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    Increase in the toughness of a material obtained from a curable composition comprising at least one vinyl ester monomer
    1.
    发明授权
    Increase in the toughness of a material obtained from a curable composition comprising at least one vinyl ester monomer 有权
    由包含至少一种乙烯基酯单体的可固化组合物获得的材料的韧性提高

    公开(公告)号：US08618186B2

    公开(公告)日：2013-12-31

    申请号：US13500844

    申请日：2010-10-08

    Applicant: Mickael Krzeminski ,  Brigitte Defoort ,  Xavier Coqueret

    Inventor： Mickael Krzeminski ,  Brigitte Defoort ,  Xavier Coqueret

    IPC: C08F283/00 ,  C08J3/28 ,  C08L63/10 ,  C08L81/06

    CPC classification number: C08F283/00 ,  C08L63/10 ,  C08L81/06 ,  C09J4/06 ,  C08F220/30 ,  C08F226/06 ,  C08L81/00

    Abstract: A method increases the toughness of a material obtained by curing a composition that includes at least one vinyl ester monomer. The method includes the incorporation into the composition of a sulfonated polyaromatic thermoplastic polymer, which is achieved by dissolving the vinyl ester monomer and the thermoplastic polymer in a reactive diluent in which they are both soluble. The resulting curable composition includes at least one vinyl ester monomer, and very high toughness materials can be made from it. A curable composition can include at least one vinyl ester monomer, a sulfonated polyaromatic thermoplastic polymer and a N-vinyl lactam. The compositions can be used in the aeronautical, space, railway, nautical, automotive industries, arms and other industries.

    Abstract translation: 一种方法提高了通过固化包含至少一种乙烯酯单体的组合物获得的材料的韧性。 该方法包括通过将乙烯基酯单体和热塑性聚合物溶解在它们都可溶的反应性稀释剂中而实现的将磺化多芳族热塑性聚合物掺入组合物中。 得到的可固化组合物包括至少一种乙烯基酯单体，并且可以从其制备非常高韧性的材料。 可固化组合物可以包括至少一种乙烯基酯单体，磺化多芳族热塑性聚合物和N-乙烯基内酰胺。 该组合物可用于航空，航天，铁路，航海，汽车工业，武器等行业。

    INCREASE IN THE TOUGHNESS OF A MATERIAL OBTAINED FROM A CURABLE COMPOSITION COMPRISING AT LEAST ONE VINYL ESTER MONOMER
    2.
    发明申请
    INCREASE IN THE TOUGHNESS OF A MATERIAL OBTAINED FROM A CURABLE COMPOSITION COMPRISING AT LEAST ONE VINYL ESTER MONOMER 有权
    从包含至少一个乙烯基单体的可固化组合物获得的材料的粗糙度增加

    公开(公告)号：US20120277383A1

    公开(公告)日：2012-11-01

    申请号：US13500844

    申请日：2010-10-08

    Applicant: Mickael Krzeminski ,  Brigitte Defoort ,  Xavier Coqueret

    Inventor： Mickael Krzeminski ,  Brigitte Defoort ,  Xavier Coqueret

    IPC: C08L81/06

    CPC classification number: C08F283/00 ,  C08L63/10 ,  C08L81/06 ,  C09J4/06 ,  C08F220/30 ,  C08F226/06 ,  C08L81/00

    Abstract: A method increases the toughness of a material obtained by curing a composition that includes at least one vinyl ester monomer. The method includes the incorporation into the composition of a sulfonated polyaromatic thermoplastic polymer, which is achieved by dissolving the vinyl ester monomer and the thermoplastic polymer in a reactive diluent in which they are both soluble. The resulting curable composition includes at least one vinyl ester monomer, and very high toughness materials can be made from it. A curable composition can include at least one vinyl ester monomer, a sulfonated polyaromatic thermoplastic polymer and a N-vinyl lactam. The compositions can be used in the aeronautical, space, railway, nautical, automotive industries, arms and other industries.

    Abstract translation: 一种方法提高了通过固化包含至少一种乙烯酯单体的组合物获得的材料的韧性。 该方法包括通过将乙烯基酯单体和热塑性聚合物溶解在它们都可溶的反应性稀释剂中而实现的将磺化多芳族热塑性聚合物掺入组合物中。 得到的可固化组合物包括至少一种乙烯基酯单体，并且可以从其制备非常高韧性的材料。 可固化组合物可以包括至少一种乙烯基酯单体，磺化多芳族热塑性聚合物和N-乙烯基内酰胺。 该组合物可用于航空，航天，铁路，航海，汽车工业，武器等行业。

    Method for enhancing adherence of carbon fibers with respect to an organic matrix
    3.
    发明授权
    Method for enhancing adherence of carbon fibers with respect to an organic matrix 有权
    提高碳纤维相对于有机基质的附着力的方法

    公开(公告)号：US08328977B2

    公开(公告)日：2012-12-11

    申请号：US12065983

    申请日：2006-09-15

    Applicant: Brigitte Defoort ,  Philippe Ponsaud ,  Xavier Coqueret

    Inventor： Brigitte Defoort ,  Philippe Ponsaud ,  Xavier Coqueret

    IPC: C09J163/00 ,  C08F24/00 ,  C08F124/00 ,  C08F224/00

    CPC classification number: D01F11/16 ,  C08J5/06 ,  D01F11/14 ,  D06M14/36 ,  D06M2101/40 ,  D06M2200/50

    Abstract: The invention relates to a process for improving the adhesion of carbon fibres with regard to an organic matrix forming a composite material with these fibres, this composite material being obtained by bringing the fibres into contact with a resin which can be cured by chain polymerization and then polymerizing the resin, which process is characterized in that it comprises the grafting, to the surface of the fibres, before they are brought into contact with the resin, of groups capable of acting as chain transfer agents during the polymerization of said resin.Fields of application: aeronautical, aerospatial, railway, ship building and automobile industries but also the armaments industry, the industry of sports and leisure articles, and the like.

    Abstract translation: 本发明涉及一种改善碳纤维与这些纤维形成复合材料的有机基质的粘附性的方法，该复合材料通过使纤维与可通过链聚合固化的树脂接触而获得，然后 使树脂聚合，其特征在于它包括在与所述树脂接触的同时，在所述树脂的聚合期间将能够作为链转移剂的基团接枝到纤维的表面。 应用领域：航空，航空航天，铁路，船舶建筑和汽车工业，还有军工业，体育休闲用品行业等。

    Method For Enhancing Adherence of Carbon Fibers With Respect to an Organic Matrix
    4.
    发明申请
    Method For Enhancing Adherence of Carbon Fibers With Respect to an Organic Matrix 有权
    提高碳纤维对有机矩阵的粘附性的方法

    公开(公告)号：US20080255332A1

    公开(公告)日：2008-10-16

    申请号：US12065983

    申请日：2006-09-15

    Applicant: Brigitte Defoort ,  Philippe Ponsaud ,  Xavier Coqueret

    Inventor： Brigitte Defoort ,  Philippe Ponsaud ,  Xavier Coqueret

    IPC: C08F24/00

    CPC classification number: D01F11/16 ,  C08J5/06 ,  D01F11/14 ,  D06M14/36 ,  D06M2101/40 ,  D06M2200/50

    Abstract: The invention relates to a process for improving the adhesion of carbon fibres with regard to an organic matrix forming a composite material with these fibres, this composite material being obtained by bringing the fibres into contact with a resin which can be cured by chain polymerization and then polymerizing the resin, which process is characterized in that it comprises the grafting, to the surface of the fibres, before they are brought into contact with the resin, of groups capable of acting as chain transfer agents during the polymerization of said resin.Fields of application: aeronautical, aerospatial, railway, ship building and automobile industries but also the armaments industry, the industry of sports and leisure articles, and the like.

    Abstract translation: 本发明涉及一种改善碳纤维与这些纤维形成复合材料的有机基质的粘附性的方法，该复合材料通过使纤维与可通过链聚合固化的树脂接触而获得，然后 使树脂聚合，其特征在于它包括在与所述树脂接触的同时，在所述树脂的聚合期间将能够作为链转移剂的基团接枝到纤维的表面。 应用领域：航空，航空航天，铁路，船舶建筑和汽车工业，还有军工业，体育休闲用品行业等。

    Rigidification of structures to be deployed by inflating, particularly for use in space
    6.
    发明授权
    Rigidification of structures to be deployed by inflating, particularly for use in space 有权
    通过膨胀，特别是用于空间来部署的结构的刚性

    公开(公告)号：US08025942B2

    公开(公告)日：2011-09-27

    申请号：US11577758

    申请日：2005-10-20

    Applicant: Brigitte Defoort ,  Xavier Coqueret ,  Dominique Lacour

    Inventor： Brigitte Defoort ,  Xavier Coqueret ,  Dominique Lacour

    IPC: B32B27/12 ,  B32B27/14

    CPC classification number: C08G59/68 ,  Y10T428/13 ,  Y10T428/1303 ,  Y10T428/1352 ,  Y10T428/1359 ,  Y10T428/139 ,  Y10T428/31721 ,  Y10T428/31786

    Abstract: The invention relates to the stiffening of inflatably deployable structures, in particular for space use.More specifically, the invention relates to a flexible membrane for inflatably deployable structures, that comprises one layer of a composite and at least one polymer film that is permeable to visible radiation covering one of the faces of this layer, said composite being formed from a fibrous material impregnated with a composition incorporating an epoxide or epoxy/acrylate resin and a photoinitiator, and which is characterized in that the photoinitiator is an iron-arene complex salt of general formula (I): where A is an arene group, while X is a non-nucleophilic anion. Applications: manufacture of devices of the following types: radars, solar panels, reflectors, solar shields, antennas, solar mirrors or sails, intended to equip orbital vehicles or vehicles for space or planetary exploration.

    Abstract translation: 本发明涉及可膨胀展开结构的加强，特别是用于空间使用。 更具体地，本发明涉及一种用于可膨胀展开结构的柔性膜，其包括一层复合材料和至少一层聚合物膜，该聚合物膜可透过该层的一个表面的可见辐射，所述复合材料由纤维状 浸渍有包含环氧化物或环氧/丙烯酸酯树脂和光引发剂的组合物的材料，其特征在于光引发剂是通式（I）的铁 - 芳烃络合盐：其中A是芳族基团，而X是 非亲核阴离子。 应用：制造以下类型的设备：雷达，太阳能电池板，反射器，太阳能屏蔽，天线，太阳能反射镜或帆，旨在配备轨道车辆或车辆进行太空或行星探测。

    USE OF POLYMERISABLE RESINS WITH LOW VACUUM OUTGASSING FOR THE MANUFACTURE OF COMPOSITE MATERIALS FOR USE IN SPACE
    7.
    发明申请
    USE OF POLYMERISABLE RESINS WITH LOW VACUUM OUTGASSING FOR THE MANUFACTURE OF COMPOSITE MATERIALS FOR USE IN SPACE 审中-公开
    使用具有低真空度的聚合树脂用于制造复合材料用于空间的材料

    公开(公告)号：US20110207378A1

    公开(公告)日：2011-08-25

    申请号：US13059957

    申请日：2009-08-26

    Applicant: Brigitte Defoort ,  Roman Mahias ,  Dominiqu Lacour ,  Xavier Coqueret ,  Marion Mille

    Inventor： Brigitte Defoort ,  Roman Mahias ,  Dominiqu Lacour ,  Xavier Coqueret ,  Marion Mille

    IPC: B32B27/04 ,  B32B27/38 ,  C08F136/06 ,  C08F236/14 ,  C08L61/14 ,  C08L9/00 ,  C08K3/34

    CPC classification number: C08L83/06 ,  C08G59/027 ,  C08G59/08 ,  C08G59/688 ,  C08J5/24 ,  C08J2363/08 ,  C08J2383/06 ,  C08J2391/00 ,  C08L63/00 ,  C08L63/04 ,  C08L63/08 ,  C08L91/00 ,  Y10T442/10 ,  C08L83/00 ,  C08L2666/22 ,  C08L2666/02

    Abstract: A method of using at least one polymerisable resin R1 is disclosed. According to some aspects, the resin R1 is selected from the group consisting of epoxidised polybutadiene resins, epoxidised polyisoprene resins, epoxidised polysiloxane resins, epoxidised triglyceride resins and epoxidised polyether resins. The resin R1 having at the non-polymerised state a total mass loss (TML) value lower than about 10%, a recovered mass loss (RML) value lower than about 10%, and a collected volatile condensable material (CVCM) value lower than about 1%, as determined in accordance with standard ECSS-Q-70-02A of the European Space Agency. The resin R1 also characterized by an epoxide equivalent weight of about 100 to 600 g/mole. The resin is configured for the manufacture of a composite material for use in space, and more specifically, a composite material of a Gossamer structure. Polymerisable resin compositions are also disclosed which are useful in the manufacture of composite materials for use in space.

    Abstract translation: 公开了使用至少一种可聚合树脂R1的方法。 根据一些方面，树脂R1选自环氧化聚丁二烯树脂，环氧化聚异戊二烯树脂，环氧化聚硅氧烷树脂，环氧化甘油三酯树脂和环氧化聚醚树脂。 具有非聚合状态的树脂R1的总质量损失（TML）值低于约10％，回收质量损失（RML）值低于约10％，收集的挥发性可冷凝材料（CVCM）值低于 约1％，按照欧洲航天局ECSS-Q-70-02A标准确定。 树脂R1的特征还在于环氧当量为约100至600g / mol。 该树脂构造用于制造用于空间的复合材料，更具体地说，是一种高斯马克结构的复合材料。 还公开了可用于制造用于空间的复合材料的可聚合树脂组合物。

    RIGIDIFICATION OF STRUCTURES TO BE DEPLOYED BY INFLATING, PARTICULARLY FOR USE IN SPACE
    8.
    发明申请
    RIGIDIFICATION OF STRUCTURES TO BE DEPLOYED BY INFLATING, PARTICULARLY FOR USE IN SPACE 有权
    通过自由化，特别是在空间中使用的结构的消除

    公开(公告)号：US20090075091A1

    公开(公告)日：2009-03-19

    申请号：US11577758

    申请日：2005-10-20

    Applicant: Brigitte Defoort ,  Xavier Coqueret ,  Dominique Lacour

    Inventor： Brigitte Defoort ,  Xavier Coqueret ,  Dominique Lacour

    IPC: B32B17/10 ,  B32B27/36 ,  B29C71/02

    CPC classification number: C08G59/68 ,  Y10T428/13 ,  Y10T428/1303 ,  Y10T428/1352 ,  Y10T428/1359 ,  Y10T428/139 ,  Y10T428/31721 ,  Y10T428/31786

    Abstract: The invention relates to the stiffening of inflatably deployable structures, in particular for space use.More specifically, the invention relates to a flexible membrane for inflatably deployable structures, that comprises one layer of a composite and at least one polymer film that is permeable to visible radiation covering one of the faces of this layer, said composite being formed from a fibrous material impregnated with a composition incorporating an epoxide or epoxy/acrylate resin and a photoinitiator, and which is characterized in that the photoinitiator is an iron-arene complex salt of general formula (I): where A is an arene group, while X is a non-nucleophilic anion.Applications; manufacture of devices of the following types: radars, solar panels, reflectors, solar shields, antennas, solar mirrors or sails, intended to equip orbital vehicles or vehicles for space or planetary exploration.

    Abstract translation: 本发明涉及可膨胀展开结构的加强，特别是用于空间使用。 更具体地，本发明涉及一种用于可膨胀展开结构的柔性膜，其包括一层复合材料和至少一层聚合物膜，该聚合物膜可透过该层的一个表面的可见辐射，所述复合材料由纤维状 浸渍有包含环氧化物或环氧/丙烯酸酯树脂和光引发剂的组合物的材料，其特征在于光引发剂是通式（I）的铁 - 芳烃络合盐：其中A是芳族基团，而X是 非亲核阴离子。 应用; 制造以下类型的设备：雷达，太阳能电池板，反射器，太阳能屏蔽，天线，太阳能反射镜或帆，旨在为轨道车辆或车辆进行空间或行星探测。

    Method for improving mechanical strength of bondings made with an adhesive based on curable resin by chain polymerization
    10.
    发明授权
    Method for improving mechanical strength of bondings made with an adhesive based on curable resin by chain polymerization 失效
    用于通过链式聚合提高用基于可固化树脂的粘合剂制成的粘结机械强度的方法

    公开(公告)号：US08282764B2

    公开(公告)日：2012-10-09

    申请号：US12299044

    申请日：2007-05-10

    Applicant: Brigitte Defoort ,  Philippe Ponsaud ,  Xavier Cocqueret

    Inventor： Brigitte Defoort ,  Philippe Ponsaud ,  Xavier Cocqueret

    IPC: B32B37/12

    CPC classification number: C09J5/02 ,  C09J2463/006

    Abstract: The invention relates to a process that makes it possible to improve the mechanical strength of bonds between substrates when these bonds are produced by means of an adhesive that comprises a resin that can be cured by chain polymerization, and in particular a resin that can be cured under the effect of ionizing or light radiation.This process is characterized in that it comprises the grafting of groups capable of acting as chain transfer agents during the polymerization of said resin to the surface of the substrates, before the latter are brought into contact with the adhesive.Applications: assembling of structural, engine, passenger compartment or bodywork parts in the aeronautical, space, railway, ship-building and automotive industries.

    Abstract translation: 本发明涉及一种方法，其可以通过包含可通过链式聚合固化的树脂的粘合剂生产这些粘合剂，特别是能够固化的树脂，从而提高基材之间的粘结的机械强度 在电离或光辐射的作用下。 该方法的特征在于，在将所述树脂与粘合剂接触之前，其包括在所述树脂聚合成基材表面期间能够作为链转移剂的基团的接枝。 应用：航空，太空，铁路，造船和汽车行业的结构，发动机，客舱或车身部件的组装。

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