  B01J2229/36 ,  B01J2229/37 ,  C07C4/06 ,  C07C2529/06 ,  C07C2529/08 ,  C07C2529/40 ,  C10G11/18 ,  C10G47/16 ,  C10G2300/1033 ,  C10G2300/1044 ,  C10G2300/1048 ,  C10G2300/1051 ,  C10G2300/1055 ,  C10G2300/1059 ,  C10G2300/107 ,  C10G2300/301 ,  C10G2400/02 ,  C10G2400/20 ,  C10G2400/30

摘要： A catalyst is provided for production of monocyclic aromatic hydrocarbons having a carbon number of 6 to 8 from feedstock in which a 10 vol % distillation temperature is 140° C. or higher and a 90 vol % distillation temperature is 380° C. or lower. The catalyst contains crystalline aluminosilicate including large-pore zeolite having a 12-membered ring structure, and intermediate-pore zeolite having a 10-membered ring structure.

摘要翻译： 提供了一种催化剂，用于生产碳原子数为6〜8的单体芳烃，其中10体积％蒸馏温度为140℃以上，90体积％蒸馏温度为380℃以下的原料。 催化剂含有包含具有12元环结构的大孔沸石的结晶硅铝酸盐和具有10元环结构的中孔沸石。

公开(公告)号：US20110270005A1

公开(公告)日：2011-11-03

申请号：US13138064

申请日：2010-03-26

申请人： Shinichiro Yanagawa ,  Yuko Aoki ,  Kazuaki Hayasaka

发明人： Shinichiro Yanagawa ,  Yuko Aoki ,  Kazuaki Hayasaka

IPC分类号： C07C5/367

CPC分类号： C10G35/095 ,  C10G45/54 ,  C10G45/68 ,  C10G49/007 ,  C10G63/04 ,  C10G69/04 ,  C10G2300/4012 ,  C10G2400/30

摘要： A method for producing aromatic hydrocarbons by bringing a feedstock derived from a fraction containing a light cycle oil produced in a fluid catalytic cracking into contact with a catalyst containing a crystalline aluminosilicate, wherein the proportion of the naphthene content within the feedstock is adjusted so as to be greater than the proportion of the naphthene content in the fraction containing the light cycle oil, and the contact between the feedstock and the catalyst is performed under a pressure within a range from 0.1 MPaG to 1.0 MPaG.

摘要翻译： 通过使来自含有流化催化裂化生产的轻循环油的馏分的原料与含有结晶性硅铝酸盐的催化剂接触来制造芳香族烃的方法，其中调整原料内环烷烃含量的比例，使得 大于含有轻质循环油的级分中的环烷烃含量的比例，原料和催化剂之间的接触在0.1MPaG至1.0MPaG范围内的压力下进行。

公开(公告)号：US20110270002A1

公开(公告)日：2011-11-03

申请号：US13138065

申请日：2010-03-26

申请人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Yuko Aoki ,  Kazuaki Hayasaka

发明人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Yuko Aoki ,  Kazuaki Hayasaka

IPC分类号： C07C5/02 ,  B01J27/182

CPC分类号： C07C4/06 ,  B01J29/061 ,  B01J29/405 ,  B01J37/28 ,  B01J2229/37 ,  C07C2529/06 ,  C07C2529/40 ,  C07C2529/85 ,  C07C2529/87 ,  C10G2300/1033 ,  C10G2300/1044 ,  C10G2300/1048 ,  C10G2300/1051 ,  C10G2300/1055 ,  C10G2300/1059 ,  C10G2300/301 ,  C10G2400/30

摘要： A catalyst for producing monocyclic aromatic hydrocarbons, used for producing monocyclic aromatic hydrocarbons of 6 to 8 carbon number from a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and an end point temperature of not more than 400° C., wherein the catalyst contains a crystalline aluminosilicate, gallium and/or zinc, and phosphorus, the molar ratio between silicon and aluminum (Si/Al ratio) in the crystalline aluminosilicate is not more than 100, the molar ratio between the phosphorus supported on the crystalline aluminosilicate and the aluminum of the crystalline aluminosilicate (P/Al ratio) is not less than 0.01 and not more than 1.0, and the amount of gallium and/or zinc is not more than 1.2% by mass based on the mass of the crystalline aluminosilicate.

摘要翻译： 一种用于生产单环芳烃的催化剂，用于从具有10体积％蒸馏温度至少为140℃，终点温度不超过400℃的原料油制备6至8个碳原子的单环芳烃 ，其中催化剂含有结晶硅铝酸盐，镓和/或锌和磷，结晶硅铝酸盐中硅和铝之间的摩尔比（Si / Al比）不大于100，所支持的磷之间的摩尔比 结晶硅铝酸盐和结晶硅铝酸盐（P / Al比）的结晶铝硅酸盐和铝的含量不小于0.01且不大于1.0，镓和/或锌的量不超过1.2质量％ 结晶硅铝酸盐。

公开(公告)号：US20130015102A1

公开(公告)日：2013-01-17

申请号：US13574410

申请日：2011-01-20

申请人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Kazuaki Hayasaka

发明人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Kazuaki Hayasaka

IPC分类号： C01B39/02 ,  C01B39/54 ,  C10G11/05

CPC分类号： B01J29/18 ,  B01J29/06 ,  B01J29/061 ,  B01J29/08 ,  B01J29/082 ,  B01J29/084 ,  B01J29/085 ,  B01J29/087 ,  B01J29/088 ,  B01J29/7007 ,  B01J29/7057 ,  B01J37/0009 ,  B01J37/28 ,  B01J2229/18 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  C10G11/18 ,  C10G2300/107 ,  C10G2400/20 ,  C10G2400/30

摘要： A catalyst is provided for production of hydrocarbons including monocyclic aromatic hydrocarbons having a carbon number of 6 to 8 and aliphatic hydrocarbons having a carbon number of 3 to 4 from feedstock in which a 10 vol % distillation temperature is 140° C. or higher and a 90 vol % distillation temperature is 380° C. or lower. The catalyst includes crystalline aluminosilicate including large-pore zeolite having a 12-membered ring structure.

摘要翻译： 提供催化剂用于生产碳原子数为6〜8的单环芳烃和碳原子数为3〜4的脂肪族烃，其中10体积％蒸馏温度为140℃以上， 90体积％的蒸馏温度为380℃以下。 催化剂包括结晶硅铝酸盐，其包括具有12元环结构的大孔沸石。

公开(公告)号：US09827558B2

公开(公告)日：2017-11-28

申请号：US13574410

申请日：2011-01-20

申请人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Kazuaki Hayasaka

发明人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Kazuaki Hayasaka

IPC分类号： B01J29/18 ,  B01J29/06 ,  B01J29/08 ,  B01J37/28 ,  B01J29/70 ,  C10G11/18 ,  B01J37/00

CPC分类号： B01J29/18 ,  B01J29/06 ,  B01J29/061 ,  B01J29/08 ,  B01J29/082 ,  B01J29/084 ,  B01J29/085 ,  B01J29/087 ,  B01J29/088 ,  B01J29/7007 ,  B01J29/7057 ,  B01J37/0009 ,  B01J37/28 ,  B01J2229/18 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  C10G11/18 ,  C10G2300/107 ,  C10G2400/20 ,  C10G2400/30

摘要： A catalyst is provided for production of hydrocarbons including monocyclic aromatic hydrocarbons having a carbon number of 6 to 8 and aliphatic hydrocarbons having a carbon number of 3 to 4 from feedstock in which a 10 vol % distillation temperature is 140° C. or higher and a 90 vol % distillation temperature is 380° C. or lower. The catalyst includes crystalline aluminosilicate including large-pore zeolite having a 12-membered ring structure.

公开(公告)号：US09243192B2

公开(公告)日：2016-01-26

申请号：US13138064

申请日：2010-03-26

申请人： Shinichiro Yanagawa ,  Yuko Aoki ,  Kazuaki Hayasaka

发明人： Shinichiro Yanagawa ,  Yuko Aoki ,  Kazuaki Hayasaka

IPC分类号： C07C5/367 ,  C10G35/095 ,  C10G45/68 ,  C10G63/04 ,  C10G69/04 ,  C10G45/54 ,  C10G49/00

CPC分类号： C10G35/095 ,  C10G45/54 ,  C10G45/68 ,  C10G49/007 ,  C10G63/04 ,  C10G69/04 ,  C10G2300/4012 ,  C10G2400/30

摘要： A method for producing aromatic hydrocarbons by bringing a feedstock derived from a fraction containing a light cycle oil produced in a fluid catalytic cracking into contact with a catalyst containing a crystalline aluminosilicate, wherein the proportion of the naphthene content within the feedstock is adjusted so as to be greater than the proportion of the naphthene content in the fraction containing the light cycle oil, and the contact between the feedstock and the catalyst is performed under a pressure within a range from 0.1 MPaG to 1.0 MPaG.

摘要翻译： 通过使来自含有流化催化裂化生产的轻循环油的馏分的原料与含有结晶性硅铝酸盐的催化剂接触来制造芳香族烃的方法，其中调整原料内环烷烃含量的比例，使得 大于含有轻质循环油的级分中的环烷烃含量的比例，原料和催化剂之间的接触在0.1MPaG至1.0MPaG范围内的压力下进行。

公开(公告)号：US20110270004A1

公开(公告)日：2011-11-03

申请号：US13138082

申请日：2010-03-26

申请人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Yuko Aoki ,  Kazuaki Hayasaka

发明人： Shinichiro Yanagawa ,  Masahide Kobayashi ,  Yuko Aoki ,  Kazuaki Hayasaka

IPC分类号： C07C15/02 ,  B01J29/40 ,  B01J29/18 ,  B01J27/182

CPC分类号： C07C4/06 ,  B01J29/061 ,  B01J29/405 ,  B01J37/28 ,  B01J2229/37 ,  C07C2529/06 ,  C07C2529/40 ,  C07C2529/87 ,  C10G45/68 ,  C10G2300/1033 ,  C10G2300/1044 ,  C10G2300/1048 ,  C10G2300/1051 ,  C10G2300/1055 ,  C10G2300/1059 ,  C10G2300/301 ,  C10G2400/30

摘要： A catalyst for producing monocyclic aromatic hydrocarbons of 6 to 8 carbon number from a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and an end point temperature of not more than 400° C., or a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and a 90 volume % distillation temperature of not more than 360° C., wherein the catalyst contains a crystalline aluminosilicate, gallium and/or zinc, and phosphorus, and the amount of phosphorus supported on the crystalline aluminosilicate is within a range from 0.1 to 1.9% by mass based on the mass of the crystalline aluminosilicate; and a method for producing monocyclic aromatic hydrocarbons, the method involving bringing a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and an end point temperature of not more than 400° C., or a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and a 90 volume % distillation temperature of not more than 360° C., into contact with the above-mentioned catalyst for producing monocyclic aromatic hydrocarbons.

摘要翻译： 一种催化剂，用于从具有10体积％蒸馏温度至少为140℃，终点温度不高于400℃的原料油生产6至8个碳原子的单环芳族烃，或具有 至少140℃的10体积％蒸馏温度和不高于360℃的90体积％蒸馏温度，其中所述催化剂含有结晶硅铝酸盐，镓和/或锌和磷，以及 在结晶硅铝酸盐上负载的磷的含量相对于结晶性铝硅酸盐的质量为0.1〜1.9质量％ 和单环芳烃的制造方法，其特征在于，使具有10体积％馏出温度的原料油为至少140℃，终点温度为400℃以下的方法， 10体积％的蒸馏温度为至少140℃，90体积％蒸馏温度为不高于360℃，与上述用于制备单环芳烃的催化剂接触。

公开(公告)号：US09518232B2

公开(公告)日：2016-12-13

申请号：US12865921

申请日：2009-02-04

申请人： Kazuaki Hayasaka

发明人： Kazuaki Hayasaka

IPC分类号： B01J29/06 ,  C10G25/03 ,  C10G45/64 ,  B01J29/064 ,  B01J29/076 ,  B01J29/72 ,  C01B39/48 ,  B01J29/068 ,  B01J37/00 ,  B01J29/74 ,  B01J29/78 ,  B01J35/02 ,  B01J35/10

CPC分类号： C10G45/64 ,  B01J29/064 ,  B01J29/068 ,  B01J29/076 ,  B01J29/7284 ,  B01J29/7461 ,  B01J29/7484 ,  B01J29/7492 ,  B01J29/7861 ,  B01J29/7884 ,  B01J29/7892 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0009 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/48 ,  C10G2300/1022 ,  C10G2300/1085 ,  C10G2400/10

摘要： A hydroisomerization catalyst of the present invention is obtained by calcining a catalyst composition containing an ion-exchanged molecular sieve or a calcined product thereof, and at least one metal selected from the group consisting of metals of Groups 8 to 10 in Periodic Table of the elements, molybdenum and tungsten, carried on the ion-exchanged molecular sieve or the calcined product thereof, wherein the ion-exchanged molecular sieve is obtained by ion-exchanging a molecular sieve, which includes nanocrystals having a pore structure of ten-membered rings or eight-membered rings and having a ratio of the pore volume to the external surface area ([pore volume]/[external surface area]) of 2.0×10−4 mL/m2 to 8.0×10−4 mL/m2 and contains an organic template, in a solution containing a cationic species.

摘要翻译： 通过煅烧含有离子交换分子筛或其煅烧产物的催化剂组合物和选自元素周期表第8〜10族金属中的至少一种金属，得到本发明的加氢异构化催化剂 ，钼和钨载带在离子交换分子筛或其煅烧产物上，其中离子交换分子筛是通过离子交换分子筛获得的，分子筛包括具有十元环或八元孔结构的纳米晶体 具有2.0×10 -4 mL / m 2的孔体积与外表面积（[孔体积] / [外表面积]）的比例为8.0×10 -4 mL / m 2，并且含有有机物 模板，在含有阳离子物质的溶液中。

公开(公告)号：US09283552B2

公开(公告)日：2016-03-15

申请号：US13391727

申请日：2010-08-30

申请人： Kazuaki Hayasaka ,  Hideki Ono ,  Akira Koyama ,  Hideshi Iki

发明人： Kazuaki Hayasaka ,  Hideki Ono ,  Akira Koyama ,  Hideshi Iki

IPC分类号： C07C1/00 ,  B01J29/74 ,  B01J23/883 ,  C10G3/00 ,  C10G45/64 ,  C10L1/04 ,  B01J23/85 ,  B01J29/85

CPC分类号： B01J29/7484 ,  B01J23/85 ,  B01J23/883 ,  B01J29/7461 ,  B01J29/7492 ,  B01J29/85 ,  C10G3/46 ,  C10G3/49 ,  C10G3/50 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2400/08 ,  C10L1/04 ,  Y02P30/20

摘要： A method for producing an aviation fuel oil base, including: a first step of obtaining a first generated oil by hydrotreating a feedstock by bringing a feedstock which includes an oxygen-containing hydrocarbon compound derived from an animal or vegetable oils and fat into contact with a first dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of group 6B of the periodic table, a metal of group 8, and an amorphous solid acidic substance, in the presence of hydrogen; and a second step of obtaining a second generated oil including an aviation fuel oil base by hydroisomerizing the first generated oil by bringing the first generated oil into contact with a second dual functional catalyst which has dehydrogenation and hydrogenation functions and which includes a metal of the group 8 of the periodic table and a crystalline solid acidic substance, in the presence of hydrogen.

摘要翻译： 一种生产航空燃料油基料的方法，包括：第一步骤，通过将包含来源于动物或植物油脂的含氧烃化合物的原料与一种原料接触而将原料加氢处理获得第一产生的油 具有脱氢和氢化功能的第一双官能催化剂，其包含周期表第6B族金属，第8族金属和无定形固体酸性物质，在氢的存在下; 以及第二步骤，通过使第一产生的油与具有脱氢和氢化功能的第二双功能催化剂接触，并且包括该组的金属，获得包含航空燃料油基的第二产生的油， 8和结晶固体酸性物质，在氢的存在下。