公开(公告)号：US08759598B2

公开(公告)日：2014-06-24

申请号：US13291290

申请日：2011-11-08

申请人： Mikio Hayashi ,  Masashi Yamaguchi ,  Yumiko Yoshikawa ,  Takahiko Takewaki ,  Tohru Setoyama

发明人： Mikio Hayashi ,  Masashi Yamaguchi ,  Yumiko Yoshikawa ,  Takahiko Takewaki ,  Tohru Setoyama

IPC分类号： C07C11/06 ,  C07C2/00 ,  C07C2/06 ,  C07C2/02 ,  C07C2/12

CPC分类号： B01J29/70 ,  B01J35/002 ,  B01J2229/12 ,  B01J2229/36 ,  C07C2/76 ,  Y02P20/52 ,  C07C11/06

摘要： An object of the present invention is to provide a process of producing propylene by contacting ethylene with a catalyst, where propylene is produced with high selectivity. The present invention relates to a production process of propylene, comprising contacting ethylene with a catalyst, wherein the catalyst comprises a zeolite as an active ingredient and an acid content in the outer surface of the zeolite is 5 % or less based on an acid content of the entire zeolite.

摘要翻译： 本发明的目的是提供一种通过使乙烯与催化剂接触来制备丙烯的方法，其中以高选择性制备丙烯。 本发明涉及丙烯的生产方法，包括使乙烯与催化剂接触，其中催化剂包含沸石作为活性成分，沸石外表面的酸含量基于酸的含量为5％以下 整个沸石。

公开(公告)号：US08647999B2

公开(公告)日：2014-02-11

申请号：US13370778

申请日：2012-02-10

申请人： Mikio Hayashi ,  Masahiro Hara ,  Masashi Yamaguchi ,  Yumiko Yoshikawa ,  Takahiko Takewaki ,  Tohru Setoyama ,  Naoyuki Sakamoto

发明人： Mikio Hayashi ,  Masahiro Hara ,  Masashi Yamaguchi ,  Yumiko Yoshikawa ,  Takahiko Takewaki ,  Tohru Setoyama ,  Naoyuki Sakamoto

IPC分类号： B01J38/10 ,  C07C2/02

CPC分类号： B01J31/403 ,  B01J29/061 ,  B01J29/7015 ,  B01J29/723 ,  B01J29/783 ,  B01J29/90 ,  B01J35/1057 ,  B01J37/0063 ,  B01J37/0201 ,  B01J2229/186 ,  B01J2229/32 ,  B01J2229/42 ,  C07C6/04 ,  C07C2529/70 ,  Y02P20/52 ,  Y02P20/584 ,  C07C11/06

摘要： A method for manufacturing a catalyst, which comprises regenerating a catalyst comprising a CHA zeolite as an active ingredient and having an ethylene conversion lowered through reaction of producing propylene by bringing into contact with ethylene in a vapor phase, by bringing the catalyst into contact with a gas which does not comprise oxygen and comprises hydrogen having a hydrogen partial pressure of 0.01 MPa or more as an absolute pressure thereof.

摘要翻译： 一种催化剂的制造方法，其特征在于，使含有CHA沸石作为活性成分的催化剂再生，通过与气相中的乙烯接触而使丙烯反应生成乙烯转化率降低，通过使催化剂与 不含氧的气体，其氢分压为0.01MPa以上的氢为绝对压力。

公开(公告)号：US20120059139A1

公开(公告)日：2012-03-08

申请号：US13291290

申请日：2011-11-08

申请人： Mikio HAYASHI ,  Masashi Yamaguchi ,  Yumiko Yoshikawa ,  Takahiko Takewaki ,  Tohru Setoyama

发明人： Mikio HAYASHI ,  Masashi Yamaguchi ,  Yumiko Yoshikawa ,  Takahiko Takewaki ,  Tohru Setoyama

IPC分类号： C08F110/06 ,  C01B39/02 ,  C07C2/00

CPC分类号： B01J29/70 ,  B01J35/002 ,  B01J2229/12 ,  B01J2229/36 ,  C07C2/76 ,  Y02P20/52 ,  C07C11/06

摘要： An object of the present invention is to provide a process of producing propylene by contacting ethylene with a catalyst, where propylene is produced with high selectivity. The present invention relates to a production process of propylene, comprising contacting ethylene with a catalyst, wherein the catalyst comprises a zeolite as an active ingredient and an acid content in the outer surface of the zeolite is 5% or less based on an acid content of the entire zeolite.

摘要翻译： 本发明的目的是提供一种通过使乙烯与催化剂接触来制备丙烯的方法，其中以高选择性制备丙烯。 本发明涉及丙烯的生产方法，包括使乙烯与催化剂接触，其中催化剂包含沸石作为活性成分，沸石外表面的酸含量基于酸的含量为5％以下 整个沸石。

公开(公告)号：US5157179A

公开(公告)日：1992-10-20

申请号：US726199

申请日：1991-07-05

申请人： Tohru Setoyama ,  Takahiko Takewaki ,  Takao Maki

发明人： Tohru Setoyama ,  Takahiko Takewaki ,  Takao Maki

IPC分类号： B01J23/46 ,  B01J23/656 ,  B01J32/00 ,  B01J35/10 ,  C07B61/00 ,  C07C5/11 ,  C07C13/20

CPC分类号： C07C5/11 ,  B01J23/462 ,  B01J35/1038 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1076 ,  B01J35/108 ,  C07C2101/16

摘要： A method for producing a cycloolefin which comprises partially hydrogenating an aromatic hydrocarbon with hydrogen in a liquid phase in the presence of water and a catalyst having as main component ruthenium supported on a carrier, to form the corresponding cycloolefin, wherein an oxide with the total pore volume of pores having radii of from 20 to 100,000 .ANG. being from 0.3 to 10 cc/g and with the volume of pores having radii of from 20 to 200 .ANG. constituting at most 15% of the total pore volume, is used as the carrier for the catalyst.

公开(公告)号：US08815388B2

公开(公告)日：2014-08-26

申请号：US13727335

申请日：2012-12-26

申请人： Masanori Yamazaki ,  Takahiko Takewaki ,  Ritsuko Yamauchi ,  Yuuichi Katou ,  Atsushi Takaki

发明人： Masanori Yamazaki ,  Takahiko Takewaki ,  Ritsuko Yamauchi ,  Yuuichi Katou ,  Atsushi Takaki

IPC分类号： G02B1/04 ,  C08K3/00 ,  C08K7/00 ,  C08L33/02 ,  C08L63/00 ,  C08L83/00 ,  C08K3/22 ,  C08F2/44 ,  B32B27/20 ,  C08K5/37 ,  C08K5/00

CPC分类号： G02B1/045 ,  C08F2/44 ,  C08K3/22 ,  C08K5/005 ,  C08K5/37 ,  C08K7/00 ,  C08L63/00 ,  G02B1/04 ,  Y10T428/25 ,  Y10T428/26 ,  Y10T428/269 ,  C08L81/00 ,  C08F220/20 ,  C08F2222/1093 ,  C08F230/02

摘要： The invention relates to an inorganic-organic hybrid material which comprises an inorganic component and an organic component, has a content of the inorganic component of 20-80% by mass, and has a refractive index of 1.60 or higher, wherein, when preparing a strip specimen having a thickness of 1,000 μm, a width of 5 mm and a length of 70 mm by using the inorganic-organic hybrid material and winding the specimen by 180° on a cylindrical metal rod having a diameter of 10 mm at 25° C., the specimen does not crack.

摘要翻译： 本发明涉及无机组分和有机组分的无机 - 有机杂化材料，其无机组分的含量为20-80质量％，折射率为1.60以上，其中，当制备 通过使用无机 - 有机杂化材料，将厚度为1000μm，宽度为5mm，长度为70mm的带状试样，并将试样卷绕180°，在25℃的直径为10mm的圆筒形金属棒上 ，样品不破裂。

公开(公告)号：US07527777B2

公开(公告)日：2009-05-05

申请号：US11311562

申请日：2005-12-20

申请人： Hiromu Watanabe ,  Takahiko Takewaki ,  Masanori Yamazaki ,  Hiroyuki Kakiuchi ,  Kouji Inagaki ,  Atsushi Kosaka ,  Norikazu Hosokawa

发明人： Hiromu Watanabe ,  Takahiko Takewaki ,  Masanori Yamazaki ,  Hiroyuki Kakiuchi ,  Kouji Inagaki ,  Atsushi Kosaka ,  Norikazu Hosokawa

IPC分类号： C01B37/04 ,  C01B37/06 ,  C01B37/08 ,  F25B15/00 ,  F28D20/00 ,  F28F23/00 ,  F28F21/00

CPC分类号： B82Y30/00 ,  B01J20/0292 ,  B01J20/18 ,  B82Y10/00 ,  C01B37/04 ,  C01B37/06 ,  C01B37/08 ,  C01B39/54 ,  F25B17/08 ,  Y02P20/129 ,  Y10S423/30

摘要： Subjects for the invention are to provide a zeolite reduced in performance deterioration in repetitions of use or during long-term use and a process for producing the same and to provide an adsorbent comprising the zeolite and a heat utilization system or the like employing the adsorbent.The invention relates to a zeolite which has a framework density of from 10 T/nm3 to 16 T/nm3 and a carbon content of from 1% by weight to 6% by weight and satisfies the following (1) or (2): (1) the zeolite is an aluminophosphate which has a nitrogen content of from 0.5% by weight to 12% by weight and in which the aluminum may be partly replaced by Me; (2) the zeolite is a silicoaluminophosphate in which the aluminum may be partly replaced by Me and which, when burned to a carbon content lower than 0.3% by weight, retains the framework structure possessed by the silicoaluminophosphate before the burning: (provided that Me in (1) and (2) above is at least one element selected from the elements in Groups 2A, 7A, 8, 1B, and 2B of the periodic table).

摘要翻译： 本发明的目的是提供在使用重复或长期使用中降低性能劣化的沸石及其制备方法，并提供使用该吸附剂的沸石的吸附剂和热利用系统等。 本发明涉及一种沸石，其骨架密度为10T / nm 3至16T / nm 3，碳含量为1％至6％（重量），满足下列（1）或（2）：（ 1）沸石是氮含量为0.5重量％至12重量％的铝磷酸盐，其中铝可部分被Me取代; （2）沸石是硅铝磷酸盐，其中铝可以部分地被Me替代，并且当燃烧到低于0.3重量％的碳含量时，在燃烧之前保留硅铝磷酸盐所具有的骨架结构：（如果Me 在上述（1）和（2）中，是选自元素周期表第2A，7A，8，1B和2B族元素中的至少一种元素）。

公开(公告)号：US20120020875A1

公开(公告)日：2012-01-26

申请号：US13188647

申请日：2011-07-22

申请人： Takeshi MATSUO ,  Takahiko Takewaki ,  Daisuke Nishioka ,  Kazunori Oshima ,  Haijun Chen ,  Hiroyuki Kakiuchi

发明人： Takeshi MATSUO ,  Takahiko Takewaki ,  Daisuke Nishioka ,  Kazunori Oshima ,  Haijun Chen ,  Hiroyuki Kakiuchi

IPC分类号： B01D53/94 ,  B01J29/85 ,  C01B39/54 ,  B82Y30/00

CPC分类号： B01J29/85 ,  B01D53/9418 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/65 ,  B01D2255/707 ,  B01D2255/9202 ,  B01D2258/012 ,  B01J23/72 ,  B01J29/83 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0009 ,  B01J37/0045 ,  B01J2229/20 ,  F01N2510/063

摘要： The object is to provide an exhaust gas reduction catalyst that exhibit high nitrogen oxide reduction performance, and to provide a simple and efficient method for producing the catalyst, in which the amount of the waste liquid is reduced, further, an object of the invention is to provide a zeolite-containing catalyst for reducing nitrogen oxides, which does not use an expensive noble metal or the like and which has high nitrogen oxide reduction performance. The present invention relates to a catalyst for reducing nitrogen oxides, which comprises: zeolite at least containing an aluminium atom and a phosphorus atom in the framework thereof; and a metal supported on the zeolite, wherein a coefficient of variation of intensity of the metal is at least 20%, when performing an elemental mapping of the metal in the catalyst with an electron probe microanalyzer, and, a catalyst for reducing nitrogen oxides, which comprises the zeolite containing at least a silicon atom, a phosphorus atom and an aluminium atom, and having an adsorption retention rate of at least 80% in a water vapor cyclic adsorption/desorption test at 90° C.

摘要翻译： 本发明的目的是提供一种具有高氮氧化物还原性能的废气还原催化剂，并且提供一种制备催化剂的简单有效的方法，其中废液的量减少，此外，本发明的目的是 以提供不使用昂贵的贵金属等并且具有高氮氧化物还原性能的还原氮氧化物的含沸石催化剂。 本发明涉及一种用于还原氮氧化物的催化剂，其包括：在其骨架中至少含有铝原子和磷原子的沸石; 和负载在沸石上的金属，其中当用电子探针显微分析仪进行催化剂中金属的元素映射时，金属的强度变化系数为至少20％，还原氮氧化物的催化剂， 其包含至少含有硅原子，磷原子和铝原子的沸石，并且在90℃的水蒸汽循环吸附/解吸试验中具有至少80％的吸附保持率。

公开(公告)号：US20090025403A1

公开(公告)日：2009-01-29

申请号：US12243278

申请日：2008-10-01

申请人： Hiroyuki Kakiuchi ,  Takahiko Takewaki ,  Masaru Fujii ,  Masanori Yamazaki ,  Hideaki Takumi ,  Hiromu Watanabe ,  Kouji Inagaki ,  Atsushi Kosaka ,  Seiji Inoue ,  Satoshi Inoue

发明人： Hiroyuki Kakiuchi ,  Takahiko Takewaki ,  Masaru Fujii ,  Masanori Yamazaki ,  Hideaki Takumi ,  Hiromu Watanabe ,  Kouji Inagaki ,  Atsushi Kosaka ,  Seiji Inoue ,  Satoshi Inoue

IPC分类号： F25B15/00 ,  F25B13/00

CPC分类号： F25B30/04 ,  B01J20/0292 ,  B01J20/18 ,  B01J20/28011 ,  F25B17/083

摘要： An adsorption heat pump is provided in which water vapor can be efficiently adsorbed and desorbed using a heat source having a lower temperature than ones heretofore in use because the pump employs an adsorbent which has a large difference in water adsorption amount in adsorption/desorption and can be regenerated (release the adsorbate) at a low temperature.The invention provides an adsorption heat pump which comprises an adsorbate, an adsorption/desorption part having an adsorbent for adsorbate adsorption/desorption, a vaporization part for adsorbate vaporization which has been connected to the adsorption/desorption part, and a condensation part for adsorbate condensation which has been connected to the adsorption/desorption part, wherein the adsorbent, when examined at 25° C., gives a water vapor adsorption isotherm which, in the relative vapor pressure range of from 0.05 to 0.30, has a relative vapor pressure region in which a change in relative vapor pressure of 0.15 results in a change in water adsorption amount of 0.18 g/g or larger.

摘要翻译： 提供了一种吸附热泵，其中使用具有比以前使用的温度低的热源可以有效地吸附和解吸水蒸汽，因为泵采用吸附/解吸中的吸水量差异大的吸附剂，并且可以 在低温下再生（释放被吸附物质）。 本发明提供了一种吸附热泵，其包括被吸附物，吸附/解吸部分，其具有用于吸附/解吸附的吸附剂，吸附/解吸部分连接的用于吸附汽化的汽化部分和用于吸附冷凝的冷凝部分 其与吸附/解吸部分连接，其中当在25℃下检查时，吸附剂得到水蒸气吸附等温线，其在相对蒸气压范围为0.05至0.30的相对蒸汽压力范围内为 相对蒸气压的变化为0.15，导致吸水量的变化为0.18g / g以上。

公开(公告)号：US07422993B2

公开(公告)日：2008-09-09

申请号：US11235704

申请日：2005-09-27

申请人： Takahiko Takewaki ,  Masanori Yamazaki ,  Hiromu Watanabe ,  Hiroyuki Kakiuchi ,  Eri Kanamori ,  Shigeru Terada ,  Miki Iwade

发明人： Takahiko Takewaki ,  Masanori Yamazaki ,  Hiromu Watanabe ,  Hiroyuki Kakiuchi ,  Eri Kanamori ,  Shigeru Terada ,  Miki Iwade

IPC分类号： F25B17/08 ,  B01J20/08 ,  B01D53/28

CPC分类号： F25B30/04 ,  B01D53/28 ,  B01J20/08 ,  B01J20/18 ,  C09K5/047 ,  F24F2203/1036 ,  F25B17/08

摘要： The present invention provides an adsorbent for adsorption heat pump and humidity-control air conditioner, which is capable of adsorbing an adsorbate therein and desorbing the adsorbate therefrom in a narrow relative vapor pressure range, and can be regenerated (desorption) at a low temperature. Also, the present invention provides an adsorption heat pump and humidity-control air conditioner using the adsorbent which can be effectively operated even by a low-temperature heat source, as well as methods of operating the adsorption heat pump and humidity-control air conditioner by effectively utilizing low-temperature exhaust heat. The absorbent of the present invention comprises zeolite containing (i) aluminum, (ii) phosphorus and (iii) iron and/or gallium in a skeletal structure thereof, which is substantially free from change in structure upon subjecting the adsorbent to adsorption and desorption of water vapor.

摘要翻译： 本发明提供一种吸附热泵和调湿空调器的吸附剂，其能够吸附被吸附物质并在较窄的相对蒸汽压力范围内将其吸附物解吸，并可在低温下再生（解吸）。 此外，本发明还提供一种使用能够通过低温热源有效运行的吸附剂的吸附热泵和调湿空调，以及通过以下方法操作吸附热泵和调湿空调器 有效利用低温余热。 本发明的吸收剂包含沸石，其含有（i）铝，（ii）磷和（iii）其骨架结构中的铁和/或镓，其在吸附和吸附时基本上没有结构变化 水蒸气。

公开(公告)号：US20060245994A1

公开(公告)日：2006-11-02

申请号：US11311562

申请日：2005-12-20

申请人： Hiromu Watanabe ,  Takahiko Takewaki ,  Masanori Yamazaki ,  Hiroyuki Kakiuchi ,  Kouji Inagaki ,  Atsushi Kosaka ,  Norikazu Hosokawa

发明人： Hiromu Watanabe ,  Takahiko Takewaki ,  Masanori Yamazaki ,  Hiroyuki Kakiuchi ,  Kouji Inagaki ,  Atsushi Kosaka ,  Norikazu Hosokawa

IPC分类号： B01J27/00 ,  B01J27/182 ,  C01B15/16 ,  C01B25/26 ,  C01B37/04 ,  C01B37/08

CPC分类号： B82Y30/00 ,  B01J20/0292 ,  B01J20/18 ,  B82Y10/00 ,  C01B37/04 ,  C01B37/06 ,  C01B37/08 ,  C01B39/54 ,  F25B17/08 ,  Y02P20/129 ,  Y10S423/30

摘要： Subjects for the invention are to provide a zeolite reduced in performance deterioration in repetitions of use or during long-term use and a process for producing the same and to provide an adsorbent comprising the zeolite and a heat utilization system or the like employing the adsorbent. The invention relates to a zeolite which has a framework density of from 10 T/nm3 to 16 T/nm3 and a carbon content of from 1% by weight to 6% by weight and satisfies the following (1) or (2): (1) the zeolite is an aluminophosphate which has a nitrogen content of from 0.5% by weight to 12% by weight and in which the aluminum may be partly replaced by Me; (2) the zeolite is a silicoaluminophosphate in which the aluminum may be partly replaced by Me and which, when burned to a carbon content lower than 0.3% by weight, retains the framework structure possessed by the silicoaluminophosphate before the burning: (provided that Me in (1) and (2) above is at least one element selected from the elements in Groups 2A, 7A, 8, 1B, and 2B of the periodic table).

摘要翻译： 本发明的目的是提供在使用重复或长期使用中降低性能劣化的沸石及其制备方法，并提供使用该吸附剂的沸石的吸附剂和热利用系统等。 本发明涉及一种沸石，其骨架密度为10T / nm 3至16T / nm 3，碳含量为1％至6％ 重量百分比，满足下列（1）或（2）：（1）沸石是氮含量为0.5重量％至12重量％的铝磷酸盐，其中铝可部分被Me取代 ; （2）沸石是硅铝磷酸盐，其中铝可以部分地被Me替代，并且当燃烧到低于0.3重量％的碳含量时，在燃烧之前保留硅铝磷酸盐所具有的骨架结构：（如果Me 在上述（1）和（2）中，是选自元素周期表第2A，7A，8，1B和2B族元素中的至少一种元素）。