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34 条记录 (耗时 0.023 秒)

    Enantioselective amination and etherification
    1.
    发明授权
    Enantioselective amination and etherification 失效
    对映选择性胺化和醚化

    公开(公告)号：US07732365B2

    公开(公告)日：2010-06-08

    申请号：US10527899

    申请日：2003-09-12

    申请人： John F. Hartwig ,  Chutian Shu ,  Toshimichi Ohmura ,  Christoph Kiener ,  Fernando Garcia Lopez

    发明人： John F. Hartwig ,  Chutian Shu ,  Toshimichi Ohmura ,  Christoph Kiener ,  Fernando Garcia Lopez

    IPC分类号： B01J31/00 ,  B01J27/24 ,  B01J27/00 ,  B01J27/185

    CPC分类号： C07B53/00 ,  B01J31/122 ,  B01J31/186 ,  B01J2231/44 ,  B01J2531/0266 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2531/827 ,  C07B2200/07 ,  C07C209/08 ,  C07C209/16 ,  C07F9/657154 ,  C07F15/0033

    摘要： The present invention is directed to a catalyst composition, comprising: (1) a catalyst precursor having the general structure MSXn wherein M is a transition metal selected from the group consisting of iridium, molybdenum, and tungsten; S is a coordinating ligand; X is a counterion; and n is an integer from 0 to 5; and (2) a phosphoramidite ligand having the structure wherein O—Cn—O is an aliphatic or aromatic diolate and wherein R1, R2, R3 and R4 are selected from the group consisting of substituted or unsubstituted aryl groups, substituted or unsubstituted heteroaryl groups, substituted or unsubstituted aliphatic groups, and combinations thereof, with the proviso that at least one of R1, R2, R3, or R4 must be a substituted or unsubstituted aryl or heteroaryl group. The present invention is also directed to activated catalysts made from the above catalyst composition, as well as methods of allylic amination and etherification using the above catalysts.

    摘要翻译： 本发明涉及一种催化剂组合物，其包括：（1）具有一般结构MSXn的催化剂前体，其中M是选自铱，钼和钨的过渡金属; S是配位配体; X是抗衡离子 n为0〜5的整数。 和（2）具有以下结构的亚磷酰胺配体，其中O-Cn-O是脂族或芳族二醇酯，并且其中R 1，R 2，R 3和R 4选自取代或未取代的芳基，取代或未取代的杂芳基， 取代或未取代的脂族基团及其组合，条件是R 1，R 2，R 3或R 4中的至少一个必须是取代或未取代的芳基或杂芳基。 本发明还涉及由上述催化剂组合物制备的活化催化剂，以及使用上述催化剂的烯丙基胺化和醚化的方法。

    Enantioselective amination and etherification
    2.
    发明申请
    Enantioselective amination and etherification 失效
    对映选择性胺化和醚化

    公开(公告)号：US20060199728A1

    公开(公告)日：2006-09-07

    申请号：US10527899

    申请日：2003-09-12

    申请人： John Hartwig ,  Chutian Shu ,  Toshimichi Ohmura ,  Christoph Kiener ,  Fernando Lopez

    发明人： John Hartwig ,  Chutian Shu ,  Toshimichi Ohmura ,  Christoph Kiener ,  Fernando Lopez

    IPC分类号： B01J31/00

    CPC分类号： C07B53/00 ,  B01J31/122 ,  B01J31/186 ,  B01J2231/44 ,  B01J2531/0266 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2531/827 ,  C07B2200/07 ,  C07C209/08 ,  C07C209/16 ,  C07F9/657154 ,  C07F15/0033

    摘要： The present invention is directed to a catalyst composition, comprising: (1) a catalyst precursor having the general structure MSXn wherein M is a transition metal selected from the group consisting of iridium, molybdenum, and tungsten; S is a coordinating ligand; X is a counterion; and n is an integer from 0 to 5; and (2) a phosphoramidite ligand having the structure wherein O—Cn—O is an aliphatic or aromatic diolate and wherein R1, R2, R3 and R4 are selected from the group consisting of substituted or unsubstituted aryl groups, substituted or unsubstituted heteroaryl groups, substituted or unsubstituted aliphatic groups, and combinations thereof, with the proviso that at least one of R1, R2, R3, or R4 must be a substituted or unsubstituted aryl or heteroaryl group. The present invention is also directed to activated catalysts made from the above catalyst composition, as well as methods of allylic amination and etherification using the above catalysts.

    摘要翻译： 本发明涉及一种催化剂组合物，其包含：（1）具有一般结构MSX N的催化剂前体，其中M是选自铱，钼和钨的过渡金属; S是配位配体; X是抗衡离子 n为0〜5的整数。 和（2）具有以下结构的亚磷酰胺配体，其中OC n-O是脂族或芳族二醇酯，并且其中R 1，R 2， R 3和R 4选自取代或未取代的芳基，取代或未取代的杂芳基，取代或未取代的脂族基团及其组合，与 条件是R 1，R 2，R 3或R 4中的至少一个必须是取代的 或未取代的芳基或杂芳基。 本发明还涉及由上述催化剂组合物制备的活化催化剂，以及使用上述催化剂的烯丙基胺化和醚化的方法。

    PROCESS FOR PREPARING COPPER-COMPRISING METAL ORGANIC FRAMEWORKS
    7.
    发明申请
    PROCESS FOR PREPARING COPPER-COMPRISING METAL ORGANIC FRAMEWORKS 审中-公开
    制备包含金属有机骨架的方法

    公开(公告)号：US20090306420A1

    公开(公告)日：2009-12-10

    申请号：US12375218

    申请日：2007-07-13

    申请人： Markus Schubert ,  Faruk Oezkirim ,  Christoph Kiener ,  Ulrich Mueller ,  Markus Tonigold

    发明人： Markus Schubert ,  Faruk Oezkirim ,  Christoph Kiener ,  Ulrich Mueller ,  Markus Tonigold

    IPC分类号： C07F1/08

    CPC分类号： C07F1/005

    摘要： The present invention relates to a process for preparing a porous metal organic framework comprising a first and at least one second at least bidentate organic compound coordinated to at least one copper ion, which comprises the steps (a) reaction of a reaction mixture in the liquid phase comprising at least one copper compound and the first at least bidentate organic compound to form an intermediate complex comprising the at least one copper ion and the first at least bidentate organic compound, with the first at least bidentate organic compound being derived from a dicarboxylic acid and having a skeleton which is a hydrocarbon, and (b) reaction of the intermediate complex with the at least second at least bidentate organic compound, with the at least second at least bidentate organic compound being an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons have been replaced by heteroatoms selected from the group consisting of N, O and S, wherein the reaction mixture in step (a) comprises less than a 3-fold excess of formic acid based on the copper of the copper compound used.

    摘要翻译： 本发明涉及一种制备多孔金属有机骨架的方法，所述多孔金属有机骨架包括与至少一种铜离子配位的第一和至少一种第二至少二齿有机化合物，其包括以下步骤：（a）将反应混合物在液体 包含至少一种铜化合物和第一至少二齿有机化合物以形成包含至少一种铜离子和第一至少二齿有机化合物的中间体络合物，第一至少二齿有机化合物衍生自二羧酸 并且具有作为烃的骨架，和（b）中间体络合物与至少第二至少二齿有机化合物的反应，至少第二至少二齿有机化合物是任选取代的单环，双环或多环饱和或 不饱和烃，其中至少两个环碳原子被杂原子所取代 由N，O和S组成，其中步骤（a）中的反应混合物包含基于所使用的铜化合物的铜少于3倍过量的甲酸。

    Process for preparing a support for olefin polymerization catalysts
    8.
    发明授权
    Process for preparing a support for olefin polymerization catalysts 失效
    制备烯烃聚合催化剂载体的方法

    公开(公告)号：US07598201B2

    公开(公告)日：2009-10-06

    申请号：US12086319

    申请日：2006-12-04

    申请人： Christoph Kiener ,  Ingo Treffkorn ,  Guido Funk

    发明人： Christoph Kiener ,  Ingo Treffkorn ,  Guido Funk

    IPC分类号： B01J21/00 ,  C08F4/72 ,  C08F4/44 ,  C08F4/06

    CPC分类号： C08F10/00 ,  B01J21/08 ,  B01J35/08 ,  B01J35/1023 ,  B01J35/1047 ,  B01J37/036 ,  C01B33/16 ,  C01G9/02 ,  C01G23/047 ,  C01G25/02 ,  C01P2004/32 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/82 ,  C08F4/24 ,  C08F4/025

    摘要： The invention relates to a process for preparing an essentially spherical support for olefin polymerization catalysts, which comprises the steps: preparation of a hydrogel comprising a cogel of silicon oxide and at least one further metal oxide, if appropriate, washing of the hydrogel until the content of alkali metal ions is less than 0.1% by weight, based on the weight of solids, extraction of the water from the hydrogel until the water content is less than 5% by weight, based on the total content of liquid, and drying of the hydrogel to form a xerogel. According to the invention, the extraction step comprises at least one first extraction with a first organic solvent which is at least partially miscible with water down to a water content of 50% by weight, followed by at least one second extraction with a second organic solvent which is at least partially miscible with water.

    摘要翻译： 本发明涉及一种制备用于烯烃聚合催化剂的基本上为球形的载体的方法，其包括以下步骤：制备包含氧化硅和至少一种其它金属氧化物的共凝胶的水凝胶（如果合适的话），洗涤水凝胶，直到含量 的碱金属离子的含量小于0.1重量％，基于固体的重量，从水凝胶中提取水直到水含量低于5重量％，基于液体的总含量，并干燥 水凝胶形成干凝胶。 根据本发明，提取步骤包括至少一次首先用第一有机溶剂进行萃取，所述第一有机溶剂至少部分地与水混合至水含量为50重量％，然后用第二有机溶剂至少一次萃取 其至少部分地与水混溶。