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    Oligomerization of olefins to highly linear oligomers, and catalysts for this purpose
    9.
    发明授权
    Oligomerization of olefins to highly linear oligomers, and catalysts for this purpose 失效
    将烯烃低聚成高度线性的低聚物，为此目的使用催化剂

    公开(公告)号：US5849972A

    公开(公告)日：1998-12-15

    申请号：US646298

    申请日：1996-05-16

    申请人： Maximilian Vicari ,  Peter Polanek

    发明人： Maximilian Vicari ,  Peter Polanek

    IPC分类号： B01J23/78 ,  C07C2/10 ,  C07C11/02 ,  C08F4/26 ,  C08F4/64 ,  C08F4/70 ,  C08F4/80 ,  C08F10/00 ,  C10G50/00 ,  C07C2/02 ,  B01J23/00

    CPC分类号： B01J23/755 ,  B01J37/031 ,  C07C2/10 ,  C08F10/00 ,  B01J37/0009 ,  B01J37/0045 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/755

    摘要： Straight-chain C.sub.2 -C.sub.6 -olefins are oligomerized to their dimers, trimers and tetramers by means of a fixed-bed catalyst, at superatmospheric pressure and at room temperature or elevated temperatures, by a process in which the catalyst used is one which contains, as active components, after deduction of the loss on ignition following heating at 900.degree. C., from 10 to 70% by weight of nickel oxide, calculated as NiO, from 5 to 30% by weight of titanium dioxide or zirconium dioxide, from 0 to 20% by weight of alumina, from 20 to 40% by weight of silica and from 0.01 to 1% by weight of an alkali metal oxide, with the proviso that the contents of the individual components in the catalyst sum to 100% by weight.

    摘要翻译： PCT No.PCT / EP94 / 03838 Sec。 371日期：1996年5月16日 102（e）日期1996年5月16日PCT 1994年11月21日PCT PCT。 公开号WO95 / 14647 日期：1995年6月1日直链C 2 -C 6烯烃通过固定床催化剂在超大气压和室温或高温下通过使用催化剂的方法低聚至其二聚体，三聚体和四聚体 是在900℃下加热后的灼烧损失扣除10至70重量％的以NiO计的氧化镍，5至30重量％的二氧化钛或 二氧化锆，0至20重量％的氧化铝，20至40重量％的二氧化硅和0.01至1重量％的碱金属氧化物，条件是催化剂中各组分的含量总和 至100重量％。

    Process for preparing acetylene by the Sachsse-Bartholomé process
    10.
    发明授权
    Process for preparing acetylene by the Sachsse-Bartholomé process 有权
    通过Sachsse-Bartholomé工艺制备乙炔的方法

    公开(公告)号：US08975460B2

    公开(公告)日：2015-03-10

    申请号：US13183683

    申请日：2011-07-15

    申请人： Lucia Königsmann ,  Maximilian Vicari ,  Thomas Heidemann ,  Dirk Groβschmidt ,  Jürgen Michel

    发明人： Lucia Königsmann ,  Maximilian Vicari ,  Thomas Heidemann ,  Dirk Groβschmidt ,  Jürgen Michel

    IPC分类号： C07C5/02 ,  C07C5/03 ,  C07C2/78

    CPC分类号： C07C2/78 ,  C07C11/24

    摘要： A process is proposed for preparing acetylene by the Sachsse-Bartholomé process by combustion of a natural gas/oxygen mixture in one or more burners to obtain a cracking gas which is cooled in two or more stages in burner columns, each burner having one or more burner columns assigned thereto, and said cracking gas being quenched with pyrolysis oil in the first cooling stage, to obtain a low boiler fraction comprising benzene, toluene and xylene from the one or more burner columns, which is cooled with direct cooling water and separated in a phase separator into an aqueous phase and an organic phase which comprises benzene, toluene and xylene and is fully or partly introduced to the top of the one or more burner columns as a return stream, wherein the organic phase comprising benzene, toluene and xylene from the phase separator, prior to full or partial recycling to the top of the one or more burner columns, is supplied to a selective hydrogenation over a catalyst which comprises at least one platinum group metal on an inorganic metal oxide as support, comprising 0.05 to 5% by weight of platinum group metal, based on the total weight of the catalyst, and wherein the selective hydrogenation is performed at a pressure in the range from 10 to 70 bar gauge and a temperature in the range from 0 to 100° C.

    摘要翻译： 提出了一种通过Sachsse-Bartholomé方法通过在一个或多个燃烧器中燃烧天然气/氧气混合物来制备乙炔的方法，以获得在燃烧器柱中两级或更多级冷却的裂化气体，每个燃烧器具有一个或多个 燃烧器列，并且在第一冷却阶段，所述裂解气体用热解油淬火，以从一个或多个燃烧器柱获得包含苯，甲苯和二甲苯的低沸点馏分，其用直接冷却水冷却并分离 相分离器进入水相和有机相，其包含苯，甲苯和二甲苯，并作为回流完全或部分地引入到一个或多个燃烧器塔的顶部，其中有机相包含苯，甲苯和二甲苯 在完全或部分再循环到一个或多个燃烧器塔的顶部之前，将相分离器供应到催化剂上的选择性氢化，所述催化剂包括在l 在一个无机金属氧化物上的一个铂族金属作为载体，包含0.05-5重量％的铂族金属，基于催化剂的总重量，其中选择性氢化在10〜 70巴规，温度范围为0至100℃。