摘要:
Provided is a pressure-sensitive adhesive for polarizing plates which can adhere a polarizing plate on a liquid crystal cell with good adhesion durability and has the characteristic that a liquid crystal display device obtained therefrom is less liable to cause light leakage even under the environment of high temperature and high humidity and which makes it possible remove the polarizing plate.The pressure-sensitive adhesive for polarizing plates is prepared by irradiating a pressure-sensitive adhesive material comprising (A) an acrylic base polymer having a weight average molecular weight of 1,000,000 or more comprising a monomer having a hydroxyl group in a monomer composition ratio of 10 mass % or less, (B) an acrylic base polymer having a weight average molecular weight of 1,000,000 or more comprising a monomer having a carboxyl group in a monomer composition ratio of 10 mass % or less and (C) an active energy beam-curable compound with an active energy beam, wherein a mass ratio of the component (A) to the component (B) is 100:1 to 100:50, and a storage elastic modulus (G′) at 23° C. is 0.3 MPa or more.
摘要:
Provided are a pressure-sensitive adhesive for polarizing plates which can apply a polarizing plate on a liquid crystal cell with good adhesion and has the characteristic that a liquid crystal display device obtained therefrom is less liable to cause light leakage even under the environment of high temperature and high humidity and which has a removability and a polarizing plate with the above pressure-sensitive adhesive and a production process for the same. The pressure-sensitive adhesive for polarizing plates is prepared by irradiating a pressure-sensitive adhesive material comprising (A) an acrylic base polymer comprising a monomer having a carboxyl group in a monomer composition ratio of 0.5 mass % or less and (B) an active energy beam-curable compound with an active energy beam and it has a storage elastic modulus (G′) of 0.3 MPa or more at 23° C.
摘要:
Provided is a pressure-sensitive adhesive for polarizing plates which can adhere a polarizing plate on a liquid crystal cell with good adhesion durability and has the characteristic that a liquid crystal display device obtained therefrom is less liable to cause light leakage even under the environment of high temperature and high humidity and which makes it possible remove the polarizing plate.The pressure-sensitive adhesive for polarizing plates is prepared by irradiating a pressure-sensitive adhesive material comprising (A) an acrylic base polymer having a weight average molecular weight of 1,000,000 or more comprising a monomer having a hydroxyl group in a monomer composition ratio of 10 mass % or less, (B) an acrylic base polymer having a weight average molecular weight of 1,000,000 or more comprising a monomer having a carboxyl group in a monomer composition ratio of 10 mass % or less and (C) an active energy beam-curable compound with an active energy beam, wherein a mass ratio of the component (A) to the component (B) is 100:1 to 100:50, and a storage elastic modulus (G′) at 23° C. is 0.3 MPa or more.
摘要:
Provided are a pressure-sensitive adhesive for polarizing plates which can apply a polarizing plate on a liquid crystal cell with good adhesion and has the characteristic that a liquid crystal display device obtained therefrom is less liable to cause light leakage even under the environment of high temperature and high humidity and which has a removability and a polarizing plate with the above pressure-sensitive adhesive and a production process for the same.The pressure-sensitive adhesive for polarizing plates is prepared by irradiating a pressure-sensitive adhesive material comprising (A) an acrylic base polymer comprising a monomer having a carboxyl group in a monomer composition ratio of 0.5 mass % or less and (B) an active energy beam-curable compound with an active energy beam, and it has a storage elastic modulus (G′) of 0.3 MPa or more at 23° C.
摘要:
The disclosed a pressure sensitive adhesive for polarizing plates which has a storage elastic modulus (G′) at 23° C. of at least 0.3 MPa; a polarizing plate having a pressure sensitive adhesive; a process for producing the above polarizing plate which comprises sticking a polarizing plate on a tacky adhesive material layer formed on a releasing layer of a releasing sheet, and thereafter irradiating with an active energy beam from the releasing sheet side; an optical film which comprises a polarizing plate and a phase difference plate; and a process for producing the above optical film. The pressure sensitive adhesive and polarizing plate having the pressure sensitive adhesive are characterized in that they are capable of sticking with high durability, the polarizing plate to a and phase difference plate, and the resultant liquid crystal display unit is less liable to cause light leakage under the conditions of high temperature.
摘要:
The disclosed a pressure sensitive adhesive for polarizing plates which has a storage elastic modulus (G′) at 23° C. of at least 0.3 MPa; a polarizing plate having a pressure sensitive adhesive; a process for producing the above polarizing plate which comprises sticking a polarizing plate on a tacky adhesive material layer formed on a releasing layer of a releasing sheet, and thereafter irradiating with an active energy beam from the releasing sheet side; an optical film which comprises a polarizing plate and a phase difference plate; and a process for producing the above optical film. The pressure sensitive adhesive and polarizing plate having the pressure sensitive adhesive are characterized in that they are capable of sticking with high durability, the polarizing plate to a and phase difference plate, and the resultant liquid crystal display unit is less liable to cause light leakage under the conditions of high temperature.
摘要:
According to the present invention, there can be obtained a pressure sensitive adhesive sheet having an adhesive layer which even when the thickness is reduced to 5 μm or less, exhibits a desired adhesive strength. The pressure sensitive adhesive sheet includes a base material having an adhesive layer provided on at least one surface thereof, wherein a pressure sensitive adhesive constituting the adhesive layer contains (A) an acrylic copolymer having a crosslinkable functional group and (B) a urethane resin, the urethane resin is a product obtained by allowing an isocyanate-terminated urethane prepolymer obtained by a reaction between [b1] a diol and [b2] a polyvalent isocyanate compound to react with [b3] a chain extender, and the chain extender is composed of [b4] a compound having two hydroxyl groups and/or amino groups and [b5] a compound having three or more hydroxyl groups and/or amino groups, in a proportion of [b4] to [b5] of from 7/3 to 10/0 in terms of a mass ratio.
摘要:
The present invention relates to a pressure sensitive adhesive sheet including a pressure sensitive adhesive layer on at least one surface of a base material, wherein the pressure sensitive adhesive layer is made of a two-layer structure of a first pressure sensitive adhesive layer and a second pressure sensitive adhesive layer in this order from the side of the base material; a first pressure sensitive adhesive constituting the first pressure sensitive adhesive layer has a loss tangent (tan δ) value at 0° C. of 0.25 or more and a storage elastic modulus value at 0° C. of from 0.01 to 0.80 MPa; and a resin component contained in a second pressure sensitive adhesive constituting the second pressure sensitive adhesive layer contains from 10 to 100 t by mass of an acrylic copolymer having a crosslinkable functional group. The pressure sensitive adhesive sheet according to the present invention exhibits an excellent adhesive strength even when the pressure sensitive adhesive layer is reduced in thickness.
摘要:
An adhesive composition for a semiconductor includes an acrylic polymer (A), an epoxy-based heat curable resin (B), a heat curing agent (C), a silane compound (D) having an organic functional group, molecular weight of 300 or more and an alkoxy equivalent of larger than 13 mmol/g, and a silane compound (E) having an organic functional group, molecular weight of 300 or less and an alkoxy equivalent of 13 mmol/g or less.
摘要:
A pressure-sensitive adhesive layer of pressure-sensitive adhesive sheet is formed by using: a pressure-sensitive adhesive composition comprising (A) a polyrotaxane having a linear-chain molecule passing through opening portions of at least two cyclic molecules, the cyclic molecules having a reactive group, the polyrotaxane having blocking groups at both ends of the linear-chain molecule, and (B) a pressure-sensitive adhesive polymer having two or more functional groups capable of reacting with the reactive group; or, a pressure-sensitive adhesive composition comprising (A) a polyrotaxane having a linear-chain molecule passing through opening portions of at least two cyclic molecules, the cyclic molecules having a reactive group, the polyrotaxane having blocking groups at both ends of the linear-chain molecule, (B′) a pressure-sensitive adhesive polymer having two or more reactive groups, and (C) a compound having two or more functional groups capable of reacting with the reactive group of the polyrotaxane (A) and the reactive groups of the polymer (B′). As a result there can be provided a pressure-sensitive adhesive sheet comprising a pressure-sensitive adhesive layer excellent in flexibility and having high gel fraction and durability, and a pressure-sensitive adhesive composition that constitutes the pressure-sensitive adhesive layer.