摘要:
In an exhaust aftertreatment system, two LNTs having differing compositions are configured in series downstream from an inline fuel reformer. The downstream LNT is adapted for desulfation at higher temperatures than the upstream LNT. During desulfation, the system develops temperature gradients with the temperatures increasing in the direction of exhaust flow. The ordering of the LNTs is designed utilize these gradients. In a preferred embodiment, the system also includes two SCR catalysts having different compositions. The SCR catalyst with a composition adapted to tolerate higher temperatures is located nearer the downstream end of the system.
摘要:
Desulfation methods for an exhaust treatment system having a fuel reformer configured upstream of a LNT. Reductant is injected upstream of the fuel reformer. The reductant reacts within the reformer to generate heat, but the system is configured for some reductant to breakthrough and react in the LNT to generate further heat. This configuration allows the LNT to operate at temperatures higher the than first device and facilitates independent control of the LNT and first device temperatures. An outer loop controls the LNT temperature by issuing instructions to an inner loop that controls the reformer. Typically, the inner loop will pulse the reductant injection rate in order to limit the reformer temperature. The outer loop can pulses the loop on a longer time scale, resulting in two pulse periods. Through timing, a reformate peak from one period is made to overlap a temperature peak from a previous period.
摘要:
In an exhaust aftertreatment system comprising a NOx adsorber-catalyst followed by an SCR catalyst, means are provided for preventing the SCR catalyst from becoming heated to near the same peak temperatures as the NOx adsorber-catalyst during desulfation. In one embodiment, the means is a thermal mass between the NOx adsorber-catalyst and the SCR catalyst. In another embodiment, the means is a valve configured to selectively divert exhaust leaving the NOx adsorber-catalyst from the SCR catalyst. In a method of the invention, the NOx adsorber-catalyst temperature is cycled during desulfation. The peaks of the cycles are within an appropriate temperature range for desulfating the NOx adsorber-catalyst, but the average temperature is below the temperature range at which the SCR catalyst is damaged. The temperature peaks are damped as they travel from the NOx adsorber-catalyst to the SCR, whereby the SCR experiences much lower peak temperatures than the NOx adsorber-catalyst.
摘要:
One or more parameters for denitration or desulfations of a LNT is varied, whereby the saturation of NOx and/or SOx in the LNT is reduced to a lower level when an operating state makes the LNT otherwise less effective or places a greater demand for conversion efficiency on the LNT. The operating state can relate to whether the LNT is at the limit of its effective operating temperature range, a degree of poisoning, or an engine operating state. Selectively tolerating high degrees of sulfur poisoning or NOx saturation during periods of low exhaust flow allows the efficiency of denitrations and/or desulfations to be increased over a large portion of a vehicle's operating cycle, particularly when the engine uses a CVT. Another concept relates to a power generation system comprising an engine tuned to efficiently operate in a narrow speed range for all levels of power output.
摘要:
One aspect of the invention relates to a particulate filter useful in treating exhaust from a diesel-power vehicle. The particulate filter comprises filter elements for removing particulate matter and an ammonia SCR catalyst. Ammonia can be produced during regeneration of an NOx adsorbant. The adsorbant can be contained in a separate device upstream of the particulate filter or be incorporated within the particulate filter. Another aspect of the invention relates to a method of cleaning exhaust comprising passing the exhaust over an NOx adsorber to adsorb a portion of NOx from the exhaust; passing the exhaust through a particulate filter to remove particulate matter from the exhaust; and removing a further portion of NOx from the exhaust by reducing it with ammonia over an ammonia SCR catalyst. Preferably, a catalyst contained within the adsorbant provides NO2 for continuously regenerating the particulate filter.
摘要:
A diesel exhaust aftertreatment system comprises an LNT within an exhaust line. A low thermal mass DPF and a low thermal mass fuel reformer are configured within the exhaust line upstream from the LNT. A thermal mass is configured downstream from the fuel reformer and the DPF, but upstream from the LNT. For LNT denitration, the fuel reformer is rapidly heated and then used to catalyze steam reforming. The DPF is also rapidly heat each time the fuel reformer is heated and the LNT denitrated. The system operates to regenerate the DPF each time the LNT is denitrated. Preferably, a second DPF is provided to augment the performance of the first DPF. Preferably, the first DPF is small and of the flow through type whereas the second DPF is much larger and of the wall flow filter type. The second DPF can be used as the thermal mass.
摘要:
Rhodium utilization in LNT/SCR-based exhaust after treatment systems for medium and heavy duty trucks is reduced by operating inline fuel reformers in a certain manner. The fuel processors are operated at steam reforming temperatures to produce a reformate-containing exhaust having a hydrogen to CO ratio of at least about 3:2 or at least about 3% hydrogen, This generally involves operating the fuel reformers at temperatures from about 500 to about 625° C. and with an overall fuel to air ratio from about 1.10 to about 1.40. In this manner, regeneration can be efficiently carried out while limiting the catalyst loading of the fuel processors to no more than about 1.0 grams rhodium per liter maximum displacement of the diesel engine and the catalyst loading of the LNTs to no more than about 0.50 grams rhodium per liter maximum displacement of the diesel engine.
摘要:
A power generation system comprising a LNT for exhaust aftertreatment. The LNT has an effective operating temperature range. When the LNT is near a limit of its effective operating temperature range, the transmission is used to select operating points that increase the LNT's effectiveness. Generally, these operating points reduce the exhaust flow rate, although other factors such as the exhaust temperature may also be taken into account in selecting the operating points. Preferably, the LNT's effective operating temperature-range includes exhaust temperatures produced by the engine at its point of peak power output, whereby the LNT does not approach the limits of its effective operating temperature range except when the engine is at less than peak power. At lower power levels, it is generally possible to select operating points that provide lower exhaust flow rates than the flow rate occurring at the peak power level.
摘要:
The invention relates to a power generation system with a continuously operating fuel reformer. Preferably, the fuel reformer is either off, warming up, or operating with an essentially constant fueling rate. Some of the reformed fuel is intermittently used to regenerate a NOx trap that treats the exhaust of an internal combustion engine. Any reformed fuel not used for other purposes is supplied to a fuel cell. The fuel reformer does not shut down between NOx trap regeneration cycles except when the engine is also shut down. The invention substantially eliminates issues of reformer response time as they relate to NOx trap regeneration.
摘要:
A circular cross-sectional fuel pipe can be prevented from undesired rotation in an engine cylinder head, by a key-key slot combination having a relatively small radial dimension. The key slot is formed by a groove formed in a cylindrical sleeve that is press fit in a counterbore machined in the cylinder head. The mating key can be a ball, or pin, or bar press fit into a side surface of the fuel pipe.